Sn基焊料/Cu界面IMC形成机理的研究进展

锡基无铅焊料和Cu基材界面间容易形成Cu<,6>Sn<,5>、Cu<,3>Sn及其他金属间化合物(IMC),而IMC将剧烈地影响焊接接头的性能,故对其的研究有助于了解IMC形成的本质,从而控制其形成和长大,以改善接头性能.综述了近期的研究结果,指出Cu<,6>Sn<,5>易形成扇贝状,而Cu<,3>Sn常常为薄层状;其...     

IMC生长对无铅焊球可靠性的影响

通过模拟及实验研究了IMC层及其生长对无铅焊点可靠性的影响.采用回流焊将无铅焊球(Sn3.5Ag0.7Cu)焊接到PCB板的铜焊盘上,通过-55～125℃的热循环实验,获得了IMC厚度经不同热循环次数后的生长规律.采用有限元法模拟了热循环过程中IMC厚度生长对无铅BGA焊点中应力变化的影响,并由能量疲劳模型预测了无铅焊点寿命.计算结果显示,考虑IMC层生长所预测的焊点热疲劳寿命比不考虑IMC层生长时缩短约30%.     

添加Sn—Ag对Sn—Bi焊接特性的改善

研究了ｘ４２Ｓｎ５８Ｂｉ－（１－ｘ）９６。．５Ｓｎ３．５Ａｇ系中不同组成的焊料,表明在４２Ｓｎ５８Ｂｉ（简称ＳＢ）焊料中添加适量的９６．５Ｓｎ３．５Ａｇ,能改善焊妆温度。通过对焊向拉力的测试分析,发现一的ＳＡ能提高焊点的强度并在高低温分别为＋１２５℃和－４０℃下进行热冲击１０００次后,其强度减不程度远小于纯的ＳＢ焊料焊点。其焊点的机械及疲劳性能得到了提高。通过透射Ｘ射线及扫描电子显微镜（ＳＥＭ）分     

电流密度对Sn3.0Ag0.5Cu焊点蠕变行为的影响

通过观察焊点的电阻变化和显微组织演变,研究了电流密度对Sn3.0Ag0.5Cu焊点蠕变行为的影响。结果表明:焊点在低电流密度条件下蠕变时,其电阻波动大、寿命长,失效机制由蠕变过程主导,损伤逐渐累积导致最终失效;焊点在高电流密度条件下蠕变时,其电阻波动小、寿命短,电迁移作用缓解了焊点的初期蠕变损伤,但是加速了焊点后期脆性断裂失效。     

时效对Sn3.0Cu0.15Ni/Cu界面组织的影响

研究了150℃时效0,200,500h对Sn3.0Cu0.15Ni/Cu界面组织结构的影响.结果表明:界面金属间化合物层由Cu6Sn5层和Cu3Sn层组成,质量分数为0.15％的Ni的加入会使IMC层最初变厚,但在时效过程中,热稳定性强的界面化合物(Cu,Ni)6Sn5的生成,会抑制Cu3Sn化合物层的生长;同时Ni的加入会降低Cu6Sn5颗粒的长大速度,并且随着时效时间的延长,Cu6Sn5颗粒的形貌呈多面体结构.     

基板稀土微合金化对Sn3Ag0.5Cu/Cu钎焊界面反应的影响

研究了在Cu基板中加入质量分数1%的稀土元素Ce、Er后,与Sn3Ag0.5Cu(SAC305)无铅钎料进行钎焊并时效处理后的界面反应及其化合物(IMC)生长行为。结果表明:钎焊完成后,在SAC305/Cu钎焊界面只观察到Cu_6Sn_5,而SAC305/Cu-1Ce及SAC305/Cu-1Er界面还有Cu_3Sn形成;在时效处理过程中,纯Cu基板上的金属间化合物生长速率最快,Cu-1Ce基板次之,Cu-1Er基板最慢,且形成的IMC厚度也是依次递减;加入质量分数1%的Ce、Er元素对IMC生长均有抑制作用,且Er的抑制作用较Ce强。     

采用锡铅焊膏粘接的Sn—Ag—Cu BGA元件的焊点可靠性

在转向无铅电子产品过程中，元件供应商可能需要支持无铅和合铅元件的双线生产。而这可能合在生产制造中引起广泛的后勤问题。全部使用无铅元件是这个问题的一个解决方法。因此，用锡铅共晶焊膏粘接的Sn-Ag—Cu BGA元件的焊点可靠性需加讨论。在这篇论文中介绍了对两种无铅封装：超细间距BGA(VFBGA)和层叠式CSP(SCSP)的焊点可靠性评估结果，它们是应用锡铅共晶焊膏贴在PCB板上。而这些封装都是采用不同的回流曲线在标准的锡铅组装条件下组装的。采用合保温区或斜升区的热度曲线。回流峰值温度为208℃和222℃。组装后PCB(称为板级)进行温度循环(-40℃—125℃，每个循环30分钟)和落体实验。下面将会详细叙述失效分析。     

