In-situ high temperature X-ray diffraction study of Ni/SiC interface reactions

In-situ experiments on the Ni/SiC interface reaction were carried out with a high temperature X-ray diffractometer capable of measuring the X-ray diffraction pattern in 1–2 s using an imaging plate. The kinetic formation processes of the interface reaction layer were measured in short-period exposure experiments with the apparatus. The time-temperature phase diagram of Ni/SiC in N2 was determined. -Ni2Si and -Ni2Si (high temperature phase of -Ni2Si) were formed at the Ni/SiC interface between 1072 K and 1418 K in N2. The formation of -Ni2Si obeyed the parabolic rate law. The value of the activation energy suggests that the diffusion of Ni through -Ni2Si controls the rate of formation. The results of thermal expansion coefficient measurements suggest that when a sample is cooled to room temperature, compression caused by -Ni2Si occurs on SiC.     

Piezoelectric and mechanical properties of ceria-doped lead zirconate titanate ceramics

Phases, microstructures and properties of lead-zirconate-titanate (PZT) ceramics with the compositions Pb(Zr_0.535– Ce Ti_0.465) O₃ where =0.0, 0.001, 0.01, 0.02 and 0.05 were studied. Rhombohedral and tetragonal phases were present at =0.0. The amount of the rhombohedral phase increased with increasing , and only the tetragonal phase was present for >0.001. Thec/a ratio of the tetragonal phase also increases with increasing . Particles of CeO₂ were found to be present in compositions with >0.01, indicating that the solubility of CeO₂ is less than 1a/o on the metals basis. The piezoelectric and electromechanical constants achieved maximum values for =0.001. The hardness increased monotonically with increasing . The modulus of rupture and the fracture toughness, however, went through a minimum and both stayed lower than their values for =0.     

Some observations on the deformation characteristics of bulk polycrystalline zirconium hydrides

The deformation behaviour of bulk polycrystalline zirconium hydrides in the composition range ZrH_1.27 to ZrH_1.66 has been investigated by compressive loading at temperatures between room temperature and 500° C. Single-phase -zirconium hydride is brittle below 100° C. Analyses of slip traces on specimens deformed at temperatures between 100 and 250° C have shown that the glide planes are {111} types. The deformation characteristics of and ( + ) alloys at temperatures between 100 and 500° C are consistent with the hydrogen vacancies in the -phase providing significant lattice friction to the movement of dislocations in the zirconium lattice of the hydride structure. The room temperature fracture stress of ( + ) alloys increases with the volume fraction of the -phase and this can be related to the resistance offered by platelets to the propagation of cleavage cracks in the matrix. In a ( + + ) alloy the resistance to crack propagation at room temperature is further increased by the soft -zirconium phase.     

Temperature and randomness dependence of the pair-breaking parameter in superconducting aluminum films

Magnetoconductance and excess conductance due to superconducting fluctuations in aluminum films are measured in order to study the temperature dependence of the pair-breaking parameter at temperatures nearT _c . The parameter _M is estimated from the relation =/8k _B T_in, where _in is the inelastic scattering time deduced from the analysis of the magnetoconductance. The parameter _F is determined by fitting theories to data on the excess conductance at zero magnetic field. It is shown that: (1) For films with a wide range of the sheet resistanceR , 12R 200 /, the temperature dependence of _M nearT _c agrees well with the theory of Brenig et al. (2) For clean films withR 100 /, the value of _F analyzed with theories including the correction term to the Maki-Thompson contribution shows almost the same temperature dependence as _M . In a film withR 200 /, however, a discrepancy between _M and _F remains.On leave from College of General Education, Kyushu University, Ropponmatsu, Fukuoka, Japan.     

