共查询到17条相似文献,搜索用时 140 毫秒
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以 2 ,2′ -双 ( 2 -唑啉 ) (BOZ)为扩链剂 ,对聚对苯二甲酸丁二醇酯 (PBT)进行扩链改性 ,考察了反应时间、扩链剂用量对扩链效果的影响 ,测试了扩链后PBT的热失重、力学性能和DSC。结果表明 ,BOZ的用量为 0 .44 % ,反应时间 3~ 5min ,PBT的最大扩链效率可达 72 .9% ,PBT的特性粘数从 0 .83dL/g提高到 1.2 1dL/ g ,扩链后PBT热稳定性和力学性能都得到提高。 相似文献
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分别加入羧基加成型的双噁唑啉(BOZ)和羟基加成型的均苯四甲酸酐(PMDA)为扩链剂,考察了反应挤出前后PET特性黏度([η])和羧基值的变化情况。实验结果表明:BOZ的扩链效果不明显;PMDA能较大程度地提高PET的[η],但产品羧基值较高;BOZ和PMDA联用可得到高[η]低羧基值的产品,扩链效果最佳。当挤出机工艺条件为:反应段温度260℃、螺杆转速45 r/min、反应段压力1 kPa、BOZ和PMDA质量分数均为0.2%时,可得到[η]为0.90 dL/g,羧基值为25 mol/t的PET产品。 相似文献
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从扩链剂用量、反应时间分别研究了2,2一双(2-噁唑啉)(BOZ)与2,2-(1,3-苯撑)-双(2-噁唑啉)(PBO)对回收的聚对苯二甲酸乙二醇酯(PET)的扩链效果。结果表明:扩链剂量为理论量的3倍,反应时间为4~6rain时获得最大扩链效果。其中BOZ对PET特性黏数的提高效果较好,从0.61提高到0.80。利用红外差减光谱分析了BOZ与PET的扩链反应前后的结构变化,酰胺基团出现以及酯基增加、羧基减少证实了扩链反应的发生;而五元环的存在则表明反应过程是分两步进行的。利用差示扫描量热分析仪分析了残余扩链剂对产物热性能的影响;当扩链剂的添加量较低时,熔融过程中产物的相对分子质量进一步提高,结晶度下降;而当扩链剂添加量较高时,相对分子质量反而下降,结晶度上升。 相似文献
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2,2-双(2-噁唑啉)改性回收PET的研究 总被引:5,自引:0,他引:5
以扩链剂2,2-双(2-噁唑啉)对回收PET进行扩链增粘,从特性粘度和羧值的变化考察了其扩链效果,并用DSC法研究了不同添加量噁唑啉对PET热性能的影响。结果表明:双噁唑啉对PET有一定的扩链效果,且影响PET的冷结晶行为。 相似文献
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高特性粘度聚酯的研究—化学增粘法 总被引:4,自引:0,他引:4
合成了对聚酯树酯端基具有活性的扩链剂BOZ,研究了对聚对苯二甲酸乙二酯(PET)和聚对苯二甲酸丁二酯(PBT)的扩链反应过程,扩链反应时间和扩链剂用量等对特性粘度的影响。实验结果表明:合成的扩链剂对PET和PBT能起扩链增粘作用,使分子量提高。可得到特性粘度0.98的PET树脂和特性粘度1.62的PBT树脂。 相似文献
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分别使用均苯四甲酸二酐(PMDA)、环氧树脂及两者的混合物作为回收PET瓶的扩链剂,利用反应挤出技术在同向双螺杆挤出机中反应,研究回收PET瓶烘干时间、扩链剂种类、扩链剂用量对PET产物的特性粘度、端羧基的质量摩尔浓度的影响。实验结果表明:均苯四甲酸二酐(PMDA)和环氧树脂均对PET有一定的扩链作用,且二者合用时扩链效果更佳,反应后PET的特性粘度由0.45dl/g提高到0.58dl/g,摩尔质量也显著提高;随着干燥时间增加,改性的回收PET样品的特性粘度增加的幅度较大;其中单独使用环氧树脂为扩链剂时,可以使反应后的PET端羧基的质量摩尔浓度显著下降。 相似文献
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用超支化聚硅氧烷修饰纳米SiO2粒子(HBPSi-SiO2),将其加入到苯并恶嗪(BOZ)树脂中制备了BOZ/HBPSi-SiO2复合材料,并与普通处理的纳米SiO2(Nano-SiO2)进行比较,研究了该复合材料的摩擦性能。结果表明,HBPSi-SiO2具有比Nano-SiO2更优异的减摩抗磨效果。相对于纯BOZ树脂,BOZ/Nano-SiO2复合材料的磨损率降低了59.4%,而BOZ/HBPSi-SiO2复合材料的磨损率降低了87.2%,摩擦系数也有所降低。 相似文献
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Haihua Yang Jinghong Ma Wengang Li Borun Liang Yihua Yu 《Polymer Engineering and Science》2002,42(8):1629-1641
Reactive blending of poly(ethylene terephthalate)/poly(ethylene naphthalene 2,6dicarboxylate) with addition of 2,2'‐bis(1,3‐oxazoline) (BOZ) has been studied under various mixing conditions for the different compositions. The transesterification level, the sequence length of both PET and PEN short blocks, and the degree of randomness were estimated using1H NMR. The results indicate that both mixing time and temperature are the primary factors controlling the transesterification, while the chain extender BOZ can significantly accelerate the transesterification between PET and PEN at 275°C. The composition also, to some extent, influences the transerification level as the mixing time is increased. As a consequence of transesterification proceeding, the sequence structures of the reactive blends are also markedly changed, which corresponds to a transfer from an initial block structure to a multiblock structure with higher randomness. The change in the microstructure of the reactive blends has also been analyzed by a Bernoullian statistics model. The effect of the BOZ on the intrinsic viscosity of the reactive blends is discussed. 相似文献