Ce对Sn-Ag-Cu系焊料合金的组织与性能影响

通过添加稀土Ce研究了Sn-3.0Ag-2.8Cu系焊料合金的显微组织和性能。用光学显微镜、SEM、EDX对其显微组织进行分析,并且对其导电性,润湿性,硬度等重要性能进行测试。结果表明,添加稀土w(Ce)为1%焊料合金的导电性明显提高;而润湿角明显减小,润湿性增强;同时焊料合金的硬度也有所增加。     

IMC生长对焊盘润湿性能的影响

无铅热风整平(又称:无铅喷锡)是适应市场无铅化要求的一种表面处理,近年来得到发展。热风整平工艺在完成后,焊盘Cu基与焊料已然形成金属间化合物(IMC),此界面对于后续焊接性能及焊点物理属性都有非常重要影响。业界对热风整平基板焊盘上IMC生长的研究报道较少。本文对此表面处理形成IMC层的影响及及生长模式进行了研究,发现IMC过度生长对焊盘在贴装过程中的润湿性能影响巨大,并对工艺中如何控制IMC生长做了进一步的探讨,以为业界同行参考。     

微量Ni对Sn-3.0Ag-0.5Cu钎料及焊点界面的影响

研究了Ni的含量对无铅钎料Sn-3.0Ag-0.5Cu润湿性、熔点、重熔及老化条件下界面化合物(IMC)的影响。结果表明:微量Ni的加入使SnAgCu润湿力增加6%;使合金熔点略升高约3℃;重熔时在界面形成了(Cu,Ni)6Sn5IMC层,且IMC厚度远高于SnAgCu/Cu的Cu6Sn5IMC厚度。在150℃老化过程中,SnAgCuNi/Cu重熔焊点IMC随着时间的增加,其增幅小于SnAgCu/Cu的增幅,此时Ni对IMC的增长有一定抑制作用。     

微合金化对Sn-9Zn基无铅钎料润湿性能的影响

熔炼制备了纯的以及含微量Al、Mg、Ti、Bi、重稀土Y、混合轻稀土RE和一种富P非金属活性组元NM的Sn-9Zn基合金,通过测量这些合金以及商用Sn-37Pb焊料在铜基板上的铺展面积比较了它们对铜的润湿性能。结果表明Al、Ti和 Mg不利于提高合金在铜上的润湿性或附着力;Y的改善作用不大;而Bi、RE和NM则能明显改善Sn-9Zn合金对铜的润湿性。在此基础上进一步研究了RE和NM含量对Sn-9Zn润湿性能的影响。以铺展面积衡量,本研究所达到的最佳改善效果使Sn-9Zn合金对铜的润湿性由Sn-37Pb焊料润湿性水平的45.4%提高到了70.3%。     

Properties of Sn3.8Ag0.7Cu Solder Alloy with Trace Rare Earth Element Y Additions

In the current research, trace rare earth (RE) element Y was incorporated into a promising lead-free solder, Sn3.8Ag0.7Cu, in an effort to improve the comprehensive properties of Sn3.8Ag0.7Cu solder. The range of Y content in Sn3.8Ag0.7Cu solder alloys varied from 0 wt.% to 1.0 wt.%. As an illustration of the advantage of Y doping, the melting temperature, wettability, mechanical properties, and microstructures of Sn3.8Ag0.7CuY solder were studied. Trace Y additions had little influence on the melting behavior, but the solder showed better wettability and mechanical properties, as well as finer microstructures, than found in Y-free Sn3.8Ag0.7Cu solder. The Sn3.8Ag0.7Cu0.15Y solder alloy exhibited the best comprehensive properties compared to other solders with different Y content. Furthermore, interfacial and microstructural studies were conducted on Sn3.8Ag0.7Cu0.15Y solder alloys, and notable changes in microstructure were found compared to the Y-free alloy. The thickness of an intermetallic compound layer (IML) was decreased during soldering, and the growth of the IML was suppressed during aging. At the same time, the growth of intermetallic compounds (IMCs) inside the solder was reduced. In particular, some bigger IMC plates were replaced by fine, granular IMCs.     