Types of superplasticm-δ curves of Ti-6Al-4V alloy and their intertransformation

The superplasticm- curves of Ti-6Al-4 alloy have been determined at different temperatures and strain rates; all were of them _L=m _max type, and were of either fundamental, descending or ascending types. The latter two types were transformed from the former through the processes ofm _Lm _O, _LO andm _Lm _F, _LF, respectively. The highest total elongation, _F, was 1150% obtained at 950C and 1.55×10^–3 s^–1. The Chin Liu equation has been applied to all types ofm- curves. The parameters characteristic of all types ofm- curves have been obtained and were found to vary with temperature and strain rate. The total elongation, _F, is determined by the resultant effects of all other parameters, not by a singlem value, theoretically considered to be constant and determined practically by a tensile strain of about 30%–50% (m _30%–50%) as usual.Nomenclature C (=k/k _o ) the normalized slope ofm- curve corresponding to - a material constant corresponding to - m strain-rate sensitivity index corresponding to - m _max maximum on them- curve corresponding to _L - m _min minimum on them- curve corresponding to _L - crosshead speed during the tensile test - the strain of the entire stretching process (has same significance as ordinarily adopted ) - _F total elongation at fracture chosen for the present work - _I intermediate strains including _I1, _I2, _I3, ..., _I(i–1), _Ii , _I(i+1), ..., chosen for the present work - _L limit strain separatingm- curves into sections - _O (=0) starting strain - strain rate - flow stress     

Phase transformation and impact properties of type 17-8-2 austenitic weld metals

The influence of stress relieving and ageing treatments in the range 600 to 900° C on the phase transformations and change in room temperature impact properties has been studied for two manual metal arc 17-8-2 weld metals. The transformation of the-ferrite in the range 600 to 800° C was found to conform to a classical Johnson-Mehl equation; the initial precipitates were M₂₃C₆ carbides followed by the intermetallic-phase. At higher temperatures a slower transformation rate was found suggesting a C curve type of behaviour and the dominant intermetallic phase changed to. Room temperature impact toughness values were found to change with ageing time. Below 800° C there was a consistent fall in these values which became very marked when the-phase developed at the/-boundaries, Above 800° C, spherodization of the carbides and intermetallic phases delayed the fall in the impact values, and led to significant increases in the early stages of ageing. Scanning electron microscopy confirmed that the change from ductile to brittle fracture mode was normally associated with the development of the and phases, but at 600° C the fall in impact properties could be atrributed to carbide development.     

Wide-band phase-metering frequency transducers with fixed frequency heterodynes

Conclusions It has already been pointed out [3] that the PMFTs with a repeated sequential transformation of frequency in ISSs and restoration of the heterodyne frequency contain a minimum number of transducers (two WBFSs) and provide, only for the condition that <, an adequately small error due to an incomplete suppression of the image frequencies (₁₂) in the WBFSs.Over a wider frequency range (), i.e., at any frequency with the exception of=, the PMFTs operate with the same small errors due to an incomplete suppression of the WBFS image frequencies (₁₂), provided that the ISS contains two WBFSs and an SM, or three WBFSs, and that the reference-signal shaping channel consists of a frequency doubler and k₁=k₂=1.Certain PMFTs which contain an FST at one of the heterodyne outputs [5] (k₂>k₁=1) have even a. wider band. Thus, the PMFTs corresponding to combinations of their component transducers shown in the lines 2, 5, 8, and 11 of Table 1 operate, for any relationship of the frequencies ₁ and k₂, with adequately small errors due to an incomplete supression of the image frequency (₁₂) in the WBFSs.The above error, with the remaining conditions being the same, is minimal (¹²³) in the PMFTs which consist of three WBFSs and have transducer combinations shown in the lines 1 and 3 of Table 1.Bearing in mind that WBFSs can now be made with an image frequency suppression factor of the order of 5·10^–3, the error under consideration of such PMFTs can be of the order of 10^–7 rad or 5·10^–5 degrees, i.e., it can be small as compared with other modern phase-metering devices' error components (due to coupling between channels, presence of higher signal harmonic components, etc).Translated from Izmeritel'naya Tekhnika, No. 1, pp. 21–25, January, 1974.     

Reconfirmation of the existence of δ2 in dental amalgams

The 90°C endotherm peak in the thermogram of a conventional dental amalgam is due to two overlapping peritectic transitions involving SnHg-2 and HgAgSn-1, respectively. The aim of the present study is to separate these two events and thus confirm that the 2 phase is indeed a part of an amalgam microstructure. The materials used in this study were: sample 1, 1+1 wt% Sn; sample 2, 1+2 wt% Sn; sample 3, 1+3 wt% Sn; and sample 4, a commercial conventional amalgam with 48 wt% Hg. In powder form, they were exposed to 1 wt% NaCl solution at 37 °C for up to 45 days. At 15 day intervals, samples were withdrawn from the solution, washed, dried and then characterized by the differential scanning calorimetry (DSC) technique. Corrosion of Sn from ternary 1 matrix and intergranular 2 in respective materials during their exposure to the NaCl solution led to the following: (a) a progressive increase in 11 transition temperature in samples 1 and 2; (b) a gradual decrease in 2 peak and its disappearance in sample 2; and (c) in samples 3 and 4, initial splitting of the 90°C peak into two distinct endotherms associated with 2 and 1, respectively. Continued corrosion of the last two materials produced further changes in 2 and 1 in a manner similar to that seen in samples 1 and 2. On the basis of these observations, we have concluded that the 90°C endotherm is a valid indicator of the existence of the 2 phase in dental amalgams.     

