Modeling of hydrogen dispersion from hydrogen fuel cell vehicles in an underground parking garage

Hydrogen is a promising energy carrier that will become competitive in the near future. The present study modeled hydrogen leaks and diffusion in an actual size underground parking garage with the numerical model validated by scale experimental data. The results show that the hydrogen concentration distributions are not uniform in the gas mixture layer along the ceiling and the initial front velocity of the gas mixture layer decays with horizontal distance from the leaking car. The vertical filling front velocity for times after 600 s remain constant in the near field but increases linearly with distance in the far field. The corner walls did not significantly affect the far-field concentration distributions and the ventilation layout with vents in the garage corners provided better hydrogen removal. These results can be used to predict the hydrogen concentration buildup in large confined spaces and to help design underground parking garage ventilation systems.     

Design layout of hydrogen research and development garage

Research and development programs toward fuel cells and other hydrogen technologies have increased significantly during the past two decades. These programs require appropriate facilities to undertake the research and development programs. This paper discusses the design layout of one such facility, the “Missouri S&T EcoCAR Hydrogen Vehicle Garage”, which can be used as a model while designing a hydrogen R&D garage. The Missouri S&T EcoCAR garage is a 12.2 m × 7.6 m garage situated at the Missouri University of Science and Technology (Missouri S&T) and serves as the headquarters for the Missouri S&T EcoCAR team. Within the garage, students will gain real-world, hands-on experience by transforming a standard production vehicle into a hydrogen Fuel Cell Plug-in Hybrid Electric Vehicle (FC-PHEV). The garage is classified as a Class 1 Division 2, Group B hazardous location and is equipped to safely test and integrate the vehicle prototype. Specifically, the design includes (i) a hydrogen gas detection system, (ii) hazardous location electrical service, heating, ventilation and air-conditioning, lighting, and compressed air systems, and (iii) emergency backup electric power system with alarms/monitors/security cameras for the hydrogen R&D facility. The garage will be connected to an external backup power supply unit which will be powered by a PEM fuel cell.     

Safety study of a hydrogen leak in a fuel cell vehicle using computational fluid dynamics

This paper analyzes safety aspects inside a Fuel Cell vehicle using Computational Fluid Dynamics (CFD) tools. The research considers an introduction of a leak of hydrogen inside the vehicle, and its dispersion for a set of typical ventilation conditions is analyzed. The leak of hydrogen has been modelled according to the properties of hydrogen and depending on the pressure difference between the hydrogen storage tank (200 bar) and the atmosphere. The parameters considered for the simulations are the flow rate of cabin ventilation air and hydrogen’s leak. The results obtained for the hydrogen molar concentration are investigated in different sections of the vehicle. Significant differences between front and rear areas are observed, with higher hydrogen concentrations near the rear ventilation vents. The volume of the vehicle within ignition risk (4–75% hydrogen concentration) is also investigated. Finally, different risk mitigation measures are also proposed.     

HySafe SBEP-V20: Numerical studies of release experiments inside a naturally ventilated residential garage

This work presents the results of the Standard Benchmark Exercise Problem (SBEP) V20 of Work Package 6 (WP6) of HySafe Network of Excellence (NoE), co-funded by the European Commission, in the frame of evaluating the quality and suitability of codes, models and user practices by comparative assessments of code results. The benchmark problem SBEP-V20 covers release scenarios that were experimentally investigated in the past using helium as a substitute to hydrogen. The aim of the experimental investigations was to determine the ventilation requirements for parking hydrogen fuelled vehicles in residential garages. Helium was released under the vehicle for 2 h with 7.200 l/h flow rate. The leak rate corresponded to a 20% drop of the peak power of a 50 kW fuel cell vehicle. Three double vent garage door geometries are considered in this numerical investigation. In each case the vents are located at the top and bottom of the garage door. The vents vary only in height. In the first case, the height of the vents is 0.063 m, in the second 0.241 m and in the third 0.495 m. Four HySafe partners participated in this benchmark. The following CFD packages with the respective models were applied to simulate the experiments: ADREA-HF using k–? model by partner NCSRD, FLACS using k–? model by partner DNV, FLUENT using k–? model by partner UPM and CFX using laminar and the low-Re number SST model by partner JRC. This study compares the results predicted by the partners to the experimental measurements at four sensor locations inside the garage with an attempt to assess and validate the performance of the different numerical approaches.     

