Efficiency of HCl- and H2SO4-acidulated rock phosphates for a rice based cropping system

Pot experiments were conducted with an acid laterite soil and a shallow black calcareous soil to study the effect of initial application of North Carolina and Udaipur rock phosphates, acidulated with HCl or H₂SO₄ to the extent of 25, 50, 75 or 100% of the requirement for complete conversion into superphosphate, on the grain yield and P uptake by crops in rice—wheat and wheat—rice cropping sequences. The products obtained on acidulation with HCl or H₂SO₄ at a given degree behaved similarly. Rock phosphates partially acidulated with HCl or H₂SO₄ to 50–75% could be used successfully for growing rice or wheat on both the soil types. In the rice—wheat sequence, the wheat crop following rice gave very low grain yields compared to the wheat crop in the wheat—rice rotation, while in the wheat—rice rotation the rice crop following wheat gave yields comparable to that of rice in the rice—wheat rotation. The reasons for this differential effect have been made plausible. The studies indicate that a 50–75% H₂SO₄ - or HCl-acidulated rock phosphate may be used as a single application to an upland crop in an upland crop—rice rotation especially on acid soils, where the water soluble fractions of the product are used by the wheat crop. During the process of growth of the upland crop under aerobic soil conditions, the citrate soluble and insoluble fractions undergo such transformations that make it possible for the following rice crop to utilize them under waterlogged conditions.     

Effectiveness of partially acidulated phosphate rock as a source to plants in calcareous soils

In a series of greenhouse experiments granulated phosphate fertilizers prepared by mixing triple superphosphate with phosphate rock and partially acidulated phosphate rock, ranging in their content of water souble P from 95 to 17 per cent of total P were applied to neutral and slightly alkaline (pH 6.9–7.8), sandy loam to clay soils ranging in calcium carbonate content from 2 to 35 percent. Dry matter yield of clover, alfalfa, millet or maize were obtained, P uptake determined and sodium bicarbonate extractable P in soil measured. In one field experiment triple superphosphate was compared to mixture of triple superphosphate and phosphate rock on maize. X ray difraction on one triple superphosphate — phosphate rock mixture and on one partially acidulated phosphate rock showed that both fertilizers contain mainly monocalcium phosphate and fluorapatite. After incubation in soil the dicalcium phosphate content rose and the monocalcium phosphate disappeared.Parameters received in greenhouse experiments and in the field indicate that phosphate fertilizers composed of superphosphate and up to 50 percent phosphate rock are as efficient source of P to plants on calcareous and slightly alkaline soils as superphosphate. If this indication would be proven in extensive field experimentation it would lead to savings in acid consumption and in fertilizer manufacturing plant capacity for calcareous soils.     

Reactive rock phosphate fertilizers and soil testing for phosphorus: The effect of particle size of the rock phosphate

North Carolina rock phosphate (NCRP) (highly carbonate—substituted apatite) was ground to produce three samples with different particle size distributions. The effectiveness of these fertilizers was compared with the effectiveness of superphosphate in a field experiment and three glasshouse experiments using lateritic soils from south-western Australia. Non-reactive Queensland rock phosphate (low carbonate-substituted apatite from the Duchess deposit) was also used in the pot experiments. Bicarbonate-soluble phosphorus extracted from the soil is widely used in Western Australia to predict plant yields from previously-applied fertilizer dressings. For both field and pot experiments bicarbonate-extractable phosphorus (soil test value) was measured and related to subsequent plant yields.As calculated from the initial slope of the relationship between yield and the level of P applied, finely powdered NCRP was about 5–32% as effective as freshly-applied superphosphate in the year of application and also for two years after application in the field experiment, and for two successive crops in the three pot experiments. For both field and pot experiments, finely powdered NCRP, was at best, 1.5–2.0 times as effective as granular NCRP. Relative to freshly-applied superphosphate, the effectiveness of rock phosphates usually decreased with increasing level of application.For each of the crops in the field experiment, the relationships between yield and phosphorus content of plants (i.e. internal efficiency curves) were similar for all fertilizers. Thus the low effectiveness of the rock phosphates relative to superphosphate was solely due to much less phosphorus being taken up by plants. By contrast, in the pot experiments internal efficiency curves differed for different fertilizers. This is attributed to differences in the rate of phosphorus uptake by plant roots during the early stages of plant growth.For both field and pot experiments, soil test calibrations (the relationship between yield and soil test value) differed for rock phosphates and superphosphate. For superphosphate, soil test calibrations also differed for the three different years after the initial application of this fertilizer in the field experiment. For the second crop in the pot experiment, soil test calibrations differed for superphosphate applied at different times (before the first and the second crop). These results point out the difficulty of applying soil testing procedures to soils that have experienced different histories of fertilizer application.     

