Mixture distribution measurement using laser induced breakdown spectroscopy in hydrogen direct injection stratified charge

Reduction in cooling loss due to the heat transfer from burning gas to the combustion chamber wall is very important for improving the thermal efficiency in hydrogen engines. The previous research has shown that the direct injection stratified charge can be a technique to reduce the cooling loss and improve thermal efficiency in hydrogen combustion. For effective reductions in cooling loss by the stratified charge, it is very important to know the relation between the fuel injection conditions and mixture distribution. The current research employs the laser induced breakdown spectroscopy as a method to measure the hydrogen concentration distribution in the direct injection stratified charge. Measurement of instantaneous local equivalence ratio by the method clears the characteristics of mixture formation in hydrogen direct injection stratified charge. This research also tries to actively control the mixture distribution using a split fuel injection.     

Improving the combustion performance of a gasoline rotary engine by hydrogen enrichment at various conditions

The combustion process within the cylinder directly influences the thermal efficiency and performance of the engines. As for the rotary engine, the long-narrow combustion chamber prevents the mixture from fully burning, which worsens the performance of the rotary engine. As a fuel with excellent properties, hydrogen can improve the combustion of the original engine. In this paper, improvements in combustion of a gasoline rotary engine by hydrogen supplement under different operating conditions were experimentally investigated. The experiment was conducted on a modified hydrogen-gasoline dual-fuel rotary engine equipped with an electronically-controlled fuel injection system. An electronic control module was specially made to command the fuel injection, excess air ratio and hydrogen volumetric fraction. Integral heat release fraction (IHRF) was employed to evaluate the combustion of the tested engine. The tested engine was first run at the idle speed of 2400 rpm and then operated at 4500 rpm to investigate the combustion of the hydrogen-blended gasoline rotary engine under different hydrogen volume fractions, excess air ratios and spark timings. The testing results demonstrated that the combustion of the gasoline rotary engine were all improved when the hydrogen was blended into the chamber under all tested conditions.     

Increasing the power output of hydrogen internal combustion engines by means of supercharging and exhaust gas recirculation

Spark ignition engines can be relatively easily converted to hydrogen using port fuel injection (PFI). However, because of the lower volumetric energy density of a hydrogen–air mixture and the occurrence of abnormal combustion phenomena such as backfire, hydrogen-fueled PFI engines suffer from a power deficit in comparison with gasoline engines. This paper reports measurements on a single-cylinder hydrogen engine equipped with a supercharger and an exhaust gas recirculation (EGR) system. Using EGR combined with supercharging and a three-way catalyst (TWC) is shown to significantly increase the power output while limiting tailpipe emissions of oxides of nitrogen (NO_x).     

Biofuels and thermal barrier: A review on compression ignition engine performance,combustion and exhaust gas emission

