首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到19条相似文献,搜索用时 202 毫秒
1.
研究了Ba_(6-3x)(Nd_(1-y)Bi_y)_(8+2x)Ti_(18)O_(54)(x=0~1)陶瓷微波性能,并对其微观机理和晶体结构进行分析.随Bi_2O_3含量的增加,系统介电常数(ε)迅速增大,品质因数与频率的乘积(Q·f)逐渐减小.掺入Bi_2O_3后,系统中出现具有高ε的Bi_4Ti_3O_(12)晶相,并形成了类填满型钨青铜结构,阳离子极化增强,因此ε随Bi_2O_3含量的增加而增大.实验表明,当y=0.25~0.3时,Ba_(6-3x)(Nd_(1-y)Bi_y)_(8+2x)Ti_(18)O_(54)(x =0~1) 陶瓷具有优良的微波介电性能,其主要工艺条件和性能参数为烧结温度1 200 ℃保温4 h,ε≈102~107,Q·f≈20 000~22 000 GHz(1 GHz测量), 容量温度系数|αc|<10×10~(-6)/℃.  相似文献   

2.
为了获得低温烧结的陶瓷材料,用固相反应制备了(1–x)Ba3(VO4)2-x Li2WO4(0.05≤x≤0.20)微波介质陶瓷。实验结果表明:随着添加剂Li2WO4的增加,复合陶瓷的相对体密度、相对介电常数εr和品质因数Q·f都呈现出先增加随后又降低的趋势,而谐振频率温度系数τf呈线性降低。添加了摩尔分数0.15Li2WO4的微波介质陶瓷在850℃烧结2 h达到约96.8%的致密度,并获得最佳的微波介电性能:εr=13.7,Q·f=97000 GHz,τf=1.8×10–6/℃。  相似文献   

3.
采用射频磁控溅射和微细加工技术制备了不同尺寸的钛酸锶钡(Ba0.5Sr0.5TiO3,BST)平行板电容,研究了低频和高频条件下不同尺寸BST平行板电容的电容密度和Q值的变化情况。结果表明,由于存在边缘效应,BST薄膜电容的电容密度及Q值都具有尺寸效应。低频时,随着电容面积增大,电容密度减小,Q值增大。高频时,随着电容面积增大,电容密度及Q值减小。  相似文献   

4.
(ZnxMg1-x)TiO3微波介电性能及其TiO2掺杂研究   总被引:1,自引:0,他引:1  
调节不同的r(Zn/Mg)值,用普通固相合成法制备了(ZnxMg1-x)TiO3(x=0.1~0.5(摩尔比)微波陶瓷基料,研究了r(Zn/Mg)及预烧温度对其微波和烧结性能的影响,并通过TiO2和CaSiO3玻璃掺杂改善了(ZnxMg1-x)TiO3基料的微波性能,最终获得了可在1 170℃烧成的相对介电常数rε=26~28,品质因数与频率之积Q.f>70 000(10 GHz),谐振频率温度系数τf<±10×10-6/°C的微波陶瓷。  相似文献   

5.
陆大成 《半导体学报》1990,11(3):163-169
金属有机化学汽相淀积(MOCVD)通常被认为是一个非平衡过程。然而在生长速度的扩散控制区,可以假定在汽-固界面存在平衡。本文用平衡模型计算了用二甲基锌(DMZ)或二乙基锌(DEZ)与硫化氢和硒化氢为源,生长ZnS_xSe_(1-x)三元合金时,各反应参数对固溶体组分的影响。本模型考虑了汽相中H_2S和H_2Se的热分解,固溶体的非理想行为,计算了生长温度、压力、输入反应室的、[Ⅵ/Ⅱ]比和初始氢含量对固溶体成分的影响,并把计算值与实验结果进行了比较。  相似文献   