Evaluation of two rock phosphates and a calcined rock phosphate as maintenance fertilizers for crop — pasture rotations in Western Australia

Two long-term (11 and 12 y) field experiments in south-western Australia are described that measured the relative effectiveness of three rock phosphate fertilizers (C-grade ore, Calciphos and Queensland (Duchess) rock phosphate), single, double and triple superphosphate. The experiments were on established subterranean clover (Trifolium subterraneum) — based pasture that had received large, yearly, applications of single superphosphate for many years before the experiments began so that in the first year the nil phosphorus (P) treatment produced 80 to 90% of the maximum yield. The experiments were conducted using a rotation of one year cereal crop (oats,Avena sativa at one site, and barley,Hordeum vulgare, at the other): 2 y pasture, a typical rotation on farms in the region. Five levels of each P fertilizer were applied every third year with the crop. Grain yield of cereals, P content of grain, pasture yield, and bicarbonate-soluble P extracted from the soil (available P) were used to estimate fertilizer effectiveness values.The three superphosphate fertilizers had identical values of fertilizer effectiveness. Superphosphate was always the most effective fertilizer for producing grain. The rock phosphate fertilizers were one-seventh to one-half as effective per kg P as superphosphate when assessed on the yield or P content (P concentration × yield) of grain within each cropping year. Bicarbonate-extractable soil P values demonstrated that superphosphate was two to fifteen times as effective as the rock phosphate fertilizers. The relationship between grain yield and P content in grain (i.e. the internal efficiency of P use curve) was similar for the different P fertilizers. Thus for all P fertilizers yield was not limited by other factors as it varied solely in response to the P content, which in turn presumably depended on the P supply from the fertilizers.The relative agronomic effectiveness of rock phosphates is greater for marginally P deficient soils than for highly P deficient soils but rock phosphate remains less effective than superphosphate. We conclude that the rock phosphates studied should not be substituted for superphosphate as maintenance fertilizers for soils in Western Australia that are marginally deficient in P. This result is consistent with the results of many field experiments on highly P deficient soils in south-western Australia. These have shown that a wide variety of rock phosphate fertilizers are much less effective than superphosphate in both the short and long term.     

Effectiveness of two partially acidulated rock phosphates,coastal superphosphate and Ecophos,compared with North Carolina reactive rock phosphate and superphosphate

The effectiveness of coastal superphosphate, a partially acidulated rock phosphate (PARP) made from apatite, and Ecophos, a PARP made from calcium iron aluminium (crandallite millisite) rock phosphate, was compared in pot experiments with the effectiveness of ordinary superphosphate (OSP) and North Carolina reactive apatite rock phosphate (NCRP). There were three experiments using different lateritic soils collected in Western Australia. Fertilizer effectiveness was measured using yield of dried wheat (Triticum aestivum) tops grown for 28 days. Three successive crops were grown. The phosphorous (P) fertilizers were applied and mixed with the soils before sowing the first crop. In addition, OSP was added to extra pots before sowing crops 2 and 3 in order to measure the effectiveness of the original P fertilizers relative to freshly-applied OSP for these crops.As measured using plant yield, coastal superphosphate was the most effective P fertilizer for three crops on an acidic peaty sand (pH water 5.0). Relative to freshly-applied OSP, it was 154% as effective for crop 1, 75% as effective for crop 2, and 36% as effective for crop 3. Corresponding values for Ecophos were 44, 29 and 19%, and for NCRP, 77, 67 and 29%, with the original OSP treatment being 61 and 56% as effective for crops 2 and 3. For three crops on a lateritic gravel loam (pH 6.5), both coastal superphosphate and OSP were the most effective fertilizers, and were equally effective for crop 1, and relative to freshly-applied OSP, were about 31% as effective for crop 2, and 16 and 21 % as effective for crop 3. Corresponding values for Ecophos were 47,15 and 11%, and NCRP, 33,15 and 5%. For two crops in a loamy sand (pH 5.4), OSP was the most effective fertilizer, and, relative to fresh OSP, it was 36% as effective for crop 2. Relative to fresh OSP, the effectiveness for crops 1 and 2 of coastal superphosphate was 57 and 18%, for Ecophos 71 and 27%, and for NCRP 50 and 36%.     