The performance of an internal combustion engine is affected when renewable biofuels are used instead of fossil fuels in an unmodified engine. Various engine modifications were experimented by the researchers to optimise the biofuels operated engine performance. Thermal barrier coating is one of the techniques used to improve the biofuels operated engine performance and combustion characteristics by reducing the heat loss from the combustion chamber. In this study, engine tests results on performance, combustion and exhaust emission characteristics of the biofuels operated thermal barrier coated engines were collated and reviewed. The results found in the literature were reviewed in three scenarios: (i) uncoated versus coated engine for fossil diesel fuel application, (ii) uncoated versus coated engine for biofuels (and blends) application, and (iii) fossil diesel use on uncoated engine versus biofuel (and blends) use on coated engine. Effects of injection timing, injection pressure and fuel properties on thermal barrier coatings were also discussed. The material type, thickness and properties of the coating materials used by the research community were presented. The effectiveness and durability of the coating layer depends on two key properties: low thermal conductivity and high thermal expansion coefficient. The current study showed that thermal barrier coatings could potentially offset the performance drop due to use of biofuels in the compression ignition engines. Improvements of up to 4.6% in torque, 7.8% in power output, 13.4% in brake specific fuel consumption, 15.4% in brake specific energy consumption and 10.7% in brake thermal efficiency were reported when biofuels or biofuel blends were used in the thermal barrier coated engines as compared to the uncoated engines. In coated engines, peak cylinder pressure and exhaust gas temperature were increased by up to 16.3 bar and 14% respectively as compared to uncoated condition. However, changes in the heat release rates were reported to be between ?27% and +13.8% as compared to uncoated standard engine. Reductions of CO, CO₂, HC and smoke emissions were reported by up to 3.8%, 11.1%, 90.9% and 63% respectively as compared to uncoated engines. Significant decreases in the PM emissions were also reported due to use of thermal barrier coatings in the combustion chamber. In contrast, at high speed and at high load operation, increase in the CO and CO₂ emissions were also reported in coated engines. Coated engines gave higher NO_x emissions by about 4–62.9% as compared to uncoated engines. Combined effects of thermal barrier coatings and optimisation of fuel properties and injection parameters produced further performance and emissions advantages compared to only thermal barrier coated engines. Overall, current review study showed that application of thermal barrier coatings in compression ignition engines could be beneficial when biofuels or biofuel blends are used instead of standard fossil diesel. However, more research is needed combining coatings, types of biofuels and other engine modifications to establish a concrete conclusion on the effectiveness of the thermal barrier when biofuels are used in the compression ignition engine. Reduction of NO_x emissions is another important R & D area.     

Improvement of thermal efficiency and reduction of NOx emissions by burning a controlled jet plume in high-pressure direct-injection hydrogen engines

A new combustion process called the Plume Ignition Combustion Concept (PCC), in which the plume tail of the hydrogen jet is spark-ignited immediately after the completion of fuel injection to accomplish combustion of a rich mixture has been proposed by the authors. This PCC combustion process markedly reduces nitrogen oxides (NOx) emissions in the high-output region while maintaining high levels of thermal efficiency and power. On the other hand, as burning lean mixture of fuel and air is the conventional way to improve thermal efficiency and reduce NOx, a high λ premixed mixture of hydrogen and air formed by injecting hydrogen in the early stage of the compression stroke has been used in direct-injection hydrogen engines. It was recently reported, however, that this mixture condition does not always offer expected improved thermal efficiency under even lean mixture conditions by increasing unburned hydrogen emissions caused by incomplete flame propagation in the non-uniform and extremely lean portion of the mixture. In this study, the effect of retarding the injection timing to late in the compression stroke but slightly advanced from original PCC was examined as a way of reducing unburned hydrogen emissions and improving thermal efficiency. These effects result from a centroidal axially stratified mixture that positions a fairly rich charge near the spark plug. This stratified mixture is presumably effective in reducing incomplete flame propagation thought to be the cause of unburned hydrogen emissions and also promoting increasing burning velocity of the mixture that improve thermal efficiency. Finally, this research is characterized by measuring the hydrogen fuel concentration at the point and the time of spark ignition quantitatively by spark-induced breakdown spectroscopy in order to identify the changes in mixture ratio mentioned above caused by the parameters involved.     

An experimental study on the effect of hydrogen enrichment on diesel fueled HCCI combustion

This paper experimentally investigates the influence of hydrogen enrichment on the combustion and emission characteristics of a diesel HCCI engine using a modified Cooperative Fuel Research (CFR) engine. Three fuels, n-heptane and two middle distillates with cetane numbers of 46.6 and 36.6, are studied.The results show that hydrogen enrichment retards the combustion phasing and reduces the combustion duration of a diesel HCCI engine. Besides, hydrogen enrichment increases the power output and fuel conversion efficiency, and improves the combustion stability. However, hydrogen enrichment may narrow the operational compression ratio range and increase the knocking tendency. Both the overall indicated specific CO emissions (isCO) and CO emissions per unit burned diesel fuel mass are reduced by hydrogen enrichment. Although hydrogen enrichment decreases the overall indicated specific unburned hydrocarbon emissions (isHC), it does not significantly affect the HC emissions per unit burned diesel fuel mass.     

