含腈废水的生物一级处理工艺

采用好氧活性污泥法、悬浮载体膨胀床及厌氧生物反应器分别对含腈废水进行一级处理。实验结果表明,由于含腈废水的CN -毒性和难降解有机物含量高,好氧活性污泥法不适合处理含腈废水。随着活性污泥反应器运行时间的延长,污泥逐渐失去活性,大量微生物死亡。悬浮载体膨胀床处理含腈废水的效果较差,污染物去除率低于15%。厌氧生物反应器适于用作含腈废水的一级处理,污染物去除率可达到35%以上,而且可以改善水质,提高含腈废水的可生化性,有利于后续的生物处理工艺对含腈废水的深度处理。     

Performance of a fungal biofilter treating gas-phase solvent mixtures during intermittent loading

Biological treatment processes used to remove and degrade volatile organic compounds (VOCs) from contaminated gases emitted by industrial operations or waste treatment processes are almost always subjected to transient loading conditions because of the inherently unsteady-state nature of contaminant generating processes. In the study presented here, a laboratory-scale biofilter populated by a mixed culture of fungi was used to study the transient response to various periods of no contaminant loading in a system treating a model waste gas stream containing a mixture of commonly used solvents. The biofilter, packed with cubed polyurethane foam media and operated with an empty bed residence time of 15s, was supplied with a four-component mixture of n-butyl acetate, methyl ethyl ketone, methyl propyl ketone, and toluene at target influent concentrations of 124, 50.5, 174, and 44.6 mg/m(3), respectively. This corresponds to a total VOC loading rate of 94.3g/(m(3)h). Biofilter performance was evaluated over a 94-day period for three loading conditions intended to simulate processes generating contaminated gases only during daytime operation, daytime operation with weekend shutdown periods, and with long term (9-day) shutdown. Results indicate that fungal biofilters can be an effective alternative to conventional abatement technologies for treating solvent contaminated off-gases even under discontinuous loading conditions.     

Impact of process design on greenhouse gas (GHG) generation by wastewater treatment plants

The overall on-site and off-site greenhouse gas emissions by wastewater treatment plants (WWTPs) of food processing industry were estimated by using an elaborate mathematical model. Three different types of treatment processes including aerobic, anaerobic and hybrid anaerobic/aerobic processes were examined in this study. The overall on-site emissions were 1952, 1992, and 2435 kg CO₂e/d while the off-site emissions were 1313, 4631, and 5205 kg CO₂e/d for the aerobic, anaerobic and hybrid treatment systems, respectively, when treating a wastewater at 2000 kg BOD/d. The on-site biological processes made the highest contribution to GHG emissions in the aerobic treatment system while the highest emissions in anaerobic and hybrid treatment systems were obtained by off-site GHG emissions, mainly due to on-site material usage. Biogas recovery and reuse as fuel cover the total energy needs of the treatment plants for aeration, heating and electricity for all three types of operations, and considerably reduce GHG emissions by 512, 673, and 988 kg CO₂e/d from a total of 3265, 6625, and 7640 kg CO₂e/d for aerobic, anaerobic, and hybrid treatment systems, respectively. Considering the off-site GHG emissions, aerobic treatment is the least GHG producing type of treatment contrary to what has been reported in the literature.     

25 years of the AMTREAT® process treating high‐strength ammonia liquors

Over the last 30 years, a number of biological treatment processes have emerged for treating high‐strength ammonia liquors arising from the dewatering of anaerobic digestate. The AMTREAT® process was the first process to become established and recognised as a viable and reliable process to treat these high‐strength ammonia liquors. The process is a high‐rate activated sludge plant supplied by ACWA Services Ltd. The first full‐scale plant was installed in 1995, treating centrate produced when dewatering anaerobically digested sludge. The process is a compact, high‐rate ammonia treatment system, which has a relatively small footprint compared to conventional activated sludge treatment processes. Originally designed to fully nitrify dewatering ammonia liquors by controlling the environmental conditions of the treatment reactor, the process has evolved first to include alkalinity recovery and subsequently to offer total nitrogen removal. This paper discusses the development of the AMTREAT® process from its initial development in 1992, to the modern day third generation plants which achieve typical achieve ammonia removal exceeding 99% and total nitrogen removal in excess of 80%.     