An intercomparison of CFD models to predict lean and non-uniform hydrogen mixture explosions

The paper describes an exercise on comparison of Computational Fluid Dynamics (CFD) models to predict deflagrations of a lean uniform hydrogen–air mixture and a mixture with hydrogen concentration gradient. The exercise was conducted within the work-package “Standard Benchmark Exercise Problem” of the EC funded Network of Excellence “Safety of Hydrogen as an Energy Carrier”, which seeks to provide necessary quality in the area of applied hydrogen safety simulations. The experiments on hydrogen–air mixture deflagrations in a closed 1.5 m in diameter and 5.7 m high cylindrical vessel were chosen as a benchmark problem to validate CFD codes and combustion models used for prediction of hazards in safety engineering. Simulations of two particular experiments with approximately the same amount of hydrogen were conducted: deflagration of a uniform 12.8% vol. hydrogen mixture and deflagration of a non-uniform hydrogen mixture, corresponding to an average 12.6 % vol. hydrogen concentration (27% at the top of the vessel, 2.5% at the bottom of the vessel) with ignition at the top of the vessel in both cases. The comparison of the simulation results for pressure and flame dynamics against the experimental data is reported.     

Hydrogen combustion experiments in a vertical semi-confined channel

Experiments in an obstructed semi-confined vertical combustion channel with a height of 6 m (cross-section 0.4 × 0.4 m) inside a safety vessel of the hydrogen test center HYKA at the Karlsruhe Institute of Technology (KIT) are reported. In the work, homogeneous hydrogen-air-mixtures as well as mixtures with different well-defined H₂-concentration gradients were ignited either at the top or at the bottom end of the channel. The combustion characteristics were recorded using pressure sensors and sensors for the detection of the flame front that were distributed along the complete channel length. In the tests slow subsonic and fast sonic deflagrations as well as detonations were observed and the conditions for the flame acceleration (FA) to speed of sound and deflagration-to-detonation transition (DDT) are compared with the results of similar experiments performed earlier in a larger semi-confined horizontal channel.     

Numerical study of hydrogen dispersion in a fuel cell vehicle under the effect of ambient wind

In the rescue of hydrogen-fueled vehicle accidents, once accidental leakage occurs and hydrogen enters the cabin, the relatively closed environment of the vehicle is prone to hydrogen accumulation. Excessive hydrogen concentration inside the vehicle cabin may cause suffocation death of injured passengers and rescue crews, or explosion risk. Based on hydrogen fuel cell vehicle (HFCV) with hydrogen storage pressure 70 MPa, four different scenarios (i. with opened sunroof, ii. opened door windows, iii. opened sunroof and door windows and iv. opened sunroof, door windows and rear windshield) under the condition of accidental leakage were simulated using computational fluid dynamics (CFD) tools. The hydrogen concentration inside the vehicle and the distribution of flammable area (>4% hydrogen mole fraction) were analyzed, considering the effect of ambient wind. The results show that in the case of convection between interior and exterior of the vehicle via the sunroof, door windows or rear windshield, the distribution of hydrogen inside the vehicle is strongly affected by the ambient wind speed. In the least risk case, ambient wind can reduce the hydrogen mole fraction in the front of the vehicle to less than 4%, however the rear of the vehicle is always within flammable risk.     