Die Entwicklung von Längswirbeln in zeitlich anwachsenden Grenzschichten an konkaven Wänden

Zusammenfassung Messungen des Anwachsens von Längswirbeln in zeitlich anwachsenden Grenzschichten an konkav gekrümmten Wänden (Görtler-Taylor-Wirbel) ergaben drei deutlich getrennte Bereiche: Es traten zunächst Wirbel mit der Wellenläge 0,9 auf (=Grenzschichtdicke, =Höhe einer Zelle, die zwei gegensinnig drehende Wirbel enthält). Je nach Größe der mit der Verdrängungsdicke ₁ der Grenzschicht gebildeten Reynolds-Zahl erschienen dann kurze Zeit später Wirbel mit 2,5, wenn war. Im Bereiche dagegen traten stattdessen bei den hier durchgeführten Versuchen immer Wirbel mit der Wellenlänge 6,5 auf. Bei werden die ersten Tollmien-Schlichting-Wellen mit der Wellenlänge _TS 6· angefacht. In ihren wandnahen Bereichen der Wellentäler könnten sich dann die oben genannten Längswirbel der Wellenlänge 6,5· ausbilden, die die zwei-in eine dreidimensionale Störung allseits gleicher Größenordnung verwandeln können.

---

The development of longitudinal vortices in boundary layers growing with time along concave walls

Summary Measurements of the growth of longitudinal vortices in boundary layers growing with time along concave walls (Görtler-Taylor vortices) rendered three distinctly separated regions. First, vortices with a wave-length 0.9 appeared (-boundary layer thicness, =height of a cell containing two counterrotating vortices). Then, depending on the Reynolds number R _{a 1}/v ₁=displacement thickness), vortices with 2.5 appeared shortly afterwards, provided . In the region , however, the wave-length was 6.5. For the first Tollmien-Schlichting waves with _TS 6 were excited. In the wave-throughs close to the wall the abovementioned longitudinal vortices with wave length 6.5 may then be formed. This might transform the two-dimensional into a three-dimensional flow of equal order of magnitude in all directions.

---

Zeichenerklärungen R _a Innenradius - Re _a Reynolds-Zahl gebildet mit dem InnenradiusR _a - Reynolds-Zahl gebildet mit der Verdrängungsdicke ₁ - kritische Taylor-Zahl - h Standhöhe der Flüssigkeit im Zylinder - t Zeit - z Anzahl - Steigungswinkel der Geraden - Grenzschichtdicke - ₁ Verdrängungsdicke - Wellenlänge (enthält ein gegensinnig rotierendes Längswirbelpaar) - v kinematische Zähigkeit - Winkelgeschwindigkeit Indizes K Knickpunkt der Geradensteigung - L unterhalb des Knickpunktes der Geradensteigung - TS Tollmien-Schlichting - e Einsatz der Wirbelentstehung     

Phases in as-spun and aged binary aluminium-lithium ribbons

As-spun aluminium-lithium ribbons, containing up to 10wt% Li, and an Al-1.79 wt % Li ribbon aged at different temperatures (room temperature, 66, 175 and 200 °C) were investigated by transmission electron microscopy (TEM) and microhardness testing. It was found that the metastable phase Al₃Li () did not form either in the as-cast ribbons containing less than 1.79 wt% Li or in the featureless zone of Li-rich ribbons (Li content >3 wt%) but it did form, as the stable phase AlLi (), in the segregated zone of the later ribbons. The study of the early stage of precipitation showed that the mechanism of formation of depended on the ageing temperature. At a low temperature (66°C), the phase occurred by homogeneous spinodal decomposition. Whereas, it formed by heterogeneous nucleation at higher temperatures (175 and 200°C). These results are consistent with the presence of a spinodal curve within the miscibility gap ( + ). All investigations performed both on the as-cast and aged ribbons did not reveal any evidence for the formation of G.P. zones. It was also observed in this study that contamination of aluminium-lithium ribbons by impurities such as O₂ and CO₂ could alter the precipitation process and lead to the formation of lithium carbonate.     