Landfill evolution and treatability assessment of high‐strength leachate from msw with high organic and moisture content

The generation of contaminated leachate remains an inevitable consequence of the practice of solid waste disposal in landfills. The collection and treatment of leachate have become common practice in order to prevent environmental pollution. Leachate treatment is highly dependent on the quality of leachate, which in turn is influenced by various factors including waste composition and operational procedures. This paper investigates the treatability of high‐strength leachate from pre‐sorted and baled municipal solid waste characterized by high organic and moisture content. For this purpose, waste disposal and leachate generation rates were monitored. Leachate samples were collected and analysed for selected indicators including BOD, COD, pH, and NH₄‐N and a pilot scale treatment plant with coagulation, precipitation and sequential batch biological reactors was constructed to evaluate the feasibility of leachate treatment. Concentration levels were related to biological activity within the landfill and the results indicated that (1) pre‐sorting and baling of the waste did not hinder waste stabilization; and (2) the high organic and moisture contents resulted in an extremely strong leachate, particularly at the onset of biodegradation processes, which can affect the leachate treatment facility. The effectiveness of the pilot plant in treating the leachate exceeded 90% using COD and NH₄‐N as indicators.     

CONSTRUCTED WETLANDS FOR MINEWATER TREATMENT: PERFORMANCE AND SUSTAINABILITY

Wetlands were constructed between 1995 and 1999 to treat discharges from abandoned coalmines in the Pelenna Valley, South Wales. This was one of the first and most comprehensive demonstrations of passive minewater treatment technology in Europe, incorporating aerobic and anaerobic cells, including 'reducing and alkalinity-producing systems. The wetlands were monitored to assess their performance and longevity and were found to remove 82-96% of the incoming iron, with no decline in treatment performance over the monitoring period to 2002. Oxidation was found to be the dominant iron-removal process, even in vertical-flow cells which were designed to utilise anaerobic processes. Factors limiting the longevity of iron-removal processes were identified. maintenance requirements were highlighted and life-span predictions were calculated for the systems. The wetlands were shown to be an effective and low maintenance (but not maintenance-free) method of treating net-acidic and net-alkaline minewater.     

Effectiveness of soil washing, nanofiltration and electrochemical treatment for the recovery of metal ions coming from a contaminated soil

This research was conducted to integrate soil washing, nanofiltration (NF) membranes and electrochemical treatment as feasible methods for the remediation of contaminated soils. For this investigation, two acidic leachates (pH=2) were prepared using HCl and H(2)SO(4)-NaCl as soil-washing agents. The results of the soil washing indicated that HCl and the combined H(2)SO(4)-NaCl were effective for the extraction of ions resulting from a contaminated soil. It was observed that both leachates presented similar chemical compositions. Following this procedure, the leachate solutions were pre-filtered by microfiltration, followed by NF using the Desal-5 (DK) membrane. The experiment results showed that NF membranes presented a high ion-retention rate for the two leachates. In general, better retentions were observed with the leachate prepared with HCl than H(2)SO(4)-NaCl. In order to treat the concentrate resulting from the NF treatment, it underwent an electrochemical procedure (electrochemical deposition) as an alternative method for safe disposal. The results showed a high reduction of toxic ions, such as Pb and Cu, from the solution. These three processes applied in conjunction not only indicated that the treatment of solutions heavily contaminated with inorganic pollutants resulting from contaminated soils were feasible but also suggested the possibility of treating different types of heavy industrial effluents.     

Anaerobic treatment of domestic wastewater in temperate climates: treatment plant modelling with economic considerations.

Although research suggests that anaerobic treatment of low-strength domestic wastewater is possible in temperate climates, to date, full-scale applications have only been pioneered in hot regions. However, burgeoning environmental legislation in developed countries is giving the impetus to develop anaerobic wastewater treatment systems due to potential economic and environmental benefits they hold over traditional aerobic techniques. In this paper a design rationale for low-temperature, low-strength (COD < 1,000 mgl(-1)), two-phase anaerobic wastewater treatment is developed through empirical modelling of data from published research, and from assumptions arising from a literature review. Model calculations are applied to typical domestic sewage characteristics at two different flow rates, based on population equivalents. Results indicate that soluble COD production in the model hydrolytic tank are similar to those achieved in pilot scale plants in the Netherlands. Model anaerobic reactor sludge characteristics are similar to those achieved in pilot and full-scale anaerobic reactors treating low-strength wastewaters. Indicative cost figures for a two-phase anaerobic treatment plant are given, but are incomplete without an assessment of the cost of post-treatment processes. Anaerobic treatment is likely to become more attractive in the future as new legislation relating to sludge disposal and renewable energy generation are introduced.     

