Life cycle cost analysis of single slope hybrid (PV/T) active solar still

This paper presents the life cycle cost analysis of the single slope passive and hybrid photovoltaic (PV/T) active solar stills, based on the annual performance at 0.05 m water depth. Effects of various parameters, namely interest rate, life of the system and the maintenance cost have been taken into account. The comparative cost of distilled water produced from passive solar still (Rs. 0.70/kg) is found to be less than hybrid (PV/T) active solar still (Rs. 1.93/kg) for 30 years life time of the systems. The payback periods of the passive and hybrid (PV/T) active solar still are estimated to be in the range of 1.1–6.2 years and 3.3–23.9 years, respectively, based on selling price of distilled water in the range of Rs. 10/kg to Rs. 2/kg. The energy payback time (EPBT) has been estimated as 2.9 and 4.7 years, respectively.     

Optimization of number of collectors for integrated PV/T hybrid active solar still

The aim of this paper is to optimize the number of collectors for PV/T hybrid active solar still. The number of PV/T collectors connected in series has been integrated with the basin of solar still. The optimization of number of collectors for different heat capacity of water has been carried out on the basis of energy and exergy. Expressions of inner glass, outer glass and water temperature have been derived for the hybrid active solar system. For the numerical computations data of a summer day (May 22, 2008) for Delhi climatic condition have been used. It has been observed that with increase of the mass of water in the basin increases the optimum number of collector. However the daily and exergy efficiency decreases linearly and nonlinearly with increase of water mass. It has been observed that the maximum yield occurs at N = 4 for 50 kg of water mass on the basis of exergy efficiency. The thermal model has also been experimentally validated.     

Experimental study of condensation heat transfer of R-134a flow in corrugated tubes with different inclinations

This experimental study is performed to investigate condensation heat transfer coefficient of R-134a flow inside corrugated tube with different inclinations. Different inclinations of test condenser ranging from − 90^° to + 90^° and various flow mass velocities in the range of 87 to 253 [kg/m²s] are considered in this study. Data analysis showed that change in the tube inclination had a significant effect on condensation heat transfer behavior. At low mass velocities, and low vapor qualities, the highest condensation heat transfer coefficient was obtained for α = + 30^° which was 1.41 times greater than the least one obtained for α = − 90^°. The results also showed that at all mass velocities, the highest average heat transfer coefficients were achieved for α = + 30^°. Based on the experimental results, a new empirical correlation is proposed to predict the condensation heat transfer coefficient of R134a flow in corrugated tubes with different inclinations.     

Thermal property measurement and heat transfer analysis of acetamide and acetamide/expanded graphite composite phase change material for solar heat storage

As a phase change material (PCM), acetamide (AC) can be a potential candidate for energy storage application in the active solar systems. Its utilization is however hampered by poor thermal conductivity. In this work, AC/expanded graphite (EG) composite PCM with 10 wt% (mass fraction) EG as the effective heat transfer promoter was prepared; its thermal properties were studied and compared with those of pure AC. Transient hot-wire tests showed that the addition of 10 wt% EG led to about five-fold increase in thermal conductivity. Investigations using a differential scanning calorimeter revealed that the melting/freezing points shifted from 66.95/42.46 °C for pure AC to 65.91/65.52 °C for AC/EG composite, and the latent heat decreased from 194.92 to 163.71 kJ kg⁻¹. In addition, heat storage and retrieval tests in a latent thermal energy storage unit showed that the heat storage and retrieval durations were reduced by 45% and 78%, respectively. Further numerical investigations demonstrated that the less improvement in heat transfer rate during the storage process could be attributed to the weakened natural convection in liquid (melted) AC because of the presence of EG.     

Evaluation of phase change materials for thermal regulation enhancement of building integrated photovoltaics

Regulating the temperature of building integrated photovoltaics (BIPV) using phase change materials (PCMs) reduces the loss of temperature dependent photovoltaic (PV) efficiency. Five PCMs were selected for evaluation all with melting temperatures ∼25 ± 4 °C and heat of fusion between 140 and 213 kJ/kg. Experiments were conducted at three insolation intensities to evaluate the performance of each PCM in four different PV/PCM systems. The effect on thermal regulation of PV was determined by changing the (i) mass of PCM and (ii) thermal conductivities of the PCM and PV/PCM system. A maximum temperature reduction of 18 °C was achieved for 30 min while 10 °C temperature reduction was maintained for 5 h at −1000 W/m² insolation.     