Dielectric properties of LaPO4 ceramics

Dielectric constant (K) and loss (tan), and hence conductivity (), have been measured for LaPO₄ ceramics prepared by a molten urea process in the frequency region 10² to 10⁷ Hz and in the temperature range –193 to 280° C. At room temperature ( 30°C),K decreases with frequency up to 10⁵ Hz, beyond which it attains a constant value; tan behaves in a similar way. The values ofK and tan at 30°C and 10⁶ Hz for this material are 14 and 2.7 × 10^–3, respectively. As a function of temperature,K exhibits two stages of increase: (i) a slow stage up to –30° C and (ii) a fast one beyond –30° C which is considerably frequency dependent,K having larger values at lower frequencies. Similar behaviour is exhibited by tan. Plots of against 1/T for LaPO₄ exhibit the usual extrinsic and intrinsic regions; the activation energy for conduction in the intrinsic region is calculated to be 0.61 eV. It seems possible to understand the results through space charge polarization effects due to lattice defects in LaPO₄.     

Strength distributions and size effects for 2D and 3D composites with Weibull fibers in an elastic matrix

Monte Carlo simulation and theoretical modeling are used to study the statistical failure modes in unidirectional composites consisting of elastic fibers in an elastic matrix. Both linear and hexagonal fiber arrays are considered, forming 2D and 3D composites, respectively. Failure is idealized using the chain-of-bundles model in terms of -bundles of length , which is the length-scale of fiber load transfer. Within each -bundle, fiber load redistribution is determined by local load-sharing models that approximate the in-plane fiber load redistribution from planar break clusters, as predicted from 2D and 3D shear-lag models. As a result the -bundle failure models are 1D and 2D, respectively. Fiber elements have random strengths following either a Weibull or a power-law distribution with shape and scale parameters and , respectively. Under Weibull fiber strength, failure simulations for 2D -bundles, reveal two regimes: When fiber strength variability is low (roughly >2) the dominant failure mode is by growing clusters of fiber breaks, one of which becomes catastrophic. When this variability is high (roughly 0<<2) cluster formation is suppressed by a dispersed failure mode due to the blocking effects of a few strong fibers. For 1D -bundles or for 2D -bundles under power-law fiber strength, the transitional value of drops to 1 or lower, and overall, it may slowly decrease with increasing bundle size. For the two regimes, closed-form approximations to the distribution of -bundle strength are developed under the local load-sharing model and an equal load-sharing model of Daniels, respectively. The results compare favorably with simulations on -bundles with up to 1500 fibers.     

CR-39 as a gamma dosimeter: Dielectric and infrared studies

The relative permittivity, , and dielectric loss factor, tan , were measured in the frequency range 50–10⁵ Hz for the solid state track detector CR-39 irradiated with -rays (5–100 kGy). The variation of and tan with -dose have been interpreted in terms of structural changes as emphasized from infrared spectra. A mathematical model has been introduced describing the use of CR-39 as a dielectric dosimeter.     

Low-temperature synthesis of binary cuprates from hydroxide precursor

Binary cuprates of Sr₂CuO₃₊ and SrCuO₂ have been synthesized at low temperatures below 500 °C under various values of partial oxygen-pressure by thermal decomposition of hydroxide precursors, Sr₂Cu(OH)₆ and SrCu(OH)₄, respectively. The tetragonal Sr₂CuO₃₊ ( 0.3) is obtained by the heat-treatment at 400 ° C and 0.2 atm. The value of appears to be independent of and unchangeable. On the other hand, the orthorhombic Sr₂CuO₃₊ ( 0) is obtained by the heat-treatment at 400 °C in flowing gas of N₂. For 0 < < 0.2 atm, a mixture of the tetragonal and orthorhombic phases is obtained. The orthorhombic SrCuO₂ is obtained by the heat-treatment at 500 ° C in flowing gas of N₂, although the tetragonal SrCuO₂, namely, the so-called infinite-layer compound is not obtained.     

