New deep-freezing process using renewable low-grade heat: From the conceptual design to experimental results

An exergy-based analysis applied to ideal thermochemical dipoles allowed to design an original process that could use low-grade energy, produced from a thermal solar collector at around 70 °C, to provide low-temperature cold, below −23 °C, in order to store deep-frozen food. The ideal coefficient of performance (COP) of this system is 0.5 and the exergetic yield is 1. Taking into account the process enthalpies and the sensible heat of the reactants, the COP_thermo is 0.17. The process functioning is described in this paper. It alternates between a regeneration mode during daytime and cold production mode during night-time. An experimental prototype was designed and built. It proved the feasibility of the concept and showed an experimental COP of about 0.06, which is similar to the up-to-date solar cooling systems, but at higher cold temperatures. The mean annual exergetic yield of the process is about 0.06.     

Maximization of primary energy savings of solar heating and cooling systems by transient simulations and computer design of experiments

In this paper, the simulation of the performance of solar-assisted heating and cooling systems is analyzed. Three different plant layouts are considered: (i) the first one consists of evacuated solar collectors and a single-stage LiBr–H₂O absorption chiller; here in order to integrate the system in case of insufficient solar radiation, an electric water-cooled chiller is activated; (ii) configuration of the secondly considered system is similar to the first one, but the absorption chiller and the solar collector area are sized for balancing about 30% of the building cooling load only; (iii) the layout of the thirdly considered system differs from the first one since the auxiliary electric chiller is replaced by a gas-fired heater. Such system configurations also include: circulation pumps, storage tanks, feedback controllers, mixers, diverters and on/off hysteresis controllers.     

Experimental investigation and performance analysis on a solar adsorption cooling system with/without heat storage

A solar adsorption cooling system which can be switched between a system with heat storage and a system without heat storage was designed. In the system with heat storage, a heat storage water tank was employed as the link between the solar collector circulation and the hot water circulation for the adsorption chillers. However, the heat storage water tank was isolated in the system without heat storage, and the hot water was directly circulated between the solar collector arrays and the adsorption chillers. It was found that the inlet and outlet temperatures for the solar collector arrays and the adsorption chillers in the system without heat storage were more fluctuant than those of the system with heat storage. Also found was that the system with heat storage operated stably because of the regulating effect by the heat storage water tank. However, under otherwise similar conditions, the cooling effect of the system without heat storage was similar to that of the system with heat storage. Compared with the system with heat storage, the system without heat storage has the advantages of higher solar collecting efficiency as well as higher electrical COP.     

Life cycle analysis of a solar thermal system with thermochemical storage process

Solar energy itself is generally considered as environmentally friendly, nevertheless it is still important to take into consideration the environmental impacts caused by production of thousands of solar thermal systems. In this work the standard LCA methodology has been extended to analyse the total environmental impacts of a new more efficient solar thermal system SOLARSTORE during its whole life cycle. This system is being developed by a 5th Framework EC project. The LCA results show that to produce 1 GJ energy with SOLARSTORE system will result in global warming potential of 6.3–10 kg CO₂, acidification potential of 46.6–70 g SO₂, eutrophication of 2.1–3.1 g phosphate and photochemical oxidant of 0.99–1.5 g C₂H₄. The raw material acquisition and components manufacturing processes contribute 99% to the total environmental impacts. In comparison with traditional heating systems, SOLARSTORE system provides a considerably better solution for reduction of negative environmental impacts by using solar energy more efficiently.     

Modelling of solar energy potential in Nigeria using an artificial neural network model

In this study, an artificial neural network (ANN) based model for prediction of solar energy potential in Nigeria (lat. 4–14°N, log. 2–15°E) was developed. Standard multilayered, feed-forward, back-propagation neural networks with different architecture were designed using neural toolbox for MATLAB. Geographical and meteorological data of 195 cities in Nigeria for period of 10 years (1983–1993) from the NASA geo-satellite database were used for the training and testing the network. Meteorological and geographical data (latitude, longitude, altitude, month, mean sunshine duration, mean temperature, and relative humidity) were used as inputs to the network, while the solar radiation intensity was used as the output of the network. The results show that the correlation coefficients between the ANN predictions and actual mean monthly global solar radiation intensities for training and testing datasets were higher than 90%, thus suggesting a high reliability of the model for evaluation of solar radiation in locations where solar radiation data are not available. The predicted solar radiation values from the model were given in form of monthly maps. The monthly mean solar radiation potential in northern and southern regions ranged from 7.01–5.62 to 5.43–3.54 kW h/m² day, respectively. A graphical user interface (GUI) was developed for the application of the model. The model can be used easily for estimation of solar radiation for preliminary design of solar applications.     

