嵌入式高温共固化复合材料阻尼结构层间结合性能

使用正交实验法, 研制出满足嵌入式高温共固化复合材料阻尼结构制作工艺要求的黏弹性材料组分, 提出使用刷涂工艺代替压片工艺制备黏弹性材料薄膜, 并对两种工艺制备的碳纤维/双马来酰亚胺(T300/QY8911)复合材料试件进行层间剪切测试, 获得了薄膜厚度与层间最大剪切应力的变化关系, 实验数据表明: 刷涂工艺能提高嵌入式高温共固化复合材料阻尼结构层间结合性能10%以上, 而且阻尼层越薄, 提高幅度越大; 失效表面证明: 刷涂工艺所制得试件能在阻尼薄膜与复合材料界面间形成互穿网络结构。     

嵌入式高温共固化复合材料阻尼结构层间结合性能

使用正交实验法,研制出满足嵌入式高温共固化复合材料阻尼结构制作工艺要求的黏弹性材料组分,提出使用刷涂工艺代替压片工艺制备黏弹性材料薄膜,并对两种工艺制备的碳纤维/双马来酰亚胺(T300/QY8911)复合材料试件进行层间剪切测试,获得了薄膜厚度与层间最大剪切应力的变化关系,实验数据表明:刷涂工艺能提高嵌入式高温共固化复合材料阻尼结构层间结合性能10％以上,而且阻尼层越薄,提高幅度越大;失效表面证明:刷涂工艺所制得试件能在阻尼薄膜与复合材料界面间形成互穿网络结构.     

嵌入式高温共固化复合材料阻尼结构动力学性能实验研究

提出一种新的刷涂工艺制作嵌入式高温共固化阻尼薄膜，直接将粘弹性材料溶于易挥发的有机溶剂中，刷涂在复合材料预浸料表面，然后按照T300/QY8911复合材料预浸料固化工艺曲线将其制成嵌入式高温共固化复合材料试件，并对刷涂工艺和压片工艺制作的嵌入式高温共固化复合材料试件进行模态分析实验，获得了这两种方法制备粘弹性阻尼薄膜厚度与低阶模态参数的变化关系，结果证明了刷涂工艺所制得试件具有较高阻尼性能，为轻质大阻尼复合材料构件的设计理论和制作工艺的进一步研究奠定了坚实的基础。     

湿热循环对CCF300/QY8911复合材料界面性能的影响

通过对CCF300/QY8911复合材料试样进行循环吸湿-脱湿处理,绘制吸湿和脱湿曲线并用Fick第二定律进行拟合,采用层间剪切强度(ILSS)表征不同湿热条件对纤维/树脂界面性能的影响,再通过SEM观察试样剖面和侧面的微观形貌。结果表明:CCF300/QY8911复合材料的吸湿和脱湿行为符合Fick第二定律,试样水浸(水温71℃)14天后达到饱和吸湿率;水对CCF300/QY8911复合材料纤维/树脂界面的破坏分为可逆和不可逆,脱湿处理会消除可逆破坏,使干态ILSS有所回复;湿热循环次数增加会进一步引起纤维/树脂界面产生不可逆破坏,使CCF300/QY8911复合材料ILSS降低,但吸湿是引起这种复合材料ILSS性能下降的主要因素。     

复合材料可靠性设计的小子样系数法

对试验数据进行统计分析后,找到了T300/QY8911,T300/HD03和T300/QY8911-Ⅱ等几种常用复合材料强度性能的最大标准差,并发现:0°铺层或90°铺层的复合材料单层板强度性能分散性(变异系数或方差)要比多向铺层板大,这一性质对大多数复合材料都成立。通过对T300/QY8911,T300/HD03和T300/QY8911-Ⅱ等复合材料强度性能的分布检验,发现:复合材料强度性能遵循对数正态分布。提出复合材料强度性能可靠性设计的高精度小子样系数方法,与传统方法等进行了对比计算,发现:本文方法计算结果稳定,计算精度高,可以获得比其他方法更大的数值结果,使复合材料得到更加充分的利用,并节省试件。      

