碳酸盐掺加量对M型钙锶铁氧体磁性能的影响

对以永磁钙锶铁氧体预烧料为原料制备的高性能M型钙锶铁氧体磁粉和磁体,通过碳酸盐掺加量试验考察其对铁氧体磁性能的影响。结果表明,适量的碳酸盐掺加量能明显提高M型钙锶铁氧体的磁性能;在碳酸盐掺加量为0.1%、烧结温度1 190℃时,该M型钙锶铁氧体剩磁Br=449.5 m T、内禀矫顽力Hcb=337 k A/m,磁性能最达到最佳。     

磁铁精矿生产锶铁氧体的工艺研究

研究了用磁铁精矿制备超级铁精矿及锶铁氧体过程中，磁选、烧结温度与时间、添加剂等主要因素对磁体性能的影响，并依据磁铁精矿自身特点探讨出两种新型添加剂。在此研究基础上确定了生产优质锶铁氧体的最佳工艺条件。     

霍邱铁矿粉制备高性能锶铁氧体预烧料试验

为了探讨霍邱铁矿石加工的超级精矿粉制备高性能锶铁氧体预烧料的可能性,以TFe72.1%,SiO2含量在0.1%~0.2%的超级精矿为主要原料,进行了配料SrO与Fe2O3物质的量之比、预烧料烧结温度、研磨细度对锶铁氧体性能的影响试验。结果表明,在配料SrO与Fe2O3物质的量之比为5.9、预烧温度为1 285℃、物料细度平均粒度为0.75μm时,产品的磁性能最佳,剩磁(Br)≥410 mT、材料料矫顽力(Hcb)≥255 kA/m和内禀矫顽力(Hcj)≥265 kA/m。     

用磁铁精矿生产锶铁氧体预烧料的工艺研究

究了用磁铁精矿制取超纯铁精矿,并用超纯铁精矿取代铁红或铁鳞生产锶铁氧体预烧料。在ｎ＝５．６和预烧温度为１２８０℃,预烧时间为１ｈ的条件下,可制备优质锶铁氧体预烧料     

La-Co取代M型锶铁氧体的制备及性能

采用固相球磨法制备La-Co取代系M型锶铁氧体,研究了La-Co取代量对样品晶体结构、微观形貌和磁性能的影响。结论表明：Co²⁺单一取代和La-Co联合取代均会引起样品晶格常数的变化,所制备的M型锶铁氧体均形成了六角片状结构。与Co²⁺单一取代相比,La-Co联合取代可有效抑制微粒的长大,且分布均匀。当M型锶铁氧体的化学成分为Sr0.6La0.4Fe11.7Co0.3O19时,样品的Hcj最大,达到407 kA/m,较锶铁氧体SrFe12O19的Hcj提高88.65%。     

Ca含量对 Ca-La-Co 联合取代M型锶铁氧体的影响

本文采用固相球磨法制备M型锶铁氧体,研究了Ca含量对Ca-La-Co联合取代M型锶铁氧体的影响。采用X射线衍射、场发射扫描电镜、永磁测量仪对M型铁氧体的物相、晶胞结构、微观形貌和磁性能进行了表征。Ca_²⁺部分取代Sr_²⁺会造成晶胞c轴收缩,Ca取代量x’’≤0.2 at%时,得到单一的磁铅石相,Ca取代量x’’≥0.3 at%时,开始出现α-Fe₂O₃相。Ca_²⁺与SrO等形成低共熔物,加速晶粒c轴方向上的生长,促进六角片状结构的形成,Ca取代量xx’’=0.2 at%时,粒径在1.0 μm左右,分布均匀,随着取代量的增加,出现晶粒异常长大的现象。Ca取代量的增加会降低磁体的饱和磁化强度M_s、剩磁B_r,但会提高矫顽力H_cj,当Ca取代量x’’≤0.2 at%时,样品的剩磁略微下降,而矫顽力却急剧上升。     

