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1.
Cu–Pb deposits at Funtana Raminosa in Central Sardinia were intensively exploited, mostly underground, from 1917 until 1983. Flotation tailings were dumped near the mine plant. A hydrogeochemical survey carried out in 2004 showed that mine drainage collected from several galleries was circumneutral, due to the availability of carbonate minerals that buffer the acidity produced by the oxidation of Fe-bearing sulphides. The mine waters contained higher concentrations of dissolved SO4, F, Zn, Cd, Pb, Mn, and Mo than was observed in uncontaminated spring and stream waters in the area. Drainage from the oldest flotation tailings showed much lower concentrations of Zn, Cd, and Pb than those generally observed in mine waters. In contrast, drainage from the recent flotation tailings had the highest levels of dissolved SO4, Zn, and Cd (1,600, 30, and 0.8 mg/L, respectively) when sampled in the dry season; these were two orders of magnitude lower in the rainy season under high flow condition. Pb was ≈ 5 μg/L under different flow conditions. Water in the Rio Saraxinus, a stream that drains the entire mining area, had a relatively low level of contamination (170 μg/L Zn, 7 μg/L Cd, and 0.9 μg/L Pb).  相似文献   

2.
This study assessed the combined effects of seven large-scale gold mines, one manganese mine, and scattered artisanal gold mining sites on the quality of water in the Ankobra Basin in a geologically complex terrain. Water samples from streams, boreholes, hand dug wells, and mine spoil were analysed. Scatter plots of trends among measured parameters were used to assess drainage quality and differential impacts. Drainage quality exhibits wide seasonal and spatial variations; the geology strongly influences the water chemistry. Areas with low pH (<5.5), and high sulphate ions and trace ions are suggestive of acid mine drainage while sites with high pH (>7.5), HCO3 , subdued SO4 2−, and high trace ions are suggestive of sites where acid neutralization is effective. High metal sources are largely confined to mining operations in the Birimian formation with ores containing more than 2% sulphides. However, restricted high metal regimes are observed in drainage in the Tarkwaian formation associated with scatted sulphide-bearing dolerite dykes in the operational areas of the Tarkwa and Damang mines. Earlier studies disputed sulphides in the Tarkwaian formation until recently, when acid-generating dykes were discovered in operating pits. The most degraded waters emanate from the Prestea and Iduapriem mines, and to a lesser extent, the Nsuta mine sites, all mining Birimian rocks. The Tarkwa mine showed minimal metal loading. Zn, Cu, Ni, As, SO4, pH, and specific conductance are essential and adequate parameters in determining if acid drainage is taking place at these sites, and are recommended for routine mine environmental monitoring.  相似文献   

3.
The Raibl mine (Cave del Predil village, northern Italy) belongs to the Pb–Zn minerogenetic district in the southeastern Alps, hosted in Middle Triassic carbonates. The drainage water quality reflects the high acid-buffering capacity of the carbonate rocks, which controls the mobility of most metals. In particular, Fe is non-detectable in solution, having formed hydrous-oxides precipitates. Molybdenum, Ni, Zn, Cd, Pb, and Tl are present, and the Pb, Tl, and Zn concentrations sometimes exceed the Italian regulatory thresholds. Thallium concentrations substantially exceed the 2 µg/L limit at some sampling stations, ranging between 12 and 30 µg/L in the mine drainage, and reaching 5 µg/L downstream of the mine site, despite strong dilution. The data indicate that Tl behaves almost conservatively and is not significantly scavenged by the Fe precipitates. The elevated Tl represents a potential risk for the stream ecosystem. Although Tl is not regulated in drinking water in Italy or the European Community, its distribution in natural waters may help to determine if health actions should be taken.  相似文献   

4.
Seepage water and drainage water geochemistry (pH, EC, O2, redox, alkalinity, dissolved cations and trace metals, major anions, total element concentrations) were studied at two active sulphide mine tailings impoundments in Finland (the Hitura Ni mine and Luikonlahti Cu mine/talc processing plant). The data were used to assess the factors influencing tailings seepage quality and to identify constraints for water treatment. Changes in seepage water quality after equilibration with atmospheric conditions were evaluated based on geochemical modelling. At Luikonlahti, annual and seasonal changes were also studied. Seepage quality was largely influenced by the tailings mineralogy, and the serpentine-rich, low sulphide Hitura tailings produced neutral mine drainage with high Ni. In contrast, drainage from the high sulphide, multi-metal tailings of Luikonlahti represented typical acid mine drainage with elevated contents of Zn, Ni, Cu, and Co. Other factors affecting the seepage quality included weathering of the tailings along the seepage flow path, process water input, local hydrological settings, and structural changes in the tailings impoundment. Geochemical modelling showed that pH increased and some heavy metals were adsorbed to Fe precipitates after net alkaline waters equilibrated with the atmosphere. In the net acidic waters, pH decreased and no adsorption occurred. A combination of aerobic and anaerobic treatments is proposed for Hitura seepages to decrease the sulphate and metal loading. For Luikonlahti, prolonged monitoring of the seepage quality is suggested instead of treatment, since the water quality is still adjusting to recent modifications to the tailings impoundment.  相似文献   