Fate and removal of selected endocrine‐disrupting compounds in sewage using activated sludge treatment

The variation and fate of four endocrine‐disrupting compounds (EDCs) composed of 4‐n‐nonylphenol (4‐n‐NP), bisphenol A (BPA), 17β‐estradiol (E2) and 17α‐ethinylestradiol (EE2) were investigated along treatment units in a sewage treatment plant (STP), China with anaerobic, anoxic and aerobic activated sludge processes. The mean concentrations were 64.8 ng/L (E2), 115.3 ng/L (4‐n‐NP), 171.5 ng/L (EE2), and 920.7 ng/L (BPA) in the influents, and 22.8 ng/L (E2), 50.9 ng/L (4‐n‐NP), 49.9 ng/L (EE2), and 84.3 ng/L (BPA) in the effluents. The biological treatment was more effective in removing NP, BPA and E2 from the aqueous phase than the primary treatment, while the latter could effectively remove EE2. Their possible removal mechanisms during the biological treatment with activated sludge were further explored through spiked batch experiments under three oxygen‐supplying conditions (anaerobic, anoxic and aerobic). The batch experiments showed that 4‐n‐NP, E2 and BPA were removed from the aqueous phase through biodegradation. The combination of sludge sorption and biodegradation accounted for the removal of EE2. Anoxic activated sludge showed the most rapid degradation of 4‐n‐NP, while E2 could be removed most effectively by aerobic activated sludge, and sludge sorption had a remarkable effect on its removal within the initial 15 min of the experiments under three oxygen‐supplying conditions.     

Quantitative analysis of methanogenic community dynamics in three anaerobic batch digesters treating different wastewaters

Quantitative changes in methanogenic community structures, associated with performance data, were investigated in three anaerobic batch digesters treating synthetic glucose medium, whey permeate, and liquefied sewage sludge. All digesters were initially seeded with anaerobic sludge obtained from a local municipal wastewater treatment plant. Dynamics of methanogenic populations were monitored, at order and family levels, using real-time PCR based on the 16S rRNA gene. The molecular monitoring revealed that, in each digester, the quantitative structure of methanogenic community varied continuously over treatment time and the variation corresponded well to the changes in chemical profiles. Biphasic production of methane, associated with successive increases in aceticlastic (mainly Methanosarcinaceae) and hydrogenotrophic (mainly Methanomicrobiales) methanogenic groups, was observed in each digester. This corresponded to the diauxic utilization of acetate and longer-chain volatile fatty acids (C₃-C₆), mainly propionate. Additionally, the non-metric multidimensional scaling (NMDS) analysis of the quantification results demonstrated that the community shift patterns in three digesters were totally different from each other. Considering that the operating conditions in all trials were identical except substrates, the differences in quantitative shift profiles were suggested to be due to the different substrate compositions. This implied that the composition of wastewater could affect the evolution of quantitative methanogenic community structure in an anaerobic process. Overall, our results suggested that more attention to quantitative as well as qualitative approaches on microbial communities is needed for fundamental understanding of anaerobic processes, particularly under dynamic or transitional conditions.     

水解酸化—好氧接触氧化处理生活污水的试验研究

对实际生活污水进行了中试研究。研究表明;采用填料式水解酸化与好氧接触氧化联合工艺处理生活污水效果好,其COD、BOD_5、SS去除率分别高达87％,92％,90％,试验得出了最佳设计参数和合理可行的流程组合。     

Biological black water treatment combined with membrane separation

Separate treatment of black (toilet) water offers the possibility to recover energy and nutrients. In this study three combinations of biological treatment and membrane filtration were compared for their biological and membrane performance and nutrient conservation: a UASB followed by effluent membrane filtration, an anaerobic MBR and an aerobic MBR. Methane production in the anaerobic systems was lower than expected. Sludge production was highest in the aerobic MBR, followed by the anaerobic MBR and the UASB-membrane system. The level of nutrient conservation in the effluent was high in all three treatment systems, which is beneficial for their recovery from the effluent. Membrane treatment guaranteed an effluent which is free of suspended and colloidal matter. However, the concentration of soluble COD in the effluent still was relatively high and this may seriously hamper subsequent nutrient recovery by physical-chemical processes. The membrane filtration behaviour of the three systems was very different, and seemed to be dominated by the concentration of colloidals in the membrane feed. In general, membrane fouling was the lowest in the aerobic MBR, followed by the membranes used for UASB effluent filtration and the anaerobic MBR.     