Phosphorus availability to irrigated lowland rice as affected by sources,application level and green manure

To evaluate alternative fertilizer phosphorus (P) sources in lowland rice, two field experiments were conducted under irrigated conditions in Quezon Province, Philippines during 1990–1991 crop year. In another field experiment fertilizer P recycling through a green manure crop applied in the succeeding rice, was studied. Addition of fertilizer P increased grain yield by 1.5–2.0 t/ha (46%) in 1990 wet season (WS) and by 1.6–2.1 t/ha (56%) in 1991 dry season (DS). However, fertilizer P source and application level did not effect grain yield significantly. Results indicated that the less water-soluble and less expensive partially acidulated phosphate rock (PAPR), phosphate rock (PR) and less reactive PR were as effective as the more soluble but more expensive triple superphosphate (TSP). The relative effectiveness (RE) of local guano was significantly lower than that of other sources of fertilizer P. Fertilizer P applied to a pre-rice Sesbania rostrata green manure increased rice grain yield by 1.5–1.9 t/ha during 1991 DS. Further, S. rostrata fertilized with Morocco phosphate rock (MPR) gave significantly higher rice grain yield than did rice fertilized with MPR applied alone. In the P source experiments Olsen method and Pi correlated better with growth attributes than Bray 2 P. Phoshours uptake did not differ significantly among P sources and levels. Results suggest that P uptake was improved with green manuring. Correlation analyses revealed a close correlation between P uptake and dry matter yield and P uptake and grain yield.     

Effectiveness of different phosphatic fertilizers measured using labelled superphosphate and phosphorus taken up by plants

The agronomic effectiveness of three P fertilizers (diamonium phosphate, rock phosphate and compost) was studied in a greenhouse experiment using wheat. A radioisotopic method, using triple superphosphate labelled with³²P, was used to evaluate the P in dried tops that was derived from i) the soil, ii) labelled superphosphate and iii) the fertilizer being studied.The ratio between P uptake from each fertilizer and P uptake from the soil was used to compare the effectiveness of the different fertilizers. P derived from diammonium phosphate was greater than P derived from the soil, except in one soil. P derived from rock phosphate was always lower than P derived from the soil. The effectiveness of compost depended on soil type. Compost can produce two kind of effects: i) a direct P contribution and ii) an indirect effect improving P uptake from the soil. The radioisotopic method can be used to study the effectiveness of fertilizers even when there are no differences in yield.     

Effects of different phosphate fertilizers on yield of barley and rape seed on reddish brown soils of the Ethiopian highlands

The effectiveness of six phosphorus sources at 4 rates were tested for two seasons on reddish brown soil at Holetta, Ethiopia, using barley (Hordeum vulgare L.) and rape (Brassica napus L.) as test crops. The fertilizer sources include: basic slag (BS), bone meal (BM), Ethiopian rock phosphate (ERP), Gafsa rock phosphate (GRP), triple superphosphate (TSP) and mixture of TSP and GRP in the ratio 1:4 (MIX). Yield, P uptake by both crops as well as available soil P showed a marked response to the application of the various P sources. On continuously cropped field, grain yield increase over the unfertilized plot ranged from 2.5 to 16.4 dt ha^–1 for barley and rape respectively. On newly cleared field no significant effects of the different P sources on barley were observed. On the other hand for rape, a grain yield increase over the unfertilized plot ranging from 10.6 to 17.8 dt ha^–1 was recorded. The highest agronomic effectiveness relative to TSP (RAE) for both crops was obtained with BS. Rape was found to utilize P not only from the reactive rock phosphate (RP) but also from the unreactive one, which had a total P content of only 3% and 0.4% ammonium citrate soluble P. Barley, on the contrary, could not utilize P from this magmatic rock phosphate and failed to grow.     