6.
运用超声化学法,以细化后的Zn、CCl_4和H_2O为原料合成了Zn_5(OH)_8Cl_2·H_2O微纳米片,将Zn_5(OH)_8Cl_2·H_2O微纳米片在500℃下高温裂解,收集并表征了所得固相产物的结构形貌和光致发光性能,同时重点分析了所得固相产物的形成过程和生长机理。结果表明:该制备方法反应迅速,合成的Zn_5(OH)_8Cl_2·H_2O纳米片径向尺寸分布在400 nm到3μm;所得到的固相产物为形貌不同的ZnO微纳米晶体,形成过程经历了高温裂解和置换反应;晶体生长符合VS生长机理。Si基底和Al_2O_3基底ZnO晶体在约515 nm处均出现了较宽绿峰,前者带边发光峰与深能级发光峰强度比相对较大,表明其缺陷较少结晶较好,该结果可指导Zn_5(OH)_8Cl_2·H_2O和多形貌ZnO微纳米晶体的可控制备与应用。  相似文献   

7.
Tb配合物TbY(o-MOBA)6(phen)2·2H2O的电致发光器件   总被引:1,自引:1,他引:0  
合成了一类新型稀土配合物TbY(o-MOBA)6(phen)2·2H2O,将其掺杂到导电聚合物聚乙稀咔唑(PVK)中获得了纯正、明亮的绿光发射.用这种掺杂体系分别制作了2类器件:1) ITO/PVK:TbY(o-MOBA)6(phen)2·2H2O/LiF/Al;2) ITO/PVK:TbY(o-MOBA)6(phen)2·2H2O/BCP/AlQ/LiF/Al.器件1的起亮电压为13 V,在21 V时最大亮度为18.2 cd/m2;结构优化的器件2,在23 V 时最大亮度可达124.5 cd/m2.将这种材料的发光性能与另一种稀土配合物Tb(o-MOBA)3phen·H2O相比较,并分别讨论了其光致发光(PL)和电致发光(EL)机理.  相似文献   

8.
采用水热法在低温合成了铋层状钙钛矿结构Bi_(3.15)Nd_(0.85)Ti_3O_(12)(BNdT)纳米材料,利用X-射线衍射(XRD)、扫描电子显微镜(SEM)表征产物的晶相和形貌,研究了反应温度和聚乙烯醇(PVA)对水热合成BNdT纳米结构的影响,运用X-射线光电子能谱(XPS)对BNdT纳米结构的化学组分和元素价态进行了表征.结果表明,反应温度和PVA对水热合成BNdT纳米结构的形貌有较大影响;XPS研究显示BNdT纳米结构的表面存在氧空位和轻微的Bi过量.  相似文献   

9.
马奔 《中国新通信》2013,(16):83-84
OFDM是基于多路载波的新型信号调制传输技术,相对于传统的单载波系统,虽然有效地扩展了信道容量,但多径传播各路信号难以事先关联,不可避免出现子信道信号相互干扰。如何消除各种干扰,对信号传输进行噪音降解是通信实践中的重要事项。文章依据据OFDM技术各关键技术的特点,论述噪音降解的各种手段。  相似文献   

10.
目前1.5μm LD泵浦的铒镱共掺玻璃/晶体被动调Q微型激光器广泛应用于激光测距、激光雷达等领域。随着激光器输出能量和重频的增加,玻璃面临突出的热效应问题,晶体的热导率是玻璃的10倍以上,有望能够实现比玻璃基质更大脉冲能量和更高重频的激光输出。文中报道了一种采用LD脉冲端面泵浦、铒镱共掺焦硅酸镥晶体为增益介质的1537 nm被动调Q微型激光器。通过优化泵浦光斑大小、输出镜透过率与调Q晶体初始透过率相匹配,实现激光输出重频与泵浦重频一致。最终实现了输出重频为1 kHz、单脉冲能量35μJ、脉冲宽度7 ns、峰值功率为5 kW、光束质量因子M^(2)=1.33的激光输出。以及输出重频为10 kHz、单脉冲能量10μJ、脉冲宽度10 ns、峰值功率为1 kW、光束质量因子M^(2)=1.51的激光输出。结果表明,Er^(3+)/Yb^(3+):Lu_(2)Si_(2)O_(7)晶体是实现高重频1.5μm激光输出的优良介质。文中研究结果对LD脉冲端面泵浦的kHz铒镱共掺晶体被动调Q人眼安全微片激光器具有重要的参考意义。  相似文献   