Simulation of the efficiency of hydrogen recombiners as safety devices

Passive auto-catalytic recombiners (PARs) may be used in the future as safety devices inside confined areas for the removal of accidentally released hydrogen. In the presented study, it was investigated whether a PAR designed for hydrogen removal inside an NPP containment would principally work inside a typical surrounding of hydrogen or fuel cell applications. For this purpose, a hydrogen release scenario inside a garage – based on experiments performed by CEA in the GARAGE facility (France) – has been simulated with and without PAR installation. For modeling the operational behavior of the PAR, the in-house code REKO-DIREKT was implemented in the CFD code ANSYS-CFX. The study was performed in three steps: First, a helium release scenario was simulated and validated against experimental data. Second, helium was replaced by hydrogen in the simulation. This step served as a reference case for the unmitigated scenario. Finally, the numerical garage setup was enhanced with a commercial PAR model. The study shows that the PAR works efficiently by removing hydrogen and promoting mixing inside the garage. The hot exhaust plume promotes the formation of a thermal stratification that pushes the initial hydrogen rich gas downwards and in direction of the PAR inlet. The paper describes the code implementation and simulation results.     

Large scale passive ventilation trials of hydrogen

This paper describes the investigation of a passive ventilation solution to manage the hydrogen concentration within a large ullage space (0.9–3 m deep) above a liquid (free surface area of ∼40 m²) containing a hydrogen source. The aim of the ventilation is to maintain the hydrogen concentration within the ullage space below 25% of the Lower Explosive Limit (LEL). The programme of tests involved examination of the ventilation performance in terms of sensitivity to chimney position, hydrogen release rate, hydrogen release point, ullage height and chimney diameter.The tests carried out lasted many hours, and the hydrogen concentration was monitored at a number of points within the ullage space. Pairs of ventilation chimneys with associated instrumentation systems were used to control and monitor the hydrogen concentration within the ullage space.This paper describes the approach to the testing, the results obtained and their analysis.     

Safety assessment of unignited hydrogen discharge from onboard storage in garages with low levels of natural ventilation

This study is driven by the need to understand requirements to safe blow-down of hydrogen onboard storage tanks through a pressure relief device (PRD) inside a garage-like enclosure with low natural ventilation. Current composite tanks for high pressure hydrogen storage have been shown to rupture in 3.5–6.5 min in fire conditions. As a result a large PRD venting area is currently used to release hydrogen from the tank before its catastrophic failure. However, even if unignited, the release of hydrogen from such PRDs has been shown in our previous studies to result in unacceptable overpressures within the garage capable of causing major damage and possible collapse of the structure. Thus, to prevent collapse of the garage in the case of a malfunction of the PRD and an unignited hydrogen release there is a clear need to increase blow-down time by reducing PRD venting area. Calculations of PRD diameter to safely blow-down storage tanks with inventories of 1, 5 and 13 kg hydrogen are considered here for a range of garage volumes and natural ventilation expressed in air changes per hour (ACH). The phenomenological model is used to examine the pressure dynamics within a garage with low natural ventilation down to the known minimum of 0.03 ACH. Thus, with moderate hydrogen flow rate from the PRD and small vents providing ventilation of the enclosure there will be only outflow from the garage without any air intake from outside. The PRD diameter, which ensures that the pressure in the garage does not exceed a value of 20 kPa (accepted in this study as a safe overpressure for civil structures) was calculated for varying garage volumes and natural ventilation (ACH). The results are presented in the form of simple to use engineering nomograms. The conclusion is drawn that PRDs currently available for hydrogen-powered vehicles should be redesigned along with either a change of requirements for the fire resistance rating or innovative design of the onboard storage system as hydrogen-powered vehicles are intended for garage parking. Further research is needed to develop safety strategies and engineering solutions to tackle the problem of fire resistance of onboard storage tanks and requirements to PRD performance. Regulation, codes and standards in the field should address this issue.     