Phase evolution in Al2O3 fibre prepared from an oxychloride precursor

The formation of polycrystalline -alumina during the heat treatment of aluminium oxychloride fibres occurs via transitions through various intermediate crystalline alumina phases. The different phases show a strict pseudomorphism, i.e. the external shape of the crystal is retained and there is an orientational relationship between the crystal axes, before and after the phase transition. Consequently, the phase sequences and microstructure are interdependent and controlled by the heat-treatment conditions, which determine the final properties of the fibres. The effects of water content in the fibre formulation, and sintering temperature and heating rate on the phase development from amorphous oxychloride to crystalline -alumina fibres, were investigated. The transition path for the phase evolution during heat treatment to 1200°C (when the formation of -alumina is completed) was established and correlated with fibre microstructure. In fibres with higher water content, the transition temperature for - and -alumina phase formation was higher. Only for a very high heating rate was -alumina observed as an intermediate phase during phase evolution. The axial porosity appeared to be eliminated more rapidly in the fibres at temperatures below 1200°C. Consequently, residual porosity, comprising closed pores, in the final stage of sintering, was mainly observed radially oriented toward, and on, the fibre surface. A high diametral shrinkage was measured and plotted as a function of the sintering temperatures used for fibre heat-treatment.     

Swelling parameter of polypropylene used in household appliances

Samples of unfilled copolymer polypropylene were immersed in various solvents and the equilibrium swelling was recorded. Two-dimensional solubility maps of the Hildebrand parameter, , versus hydrogen bonding parameter, _c, and _h versus _v for polypropylene were plotted. Using the calculated percentage swell values and the solubility maps, the and _h values for detergent were postulated. No changes in the polypropylene backbone were revealed by mid- or far-infrared spectra, showing that the polypropylene polymer, when subjected to a number of different solvents, had not altered substantially.     

Relations between specific heat discontinuities and Ginzburg-Landau parameters for superfluid 3He

We show that the value of the ratio ₅/₂₄ deduced from specific heat experiments is extremely sensitive to the coefficient of the quadratic term in the Ginzburg-Landau functional. A strong coupling calculation of this coefficient implies that the experimental value of ₅/₂₄ is more than three times larger than previously believed.This work was supported in part by the National Science Foundation through Grant DMR7826530.     

Thermal Evolution of Alumina Prepared by the Sol-Gel Technique

The thermal evolution of an alumina gel synthesized by hydrolysis of aluminium alkoxide (sol-gel technique) was studied by thermal analysis (DTA and TGA), X-ray diffraction, FTIR and NMR spectroscopies, and specific surface area measurements. Between 400 and 900°C, - and -aluminas were formed showing aluminium vacancies preferentially located in tetrahedral sites. The atomic rearrangements produced during -alumina formation are oriented to the progressive elimination of tetrahedral aluminium in the ultimate phase. The evolution of the specific surface area during heating is explained by changes in structure and microstructure.     

Stability of the nonequilibrium state of a superconductor irradiated by an electromagnetic field

Irradiation of a superconductor by an electromagnetic field with a frequency ₀ larger than twice the energy gap (order parameter) decreases the order parameter . We obtain the quasiparticle distribution function n and the dependence of the order parameter on the power of the electromagnetic field P by solving numerically the kinetic equations for n and in the steady state. We take ₀/₀ = 2.1, 8, and 20, where ₀ is the equilibrium value of the order parameter at T = 0 K. In the examples considered the dependence of on the pumping power P becomes double-valued above a critical power. We allow phonons also to be out of thermal equilibrium. To discuss the stability of the steady state thus obtained, we derive kinetic equations for small deviations of the quasiparticle distribution function and the order parameter from the steady state n and by means of the nonequilibrium Green's function theory. Assuming n, exp(i kr – t), (k) is computed using n _s/, where n _sis the steadystate quasiparticle distribution function for arbitrary . It is concluded in general that the steady state on the upper branch ( > _{c 2}) is stable with respect to both spatially homogeneous and inhomogeneous fluctuations, and the lower branch ( > _{c 2}) is unstable; _{c 2}is the value where the upper and lower branches of (P) coalesce.This work is partly supported by a Grant-in-Aid for Special Project Research from the Ministry of Education, Science and Culture of Japan.