Agronomic effectiveness of partially acidulated rock phosphate and fused calcium-magnesium phosphate compared with superphosphate

The agronomic effectiveness of two partially acidulated rock phosphate (PARP) fertilizers, made from either North Carolina or Moroccan apatite rock phosphate, and a fused calcium-magnesium phosphate (thermal phosphate or TP), was compared with the effectiveness of superphosphate in two glasshouse experiments. A different lateritic soil from Western Australia was used for each experiment. Oats (Avena sativa) were grown in one experiment and triticale (×Triticosecale) in the other. Fertilizer effectiveness was measured using (i) yield of dried tops, (ii) P content (P concentration in tissue multiplied by yield) of dried tops, and (iii) bicarbonate-extractable soil P (soil test value).The following relationships differed for the different fertilizers: (i) yield of dried tops and P content in the dried tops; (ii) yield and soil test values. Consequently the fertilizer effectiveness values calculated using yield data differed from those calculated using P content or soil test data. Freshly-applied superphosphate was always the most effective fertilizer regardless of the method used to calculate fertilizer effectiveness values. For one of the soils, as calculated using yield data, relative to freshly-applied superphosphate, the PARP and TP fertilizers were 15 to 30% as effective for the first crop, and 20 to 50% as effective for the second crop. The second soil was more acidic, and for the first crop the PARP and TP fertilizers were 80 to 90% as effective as freshly-applied superphosphate, but all fertilizers were only 5 to 15% as effective for the second crop. For each soil, the two PARP fertilizers had similar fertilizer effectiveness values. Generally the TP fertilizer was more effective than the PARP fertilizers.     

Influence of phosphate rock reactivity and granule size on the effectiveness of ‘biosuper’

A pot trial was conducted to determine the influence of phosphate rock (PR) reactivity and granule size on the effectiveness of biosuper. Perennial ryegrass was grown as the test crop for 9 months in a volcanic ash soil of pH 5.4. The PRs used were North Carolina (NC) (reactive) and Florida (Fl) (less reactive). Single superphosphate was used as the standard fertilizer. The fertilizers were added at 6 rates 3 mm below the soil surface.The dry matter yield and phosphate uptake data indicated that the effectiveness of the fertilizers were in the order of NC/S (biosuper indicated by adding S to the PR names) = superphosphate > NC > F1/S > F1 > control. The performance of biosupers and PRs relative to superphosphate, improved with time. The effectiveness of NC/S increased by 18–30% and that of F1/S by 50–70%, depending on the rate of application, in comparison with addition as PR granules. Plant phosphate uptake and soil Olsen bicarbonate extractable phosphate values indicated that the increase in yield in biosuper treatments was due to enhanced phosphate supply, caused by the oxidation of sulphur to sulphuric acid and the subsequent reaction of the acid with the PRs.Increasing the NC/S granule size from 0.2–0.5 to 1–2 mm range resulted in a small but significant decrease in effectiveness. However, the calculated yield maxima were the same. The size of the granules did not make significant difference with F1/S.Olsen bicarbonate extractable phosphate values increased by 140 to 310% and 140 to 330% respectively when NC and Fl were added as biosupers compared to addition as PR granules. The values for superphosphate decreased rapidly with time and were less than those for biosupers five months after addition of the fertilizers.     

Long-term effect of N and P fertilization on a pearlmillet—wheat cropping system

Results of an eight-year study on long-term effect of N and P application in a pearlmillet—wheat sequence is reported. There was little or no residual effect of N on any of the crops. Pearlmillet needed 70 to 80 kg N and wheat required more than 120 kg N ha^–1 every year for optimum grain yield. There was no soluble P build up in soil by continuous P application. Fertilizing wheat every year with 19 kg P and pearlmillet with 13 kg P ha^–1 is considered optimum.Continuous cropping leading to a production of 216 tonnes of biomass ha^–1 in 17 crops and use of high analysis N (urea) and P (triple superphosphate) fertilizers had not impaired the K and Zn supplying capacity of these alluvial soils containing illite clay minerals. The experiment is being continued to monitor the productivity of the soil as affected by continuous cropping.     

The residual value of rock phosphate and superphosphate from field sites assessed by glasshouse bioassay using three plant species with different external P requirements

A pot experiment with two lateritic soils measured the relative residual effectiveness (RRE) of superphosphate and three rock phosphate (RP) fertilizers applied six years previously in the field. Three plant species (lettuce, wheat and maize) having very different external P requirements were grown as indicators of P availability. Superphosphate had the maximum RRE (1.0) and low reactive Queensland RP had the minimum RRE (0.04–0.45) for all plant species. For one soil the RRE of reactive North Carolina RP was similar to that of superphosphate (0.87–1.04), but ranged from 0.07 to 0.30 for the other soil. The RRE of Calciphos (one soil only) ranged from 0.60 to 0.98 for all plant species.The RRE of rock phosphate decreased for the three crops in sequence maize> wheat> lettuce for a 30 days growth period. This ranking follows the increasing external P requirement of the three plant species. Very high rates of application of RP may have induced micronutrient deficiencies.     