Operational strategy of a two-step thermochemical process for solar hydrogen production

A two-step thermochemical cycle process for solar hydrogen production from water has been developed using ferrite-based redox systems at moderate temperatures. The cycle offers promising properties concerning thermodynamics and efficiency and produces pure hydrogen without need for product separation.     

Model of a solar driven steam jet ejector chiller and investigation of its dynamic operational behaviour

The solar driven steam jet ejector chiller (SJEC) is a new device for solar air-conditioning. Previously, solar SJEC has been only investigated theoretically by static models and practically by small test rigs. A demonstration plant does not exist so far, so that the operational behaviour of a solar SJEC has not been investigated in detail yet. But due to the fact that solar irradiation and cold demand are not constant, the operational behaviour is very important for the plant design and the controlling concept. This publication presents a model for a SJEC and the results of dynamic simulations. The proposed model allows creating and investigating different plant concepts by its structure in model components. After the validation of the model, simulations of a fictive solar SJEC with parabolic trough collectors are accomplished to analyse the dynamic operational behaviour of a future plant.     

Study on the heat transfer and sorption characteristics of a consolidated composite sorbent for solar-powered thermochemical cooling systems

In this paper, a new consolidated composite sorbent made from barium chloride and expanded graphite is presented for solar-powered thermochemical sorption cooling systems. A larger sorption capacity and volume cooling density can be obtained with chemisorption systems when compared with those based on physicosorption. The heat transfer and sorption characteristics of the composite sorbent were investigated. Experimental results showed that the chemical composite sorbent can effectively utilize solar energy or low-grade waste heat sources with temperature ranging from 75 to 90 °C, and it could incorporate 0.61 kg of ammonia per kg of the reactive salt. The temperature evolution in the reactor was strongly influenced by the physicochemical reaction, whereas the transient heat transfer properties in the reactive composite material were different during the decomposition and the synthesis phases owing to the variation of the ammonia content and solid configuration inside the metallic salt complex. The rate of conversion in the reactor was very sensitive to the working temperatures and pressures, and the COP (coefficient of performance) obtained with the consolidated composite sorbent varied between 0.50 and 0.53 when the evaporation temperature ranged from 0 to 15 °C at a generation temperature of 80 °C.     

Experimental and modelling performances of a roof-integrated solar drying system for drying herbs and spices

This paper presents experimental performance of solar drying of rosella flower and chili using roof-integrated solar dryer and also presents modelling of the roof-integrated solar dryer for drying of chili. Field-level tests for deep bed drying of rosella flower and chili demonstrated that drying in the roof-integrated solar dryer results in significant reduction in drying time compared to the traditional sun drying method and the dry product is a quality dry product compared to the quality products in the markets. The payback period of the roof-integrated solar dryer is about 5 years. To simulate the performance of the roof-integrated solar dryer for drying herbs and spices using hot air from roof-integrated solar collectors, two sets of equations were developed. The first set of equations was solved implicitly and the second set of equations was solved explicitly using finite difference technique. The simulated air temperatures at the collector outlet agreed well with the observed air temperatures. Good agreement was also found between experimental and simulated moisture contents.     

Research and development on membrane IS process for hydrogen production using solar heat

Thermochemical hydrogen production has attracted considerable interest as a clean energy solution to address the challenges of climate change and environmental sustainability. The thermochemical water-splitting iodine-sulfur (IS) process uses heat from nuclear or solar power and thus is a promising next-generation thermochemical hydrogen production method that is independent of fossil fuels and can provide energy security. This paper presents the current state of research and development (R&D) of the IS process based on membrane techniques using solar energy at a medium temperature of 600 °C. Membrane design strategies have the most potential for making the IS process using solar energy highly efficient and economical and are illustrated here in detail. Three aspects of membrane design proposed herein for the IS process have led to a considerable improvement of the total thermal efficiency of the process: membrane reactors, membranes, and reaction catalysts. Experimental studies in the applications of these membrane design techniques to the Bunsen reaction, sulfuric acid decomposition, and hydrogen iodide decomposition are discussed.     