5.
The Upper Silesian Coal Basin (USCB), 7500 sq.km area (including 5500 sq.km in Poland), is situated in the Variscian Upper Silesian intermountain depression. Coal-bearing Upper Carboniferous rocks occur beneath the permeable Mesozoic and Quarternary sediments in the NE part of the USCB and the impermeable Tertiary clay series in the southern and north—western parts. Studies on hydrogeochemical environment showed a normal vertical and horizontal hydrogeochemical zone in the full extent of the basin. This zone is characterized by changes in mineralization and chemical of waters along circulation routes. Strongly mineralized waters of isolated structures represent brines of the type Cl?Na and specially Cl?Na?Ca. A general trend of increased mineralization is noted along with depth of occurrence of water independently of age of the strata. The general regularity is disturbed by the phenomena of hydrochemical inversion mainly due to the mining activity. In the USCB coal deposits have began to be intensively exploited as early as the 18th century. The coal seams are exploited by the underground mining method, mainly by the longwall system, down to the average depth from 650 m to 1200 m. The steadily increasing mining depth and the opening of new mining levels increase the extent of drainage by mines and amounts as well as salinity of pumped out water. The total quantity of water pumped out of mines equals 724 m3/min. Area of decreased piezometric heads, because of the mine drainage, covers about 2000 sq.km. As the coal mine workings are carried out in different hydrochemical zones, the chemistry of the pumped mine waters vary significantly, with the mineralization of natural mine water ranging from 0.2 to 372.0 g/dm3. The artificial hydraulic interconnections created by mining activities and deep drainage cause changes in the natural hydrochemical regime of groundwater. The desalination effect caused by mining activity depends mainly on the depth and size of mining, duration of exploitation, drainage activity and geological conditions of the USCB. The present hydrochemical zone in the USCB determined by the mining impact is shown on the maps of groundwater mineralization at the depth of 500 and 750 m, as well as on the map of the depth of the occurrence of saline waters (35 g/dm3). There is a close correlation between mineralization of water in the Carboniferous within the coal fields and the type of overlying rocks as well as degree in which the rock mass is affected by mine workings. The maximum salinity of water was found in depressional structures under the cover of sealing. Tertiary rocks, host structure not covered by the Tertiary and affected by mine workings for over a hundred years are characterized by a marked desalination of waters to the depth of about 500 m.  相似文献   

6.
Techniques developed for acid mine drainage (AMD) prediction might not be suitable for contaminated neutral drainage (CND) generating sites. The Tio mine waste is known to generate Ni contaminated neutral drainage in some of the piles, but humidity cell tests fail to generate the Ni concentrations observed in the field. Weathering cell tests (small-scale humidity cell tests) were performed on fresh and weathered (produced 25 years ago) waste rock samples from the Tio mine containing various levels of hemo-ilmenite ore, and results were compared to humidity cell results on similar samples. The main constituents of the waste rock are the hemo-ilmenite ore and the plagioclase gangue; these minerals were purified from the waste rocks and the purified fractions were also submitted to weathering cell tests. The fresh waste rock samples were also submitted to sorption cells (modified weathering cells), which showed that the waste rocks have an important Ni sorption potential and that the sorbed phases are stable under weathering cell conditions. Even though the Ni concentrations obtained from the laboratory tests remain significantly lower than those obtained in field conditions (from field test pads and from waste rock piles), the results from the present study give important insight into the geochemical processes implicated in CND generation.  相似文献   