湿热、紫外环境对T300/QY8911复合材料孔板静力性能的影响

采用试验方法研究了湿热、紫外环境对T300 碳纤维/QY8911双马树脂复合材料静力拉伸和压缩性能的影响。针对 T300/QY8911复合材料层板的中心开孔试件,进行了常温干态、湿热环境、紫外辐射以及湿热和紫外共同作用下的静力拉伸和压缩试验。吸湿试验的结果表明,T300/QY8911复合材料试件的平衡吸湿率在0.6%左右。静力试验的结果表明：孔板的拉伸强度受到环境的影响较小;湿热会降低由基体性能主导的压缩强度、刚度等复合材料性能,吸湿后75℃ 和105℃ 环境下试验件压缩强度分别下降6.8%和20.3%;而紫外使复合材料孔板的压缩强度有所升高,300 MJ/m2 以上的紫外辐射量使试验件的压缩强度提高了10%左右,显示其对复合材料的性能有着更为复杂的影响规律,并且可能与湿热的影响存在交互作用。     

高温老化后嵌入式共固化阻尼复合材料结构的阻尼性能

在综合研究双马来酰亚胺树脂基碳纤维预浸料(T700/QY260)和AFLAS氟橡胶的力学性能、阻尼性能和耐高温性能基础上,通过试验的方法提出一种能够耐260℃超高温度的黏弹性阻尼材料。利用四氢呋喃溶液将该黏弹性阻尼材料制成阻尼胶浆溶液,结合双面刷涂和热压罐工艺制备出嵌入式共固化阻尼复合材料试件,利用自由振动衰减实验方法对该试件分别做常温、230℃*96 H、260℃*96 H老化实验处理后相对阻尼系数的测定,得到不同温度老化处理后的嵌入式共固化阻尼复合材料的相对阻尼系数与阻尼材料厚度的关系,证明了所制备的嵌入式共固化阻尼复合材料具有优异耐超高温性能和稳定的阻尼性能。     

上浆剂对碳纤维增强双马树脂基复合材料力学性能的影响

通过对包覆不同上浆剂的碳纤维增强双马树脂基复合材料在不同温度下的层间剪切强度、弯曲性能和三点弯曲试样破坏模式进行研究,探讨了上浆剂对碳纤维增强双马树脂基复合材料力学性能的影响。研究表明不同的国产上浆剂对CCF300/QY8911复合材料在高温环境时的层间剪切强度和弯曲强度有影响;室温下不同上浆剂的CCF300/QY8911复合材料的力学性能与T300/QY8911复合材料的相当,而高温下其力学性能的保持率低于T300/QY8911复合材料的。     

复合材料孔板疲劳寿命环境影响的试验研究

为研究环境因素对T300/QY8911疲劳性能的影响,开展了T300/QY8911含中心孔层压板疲劳试验.试验中分别采用无紫外无涂层试件、紫外无涂层试件、紫外有涂层试件测试其拉-拉疲劳寿命,并通过对试验结果的方差分析研究了有无涂层、紫外辐射及湿度等环境因素对T300/QY8911复合材料孔板拉-拉疲劳寿命影响的显著性.研究表明:无涂层、300MJ/m2紫外照射量时,湿度对试件疲劳寿命影响高度显著;干燥、无涂层时,有无紫外照射对试件疲劳寿命影响高度显著;湿润、600MJ/m2紫外照射量时,有无涂层对试件寿命影响显著.     