Modeling of a direct solar receiver reactor for decomposition of sulfuric acid in thermochemical hydrogen production cycles

Hydrogen production thermochemical cycles, based on the recirculation of sulfur-based compounds, are among the best suited processes to produce hydrogen using concentrated solar power. The sulfuric acid decomposition section is common to each sulfur-based cycle and represents one of the fundamental steps. A novel direct solar receiver-reactor concept is conceived, conceptually designed and simulated. A detailed transport phenomena model, including mass, energy and momentum balance expressions as well as suitable decomposition kinetics, is described adopting a finite volume approach. A single unit reactor is simulated with an inlet flow rate of 0.28 kg/s (corresponding to a production of approximately 11 kg_H2/h in a Hybrid Sulfur process) and a direct solar irradiation at a constant power of 143 kW/m². Results, obtained for the high temperature catalytic decomposition of SO₃ into SO₂ and O₂, demonstrate the effectiveness of the proposed concept, operating at pressures of 14 bar. A maximum temperature of 879 °C is achieved in the reactor body, with a corresponding average SO₂ mass fraction of 27.8%. The overall pressure drop value is 1.7 bar. The reactor allows the SO₃ decomposition into SO₂ and O₂ to be realized effectively, requiring an external high temperature solar power input of 123.6 kJ/molSO2 (i.e. 123.6 kJ/mol_H2).     

Simulation of a solar domestic water heating system using a time marching model

This paper presents the modelling and simulation of a solar water heating system using a time marching model. The results of simulations performed on an annual basis for a solar system, constructed and operated in Yugoslavia, which provides domestic hot water for a four-person family are presented. The solar water heater consists of a flat-plate solar collector, a water-storage tank, an electric heater, and a water-mixing device. The mathematical model is used to evaluate the annual variation of the solar fraction with respect to the volume of the storage tank, demand hot water temperature required, difference of this temperature and preset storage tank water temperature, and consumption profile of the domestic hot water demand. The results of this investigation may be used to design a solar collector system, and to operate already designed systems, effectively. The results for a number of designs with different storage tank volumes indicate that the systems with greater volume yield higher solar fraction values. The results additionally indicate that the solar fraction of the system increases with lower hot water demand temperature and higher differences between the mean storage water and the demand temperatures. However, when a larger storage tank volume is used, the solar fraction is less sensitive to a variation of these operation parameters.     

Dynamic modelling and experimental study of an ice generator heat exchanger using supercooled water

Since confirmation of the contribution of the refrigerants to ozone depletion and global warning, many solutions have been carried out to reduce their direct and indirect impact on the environment. One of them consists in using secondary refrigerant fluid (SRF) to reduce the amount of refrigerant flowing in the refrigerant loop. The new two-phase SRF present some advantages, and this paper presents a process using supercooled water to produce such fluid.     

Multi-objective optimization of a hydrogen production through the HyS process powered by solar energy in different scenarios

Thermochemical or hybrid cycles powered by concentrated solar energy are a very promising way to produce an effective clean hydrogen through the water splitting, in terms of greenhouse gas (GHG) emissions and power production sustainability. SOL2HY2 is an European project focused on this goal. It deepens the so-called HyS process in a closed or partially open version using a proper SO₂ depolarized electrolyser, and moreover, it investigates key materials and process solutions, along the entire production chain. However, the identification of the best solution to obtain a suitable hydrogen in terms of cost, efficiency, availability of energy and material, sharing of renewable energy source, continuity of operation in different locations and plant sizes, poses many challenges in terms of flexibility and complexity of the system. In fact, it involves various chemical equipment, different solar and thermal storage technologies, and variable operative conditions with different reaction temperatures and mixture concentrations. Hence it arises the importance to have a tool for the investigation of this system.In this paper, data analysis and multi-objective techniques are used to study and optimize the process under consideration. Several mathematical methods have been exploited to make the best use of the available data, such as Design of Experiments techniques, meta-modeling strategies and genetic algorithms. All these methods have been implemented in the open source environments Scilab and R.     

Evaluation of a rice drying system using a solar assisted heat pump

The use of a combined solar-heat pump rice drying system is being developed as an alternative to conventional mechanical dryers. The experimental equipment developed is a modified 7 kW R-22 air conditioning unit and is combined with a solar colector for a more precise control of temperature and humidity.     