7.
Techniques developed for acid mine drainage (AMD) prediction might not be suitable for contaminated neutral drainage (CND) generating sites. The Tio mine waste is known to generate Ni contaminated neutral drainage in some of the piles, but humidity cell tests fail to generate the Ni concentrations observed in the field. Weathering cell tests (small-scale humidity cell tests) were performed on fresh and weathered (produced 25 years ago) waste rock samples from the Tio mine containing various levels of hemo-ilmenite ore, and results were compared to humidity cell results on similar samples. The main constituents of the waste rock are the hemo-ilmenite ore and the plagioclase gangue; these minerals were purified from the waste rocks and the purified fractions were also submitted to weathering cell tests. The fresh waste rock samples were also submitted to sorption cells (modified weathering cells), which showed that the waste rocks have an important Ni sorption potential and that the sorbed phases are stable under weathering cell conditions. Even though the Ni concentrations obtained from the laboratory tests remain significantly lower than those obtained in field conditions (from field test pads and from waste rock piles), the results from the present study give important insight into the geochemical processes implicated in CND generation.  相似文献   

8.
Abstract.   The Vale de Abrutiga uranium deposit, located in Central Portugal near the Aguieira dam reservoir, was surface mined. Low-grade ore and waste rock were deposited on permeable ground, close to the mine, and were not revegetated. A lake has formed in the open pit. Surface waters draining the mine site are acidic, have high conductivity, and high concentrations of U, SO42-, Zn, Fe, Mn, Ra, Cu, Th, and Pb. The groundwater and the water from the reservoir cannot be used for human consumption or irrigation. The sampled waters show higher contaminant concentrations in winter than in summer. Stream sediments have high geoaccumulation indices for U, Fe, Ag, Zn, Cr, Co, and Pb. In general, sediments bordering the dam reservoir have higher metal contents in winter than in summer.  相似文献   

9.
The Getchell underground operations in Northern Nevada intersect groundwater associated with marble and hornfel lithologies and a sulfide bearing ore hosted within a 30-km long shear zone system. The deposit is classified as Carlin-type gold mineralization. A distinct feature of the mineralization is the high proportion of arsenic sulfides present in the ore and associated altered wallrock. This results in an intense arsenic enrichment, with some zones containing as much as 30% arsenic, and 0.5–2% arsenic throughout the mineralized envelope. Most of the groundwater in the area is well buffered by the calcareous host rocks and show a macrochemistry of Ca-Na-HCO3. Along the shear zone and in zones within the hornfel host rock, the waters are less alkaline and more saline, and have a chemistry of Na-Mg-Ca-SO4-HCO3. This latter water type occurs in sulfide-bearing zones. Arsenic speciation analysis and theoretical predictions demonstrate that higher arsenic concentrations are associated with reducing conditions, with higher Na/Ca ratios, and with low concentrations of Fe. In these waters, As occurs as arsenite, along with trace concentrations of mono-methyl arsonic acid and di-methyl arsinic acid. Natural attenuation of As appears to occur along groundwater flow paths due to co-precipitation and adsorption onto hydrous ferric oxide particles. However, elevated As is still a notable feature of groundwater quality throughout the Kelly Creek basin. This elevated As occurs in bedrock groundwater during underground mine development, rather than in near-surface alluvium groundwater. Due to this and the protracted history of mining, it is not possible to define a true background value for water quality in the area other than acknowledging that bedrock groundwater is mineralized and has little association with seasonal recharge and water quality in the alluvium cover.  相似文献   

10.
煤矿酸性矿井水中有害元素的迁移特性   总被引:7,自引:0,他引:7       下载免费PDF全文
利用电感耦合等离子质谱(ICP-MS)、离子色谱(IC)和X射线衍射(XRD)等方法研究了马兰煤矿酸性矿井水及其沉淀物的化学成分和物相组成,并通过吸附解吸实验和PHREEQC水化学模拟计算研究了典型酸性矿井水样品中Pb,Th,U,Be,Zn,Ni,Co,Cd,Cu,As,Cr,V,Ba等有害元素的迁移特性.研究表明:① 煤矿酸性矿井水中SO2-4,Fe,Mn,Al,Pb,Th,U,Be,Zn,Ni,Co,Cu等离子含量较高,对环境存在潜在危害;② 酸性矿井水中有害元素的迁移主要受pH,Fe-Al-Mn含量和水体颗粒物矿物组成的控制;③ Fe,Al和Mn的含量随pH上升而迅速下降,并控制着Pb,Th,U,Be,Zn,Ni,Co,Cu等潜在有害微量离子的迁移行为; ④ 各离子随pH上升被去除的先后顺序为: Th>Fe>Pb >Cr>Al>Cu>Be>U>Zn>As>Cd>Mn>Co>Ni>Ba;⑤ 酸性矿井水中V不能够随pH的升高而去除,反而会有更多的V溶解在水中.  相似文献   