11.
Poly(vinyl alcohol) (PVA) is a water‐soluble synthetic polymer with excellent film‐forming, emulsifying, and adhesive properties. The aim of this study is to design a simple process for PVA cross‐linking with sodium trimetaphosphate to form membrane devices suitable for biomedical applications. This procedure requires no organic solvent, nor melting process to obtain films with high mechanical strength. Fabrication of a small diameter tube from a PVA film is easy with a single wrapping step around a Teflon rod. Dynamic mechanical analysis demonstrated that, upon removal of the applied stress, the PVA film with a Young's modulus of 2 × 105 kPa returns to its original size and shape. The wall thickness of PVA tubes is 344 ± 13 µm (n = 12), which is close to the wall thickness of a human artery (350–710 µm). Suture retention of a PVA tube is excellent (140 ± 11 g), close to that of human vessels. The burst pressure of PVA tubes is found to be 507 ± 25 mm Hg, more than three times higher than the human healthy systolic arterial pressure. Under arterial pressure, there was no leakage even after needle puncture, contrary to clinical vascular expanded polytetrafluoroethylene prostheses. Finally, PVA tubes of 2 mm in diameter are used to replace a segment of an infrarenal aorta in rats. For at least one week, no mechanical nor thrombotic complications are noticed even in the absence of anticoagulant or antiplatelet treatment. Graft patency is also evidenced with non‐invasive imaging techniques. As a conclusion, this novel cross‐linking method confers to poly(vinyl alcohol) particular mechanical properties such as compliance, elasticity and resistance to mechanical stress, compatible with the circulatory blood flow.  相似文献   

12.
We report the preparation of cadmium sulfide (CdS) and lead sulfide (PdS) nanoparticle-blended poly(vinylacetate) (PVA) composite nanofibers by using an electrospinning technique. The resultant nanofibers were observed to be very smooth with uniform diameters ranging from 100 to 400 nm. The detailed analyses such as surface morphology, structure, bonding configuration, thermal, optical and electrical properties of the electrospun composite nanofibers were characterized. The introduced CdS and PdS nanoparticles in PVA were significantly enhanced by the electrical property of the composite nanofibers. The electrical conduction mechanism was further evaluated by studying the Fowler–Nordheim plots. Overall, the feasibility of obtaining uniformly dispersed CdS and PdS nanoparticles in PVA nanofibers can be useful for the realization of various nanotechnological device applications.  相似文献   

13.
用于陶瓷快速制造的聚乙烯醇凝胶热分解研究   总被引:4,自引:0,他引:4  
用DSC、IR及XRD研究了用于陶瓷快速制造的聚乙烯醇凝胶热分解过程。利用SEM观察了两种温度制度下金红石瓷的显微结构。结果表明:由于生成双二醇结构,胶凝后的聚乙烯醇红外光谱短波附近的衍射已经基本为Na2B4O7.10H2O的谱线所替代。胶凝后的聚乙烯醇DSC曲线表明,其分解温度提高约42℃,主要由于双二醇结构降低了主链旋转运动的自由度。SEM分析表明,在凝胶分解峰值前降低升温速率以及在峰值处延长保温时间有利于降低陶瓷气孔率。  相似文献   

14.
叙述了Ba(Zn1/3Ta2/3)O3介质谐振器材料的制备、结构、微波性能及典型应用。Ba(Zn1/3Ta2/3)O3介质材料介电常数εr为29.5,频率温度系数τ≈0(-55~+85℃),10GHz下最大无载Q值14700,在28GHz测得Q值约为4800。这种材料具有高Q值,特别适用于X以上波段作为振荡器电路中频率稳定元件。用这种介质谐振器已研制出8mm介质稳频微带耿氏振荡器,频率稳定度小于10×10-6/℃,最大输出功率达180mW。  相似文献   