Effectiveness of a blower in reducing the hazard of hydrogen leaking from a hydrogen-fueled vehicle

To handle a hydrogen fuel cell vehicle (HFCV) safely after its involvement in an accident, it is necessary to provide appropriate emergency response information to the first responder. In the present study a forced wind of 10 m/s or faster with and without a duct was applied to a vehicle leaking hydrogen gas at a rate of 2000 NL/min. Then, hydrogen concentrations were measured around the vehicle and an ignition test was conducted to evaluate the effectiveness of forced winds and the safety of emergency response under forced wind conditions. The results: 1) Forced winds of 10 m/s or faster caused the hydrogen concentrations in the vicinity of the vehicle to decline to less than the lower flammability limit, and the hydrogen gas in the various sections of the vehicles were so diluted that even if ignition occurred the blast-wave pressure was moderate. 2) When the first responder had located the hydrogen leakage point in the vehicle, it was possible to lower the hydrogen concentrations around the vehicle by aiming the wind duct towards the leakage point and blowing winds at 10 m/s from the duct exit.     

Safety studies on high-pressure hydrogen vehicle refuelling stations: Releases into a simulated high-pressure dispensing area

If the general public is to use hydrogen as a vehicle fuel, customers must be able to handle hydrogen with the same degree of confidence, and with comparable risk, as conventional liquid and gaseous fuels. The hazards associated with jet releases from leaks in a vehicle-refuelling environment must be considered if hydrogen is stored and used as a high-pressure gas since a jet release in a confined or congested area can create an explosion hazard. As there was insufficient knowledge of the explosion hazards, a study was initiated to gain a better understanding of the potential explosion hazard consequences associated with high-pressure leaks from hydrogen vehicle refuelling systems. This paper describes the experiments with a dummy vehicle and dispenser units to represent refuelling station congestion. Experiments with ignition of premixed 5.4 m × 6.0 m × 2.5 m hydrogen–air clouds and hydrogen jet releases up to 40 MPa (400 bar) pressure are described. The results are discussed in terms of the conditions leading to the greatest overpressures and overall conclusions are made from these.     

Numerical study on the influence of different boundary conditions on the efficiency of hydrogen recombiners inside a car garage

Passive auto-catalytic recombiners (PARs) have the potential to be used in the future for the removal of accidentally released hydrogen inside confined areas. PARs could be operated both as stand-alone or backup safety devices, e.g. in case of active ventilation failure.Recently, computational fluid dynamics (CFD) simulations have been performed in order to demonstrate the principal performance of a PAR during a postulated hydrogen release inside a car garage. This fundamental study has now been extended towards a variation of several boundary conditions including PAR location, hydrogen release scenario, and active venting operation. The goal of this enhanced study is to investigate the sensitivity of the PAR operational behavior for changing boundary conditions, and to support the identification of a suitable PAR positioning strategy. For the simulation of PAR operation, the in-house code REKO-DIREKT has been implemented in the CFD code ANSYS-CFX 15.In a first step, the vertical position of the PAR and the thermal boundary conditions of the garage walls have been modified. In a subsequent step, different hydrogen release modes have been simulated, which result either in a hydrogen-rich layer underneath the ceiling or in a homogeneous hydrogen distribution inside the garage. Furthermore, the interaction of active venting and PAR operation has been investigated.As a result of this parameter study, the optimum PAR location was identified to be close underneath the garage ceiling. In case of active venting failure, the PAR efficiently reduces the flammable gas volume (hydrogen concentration > 4 vol.%) for both stratified and homogeneous distribution. However, the simulations indicate that the simultaneous operation of active venting and PAR may in some cases reduce the overall efficiency of hydrogen removal. Consequently, a well-matched arrangement of both safety systems is required in order to optimize the overall efficiency. The presented CFD-based approach is an appropriate tool to support the assessment of the efficiency of PAR application for plant design and safety considerations with regard to the use of hydrogen in confined areas.     