A review on the technical adaptations for internal combustion engines to operate with gas/hydrogen mixtures

The use of the hydrogen as fuel in the internal combustion engine represents an alternative use to replace the hydrocarbons fuels, which produce during the combustion reaction a pollutes gases. The hydrogen is the most abundant material in the universe and during its combustion with air only produces nitrous oxides (NO_x) gas, which can collect and avoid their emission to the atmosphere. In this paper we can present the most significant advances and developments made on the technical adaptations in the internal combustion engines which operate with mixtures of gas/hydrogen, doing more emphasis in the fuel injection and cooling systems. To understand such technical adaptations, it is necessary to know the chemical and physical characteristics of the hydrogen, and the processes relate with the chemical reaction between air and hydrogen, from a point of view of the thermo-chemistry and the chemical kinetics, as well as the ratios of the mixtures in the combustion process. Also, it mentions the advantages and disadvantages of the integration of hydrogen as a fuel, such as the pre-ignition, spontaneous ignition, knocking and backfire, also the advances in the research to avoid these phenomena during the combustion. Finally, it describes the best conditions of the ratio-mixtures in the internal combustion engines when they are fed with hydrogen. Also, it describes the perspectives and the futures fields on the future investigation.     

The effect of HRG gas addition on diesel engine combustion characteristics and exhaust emissions

Extensive studies have been dedicated in the last decade to the possibility to use hydrogen in the dual-fuel mode to improve combustion characteristics and emissions of a diesel engine. The results of these studies, using pure hydrogen or hydrogen containing gas produced through water electrolysis, are notably different.The present investigation was conducted on a tractor diesel engine running with small amounts of the gas—provided by a water electrolyzer—aspirated in the air stream inducted in the cylinder. The engine was operated at light and medium loads and various speeds.It was found that the addition of HRG gas has a slight negative impact, up to 2%, on the engine brake thermal efficiency. Smoke is significantly reduced, up to 30%, with HRG enrichment, while NO_x concentrations vary in both senses, up to 14%, depending on the engine operation mode. A relative small amount of HRG gas can be used with favorable effects on emissions and with a small penalty in thermal efficiency.     

The distinctive characteristics of combustion duration in hydrogen internal combustion engine

As a practical solution to reduce the emission pollution and energy crisis, the research and development of HICE has been processed in several decades. The focus of this paper is trying to explore the new features of the combustion duration in HICE not only by engine experiment, but also by analysis of the physical properties of hydrogen, especially the obvious difference from that of gasoline. Firstly, the laminar flame speed difference between hydrogen and gasoline was studied and discussed. Secondly, a distinctive rule of combustion duration in HICE was discovered by analyzing the experiment data. Finally, as a key reference point to the HICE operation, a new characteristic of the location of 50% mixture combust up was proposed and analyzed, this will be helpful for the calibration of optimum ignition timing.     

Effect of addition of hydrogen and exhaust gas recirculation on characteristics of hydrogen gasoline engine

The effects of exhaust gas recirculation (EGR) on combustion and emissions under different hydrogen ratios were studied based on an engine with a gasoline intake port injection and hydrogen direct injection. The peak cylinder pressure increases by 9.8% in the presence of a small amount of hydrogen. The heat release from combustion is more concentrated, and the engine torque can increase by 11% with a small amount of hydrogen addition. Nitrogen oxide (NOx) emissions can be reduced by EGR dilution. Hydrogen addition offsets the blocking effect of EGR on combustion partially, therefore, hydrogen addition permits a higher original engine EGR rate, and yields a larger throttle opening, which improves the mechanical efficiency and decreases NOx emissions by 54.8% compared with the original engine. The effects of EGR on carbon monoxide (CO) and hydrocarbon (HC) emissions are not obvious and CO and HC emissions can be reduced sharply with hydrogen addition. CO, HC, and NOx emissions can be controlled at a lower level, engine output torque can be increased, and fuel consumption can be reduced significantly with the co-control of hydrogen addition and EGR in a hydrogen gasoline engine.     