11.
阿尔山地区位于中蒙边境南蒙古—东乌旗—阿尔山铁多金属成矿带上,具有巨大的找矿潜力。但由于该区为大兴安岭森林覆盖区且地质勘查程度低,长期以来找矿一直未取得较大进展。结合1∶5万矿调工作成果,将区内铁多金属矿按成因类型划分为3类,对经济价值巨大的矽卡岩型、沉积变质型铁多金属矿进行了重点分析,并与蒙古国南蒙古、我国内蒙古东乌旗地区的典型矿床进行了对比研究。结果表明:南蒙古—东乌旗—阿尔山铁多金属成矿带矽卡岩型铁多金属矿床主要受NE向大断裂及其派生的次一级断裂控制,矽卡岩都为与酸性岩浆岩有关的钙矽卡岩,容矿围岩都含有利于矽卡岩矿床成矿的碳酸盐岩石,围岩蚀变主要为矽卡岩化、硅化、碳酸盐化、绿帘石化等;该铁多金属成矿带沉积变质型铁多金属矿床主要受NE向褶皱控制,都为与大规模燕山早期酸性侵入岩有关的BIF型铁矿,都具有原始海相沉积后期变质叠加改造成矿的特点,都为低品位矿石,主要容矿围岩都为板岩、片岩、千枚岩等中低级变质岩。在此基础上,初步总结了阿尔山地区铁多金属矿的成矿地质条件与找矿方向,并划分出不同成因矿床的成矿远景区。随着地质勘探工作的进一步加强,该区有望发现大型矽卡岩型铁多金属矿、大中型沉积变质型铁多金属矿及中小型热液脉型铁多金属矿。  相似文献   

12.

This publication is a case study of the seasonal variability of mine water drainage from the Saint Louis Tunnel (SLT) at the inactive Rico-Argentine mine site located in southwestern Colorado. It is an introductory paper for the two passive water treatment system technology evaluations contained in this issue. Mine water chemistry changes from baseflow to a snowmelt runoff event (SMRE) where snowmelt runoff follows preferential migration pathways to flush acidic weathering products from the upper mine workings to the SLT. Baseflow mine drainage is characterized as circumneutral, with Zn, Cd, Mn, and Ni concentrations primarily in the dissolved form. Dissolved Zn, Mn, Fe, and potentially Cd illustrate equilibrium with carbonate minerals. Total concentrations of Fe, Cu, Pb, and As are primarily in the suspended form and suggest sorption to Fe oxides. Mine water chemistry during the SMRE reflects mixing of circumneutral baseflow waters with more acidic waters flushing the upper mine workings. Geothermal activity provides for a consistently warm mine water discharge from the SLT. The two seasons that provide the most challenge to passive water treatment of SLT mine drainage are the SMRE period and the low flow stage of the Dolores River. Mine water flow and chemistry during SMRE are highly correlated with Dolores River flow and this site conceptual model was and will be used to assist in pilot project evaluation, water treatment system design, monitoring system design, a seasonal compliance approach, and water management.

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13.
针对某钨矿山多金属硫化矿的矿石性质特点,开展了优先浮钼—铜铋混合浮选工艺、优先浮钼—浮铜—浮铋工艺和钼铜混合浮选—浮铋—浮锌的工艺流程对比试验,结果表明:采用钼铜混合浮选—浮铋—浮锌的全流程工艺,可获得含钼53.50%、回收率为92.72%的钼精矿,含铋11.30%、回收率为58.71%的铋精矿,含铜22.89%、回收率为87.62%的铜精矿,含锌55.28%、回收率为73.22%的锌精矿;而且铋精矿中含银9 000 g/t、含铅58.23%,回收率分别为66.89%、77.40%;同时浮选尾矿进一步回收可获得含钨38.52%、回收率为79.57%的钨精矿,实现了钼、铋、铜、锌、铅和钨的综合回收。  相似文献   

14.
广西武宣石叠水泥用灰岩矿位于广西武宣县桐岭镇,为一大型水泥用石灰岩矿床。矿床赋存于上石炭—下二叠统马平组地层中,岩性为浅灰色中厚层状生物屑微晶灰岩夹少量白云岩。矿石质量稳定,为单一的Ⅰ级品。通过对矿区地质特征及矿床成因的论述,分析了矿床沉积环境及成矿物质来源的演变过程,认为广西武宣石叠水泥用灰岩矿属浅水开阔台地型浅海相生物化学成因沉积碳酸盐矿床。  相似文献   