重庆大溪沟粪便污水处理工程设计

通过对现有粪便污水处理工艺的分析比较，根据大溪沟粪便污水处理厂的设计原则，确定采用三级厌氧-好氧-SBR-化学除磷-活性炭吸附组合工艺。结合工程设计，介绍了处理系统组成、主要设计参数和主要建构筑物设计，并对工程投资和技术经济指标进行了分析。     

Sulfolane biodegradation potential in aquifer sediments at sour natural gas plant sites

Sulfolane is used in the treatment of sour natural gas. It is a highly water soluble compound that has been introduced into soils and groundwaters at a number of sour gas processing plant sites. Aquifer sediments from contaminated locations at three sites in western Canada were assessed for microbial activity and their ability to degrade sulfolane under aerobic and five anaerobic (nitrate-, Mn(IV)-, Fe(III)-, sulfate- and CO₂-reducing) conditions. The microcosms were supplemented with 200 mg/L sulfolane and adequate supplies of N, P, and the appropriate terminal electron acceptor. Microcosms containing contaminated aquifer sediments from each of the three sites were able to degrade sulfolane aerobically at 8°C and 28°C, and the biodegradation followed zero-order kinetics. The lag times before the onset of sulfolane biodegradation were shorter when sulfolane-contaminated sediments were used as inocula than when uncontaminated soils were used. No anaerobic sulfolane biodegradation was observed at 28°C, nor was sulfolane biodegradation observed at 8°C under Fe(III)-, sulfate- and CO₂-reducing conditions. At 8°C, anaerobic degradation of sulfolane coupled to Mn(IV) reduction was observed in microcosms from two sites, and degradation coupled to nitrate reduction was seen in a microcosm from one of the contaminated sites.     

Monoaromatics removal from polluted water through bioreactors-a review

Water contaminated by oil products is becoming a major problem in water supplies as these organic compounds cause hazards for human health. Different types of aerobic and anaerobic bioreactors have been widely used for water cleanup from organic pollutants such as petroleum hydrocarbons. Many studies report that aerobic biofilm processes are a very efficient method for monoaromatic hydrocarbons removal from contaminated water as they are able to reduce up to 99% of the pollutants from water, but generally these works do not discuss possible pollutant loss through gas stripping. On the other hand, some research is related to the ability of anaerobic bioreactors for monoaromatics treatment and results have shown that anaerobic immobilized reactors are able to remove monoaromatic compounds from water with maximal efficiencies between 95-99%. But here again, no data are found about the amount of volatile organic compounds that can be found in the biogas. Also, the data generated when a solid biomass support (activated carbon, polyurethane, etc.) is present in the medium do not take care about possible solute sorption phenomena. This paper reviews various properties of monoaromatic compounds including benzene, toluene, ethylbenzene and mixture of xylenes. The sources of pollutants, various analytical methods suitable for identification and quantitative measurement of monoaromatics, and knowledge gained on the true removal rates by aerobic and anaerobic bioreactors are reviewed and discussed in this study.     

Pilot testing of manganese oxidation in a high-rate sedimentation process for the reprovisioning of the Sha Tin water treatment works, Hong Kong Special Administrative Region

The Sha Tin water treatment works (STWTW), Hong Kong Special Adminstrative Region, was commissioned in 1964 with an initial treatment capacity of 364 million litres per day (MLD). Since then it has undergone three stages of expansion to reach the current nominal capacity of 1227 MLD. The plant is in need of an in situ reprovisioning. The challenge is to complete the reprovisioning while maintaining a minimum output of 900 MLD, with any shutdown to be limited to 8 h generally. With the site already fully utilised, the key to success is to first replace the conventional low‐rate sedimentation process with high‐rate robust processes to free up the much needed space. Among other requirements, the chosen process must also be capable of treating water with variable turbidity and removing spikes of manganese effectively. The project team conducted a 4‐month pilot testing programme with an Actiflo^® high‐rate pilot plant and the key results are described.     