Experimental study of hydrogen explosion in repeated pipe congestion – Part 1: Effects of increase in congestion

Experimental studies were conducted with the objective of gaining a better understanding of the potential explosion hazard consequences that could be associated with a high-pressure leak from a hydrogen vehicle refuelling system. The first part of the study, described in this paper, was a series of experiments designed to establish hydrogen–air explosion overpressures in a well-defined and well understood 3 m × 3 m x 2 m (high) repeated pipe congestion. The results of the experiments are discussed in terms of the conditions leading to the greatest overpressures. It is concluded from the study that stoichiometric ratio in the range of 1.2–1.3 gives highest overpressure. Moreover, it was observed that increasing the congestion from 4-gate to 9-gate congestion leads to significant increase in the overpressure. In addition, it was concluded that, explosion in a hydrogen-air mixture is significantly more severe than the explosion in an ethane-air, methane-air or propane-air mixtures. This is attributed to higher laminar flame speed of hydrogen-air mixtures.     

Gas explosion field test with release of hydrogen from a high pressure reservoir into a channel

Field experiments of a high pressure release of hydrogen gas inside a 6 m long, 0.9 m wide, and 0.8 m high channel have been performed, to validate the Froude scaling and to obtain pressure and flame speed data in an inhomogeneous hydrogen–air cloud. Froude scaling with a length scale corresponding to the height of a 100% hydrogen layer in the channel was used to describe the flow of the hydrogen–air cloud in the channel. The estimated time of ignition based on the Froude scaling for release pressures of 100 bars and 150 bars agreed well with the experiments. At lower release pressures the estimated time was lower, which was most likely caused by dilution of the front of the hydrogen cloud. High speed video was used to record the flame speed. For the present experimental conditions it appeared that the deflagration taking place closer to the jet source determines the maximum explosion pressure.     

Comparative analysis on temperature characteristics of hydrogen-powered and traditional fossil-fueled vehicle fires in the tunnel under longitudinal ventilations

Vehicle fires in the tunnel are a great threat to the safe operation of the tunnel. Due to the rapid development of the hydrogen economy, the fire due to the hydrogen leakage could not be avoided and may bring great damage to the passengers and infrastructure. Due to the large difference between pool fires of traditional fossil-fueled and jet fires of hydrogen-powered vehicles, it is in doubt whether the existing longitudinal ventilation design could still be effective for the safety issue of hydrogen powered vehicles. To solve this problem, it is necessary to compare temperature characteristics of hydrogen-powered and traditional vehicle fires with and without longitudinal ventilations. In present work, we conducted a numerical investigation to discuss the different temperature distributions of traditional and hydrogen-fueled vehicle fires. Results indicate that the high temperature zone of the pool fire only exists above the ceiling of the vehicle. For hydrogen-powered vehicle fire, the high-speed hydrogen jet with the strong inertial force could push the hot smoke flows back to the ground. The ceiling temperature of hydrogen-powered vehicle fire is larger since hydrogen-powered vehicle has a larger heat release rate and the fire hazard of jet fires bring more danger compared with the pool fire. Although the temperature stratification is also obvious for the hydrogen-powered vehicle fire, the air temperature in the lower region could be heated and still high enough to bring a great damage to the passengers’ lives. This is quite different with the traditional pool fire. In addition, the critical ventilation velocity is also discussed. The theoretical equation could well predicted the critical ventilation velocity of traditional vehicle fires. For hydrogen-powered vehicle fires, the critical ventilation velocity could reach up to 6 m/s. The theoretical equation could not well predict the critical ventilation velocity of hydrogen-powered vehicle fires due to exist of hydrogen jet fires.     

Experimental analysis of plasma and heating effect on H2 permeation behavior through Pd–Cu40% membranes in 1mm gap length plate reactor