SPEEK/epoxy resin composite membranes in situ polymerization for direct methanol fell cell usages

Sulfonated poly(ether ether ketone) (SPEEK)/4,4′-diglycidyl(3,3′,5,5′-tetramethylbiphenyl) epoxy resin (TMBP) composite membranes in situ polymerization were prepared for the purpose of improving the methanol resistance and mechanical properties of SPEEK membranes with high ion-exchange capacities (IEC) for the usage in the direct methanol fuel cells (DMFCs). The effects of introduction of TMBP content on the properties of the composite membranes were investigated in detail. The composite membranes have good mechanical, thermal properties, lower swelling ratio, lower water diffusion coefficient (0.87 × 10⁻⁵ cm² s⁻¹ at 80 °C) and better methanol resistance (5.26 × 10⁻⁷ cm² s⁻¹ at 25 °C) than SPEEK membranes. The methanol diffusion coefficients of the composite membranes are much lower than that of SPEEK membrane (17.5 × 10⁻⁷ cm² s⁻¹ at 25 °C). Higher selectivity was been found for the composite membranes in comparison with SPEEK. Therefore, the SPEEK/TMBP composite membranes show a good potential in DMFCs usages.     

Performance of a concentrated photovoltaic energy system with static linear Fresnel lenses

A new type of greenhouse with linear Fresnel lenses in the cover performing as a concentrated photovoltaic (CPV) system is presented. The CPV system retains all direct solar radiation, while diffuse solar radiation passes through and enters into the greenhouse cultivation system. The removal of all direct radiation will block up to 77% of the solar energy from entering the greenhouse in summer, reducing the required cooling capacity by about a factor 4. This drastically reduce the need for cooling in the summer and reduce the use of screens or lime coating to reflect or block radiation.All of the direct radiation is concentrated by a factor of 25 on a photovoltaic/thermal (PV/T) module and converted to electrical and thermal (hot water) energy. The PV/T module is kept in position by a tracking system based on two electric motors and steel cables. The energy consumption of the tracking system, ca. 0.51 W m⁻², is less than 2% of the generated electric power yield. A peak power of 38 W m⁻² electrical output was measured at 792 W m⁻² incoming radiation and a peak power of 170 W m⁻² thermal output was measured at 630 W m⁻² incoming radiation of. Incoming direct radiation resulted in a thermal yield of 56% and an electric yield of 11%: a combined efficiency of 67%. The annual electrical energy production of the prototype system is estimated to be 29 kW h m⁻² and the thermal yield at 518 MJ m⁻². The collected thermal energy can be stored and used for winter heating. The generated electrical energy can be supplied to the grid, extra cooling with a pad and fan system and/or a desalination system. The obtained results show a promising system for the lighting and temperature control of a greenhouse system and building roofs, providing simultaneous electricity and heat. It is shown that the energy contribution is sufficient for the heating demand of well-isolated greenhouses located in north European countries.     

Modelling airflow,heat transfer and moisture transport around a standing human body by computational fluid dynamics

In this study a combined computational model of a room with virtual thermal manikin with real dimensions and physiological shape was used to determine heat and mass transfer between human body and environment. Three dimensional fluid flow, temperature and moisture distribution, heat transfer (sensible and latent) between human body and ambient, radiation and convection heat transfer rates on human body surfaces, local and average convection coefficients and skin temperatures were calculated. The radiative heat transfer coefficient predicted for the whole-body was 4.6 W m^− 2 K^− 1, closely matching the generally accepted whole-body value of 4.7 W m^− 2 K^− 1. Similarly, the whole-body natural convection coefficient for the manikin fell within the mid-range of previously published values at 3.8 W m^− 2 K^− 1. Results of calculations were in agreement with available experimental and theoretical data in literature.     

An experimental study on energy generation with a photovoltaic (PV)–solar thermal hybrid system

A hybrid system, composed of a photovoltaic (PV) module and a solar thermal collector is constructed and tested for energy collection at a geographic location of Cyprus. Normally, it is required to install a PV system occupying an area of about 10 m² in order to produce electrical energy; 7 kWh/day, required by a typical household. In this experimental study, we used only two PV modules of area approximately 0.6 m² (i.e., 1.3×0.47 m²) each. PV modules absorb a considerable amount of solar radiation that generate undesirable heat. This thermal energy, however, may be utilized in water pre-heating applications. The proposed hybrid system produces about 2.8 kWh thermal energy daily. Various attachments that are placed over the hybrid modules lead to a total of 11.5% loss in electrical energy generation. This loss, however, represents only 1% of the 7 kWh energy that is consumed by a typical household in northern Cyprus. The pay-back period for the modification is less than 2 years. The low investment cost and the relatively short pay-back period make this hybrid system economically attractive.     

