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《化学推进剂与高分子材料》2018,(6)
通过驻波管传递函数法测试了不同条件下汽车顶棚用热塑性半硬质聚氨酯泡沫的吸声性能。研究结果表明:泡沫吸声系数随密度增加而提高;泡沫厚度对中低频区吸声性能影响较大,吸声系数随厚度增加而提高;高异氰酸酯指数情况下泡沫吸声性能较好;硅藻土的引入可有效提高泡沫的吸声性能;高回弹聚氨酯泡沫与半硬质聚氨酯泡沫复合且高回弹聚氨酯泡沫为吸声面时吸声效果较好。 相似文献
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聚氨酯泡沫材料吸声频率特性研究 总被引:1,自引:0,他引:1
聚氨酯泡沫材料是目前应用较多的一种多孔性吸声材料,其吸声性能不仅与泡孔结构等材料本身性质有关,还与吸声结构和实际使用安装状态有关。本研究主要研讨了研制聚氨酯泡沫及其吸声结构板材的吸声频率特性。研究结果表明,(1)研制聚氨酯泡沫吸声材料具有优良的吸声性能,50mm厚时所测得100-5000HZ范围内的驻波管法平均吸声系数可达到0.51;(2)利用共振吸声原理来组装聚氨酯泡沫芯吸声结构可有效地调节材料的吸声频率特性;(3)在聚氨酯泡沫芯吸声结构中,将泡沫芯做成狭缝结构和尖劈结构,还可进一步拓展其吸声频率特性。 相似文献
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汽车隔音垫用聚氨酯软质高回弹泡沫的吸音性能研究 总被引:1,自引:0,他引:1
通过驻波管法测试不同隔音垫聚氨酯软质高回弹泡沫的吸声系数,结合显微镜对泡沫的力学特性和形态进行观察和分析。研究结果表明,泡沫在低频区的吸声系数随厚度的增加而提高,而在高频区则有所减弱;泡沫的吸声系数随密度增加而提高;泡孔形态对泡沫的吸声性能有显著影响,细密而均一的泡孔有利于声能的吸收;不同异氰酸酯由于反应性和结构上的差异,泡沫也表现出不同的吸声特性;高压发泡生产的泡沫峰值吸声频率稍向高频区移动,复合乙烯–醋酸乙烯共聚弹性体(EVA)后泡沫的峰值吸声频率稍向低频区移动。 相似文献
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Soybean meal (SM), an abundant biomass resource, was used as the surrogate to partially replace polyols in rigid polyurethane foam synthesis. Compared with polyurethanes based on other soybean‐based resources, such as soybean protein isolate (SPI), polyurethane foams based on activated SM showed better thermal and mechanical properties. The amount of SM in the final polyurethane foams can be as high as 30 wt % (base on the total weight of foam), which dramatically decreases the cost of the foams. The results also showed that SM played a vital role in improving the foam properties, which could be attributed to the participation of the functional groups in SM in the polyurethane foam synthesis. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献
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水声吸声材料常用于水下航行体表面,其研究对于水下目标的声隐身设计具有重要意义,在军事应用领域受到广泛关注。橡胶类和聚氨酯类粘弹性高分子材料因其独特的分子结构和可设计性得到广泛应用,此外吸声材料的结构设计对其性能也有着很大影响。本文在水声吸声材料吸声机理的基础上,对其主要材料体系和吸声结构进行了综述。 相似文献
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Min Zhu Sanchita Bandyopadhyay‐Ghosh Mustafa Khazabi Hui Cai Mohini Sain 《应用聚合物科学杂志》2012,124(6):4702-4710
Water‐blown rigid polyurethane foams from soy‐based polyol were prepared and their structure–property correlations investigated. Cellulose microfibers and nanoclays were added to the formulations to investigate their effect on morphology, mechanical, and thermal properties of polyurethane foams. Physical properties of foams, including density and compressive strength, were determined. The cellular morphologies of foams were analyzed by SEM and X‐ray micro‐CT and revealed that incorporation of microfibers and nanoclays into foam altered the cellular structure of the foams. Average cell size decreased, cell size distribution narrowed and number fractions of small cells increased with the incorporation of microfibers and nanoclays into the foam, thereby altering the foam mechanical properties. The morphology and properties of nanoclay reinforced polyurethane foams were also found to be dependent on the functional groups of the organic modifiers. Results showed that the compressive strengths of rigid foams were increased by addition of cellulose microfibers or nanoclays into the foams. Thermogravimetric analysis (TGA) was used to characterize the thermal decomposition properties of the foams. The thermal decomposition behavior of all soy‐based polyurethane foams was a three‐step process and while the addition of cellulose microfibers delayed the onset of degradation, incorporation of nanoclays seemed to have no significant influence on the thermal degradation properties of the foams as compared to the foams without reinforcements. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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Liquefaction of waste paper (WP) was conducted in the presence of polyhydric alcohols to prepare biodegradable polyurethane foam. The liquefied‐WP‐based polyol had suitable characteristics such as apparent molecular weight, hydroxyl value, and viscosity for the preparation of rigid polyurethane foam and was successfully applied to produce polyurethane foam with the appropriate combinations of foaming agents. The obtained foams showed satisfactory densities and mechanical properties as good as those of foams obtained from liquefied wood‐ and starch‐based polyols. The foams had almost the same thermal stability at initial weight loss and seemed to be potentially biodegradable because they were degraded to some extent in leaf mold. There were no mutagens or carcinogens in the water extracts of the foams. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1482–1489, 2002 相似文献
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G. Harikrishnan 《Carbon》2007,45(3):531-535
Reticulated vitreous carbon foams were prepared by carbonizing polyurethane precursor foams which were first infused with furfuryl alcohol. The cell size and the fraction of open cells of the precursor foam were controlled by the addition of clay in the polyurethane foam formulation. Addition of clay permitted control of the cell size of carbon foams. The higher open cell content in foams with clay permitted uniform infusion of furfuryl alcohol in the precursor, and thus more uniform carbon foams of higher density. These foams had a lower electrical resistance as compared to foams without clay. 相似文献
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聚氨酯泡沫塑料在低密度炸药制备中的应用 总被引:1,自引:0,他引:1
以软质聚氨酯泡沫塑料为载体,制备低密度炸药。探讨了聚氨酯泡沫塑料在低密度炸药中的应用。简单介绍了采用炸药溶液浸渍法、水分散液浸泡法和原料混合发泡法这三种方法的工艺过程以及产品的爆炸性能。 相似文献
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Halogen-free flame-retardant rigid polyurethane foams were prepared using the combination of SiO2 nanospheres/graphene oxide hybrid and a phosphorus-containing flame retardant, dimethyl methylphosphonate. The flame retardancy, mechanical, and thermal properties of flame-retardant rigid polyurethane foams containing dimethyl methylphosphonate and SiO2 nanospheres/graphene oxide were investigated. The results demonstrated that the combination of dimethyl methylphosphonate and SiO2 nanospheres/graphene oxide enhanced flame retardant and mechanical properties of rigid polyurethane foam greatly compared with pure rigid polyurethane foam and dimethyl methylphosphonate-modified foam. Morphological study indicated that the partial substitution of dimethyl methylphosphonate with SiO2 nanospheres/graphene oxide led to smaller cell sizes and more uniform cell sizes of dimethyl methylphosphonate-modified rigid polyurethane foams. 相似文献
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以聚氨酯泡沫为模板,糠醇为碳源,采用模板法制得块状泡沫炭材料,扫描电镜(SEM)观察发现:产品是由大孔组成的、具有网状结构的多孔材料。研究了不同炭化终温对产品形貌、残炭率和体积收缩率的影响;考察了对模板聚氨酯泡沫进行NaOH水解预处理的条件,即水解时间、水解温度和碱液浓度对模板及产品结构的影响。结果表明,模板的预处理去除了聚氨酯泡沫闭孔上的隔膜,提高了泡沫的浸渍能力,制得了具有更高开孔率、残炭率以及体密度的产品,说明模板预处理是改善产品结构和性能的有效手段。 相似文献
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讨论了影响聚氨酯硬质泡沫塑料强度的重要因素,并介绍了聚氨酯硬质泡沫塑料的增强技术,重点综述了混杂增强和纳米增强的研究进展。 相似文献