Test operation of a 100 kW pilot plant for solar hydrogen production from water on a solar tower

The present work describes the realisation and successful test operation of a 100 kW pilot plant for two-step solar thermo-chemical water splitting on a solar tower at the Plataforma Solar de Almería, which aims at the demonstration of the feasibility of the process on a solar tower platform under real conditions. The process applies multi-valent iron based mixed metal oxides as reactive species which are coated on honeycomb absorbers inside a receiver-reactor. By the introduction of a two-chamber reactor it is possible to run both process concepts in parallel and thus, the hydrogen production process in a quasi-continuous mode. In summer 2008 an exhaustive thermal qualification of the pilot plant took place, using uncoated ceramic honeycombs as absorbers. Some main aspects of these tests were the development and validation of operational and measurement strategy, the gaining of knowledge on the dynamics of the system, in particular during thermal cycling, the determination of the controllability of the whole system, and the validation of practicability of the control concept. The thermal tests enabled to improve, to refine and finally to prove the process strategy and showed the feasibility of the control concept implemented. It could be shown that rapid changeover between the modules is a central benefit for the performance of the process.In November of 2008 the absorber was replaced and honeycombs coated with redox material were inserted. This allowed carrying out tests of hydrogen production by water splitting. Several hydrogen production cycles and metal oxide reduction cycles could be run without problems. Significant concentrations of hydrogen were produced with a conversion of steam of up to 30%.     

Dynamic modelling and simulation of a new air conditioning prototype by solar energy

This work presents a new design of an air conditioning prototype by solar energy developed at the Laboratory of Electromechanical Systems of the National Engineering School of Sfax, Tunisia. The new conception permits to produce heat or cold by using solar energy without polluting the environment. The installation, composed of four compartments, consists of three functioning modes according to the season of the year and according to the climatic conditions.A numerical model is developed to study the behaviour of the unit. This model uses real meteorological data to predict the performance of a thermal solar driven system. The dynamic modelling and simulation of only two modes of functioning (winter mode and summer mode without pre-cooling of air) are presented in this paper. This theoretical model is expected to help in predicting the behaviour of the installation in various climatic conditions. Besides, it would enhance the performance of such installation.     

Band-approximated radiative heat transfer analysis of a solar chemical reactor for the thermal dissociation of zinc oxide

A solar chemical reactor for the thermal dissociation of ZnO is modeled by means of a detailed heat transfer analysis that couples radiative transport to the reaction kinetics. An extended band-approximated radiosity method enables the analysis of directional and wavelength depended radiation exchange. Boundary conditions included the incident concentrated solar radiation, determined by the Monte Carlo ray-tracing technique, and the hemispherical and band-approximated optical properties derived for the quartz window. Validation was accomplished by comparing the numerically modeled and experimentally measured window temperatures, reaction rates, and energy conversion efficiencies. The experimentally measured solar-to-chemical energy conversion efficiency increased with temperature, peaked at 14% for a reactor temperature of 1900 K and ZnO dissociation rate of 12 g/min, and decreased as the reactor approached its stagnation temperature. The conditions for which this efficiency can be augmented are discussed.     

Catalytic thermochemical reactor/receiver for solar reforming of natural gas: Design and performance

The advantages of thermochemical conversion of concentrated solar energy using catalytic processes are discussed. The design of a solar volumetric thermochemical reactor/receiver (TCRR) with catalytic absorber, method for synthesis of catalytically activated ceramics, and preparation of catalytic absorber have been described. The prototype TCRR was tested in the high flux solar furnace at the DAC, Cologne by using the dioxide reforming of methane. The tests were performed to check the main concept of the TCRR design and catalytic absorber, to study the influence of solar flux distribution, the reagent flows and their ratio on the productivity or conversion, determine the reagent's conversion depending on the focal point disposition with respect to the absorber, and to study the efficiency of the thermochemical conversion. The chemical and total efficiencies of the CO₂–methane conversion were calculated using the experimentally measured concentrations of the reaction products. The highest overall efficiency achieved in these experiments was 30% with the Ni–Cr catalytic absorber.     

Modelling solar effects on the heat and mass transfer in a street canyon, a simplified approach

In urban areas, the climatic loads on buildings in summer conditions are largely affected by solar radiation. In this paper a modified simplified method for radiant interchange determination is used in a solar energy study. The good agreement with the radiosity method allows one to use this simplified method in the street canyon case. In a building pilot study, parametric analysis and building thermal behaviour can be assessed by simplified models which are useful for long-period simulation. Then this radiant interchange model is introduced in a zonal model of a canyon street and performed with a variable climatic conditions show case. The solar radiation is the only driving force in the street air movement. The interest of such approach for complex coupled phenomena studies is highlighted by obtained results and the assessment of variable climatic loads for different building zones can be considered with the model detailed herein. Future developments are planned in order to improve simulation accuracy by the addition of other local phenomena.