Highly conductive composites made of phase change materials and graphite for thermal storage

Conventional phase change materials (PCMs) are already well known for their high thermal capacity and constant working temperature for thermal storage applications. Nevertheless, their low thermal conductivity (around 1 W m⁻¹ K⁻¹) leads to low and decreasing heat storage and discharge powers. Up to now, this major drawback has drastically inhibited their possible applications in industrial or domestic fields. The use of graphite to enhance the thermal conductivity of those materials has been already proposed in the case of paraffin but the corresponding applications are restricted to low-melting temperatures (below 150 °C). For many applications, especially for solar concentrated technologies, this temperature range is too low. In the present paper, new composites made of salts or eutectics and graphite flakes, in a melting temperature range of 200-300 °C are presented in terms of stability, storage capacity and thermal conductivity. The application of those materials to thermal storage is illustrated through simulated results according to different possible designs. The synergy between the storage composite properties and the interfacial area available for heat transfer with the working fluid is presented and discussed.     

Adsorption refrigeration—An efficient way to make good use of waste heat and solar energy

This paper presents the achievements gained in solid sorption refrigeration prototypes since the end of the l970s, when interest in sorption systems was renewed. The applications included are ice making and air conditioning. The latter includes not only cooling and heating, but also dehumidification by desiccant systems. The prototypes presented were designed to use waste heat or solar energy as the main heat source. The waste heat could be from diesel engines or from power plants, in combined cooling, heating and power systems (CCHP). The current technology of adsorption solar-powered icemakers allows a daily ice production of between 4 and 7 kg m⁻² of solar collector, with a solar coefficient of performance (COP) between 0.10 and 0.16. The silica gel–water chillers studied can be powered by hot water warmer than 55 °C. The COP is usually around 0.2–0.6, and in some commercially produced machines, it can be up to 0.7. The utilization of such chillers in CCHP systems, hospitals, buildings and grain depots are discussed. Despite their advantages, solid sorption systems still present some drawbacks such as low specific cooling power (SCP) and COP. Thus, some techniques to overcome these problems are also contemplated, together with the perspectives for their broad commercialisation. Among these techniques, a special attention was devoted to innovative adsorbent materials, to advanced cycles and to heat pipes, which are suitable devices not only to improve the heat transfer but also can help to avoid corrosion in the adsorbers. Recent experiments performed by the research group of the authors with machines that employ composite adsorbent material and heat pipes showed that it is possible to achieve a SCP of 770 W kg⁻¹ of salt and COP of 0.39 at evaporation temperatures of −20 °C and generation temperature of 115 °C.     

Experimental investigation of heat transfer coefficient of R134a during condensation in vertical downward flow at high mass flux in a smooth tube

The two-phase heat transfer coefficients of pure HFC-134a condensing inside a smooth tube-in-tube heat exchanger are experimentally investigated. The test section is a 0.5 m long double tube with refrigerant flowing in the inner tube and cooling water flowing in the annulus. The inner tube is constructed from smooth copper tubing of 9.52 mm outer diameter and 8.1 mm inner diameter. The test runs are performed at average saturation condensing temperatures between 40–50 °C. The mass fluxes are between 260 and 515 kg m^− 2s^− 1 and the heat fluxes are between 11.3 and 55.3 kW m^− 2. The quality of the refrigerant in the test section is calculated using the temperature and pressure obtained from the experiment. The average heat transfer coefficient of the refrigerant is determined by applying an energy balance based on the energy transferred from the test section. The effects of heat flux, mass flux and condensation temperature on the heat transfer coefficients are also discussed. Eleven well-known correlations for annular flow are compared to each other using a large amount of data obtained from various experimental conditions. A new correlation for the condensation heat transfer coefficient is proposed for practical applications.     