铜铟铋硫对Sn-Ag基无铅焊料性能的影响

研究了Cu、In、Bi、S元素对Sn-Ag基无铅焊料熔点和铺展性的影响。结果表明:Sn-Ag-Cu三元合金成分为95.5%Sn3.5%Ag1%Cu时具有较低熔点(215℃)和好的铺展性;加入适量的In可降低Sn-Ag合金的熔点和改善铺展性能;随w(Bi)的增加Sn-Ag-Bi三元合金的熔点降低、铺展性变好;Sn-Ag合金的熔点随w(S)的增加而升高,加入少量S能改善Sn-Ag合金的铺展性。     

Effect of Zn Addition on Interfacial Reactions Between Sn-4Ag Solder and Ag Substrates

In this study, the effect of Zn (Zn = 1 wt.%, 3 wt.%, and 7 wt.%) additions to Sn-4Ag solder reacting with Ag substrates was investigated under solid-state and liquid-state conditions. The composition and microstructure of the intermetallic compounds (IMCs) significantly changed due to the introduction of different Zn contents. In the case of Sn-4Ag solder with 1 wt.% Zn, a continuous Ag-Sn IMC layer formed on the Ag substrates; discontinuous Ag-Zn layers and Sn-rich regions formed on the Ag substrates under liquid-state conditions when the Sn-4Ag solders contained 3 wt.% and 7 wt.% Zn. If 3 wt.% Zn was added to Sn-4Ag solder, the Ag-Sn IMC would be transformed into a Ag-Zn IMC with increasing aging time. Rough interfaces between the IMCs and the Ag substrates were observed in Sn-4Ag-7Zn/Ag joints after reflowing at 260°C for 15 min; however, the interfaces between the IMCs and the Ag substrates became smooth for Sn-4Ag-1Zn/Ag and Sn-4Ag-3Zn/Ag joints. The nonparabolic growth mechanism of IMCs was probed in the Sn-4Ag-3Zn/Ag joints during liquid-state reaction, and can be attributed to the detachment of IMCs. On the other hand, the effect of gravity was also taken into account to explain the formation of IMCs at the three different interfaces (bottom, top, and vertical) during the reflow procedure.     

Joule Heating Enhanced Phase Coarsening in Sn37Pb and Sn3.5Ag0.5Cu Solder Joints during Current Stressing

This paper investigated the effect of Joule heating on the phase coarsening in Sn37Pb and Sn3.5Ag0.5Cu ball grid array (BGA) solder joints stressed at −5°C and 125°C with a 6.0 × 10² A/cm² electric current. The phase growth under current stressing was also compared with those under aging at 125°C. It was found that the current stressing produced a substantial Joule heating in the solder joints and conductive traces. Hence, the solder joints underwent a considerable temperature rise by 30–35°C when stressed at −5°C and 125°C in this study. Coarsening of Pb-rich and Ag-rich phases was confirmed to be accelerated by the current stressing as a result of enhanced diffusion at elevated temperature and atomic stimulation due to numerous collisions between electrons and atoms. Different controlling kinetics were suggested for the cases stressed or aged at different temperatures.     

无铅电子封装Sn-Cu焊料润湿性试验研究

为了改善无铅焊料的润湿性,配置活性剂松香焊剂和无机物焊剂,研究了Sn-0.75 Cu焊料的润湿性.分析讨论了影响Sn-0.75 Cu焊料润湿性的主要因素,获得了焊剂和Sn-0.75 Cu焊料的最优匹配.在镀锡铜片上,5#焊剂匹配Sn-0.75 Cu焊料能够获得最佳的润湿性(润湿角为18°),已接近Sn-37 Pb焊料的润湿性.     

Demonstration and Characterization of Sn-3.0Ag-0.5Cu/ Sn-57Bi-1Ag Combination Solder for 3-D Multistack Packaging

A combination solder of Sn-3.0Ag-0.5Cu (numbers are all in weight percent unless specified otherwise) wrapped by Sn-57Bi-1Ag was tested for application to three-dimensional (3-D) multistack packaging. The experimental variables controlled were the reflow peak temperatures (170, 185, 200, and 230°C), the reflow cycles (up to four times), and the mask which controls the amount of Sn-57Bi-1Ag solder paste (two sizes). We demonstrate and evaluate the combination solder structure, focusing on microstructural changes and the shear strength. The degree of mixing in the combination solder, which is enhanced by an increase in the reflow peak temperature, is independent of the number of reflow cycles. The ball shear strength and the lab shear strength both increased with increases in the reflow peak temperatures. This behavior is explained by the amount of the brittle Bi phase that constitutes the eutectic Sn-Bi phase.