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Giorgio Giannotta Riccardo Po' Nicoletta Cardi Elena Tampellini Ernesto Occhiello Fabio Garbassi Luigi Nicolais 《Polymer Engineering and Science》1994,34(15):1219-1223
Processing of virgin and recycled poly(ethylene terephthalate) (PET) in a twin screw extruder evidences the degradative effect caused by thermal decomposition of poly(vinyl chloride) (PVC) and other impurities, e.g. adhesives, at the processing temperature. Lower melt viscosity and molecular weight, along with higher carboxylic end group concentration, were observed for recycled PET, the extent depending on PET purity. In an attempt to investigate the correlation between the kinetics of degradation phenomena and the level of thermomechanical stress, a novel dynamic method of evaluating thermal stability in processing conditions was developed. Such a method allows the achievement of long equivalent residence times while using lab-scale extruders. As a result of these experiments, PVC-rich recycled PET was shown to reach very low melt viscosity after less than 10 min in processing conditions, while virgin PET retained high viscosity even after 30 min. 相似文献
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Sonia Japon Yves Leterrier Jan‐Anders E. Mnson 《Polymer Engineering and Science》2000,40(8):1942-1952
The increase of the elongational viscosity of recycled poly(ethylene terephthalate) (PET) is investigated with the aim of producing closed‐cell foams by means of a cost‐effective reactive extrusion technique. A recycled PET grade containing controlled contamination levels of polyvinyl chloride (PVC) and poylethylene (PE) is selected, and compared with virgin bottle‐grade PET as a reference. Reactive processing with a tetrafunctional epoxy additive induces randomly branched molecules with a lower degree of branching in recycled PET than in virgin PET, as shown by a molecular structure analysis. The corresponding increase in elongational viscosity is related to foaming experiments performed using supercritical CO2 in a pressurized vessel. Observations of foam microstructures reveal that modified virgin PET forms closed‐cell structures under a large variety of foaming conditions, as opposed to unmodified virgin and recycled PET, which collapse as a result of insufficient elongational resistance. Closed‐cell foams are also obtained using modified recycled PET, providing that the temperature at which the pressure is released is lowered to 260°. Recycling of PET into closed‐cell foams is thus achieved, although the processing window is slightly reduced compared to virgin PET. 相似文献