Greenhouse evaluation of agronomic potential of different sources of phosphate fertilizer in a typical concretionary soil of Northern Ghana

The concretionary soils of Northern Ghana, which are near neutral with respect to pH and which comprise mostly lateritic ferruginous nodules are known to sorb significant amounts of phosphate. Instead of imported superphosphate, the use of less expensive indigenous Togo rock phosphate (PR) or partially acidulated (50%) Togo rock phosphate (PAPR-50), are possible alternative phosphate fertilizer options for these soils. The objective of this research was to evaluate the effectiveness of freshly-applied SSP, PR and PAPR-50, and the effectiveness of the residues of these fertilizers in a glasshouse pot study. Laboratory studies were also undertaken to study the transformation of these fertilizers after their application to the concretionary ferruginous soils. In the greenhouse study, yield of dried tops and the P uptake by the tops of maize var. Dobidi (Zea mays) was used to measure fertilizer effectiveness. One level of P was applied for each fertilizer (26.4 kg P ha^–1). Plants were grown for 28 days. After harvesting the first crop, subsequent cropping was carried out to evaluate the effects of the residual P in the pots. The results showed that increases in dry matter yield of shoot and total P uptake followed the trend SSP > PAPR-50 > PR > control. The relative agronomic effciency (RAE) of PAPR-50 was 58% that of commercial SSP in increasing growth of the crop, while that of PR was only 23%. The residual effect of either PAPR-50 or PR on dry matter yield and total P uptake was found to be negligible compared with SSP, suggesting that apatitic P was poorly effective relative to SSP in the used soils. The P fractionation results confirmed that PR and PAPR-50 did not significantly increase any of the P fractions in either the soil fines or nodules after the first crop. By contrast, application of SSP increased all extractable Pi fractions, most of the P added being recovered from the nodules in forms associated with Fe (hydroxide and residual Pi).It is concluded that, relative to SSP, the P from residues of PAPR-50 and PR are poorly effective in the soils studied for sustainable plant production.     

A discussion of the methods for comparing the relative effectiveness of phosphate fertilizers varying in solubility

Because various phosphate (P) fertilizers differ widely in their solubility, it is commonly observed that crop response to P fertilizers varies under the same soil and crop conditions. Furthermore, a major problem encountered in the methods for determining the relative effectiveness (RE) of water-insoluble P fertilizer (e.g., phosphate rock) with respect to water-soluble P fertilizers, e.g., single superphosphate (SSP) and triple superphosphate (TSP), is that their growth response curves are usually nonlinear and often do not share a common maximum yield. In this paper, we review and discuss the advantages and disadvantages of the three most commonly used methods for calculating the RE of phosphate rock with respect to TSP (or SSP). The three methods are vertical comparison, horizontal (substitution rate) comparison, and linear-response comparison.     

Impact of rice straw management practices on yield,nitrogen uptake and soil properties in a wheat-rice rotation in northern India

To study the long term effects of rice straw management practices in a wheat-rice rotation, experiments were started from the dry season (Nov–May) of 1984 to wet season (July–Nov) of 1989. Each year, six straw management practices, viz. control (C), straw incorporation (SI), straw mulch (SM), straw burning (SB), animal manure incorporation (AM), and straw and animal manure incorporation together (SI+AM) were imposed to wheat crop and their subsequent residual effect was studied on the following rice crop under three levels of N, viz. 0, 60 and 120 kg N ha^–1. The rate of straw and animal manure used was 5 t ha^–1 on dry weight basis.The wheat yield and N uptake did not vary significantly under control and SB throughout the experimental period. But, the production level of wheat and N uptake were consistently higher under AM and SM over these two treatments. The SI+AM which had significantly lower wheat yields and N uptake over the AM during the first crop, became equal to that of AM and SM during the second and third crops, and out yielded these two treatments from the fourth crop onward. Straw incorporation which produced wheat yield and N uptake even less than control and SB during the first two crops, resulted in wheat yield and N uptake equivalent to AM and SM from the fourth crop onward.None of the straw management practices had residual effects on the yields and N uptake during the first rice crop, except SM which reduced the rice yields and N uptake in the first two crops. However, AM and SI+AM in the second crop; AM, SI+AM and SI in the third crop; and AM, SI+AM, SI and SM from the fourth crop onward had significant and positive residual effects on rice yields and N uptake. Among these four treatments, SI+AM produced residual effects which were significantly higher than the remaining three treatments. Considering the production levels of wheat and rice, SI+AM treatment resulted in savings of 60 kg N ha^–1 each for wheat and rice.After five years of experimentation, the maximum soil build-up of organic carbon; available N, P and K; and DTPA-extractable Zn, Cu, Fe and Mn was observed under SI+AM, followed by AM and SM and it was minimal under SB and control treatments. The treatments of AM and SI+AM also resulted in a high percentage of water-stable aggregates of 70.25 mm in diameter (80.9%), larger mean weight diameter (0.82 mm), higher porosity (54.2%) and lower bulk density (1.19 Mg m^–3).     