A simulation of the combustion of hydrogen in HCCI engines using a 3D model with detailed chemical kinetics

The influence of changes in the swirl velocity of the intake mixture on the combustion processes within a homogeneous charge compression ignition (HCCI) engine fueled with hydrogen were investigated analytically. A turbulent transient 3D predictive computational model which was developed and applied to the HCCI engine combustion system, incorporated detailed chemical kinetics for the oxidation of hydrogen. The effects of changes in the initial intake swirl, temperature and pressure, engine speed and compression and equivalence ratios on the combustion characteristics of a hydrogen fuelled HCCI engine were also examined. It is shown that an increase in the initial flow swirl ratio or speed lengthens the delay period for autoignition and extends the combustion period while reducing NO_x emissions. There are optimum values of the initial swirl ratio and engine speed for a certain mixture intake temperature, pressure, compression and equivalence ratios operational conditions that can achieve high thermal efficiencies and low NO_x emissions while reducing the tendency to knock     

Setting a best practice for determining the EGR rate in hydrogen internal combustion engines

Exhaust gas recirculation (EGR) is an effective way to reduce NO_x-emissions and increase the efficiency of hydrogen fueled internal combustion engines. Knowledge of the exact amount of EGR is crucial to understand the effects of EGR. As the exhaust gas flow is pulsating and chemically aggressive, the flow rate is typically not measured directly and has to be derived from other quantities. For hydrocarbon fuels, the EGR rate is generally calculated from a molar CO₂ balance, but for hydrogen engines this obviously cannot be used as there are no CO₂ emissions, and consequently no standard practice has been established. This work considers three methods to calculate the amount of EGR in a hydrogen engine. The first one is based upon a volume balance in the mixing section of exhaust gases and fresh air. The second and third method uses a molar balance of O₂ and H₂O respectively in this mixing section. The three methods are developed and tested for their accuracy with an error analysis. Additionally, the methods are applied to an experimental dataset gathered on a single cylinder hydrogen engine. Both the theoretical analysis and the experimental results confirm the method based on an O₂ molar balance as the most accurate one. The least practical method is the one based on an H₂O balance as it requires additional relative humidity sensors and is less accurate than the others.     

Modeling and simulation of hydrogen combustion in engines

Hydrogen being an ecological fuel is very attractive now for engines designers. It is already actively used in rocket engines. There exist plans to use hydrogen in pulse detonation engines. However, peculiarities of hydrogen combustion kinetics, the presence of zones of inverse dependence of reaction rate on pressure, etc. prevent from wide use of hydrogen engines. Computer aided design of new effective and clean hydrogen engines needs mathematical tools for supercomputer modeling of hydrogen–oxygen components mixing and combustion gas dynamics.     

Effect of hydrogen addition using on-board alkaline electrolyser on SI engine emissions and combustion

In this study, an electrolyser was used to supply hydrogen to the SI engine. Firstly, the appropriate operation point for the electrolyser was determined by adjusting the amount of KOH in the electrolyte to 5%, 10%, 20% and 30% by mass, and applying 12 V, 16 V, 20 V, 24 V and 28 V voltages. Tests were first carried out with the gasoline without the use of an electrolyser, followed by operating the electrolyser at the appropriate point and sending obtained H₂ and O₂ to the engine in addition to the gasoline. The SI engine was operated between 2500 rpm and 3500 rpm engine speeds with and without hydrogen addition. Cylinder pressure, the amount of gasoline, H₂ and O₂ consumed by the engine and the emission data were collected from the test system at the aforementioned engine speeds. Furthermore, indicated engine torque, indicated specific energy consumption, specific emissions and HRR values were calculated. According to the results obtained, improvement in ISEC values was observed, and CO and THC values were improved by up to 21.3% and 86.1% respectively. Even though the dramatic increase in NO_x emissions cannot be averted, they can be controlled by equipment such as EGR three-way catalytic converter.     