15.
用常规固相合成法成功地制备出Sm3 掺杂Co0.6Zn0.4Ni0.8Fe1.2O4红外辐射陶瓷材料,并通过XRD、FT-IR和IRE-2型红外发射率测量仪测试了材料的微观结构,分析了材料的结构特征与红外辐射性能的关系,发现Sm3 的掺杂导致Sm3 以一定的配位形式进入Co0.6Zn0.4Ni0.8Fe1.2O4体系中,并形成了有限置换型固溶体结构.数据分析可知,Sm3 掺杂浓度对材料的红外辐射性能存在一定的影响,样品Sm0.1在全波段的积分发射率为0.74,而在>8μm波段的平均发射率最高值可达0.94.  相似文献   

16.
Polyvinyl alcohol (PVA) nanofibers, produced by electrospinning, represent attractive high‐surface‐area supports for olefin polymerization catalysts. Tethered with metal alkyls, PVA nanofibers immobilize a great variety of transition metal compounds, thus producing highly active nanofiber‐supported Ziegler‐, metallocene‐, and post‐metallocene catalysts. Whereas most conventional heterogeneous polymerization catalysts form particles, PVA‐nanofiber‐supported catalysts enable polyolefin nanofiber and nanostructure formation by mesoscopic shape replication using electrospun nanofibers as templates. At low ethylene pressure, linear correlation between average PE/PVA core/shell fiber diameter and polymerization time are made. At elevated pressure, this control is lost, accounting for the formation of reactor blends consisting of PE granules and built‐in PE/PVA nanofibers. Whereas conventional catalysts produce micrometer‐sized particles of ultrahigh molecular weight PE (UHMWPE), PVA‐nanofiber supported chromium catalysts afford new families UHMWPE materials. They range from UHMWPE/PVA core/shell nanofibers and nonwovens to hollow UHMWPE fibers and nanoporous UHMWPE, obtained by removing the PVA component.  相似文献   

17.
(La、Nb)共掺杂TiO2压敏陶瓷第二相形成机理   总被引:1,自引:0,他引:1  
研究了(La、Nb)共掺杂TiO2压敏陶瓷第二相的形成机理.以锐钛矿TiO2、Nb2Os和La2 O3氧化物粉体为原料,采用传统固相烧结工艺制备了( La、Nb)共掺杂TiO2压敏陶瓷,采用SEM、EDS、XRD、AFM和TEM检测了(La、Nb)共掺杂TiO2压敏陶瓷样品的显微结构、化学组成、物相组成、热蚀沟和显微形貌;通过点缺陷热力学分析、晶界能和材料结构检测分析讨论了(La、Nb)共掺杂TiO2压敏陶瓷第二相的形成机理.研究结果表明,第二相的形成起源于掺杂La3+和Nb5+在晶界的偏析,偏析驱动力为弹性应变能.偏析离子在高能量晶粒表面或晶界面成核,并逐渐长大形成第二相.第二相主要在能量较高的晶面上生长,这有利于使整个材料体系的能量最低.  相似文献   

18.
Poly(vinyl alcohol) (PVA) films embedded with functional polydiacetylene (PDA) are efficiently prepared for color and fluorescence imaging. Intensely blue films are obtained by mixing and drying solutions containing PDA vesicles and PVA. A blue‐to‐red color transition is observed upon heating the polymer films. In addition, selective UV irradiation (through a photomask) of PVA films containing diacetylene monomer results in the generation of micropatterned color (without heating) and both color and fluorescent images (after heating the films at 120 °C for 10 s). Patterned two‐color (blue and red) images in the polymer film are readily obtained by a sequential process of photomasked irradiation, heating, and unmasked irradiation.  相似文献   

19.
针对目前清洗技术存在的问题进行了详细分析,研究了微电子材料表面污染物的来源及其危害,并介绍了表面活性剂在颗粒去除方面的作用。研究了化学机械抛光(CMP)后Cu布线片表面的颗粒吸附状态,分析了铜片表面颗粒的吸附机理。采用非离子表面活性剂润湿擦洗方法,使Cu表面的颗粒处于易清洗的物理吸附状态。利用金相显微镜和原子力显微镜(AFM)在清洗前后进行对比分析,实验采用聚乙烯醇(PVA)刷子分别对铜片和铜布线片进行清洗,发现非离子界面活性剂能够有效去除化学机械抛光后表面吸附的杂质,达到了较好的清洗效果。  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号