Comparison of efficiency of Mussoorie partially acidulated phosphate rock and single superphosphate in a shallow Alfisol of the Indian semiarid tropics

The agronomic effectiveness of a partially acidulated phosphate rock (PAPR) was measured in a field experiment with sorghum (Sorghum bicolor cv. CSH-6) in a shallow Alfisol at the ICRISAT farm, Patancheru (Hyderabad), India. The experiment compared PAPR with single superphosphate. The PAPR was made by acidulating an indigenous Indian phosphate rock (Mussoorie) with H₂SO₄ at 50% acidulation level. P response was evaluated at a single relatively high N rate (120 kg ha^–1) with five rates of P (0, 2.2, 4.4, 8.8, and 17.6 kg P ha^–1). A significant response to P was obtained at rates up to 17.6kg P ha^–1.There was no significant difference due to source of P in terms of sorghum grain yield or total P uptake. Both Olsen and Bray 1 soil tests underestimated P availability from PAPR with respect to that from SSP.A rapid rate of P uptake was observed during grain filling to maturity (81–102 days), when 40% of the total P was taken by the plant. The internal efficiency of both P sources was the same.     

Effect of water supply on the response of wheat and triticale to applications of rock phosphate and superphosphate

The effect of water supply on the response of wheat (Triticum aestivum) and triticale (×Triticosecale) to levels of freshly-applied rock phosphate and superphosphate, and the residues of these fertilizers applied 9 years previously in the field, was studied in three glasshouse experiments. The < 2 mm fraction of the top 10 cm of soil was used (1.8 kg soil per pot), and in one experiment, freshly-applied fertilizer was also added to the more acidic subsoil (10 to 20 cm). There were two water treatments: the soil was returned to field capacity by watering to weight, either daily (W1, adequate water) or weekly (W2, water stress). Yield of dried tops was used to calculate fertilizer effectiveness. The phosphorus (P) concentration in dried tops was used to determine critical P, which is the P concentration related to 90% of the maximum yield. Just before sowing, soil samples were collected to measure bicarbonate-extractable (soil test) P which was related to plant yield.Water stress reduced yields and maximum yield plateaus by 20 to 40%. Water stress reduced the effectiveness of all P fertilizers by between 20 to 60%, largely because of a reduction in the maximum yield potentials. In the field, water supply is seasonally dependent and it can affect the yield response of plants to freshly-applied rock phosphate and superphosphate and the residues of these fertilizers applied to the field in previous years. Relative to placing fertilizer in the topsoil, placing fertilizer in the subsoil improved effectiveness by about 26% for rock phosphate and 12% for superphosphate.The relationship between yield and P concentration in dried tops, and critical P, differed for W1 and W2. The soil test P calibration, which relates yield to soil test P, and the soil test P required to produce the same yield also differed for W1 and W2. Consequently critical P and soil test P calibrations depend on water supply, which in the field varies within and between growing seasons. This is so for freshly- and previously-applied rock phosphate and superphosphate.     