Advancement in solar photovoltaic/thermal (PV/T) hybrid collector technology

This article presents an overview on the research and development and application aspects for the hybrid photovoltaic/thermal (PV/T) collector systems. A major research and development work on the photovoltaic/thermal (PVT) hybrid technology has been done since last 30 years. Different types of solar thermal collector and new materials for PV cells have been developed for efficient solar energy utilization. The solar energy conversion into electricity and heat with a single device (called hybrid photovoltaic thermal (PV/T) collector) is a good advancement for future energy demand. This review presents the trend of research and development of technological advancement in photovoltaic thermal (PV/T) solar collectors and its useful applications like as solar heating, water desalination, solar greenhouse, solar still, photovoltaic-thermal solar heat pump/air-conditioning system, building integrated photovoltaic/thermal (BIPVT) and solar power co-generation.     

Thermal performance of a commercial alkaline water electrolyzer: Experimental study and mathematical modeling

In this paper a study of the thermal performance of a commercial alkaline water electrolyzer (HySTAT from Hydrogenics) designed for a rated hydrogen production of 1 N m³ H₂/h at an overall power consumption of 4.90 kW h/N m³ H₂ is presented. The thermal behaviour of the electrolyzer has been analyzed under different operating conditions with an IR camera and several thermocouples placed on the external surface of the main electrolyzer components. It has been found that the power dissipated as heat can be reduced by 50–67% replacing the commercial electric power supply unit provided together with the electrolyzer by an electronic converter capable of supplying the electrolyzer with a truly constant DC current. A lumped capacitance method has been adopted to mathematically describe the thermal performance of the electrolyzer, resulting in a thermal capacitance of 174 kJ °C⁻¹. The effect of the AC/DC converter characteristics on the power dissipated as heat has been considered. Heat losses to the ambient were governed by natural convection and have been modeled through an overall heat transfer coefficient that has been found to be 4.3 W m⁻² °C⁻¹. The model has been implemented using ANSYS^® V10.0 software code, reasonably describing the performance of the electrolyzer. A significant portion of the energy dissipated as heat allows the electrolyzer operating at temperatures suitable to reduce the cell overvoltages.     

Performance of a solar chimney

A mathematical model of a solar chimney was proposed in order to predict its performance under varying ambient and geometrical features. Steady state heat transfer equations were set up using a thermal resistance network and solved using matrix inversion. Existing correlations of heat transfer coefficients were utilised. Property values for the air flow in the duct were based on mean bulk or film temperatures. The performance of the chimney was evaluated by predicting the temperatures of the glass glazing and the heat-absorbing wall and also the temperature and velocity of the induced air flow in the chimney. The effects of air gap and solar radiation intensity on the performance of different chimneys were investigated. In order to verify the theoretical model, experiments were conducted on a 2 m high×0.45 m wide physical model with air gaps of 0.1, 0.2 and 0.3 m. Experiments were carried out outdoors on the roof and the experimental model exposed to both direct and diffuse solar radiation. Air velocities between 0.25 m s⁻¹ and 0.39  m s⁻¹ for radiation intensity up to 650 W m⁻² were obtained. No reverse air flow circulation was observed even at the large gap of 0.3 m.     

Thiocyanate ligand substitution kinetics of the solar cell dye Z-907 by 3-methoxypropionitrile and 4-tert-butylpyridine at elevated temperatures

The dye-sensitized solar cell dye Z-907, [RuLL′(NCS)₂] may loose a thiocyanate ligand at elevated temperatures (80-100 °C) by ligand exchange with the solar cell additive 4-tert-butylpyridine (4-TBP) or the electrolyte solvent 3-methoxypropionitrile (3-MPN). The mechanism in homogeneous solution proceeds via three equilibrium reactions Eqs. (1)-(3) with the solvent complex [RuLL′(NCS)(3-MPN)] as an intermediate:[RuLL′(NCS)₂]+3-MPN=[RuLL′(NCS)(3-MPN)]⁺+NCS⁻ (1)[RuLL′(NCS)(3-MPN)]⁺+4-TBP=[RuLL′(NCS)(4-TBP)]⁺+3-MPN (2)[RuLL′(NCS)₂]+4-TBP=[RuLL′(NCS)(4-TBP)]⁺+NCS⁻ (3)A similar mechanism describes the heterogeneous substitution reactions of Z-907 attached to the surface of TiO₂ particles with 3-MPN and 4-TBP. All the six homogeneous and heterogeneous rate constants were obtained at 100 °C by monitoring the decay of Z-907 and product formation in test-tube experiments by HPLC coupled to UV/vis and electrospray mass spectrometry.A half-lifetime t_1/2=150 h was obtained for the Z-907 dye bound to TiO₂ nanocrystalline particles at 85 °C in the presence of 4-TBP and 3-MPN. Dye-sensitized solar cells (DSC) with Z-907 as a sensitizer and application of the so-called “non-robust” electrolytes containing 4-TBP and 3-MPN is therefore not expected to be able to pass a 1000 h thermal stress test at 85 °C. Addition of thiocyanate to the cell electrolyte may however, eliminate or reduce the problems caused by dye thiocyanate ligand substitution in DSC cells.     