Co_2W型六角晶系铁氧体的磁性与微波吸收性能

采用传统的氧化物固相反应法制备组分为BaZn1.1Co0.9Fe16O27,的Co2W型六角晶系铁氧体材料,研究了工艺参数、材料组成等对软磁特性、微波电磁参量、特性阻抗及吸波性能的影响.结果表明,适当提高烧结温度有助于提高w型铁氧体材料的饱和磁化强度,减小矫顽力,从而提高其磁导率;由Co2W型六角晶系铁氧体材料构成的吸波材料的阻抗匹配特性和吸波性能可以通过材料组成、材料复合及材料厚度变化米调整,有利于高性能铁氧体吸波材料的设计和制备.     

利用铁尾矿制备多相复合材料的研究

以攀枝花选钛尾矿为主要原料,活性炭为还原剂,采用碳热还原氮化法,实现合成与烧结一体化,烧结制备了Fe₃Si-Ti(C,N)复合多相材料,探索了一条低成本利用尾矿合成复合多相材料的新途径。借助X射线衍射（XRD）、扫描电子显微镜（SEM）和能谱分析（EDS）对烧结体的物相、显微形貌及成分进行了分析,并对样品的力学性能进行了研究。XRD结果表明,产物主晶相为Fe₃Si和Ti(C,N)。通过SEM和EDS可知,生成的Ti(C,N)相富集在Fe₃Si相的周围。样品的体积密度和表面洛氏硬度随着温度的升高而升高。当合成温度为1 500 ℃、保温时间为4 h时,所得的烧结体具有较高的体积密度（ρ=4.331 g/cm³）和表面洛氏硬度（HR15N=85.0）。     

以煤矸石为原料制备堇青石-莫来石复合材料

以煤矸石、菱镁矿、高岭土为原料,采用原位反应烧结法制备堇青石-莫来石复合材料,研究烧结温度和保温时间对堇青石-莫来石复合材料的物相组成、显微结构、物理性能的影响。结果表明,适当提高烧结温度和延长保温时间,可促进堇青石和莫来石晶体的合成,使试样显气孔率下降,致密度提高,耐压强度增大,但温度过高或保温时间过长不利于堇青石相的生成,使试样体积密度和耐压强度均有所降低。烧结温度为1 350℃,保温时间为2 h时,试样内部堇青石晶体和莫来石晶体发育良好,显气孔率为33.61%,体积密度为1.795 g/cm3,耐压强度为63.12 MPa,性能最优。     

用矢铁精矿生产锶铁氧体预烧料的工艺研究

研究了用磁铁精矿制取超纯铁精矿，并用超纯铁精矿取代铁红或铁鳞生产锶铁氧化预烧料。在ｎ＝５．６和预烧温度为１２８０℃，预烧时间为１ｈ的条件下，可制备优质锶铁氧化预烧料。     

Current situation and future trend of China rare earth luminescent material industry

<正>Rare earth luminescent material is one of the most important application sectors of rare earths.China enjoys the exceptional advantage to develop rare earth luminescent material for its abundant rare earth resources.After several decades'endeavor,China's rare earth luminescent material industry,headed by rare earth phosphor for lamp and LED and high efficient rare earth energy-saving light source,has been gradually developed into a scale industry.China has become a major production base of rare earth phosphor for lamps and rare earth     

China rare earth market review

正June 1~10,2014Rare earth market remained weak.Quoted price of rare earth products was similar to that in May.There was no sign of recovery in downstream market.The market of NdFeB magnetic materials and phosphor was depressed.Catalyst,polishing powder and ceramic industries remained inactive.Demand from downstream industry was soft.Consumers purchased on their needs.Suppliers had strong intention to sell.Prices of rare earth products     

Annual Report analysis of Chinese rare earth-related listed companies in 2013

<正>Chinese rare earth-related listed companies have published their 2013 annual reports.It can be understood from their reports that production and operation activities of Chinese rare earth-related companies were still heavily affected by macro economy and industrial policies.They basically followed the steps of national economy.In 2013,world economy recovered slowly but the economy     