The effect of polymer addition on granulation in an anaerobic baffled reactor (ABR). Part II: compartmentalization of bacterial populations

The microbial ecology of wastewater treatment plants remains one of the least understood aspects in both aerobic and anaerobic systems, despite the fact that both processes are ultimately dependent on an active biomass for operational efficiency. Ultimately, future developments in anaerobic treatment processes will require a much greater understanding of the fundamental relationships between bacterial populations within the biomass if optimum process efficiency is to be fully realised. This study assesses the influence of polymer addition on granule formation within an ABR and compares the ecology of the biomass in each compartment of two ABRs treating ice-cream wastewater. To our knowledge, this is the first reported characterisation of the microbiology of acidogenic and methanogenic bacteria in the individual compartments of an ABR. The polymer-amended reactor contained sludge that had a greater density of anaerobic bacteria and larger and denser granules than the control reactor, indicating that polymer addition possibly contributed to the retention of active biomass within the ABR. The average fraction of autofluorescent methanogens was lower, with 1.5% being in the initial compartments of the ABRs, compared to the last compartment which had 15%, showing that each compartment of an ABR had a unique microbial composition. Partial spatial separation of anaerobic bacteria appeared to have taken place with acidogenic bacteria predominating in the initial compartments and methanogenic bacteria predominating in the final compartments. Scanning electron micrographs have revealed that the dominant bacteria in the initial compartments of the ABR (Compartments 1 and 2) were those which could consume H2/CO2 and formate as substrate, i.e. Methanobrevibacter, Methanococcus, with populations shifting to acetate utilisers, i.e. Methanosaeta, Methanosarcina, in the final compartments (Compartments 3 and 4). In addition, there appeared to be a stratified structure to the bacterial genera present within the granules.     

Evaluation of kinetic constants for anaerobic fixed film fixed bed reactors treating tannery wastewater

An approach has been made to evaluate the kinetic constants for a two stage anaerobic fixed film fixed bed reactor system treating tannery wastewater. The research reported herein is concerned with the bench scale performance evaluation of the reactor system treating the wastewater and application of the data to various models to evaluate the kinetic constants for substrate bio‐oxidation, biomass growth and biogas yield.     

Process selection for sanitation systems and wastewater treatment in refugee camps during disaster-relief situations

Disasters and emergency situations can disrupt the provision of clean water and hygienic sanitation, which are crucial for maintaining public health. Excreta disposal in emergencies has often been a low priority and this has led to the provision of unsuitable on‐site sanitation systems in urban areas. A decision algorithm for the selection of adequate excreta‐disposal solutions suitable for different disaster‐relief scenarios is presented. The special requirements of a wastewater treatment system for deployment during an emergency are discussed and a semi‐centralised system is recommended to serve 5000 refugees under a range of assumed loading conditions. Twenty‐three aerobic, anaerobic and natural systems are considered for secondary treatment and a process‐selection matrix is presented based around 16 evaluation criteria. A system layout is developed based around several sanitation facilities including sedimentation tanks connected to a centralised roughing trickling filter and an activated sludge unit, which provides optimal performance against the evaluation criteria. The system provides the required treatment performance in an easy‐to‐deploy, low‐cost compact installation.     

Estimation of greenhouse gas emissions from municipal wastewater treatment systems in India

Greenhouse gas (GHG) emissions generated from municipal wastewater treatment plants in India is estimated in this study. The emissions from the wastewater treatment process as well as from the electricity used during the treatment process are estimated by using the methodology of Intergovernmental Panel on Climate Change. The present treatment plants of capacity 15 997 million litres per day (MLD) contributes towards GHG emissions of 7.3 Mt of CO₂‐eq/year. The future GHG emissions would depend upon the treatment technology used for treating 34 109 MLD of untreated wastewater. The highest GHG emissions would occur if all new wastewater treatment plants are based on upflow anaerobic sludge blanket technology, 19.66 Mt CO₂‐eq/year and lowest if sequential batch reactor technology is adopted, 2.93 MtCO₂‐eq/year.