Convective boiling heat transfer characteristics of CO2 in microchannels

Convective boiling heat transfer coefficients and dryout phenomena of CO₂ are investigated in rectangular microchannels whose hydraulic diameters range from 1.08 to 1.54 mm. The tests are conducted by varying the mass flux of CO₂ from 200 to 400 kg/m² s, heat flux from 10 to 20 kW/m², while maintaining saturation temperature at 0, 5 and 10 °C. Test results show that the average heat transfer coefficient of CO₂ is 53% higher than that of R134a. The effects of heat flux on the heat transfer coefficient are much significant than those of mass flux. As the mass flux increases, dryout becomes more pronounced. As the hydraulic diameter decreases from 1.54 to 1.27 mm and from 1.27 to 1.08 mm at a heat flux of 15 kW/m² and a mass flux of 300 kg/m² s, the heat transfer coefficients increase by 5% and 31%, respectively. Based on the comparison of the data from the existing models with the present data, the Cooper model and the Gorenflo model yield relatively good predictions of the measured data with mean deviations between predicted and measured data of 21.7% and 21.2%, respectively.     

Effects of solar photovoltaic panels on roof heat transfer

Indirect benefits of rooftop photovoltaic (PV) systems for building insulation are quantified through measurements and modeling. Measurements of the thermal conditions throughout a roof profile on a building partially covered by solar photovoltaic (PV) panels were conducted in San Diego, California. Thermal infrared imagery on a clear April day demonstrated that daytime ceiling temperatures under the PV arrays were up to 2.5 K cooler than under the exposed roof. Heat flux modeling showed a significant reduction in daytime roof heat flux under the PV array. At night the conditions reversed and the ceiling under the PV arrays was warmer than for the exposed roof indicating insulating properties of PV. Simulations showed no benefit (but also no disadvantage) of the PV covered roof for the annual heating load, but a 5.9 kWh m⁻² (or 38%) reduction in annual cooling load. The reduced daily variability in rooftop surface temperature under the PV array reduces thermal stresses on the roof and leads to energy savings and/or human comfort benefits especially for rooftop PV on older warehouse buildings.     

Numerical study on thermal energy storage performance of phase change material under non-steady-state inlet boundary

Due to the solar radiation intensity variation over time, the outlet temperature or mass flow rate of heat transfer fluid (HTF) presents non-steady-state characteristics for solar collector. So, in the phase change thermal energy storage (PCTES) unit which is connected to solar collector, the phase change process occurs under the non-steady-state inlet boundary condition. In present paper, regarding the non-steady-state boundary, based on enthalpy method, a two dimensional physical and mathematical model for a shell-and-tube PCTES unit was established and the simulation code was self-developed. The effects of the non-steady-state inlet condition of HTF on the thermal performance of the PCTES unit were numerically analyzed. The results show that when the average HTF inlet temperature in an hour is fixed at a constant value, the melting time (time required for PCM completely melting) decreases with the increase of initial inlet temperature. When the initial inlet temperature increases from 30 °C to 90 °C, the melting time will decrease from 42.75 min to 20.58 min. However, the total TES capacity in an hour reduces from 338.9 kJ/kg to 211.5 kJ/kg. When the average inlet mass flow rate in an hour is fixed at a constant value, with the initial HTF inlet mass flow rate increasing, the melting time of PCM decreases. The initial inlet mass flow rate increasing from 2.0 × 10⁻⁴ kg/s to 8.0 × 10⁻⁴ kg/s will lead to the melting time decreasing from 37.42 min to 23.75 min and the TES capacity of PCM increasing from 265.8 kJ/kg to 273.8 kJ/kg. Under all the studied cases, the heat flux on the tube surface increases at first, until it reaches a maximum then it decreases over time. And the larger the initial inlet temperature or mass flow rate, the earlier the maximum value appearance and the larger the maximum value.