In this work, experimental analysis of hydrogen permeation behavior under heating only and plasma-heating effect were studied in 15  μm and 20  μm Pd–Cu40% membrane thicknesses. Apure hydrogen gas at feeding pressure of 100 kPa was injected in 1 mm gap length plate micro-channel reactor (PMCR). The permeated hydrogen flux through Pd–Cu40% membranes was measured under heating only experiment at PMCR heating temperature range of 423–573 K and hydrogen flow rates of 0.1–1 L/min. In the plasma-heating experiments, dielectric barrier discharge plasma (DBD) were used at the applied voltage ranges of 10–16 kV, PMCR heating temperatures 423–573 K and hydrogen flow rate 0.1 L/min. The hydrogen permeability was calculated according to the Fick's and Sievert's law equation. It was found that the hydrogen permeability of heating only experiments lower than that obtained from plasma-heating experiments for both Pd–Cu membrane thickness. Further, the hydrogen permeability of the plasma-heating experiments has shown anon-linearity effect which it was presented in the pre-exponential factor and the activation energy pattern. However, it was observed that the hydrogen permeability decreased while the DBD-plasma applied voltage was high, due to the hydrogen gas reverse reaction. A comparison between the hydrogen permeability and the permeation rate% of both experiments has been developed to investigate the dependence on the membrane thickness in both experiments. The analysis shows that the permeability of 15  μm membrane thickness was always higher than 20  μm membrane thickness results and the maximum hydrogen permeability was at PMCR heating temperature of 573 K.     

Natural and forced ventilation of buoyant gas released in a full-scale garage: Comparison of model predictions and experimental data

An increase in the number of hydrogen-fueled applications in the marketplace will require a better understanding of the potential for fires and explosion associated with the unintended release of hydrogen within a structure. Predicting the temporally evolving hydrogen concentration in a structure, with unknown release rates, leak sizes and leak locations is a challenging task. A simple analytical model was developed to predict the natural and forced mixing and dispersion of a buoyant gas released in a partially enclosed compartment with vents at multiple levels. The model is based on determining the instantaneous compartment over-pressure that drives the flow through the vents and assumes that the helium released under the automobile mixes fully with the surrounding air. Model predictions were compared with data from a series of experiments conducted to measure the volume fraction of a buoyant gas (at 8 different locations) released under an automobile placed in the center of a full-scale garage (6.8 m × 5.4 m × 2.4 m). Helium was used as a surrogate gas, for safety concerns. The rate of helium released under an automobile was scaled to represent 5 kg of hydrogen released over 4 h. CFD simulations were also performed to confirm the observed physical phenomena. Analytical model predictions for helium volume fraction compared favorably with measured experimental data for natural and forced ventilation. Parametric studies are presented to understand the effect of release rates, vent size and location on the predicted volume fraction in the garage. Results demonstrate the applicability of the model to effectively and rapidly reduce the flammable concentration of hydrogen in a compartment through forced ventilation.     

Analysis of acoustic pressure oscillation during vented deflagration and proposed model for the interaction with the flame front

Explosion relief panels or doors are often used in industrial buildings to reduce damages caused by a gas explosion. Decades of research produced a significant contribution to the understanding of the phenomena involved. Among the aspects that need further research, interactions between acoustic oscillations and the flame front is one of the most important. Interactions between the flame front and acoustic oscillations has raised technical problems in lots of combustion applications as well and has been studied theoretically and experimentally in such cases. Pressure oscillations have been observed in vented deflagrations and in certain cases they are responsible for the highest pressure peak generated during the event. At Scalbatraio laboratory of Pisa University a test facility (CVE) was built in order to investigate vented hydrogen deflagrations. This paper presents an overview of the results obtained during several experimental campaigns. The tests are analysed with the focus on the investigation of flame acoustic interaction phenomena. Qualitative and quantitative analysis is presented and the generated possible physical phenomena are investigated.     

CFD modeling and consequence analysis of an accidental hydrogen release in a large scale facility

In this study, the consequences of an accidental release of hydrogen within large scale, (>15,000 m³), facilities were modeled. To model the hydrogen release, an LES Navier–Stokes CFD solver, called fireFoam, was used to calculate the dispersion and mixing of hydrogen within a large scale facility. The performance of the CFD modeling technique was evaluated through a validation study using experimental results from a 1/6 scale hydrogen release from the literature and a grid sensitivity study. Using the model, a parametric study was performed varying release rates and enclosure sizes and examining the concentrations that develop. The hydrogen dispersion results were then used to calculate the corresponding pressure loads from hydrogen-air deflagrations in the facility.