Market opportunities and challenges for rare earth polishing powder

正1.Status of rare earth polishing powder Rare earth polishing powder with high content of cerium oxide began to replace iron oxide for glass polishing and became one of the key materials in glass polishing process since 1940.Compared with traditional iron oxide,rare earth polishing powder has many advantages,such as fast polishing rate,high polishing quality and long service life.It can achieve good surface quality and improve operation conditions.For example,in lens polishing,the polishing work that cerium     

Baotou Research Institute of Rare Earths developed a new RE alloy preparation technology

正Pyrometallurgy Laboratory of Baotou Research Institute of Rare Earths had independently developed a new preparation technology of rare earth alloy for NdFeB.The alloy can remarkably enhance the coercivity of NdFeB magnet but also evidently reduce the production cost of the magnet.The new master alloy was prepared in the kA pilot-scale electrolytic cell by the independent technology.The rare earth master alloy can be used as the raw material for NdFeB.Compared     

矿用防爆轴流对旋主要通风机叶片ANSYS模态分析及应用

高效节能矿用防爆对旋主要通风机的叶片是主要通风机运行的关键部件,叶片在运行时不断受到气流的作用力,从而使叶片产生振动,当叶片振动的频率与叶片的固有频率接近时,容易产生共振从而导致叶片的断裂。一旦叶片断裂时,对主要通风机的安全运行产生致命的影响,从而导致矿山、化工等企业发生重大事故,将会产生不可估量的损失。基于有限元分析软件ANSYS,对高效节能矿用防爆轴流对旋主要通风机叶片进行模态分析及产生对应的六阶模态频率,对主要通风机叶片的运行频率、固有频率及产生的共振问题进行了原理分析,并且解决了叶片频率共振的问题,从而为主要通风机叶片结构设计提供理论依据,并对主要通风机叶片的安全运行提供保障。     

2013 NdFeB export analysis

<正>China totally exported nearly 24,000 tonsof NdFeB products during 201 3,including 18,825 tons of permanent magnet,valued USD 1.34 billion at an average price of 71.4 USD/kg;3,277 tons of NdFeB magnetic powder,valued USD 1 01 million at an average price of 30.9 USD/kg;1,334 tons of strip casting ribbon,with total export value of USD 74million at an average price of 55.3 USD/kg;and 586     

Market and recycling of NiMH battery

<正>Market status and future trend of NiMH battery1.Global market of small NiMH battery Global market size of small NiMH batteries declined year on year since 2011.The trend will continue to 2018,at the rate of 5%to 10%annually.Demand for small NiMH batteries will be stable gradually.Many electrical apparatuses are powered by the built-in lithium battery today,which is the main reason for the shrunk market of small NiMH batteries.But,for some products,small NiMH     

China rare earth market review

正September 1-10,2014 Affected by the National Day holiday,rare earth transaction was stagnant and the market showed a weak steady state.As there was no good news for downstream market,some products with flat demand would likely rally slightly for some time to     

唐口煤矿深部复杂开采工作面瓦斯分源涌出规律研究

研究工作面瓦斯涌出规律对工作面瓦斯治理有重要意义。为了得到唐口煤矿深部3号煤层复杂开采条件下工作面回采时期瓦斯涌出时空演化规律,选取6304工作面作为对象,采用实测方法研究6304工作面瓦斯涌出规律。结果表明:6304工作面瓦斯涌出量为6.534 m³/min,其中煤壁占34.27%,落煤占29.62%,采空区占36.11%;沿工作面倾向由低到高,瓦斯浓度整体为上升趋势,其中1—76号架工作面瓦斯浓度小于0.20%,76—102号架瓦斯浓度上升明显,最大为0.387%;上隅角的后部采空区是工作面的瓦斯主要涌出源,上隅角1号测点瓦斯浓度0.78%,上隅角周边3号、5号、7号、8号、9号测点瓦斯浓度平均为0.643%;周期来压时,上隅角瓦斯相对平时较高。研究为针对性的瓦斯分源监控与灾害防治提供基础。