Research on the inducing factors and characteristics of knock combustion in a DI hydrogen internal combustion engine in the process of improving performance and thermal efficiency

Hydrogen energy is gaining greater attention because of the energy crisis and CO2 emissions, and knock combustion has become the main obstacle to improving thermal efficiency and power performance of hydrogen engines, which is an important method of hydrogen energy application. In this paper, the knock characteristic parameters and the factors affecting knock tendency of a 2.0 L DI hydrogen engine are investigated experimentally. The results reveal the variation in knock intensity is not linear with the retarding of SOI, which is related to the cylinder mixture distribution. Furthermore, methods such as increasing injection pressures can be useful in reducing the knock intensity. Equivalence ratio has a greater impact on knock compared with other parameters. The conclusions can be used in the further exploration of the knock combustion mechanism in DI hydrogen engines.     

Evaluation of a combustion model for the simulation of hydrogen spark-ignition engines using a CFD code

The present work deals with the evaluation of a combustion model that has been developed, in order to simulate the power cycle of hydrogen spark-ignition engines. The motivation for the development of such a model is to obtain a simple combustion model with few calibration constants, applicable to a wide range of engine configurations, incorporated in an in-house CFD code using the RNG k–? turbulence model. The calculated cylinder pressure traces, gross heat release rate diagrams and exhaust nitric oxide (NO) emissions are compared with the corresponding measured ones at various engine loads. The engine used is a Cooperative Fuel Research (CFR) engine fueled with hydrogen, operating at a constant engine speed of 600 rpm. This model is composed of various sub-models used for the simulation of combustion of conventional fuels in SI engines; it has been adjusted in the current study specifically for hydrogen combustion. The basic sub-model incorporated for the calculation of the reaction rates is the characteristic conversion time-scale method, meaning that a time-scale is used depending on the laminar conversion time and the turbulent mixing time, which dictates to what extent the combustible gas has reached its chemical equilibrium during a predefined time step. Also, the laminar and turbulent combustion velocity is used to track the flame development within the combustion chamber, using two correlations for the laminar flame speed and the Zimont/Lipatnikov approach for the modeling of the turbulent flame speed, whereas the (NO) emissions are calculated according to the Zeldovich mechanism. From the evaluation conducted, it is revealed that by using the developed hydrogen combustion model and after adjustment of the unique model calibration constant, there is an adequate agreement with measured data (regarding performance and emissions) for the investigated conditions. However, there are a few more issues to be resolved dealing mainly with the ignition process and the applicability of a reliable set of constants for the emission calculations.     

Computational modeling, validation, and utilization for predicting the performance, combustion and emission characteristics of hydrogen IC engines

Hydrogen-fueled internal combustion engines are considered to be more efficient and cleaner alternatives to their fossil-fueled counterparts. Reasonably fast and accurate predictive computational tools are essential for practical design, control and optimization of hydrogen engines. To serve for this broader purpose, a computational model, which has been widely used for gasoline and diesel engines, is investigated for its capability to simulate hydrogen engines. Specifically, fuel-specific sub-models are first incorporated by properly accounting for hydrogen’s distinct properties such as flame speed and burn rate. The accuracy of the model is then assessed by validating it in comparison to independent experimental data. Finally, it is utilized to quantify the environmental impact of exhaust gas recirculation. With these improvements, the present predictive model is shown to capture the measured engine performance and emission data well under different operating conditions. In particular, the variations of peak in-cylinder pressure, heat release rate, brake power, brake thermal efficiency, exhaust temperature, and NO_x emissions are predicted close to the measured values. With the addition of a proportional-integral-derivative controller to the engine model, exhaust gas recirculation level is varied, resulting in nearly an order of magnitude reduction in NO_x emissions during the present simulations.