The agronomic effectiveness of reactive rock phosphate,partially acidulated rock phosphate and monocalcium phosphate in soils of different pH

The initial and residual fertilizer effectiveness of North Carolina RP (rock phosphate), monocalcium phosphate and partially acidulated RP (made from North Carolina RP at 30% acidulation), both granulated and non-granulated, were measured in a glasshouse experiment. Triticale (xTriticosecale) was grown for 30 days on a soil that had been adjusted to three pH values (4.2, 5.2 and 6.2). Two crops were grown with a six month interval between crops. The effectiveness of the different fertilizers was compared using relationships between (1) yield of dried tops and the amount of P applied and (2) P content (P concentration in tissue multiplied by yield) and the amount of P applied. For the first crop, relative effectiveness (RE) of the fertilizers was calculated relative to granulated monocalcium phosphate, the most effective fertilizer. Monocalcium phosphate was not applied to the second crop, so relative residual effectiveness (RRE) was estimated for each fertilizer relative to the residual effectiveness of granulated monocalcium phosphate.The relative effectiveness of granulated monocalcium phosphate (band application) was greater (RE = 1.00) than of North Carolina RP (0.01–0.02) and partially acidulated RP (0.45–0.76) for all three soil pH values for the first crop. Granulation and band application increased the effectiveness of monocalcium phosphate and partially acidulated RP, but reduced the effectiveness of North Carolina RP. Both non-granulated monocalcium phosphate and partially acidulated RP were less effective than granulated partially acidulated RP for both crops. For the second crop granulated monocalcium phosphate was most effective and the RRE of non-granulated partially acidulated RP (0.16–0.32) and North Carolina RP (0.19–0.28) was greater than for non-granulated monocalcium phosphate (0.12). For the more acidic soil the RE of non-granulated North Carolina RP was four times higher than for the high pH soil for the first crop and 60% higher for the second crop, but it was still poorly effective relative to granulated monocalcium phosphate. Granulated North Carolina RP was least effective among all the fertilizers for all soil pH values and for both crops.     

The residual value of superphosphate and rock phosphates for lateritic soils and its evaluation using three soil phosphate tests

The residual value of superphosphate and several rock phosphates was measured in three field experiments in Western Australia. The rock phosphates were Christmas Island C-grade ore, calcined C-grade ore (Calciphos) and apatite rock phosphates. The predictive capacity of the Colwell, Olsen and Bray 1 soil tests for phosphate were also evaluated.As measured by yields of variously wheat, oats, barley or clover, the effectiveness of an initial application of superphosphate decreased to about 50% of that of newly applied superphosphate between years 1 and 2, and further decreased to about 20% over subsequent years. At low levels of application, all the rock phosphates were between 10–20% as effective as superphosphate in the year of application for all experiments. Relative to newly applied superphosphate their effectiveness remained approximately constant in subsequent years for two experiments and doubled for the other experiment.The Colwell soil test predicted that the effectiveness of superphosphate decreased to about 45% between years 2 and 3, followed by a more gradual decrease to approximately 15%. At low levels of application, the effectiveness of the rock phosphates as predicted by the Colwell soil test values was initially very low relative to superphosphate (2–30%), and remained low in subsequent years (2–20%). For superphosphate treated soil, the proportion of the added phosphorus extracted generally increased as the level of application increased. By contrast, for rock phosphate treated soil, the proportion of added phosphorus extracted decreased as the level of application increased.For all three experiments there were highly significant positive correlations between amounts of P extracted by the three soil tests. Consequently all soil tests were equally predictive of yield but usually for each soil test separate calibrations between yield and soil test values were required for the different fertilizers and for each combination of fertilizer and plant species and for each year.     

The effects of nitrogen fertilizer form on the plant availability of phosphate from soil,phosphate rock and mono-calcium phosphate

A glasshouse trial using lettuce as the test crop, and laboratory incubations were used to evaluate the influence of various nitrogen fertilizers on the availability of phosphate from an unfertilized loamy sand soil and from the same soil fertilized with Sechura phosphate rock or monocalcium phosphate. The order in which nitrogen fertilizer form increased plant yield and P uptake from soil alone and from soil fertilized with the rock was ammonium sulphate > sulphurised urea > ammonium nitrate > urea > potassium nitrate. For each rock application (both 30 and 60 mg/pot) and for soil alone, increased P uptake by the plant correlated well with decreased soil pH. In soil fertilized with the soluble P form, monocalcium phosphate, the form of the nitrogen fertilizer had little effect on plant P uptake. Subsequent laboratory incubation studies showed that increased dissolution of soil-P or Sechura phosphate rock did not occur until acidity, generated by nitrification or sulphur oxidation of the fertilizer materials, had lowered soil pH to below 5.5. A sequential phosphate fractionation procedure was used to show that in soils treated with the acidifying nitrogen fertilizers, ammonium sulphate and urea, there was considerable release of Sechura phosphate rock P to the soil, amounting to 42% and 27% of the original rock P added, respectively.