国产复合材料冲击损伤容限可靠性分析

论述了基于冲击威胁概念的复合材料结构冲击损伤容限可靠性分析方法。采用该方法对国产T300/5405和T300/QY8911复合材料层压板、加筋板以及国产T300S/9511、T800/9511和T300/9512层压板的冲击损伤容限可靠性进行了分析和评估。实例分析表明,由于所采用的方法考虑了冲击威胁分布,可以更好地发挥复合材料结构的冲击损伤容限性能。      

An Experimental Investigation into the Damage Mechanisms in Notched CCF300/QY8911 and T300/QY8911 Composites Subjected to Hygrothermal Environment Condition

An experimental study was carried out to determine the notched tension characteristics of CCF300 fiber reinforced composite and T300 fiber reinforced composite subjected to normal and hygrothermal environment conditions. First, tests to failure with residual strength were carried out and the damage progressions were carefully investigated. Scanning electron microscope (SEM) was then employed for fractographic investigations. It was found that the CCF300/QY8911 composite specimens with poor interfacial adhesion between fiber and matrix exhibited higher residual strength, while the T300/QY8911 composite specimens with well adhesion had shorter ultimate strain. Damage progression mechanisms in the two material systems were very different. The major damage mechanism of CCF300/QY8911 composites was delamination generally occurring at lower stresses, which allowed higher levels of damage formation and resulted in higher ultimate strength. When changing to hygrothermal environment condition, greater damage was observed and off axis plies were extensively pulled out from the adjacent plies. On the other hand, all of the T300/QY8911 composite specimens failed due to fiber fracture with less damage, leading to a lower residual strength regardless of the environmental conditions. Further examinations showed that the failure mode of CCF300/QY8911 composite was much more sensitive to the hygrothermal environment, for the micro-failure mode had changed from matrix failure and fiber breakage to fiber/matrix splitting and fiber bundle pullout.     

改性双马来酰亚胺树脂的研究及其初步应用

QY8911是经过改性的双马来酰亚胺树脂体系。它具有耐温高、韧性好、吸水率低和易于操作的特性。这种树脂体系可用于浸润碳纤维、凯芙拉和玻璃纤维,适用于溶剂法和热熔法制备预浸料。QY8911具有良好的工艺性,其固化规范与177℃环氧树脂相仿,可于普通热压罐中固化成型。      

Effect of Moisture and Temperature on the Compressive Failure of CCF300/QY8911 Unidirectional Laminates

CCF300/BMI composites are relevant materials for supersonic aircraft due to their high specific properties. However in aeronautical applications, the composites are exposed to severe environmental conditions, and it is known that hot and humid environments can degrade some aspects of the material performance especially the compressive strength. In this paper, the effect of moisture and temperature on the compressive failure of unidirectional CCF300 carbon fiber reinforced bismaleimide(BMI) matrix composites were studied. Also scanning electron microscope (SEM) was employed for fractographic investigations. It is observed that the plastic deformations at the fiber/matrix and interlaminar interface as well as residual stresses lower the compressive strength of the material. The failure of specimens tested in hot and wet conditions always occurs as a result of out-of-plane microbuckling that is attributed to the reduction of matrix strength. In addition, the fiber microbuckling model, fiber kinking model and combined model were employed for the compressive strength prediction of the UD CCF300/QY8911 composites subjected to different environment conditions. The comparison was done between these models. Results show that the combined model is more suitable for the compressive strength prediction of CCF300/QY8911 composite systems when suffering severe environment conditions.     

用CVI工艺制备的低密度单向C/C复合材料的阻尼性能

用化学气相渗透工艺（ＣＶＩ）制备出几种不同密度及不同炭纤维类型增强的单向Ｃ／Ｃ复合材料。在国内自制多功能内耗仪上用扭摆法测试其阻尼性能。结果表明,低密度单向Ｃ／Ｃ复合材料的阻尼随密度的升高而降低。同种工艺条件,高模炭纤维Ｔ－５０增强的单向Ｃ／Ｃ复合材料的阻尼性能优于高强炭纤维Ｔ３００增强的单向Ｃ／Ｃ复合材料,且前者在８０￣２００℃范围内有一明显的内耗峰。纤维类型和界面微观结构是影响这类单向Ｃ／Ｃ复