15.
The Apliki mine, a Cyprus-type massive sulphide deposit in Cyprus, was exploited for copper until the mid-1970s. Abandonment of the mine left a deep pit that now hosts a lake fed by surface runoff from the surrounding mineralized zone and hydrothermally altered basalt. Oxidation of the sulphide minerals and factors such as climate and terrain relief control the water–rock interactions that generate acid mine drainage (AMD), which ultimately affects and defines the quality of the lake waters. Pyrite and chalcopyrite constitute an almost inexhaustible sulphide source that leads to the formation of a variety of secondary iron and copper mineral phases. The secondary mineral assemblages in the ore zone are mainly iron, copper, and magnesium sulphates, whereas the lakeshore assemblage is dominated by magnesium-, calcium-, sodium-, and aluminum-bearing sulphate minerals. Near the lakeshore, the highly soluble iron sulphate salts dissolve in the lake water, increasing its iron content. Other less soluble salts are more stable and persist in the lakeshore environment. The precipitation and dissolution of efflorescent salts, and, to a lesser extent, the oxidative weathering of the remaining ore minerals, produce additional AMD. Due to the perpetual cycle of mineral dissolution and precipitation, the lake has a low pH (≈3) and contains high concentrations of some contaminants. The processes that contribute to the formation of the efflorescent mineral assemblages and their environmental impact on pit lake waters, and indeed the complete geochemical system, is a typical example of secondary mineral formation in Cyprus-type Cu-pyrite massive sulphide ore deposits.  相似文献   

16.
Abstract.  The Sleeper open pit gold mine operated from the mid-1980s through the mid-1990s. Operations were mostly sub-water table and extensive dewatering was required to lower groundwater levels by 180 m. Dewatering flows peaked at 930 L/s, with most flow contributed from an alluvial aquifer. After completion of mining, the pit was rapidly filled with water pumped from the alluvial aquifer to reduce the exposure time of sulfide wall rocks and waste rocks in the ultimate pit. The pumped alluvial groundwater provided a large volume of low total dissolved solids (TDS), high alkalinity water that controlled the early chemistry. The rising lake waters were amended with lime to buffer excess acidity contributed to the lake from reactive pit wall rocks during submergence. The pore water contained in submerged waste rock at the base of the pit was elevated in TDS and subsequently of higher density that the lake water. The density contrast and waste rock location limited contributions of waste rock pore water to the main body of the lake. Some stratification of the early lake occurred, with shallow water characterized by higher pH, low dissolved metals, and sulfate; deeper water had lower pH and higher dissolved metals and sulfate. The reservoir of alkalinity in the shallow layer mixed with the deeper waters and created a stabilized lake with a homogenized column that exceeded water quality expectations. Current water quality meets all Nevada primary drinking water standards with the exception of sulfate, TDS, and manganese, which are slightly elevated, as predicted. Chemistry has remained stable since development of the initial lake.  相似文献   

17.
Antimony, a toxic metalloid similar to arsenic, is present at variable levels in most gold-bearing rocks. Antimony is soluble in the surface environment, so antimony (Sb) mobilization in mine waters is an environmental issue around gold mines. The Reefton gold mine was originally developed in gold-bearing quartz veins; Sb concentrations were low (<100 mg/kg) compared to arsenic (As) concentrations (>1,000 mg/kg), and the mine waters had low dissolved Sb (<0.1 mg/L). A second stage of gold mineralization at Reefton involved brecciation and cataclasis of quartz veins and wall rocks, with addition of stibnite (Sb2S3). Processing of this ore has resulted in higher dissolved Sb in mine waters (0.1–1 mg/L), even after water treatment that removes most dissolved As (to 0.01 mg/L) by adsorption to suspended iron oxyhydroxide. Competition between As and Sb for adsorption sites on iron oxyhydroxide particles may have resulted in partial exclusion of the more weakly adsorbed Sb. The high rainfall (2,000 mm/year) at Reefton ensures adequate dilution of mine waters after discharge. The Macraes gold mine has no stibnite, and most Sb is in solid solution in the abundant arsenopyrite (Sb up to 2,000 mg/kg). Pit waters have both Sb and As dissolved up to 0.1 mg/L, partly because of evaporative concentration in a low-rainfall environment. Macraes tailings waters have high As (up to 3 mg/L) but negligible Sb (<0.001 mg/L). Reefton mine gold-bearing concentrate, containing stibnite, is transported 700 km to be processed by autoclave oxidation and cyanidation at the Macraes mine. This introduction of additional Sb to the Macraes site substantially increases the Sb content of the process stream periodically. Tailings from this process have up to 3 wt% Sb, dispersed through As-rich iron oxyhydroxides that are formed in the autoclave. The Sb-rich tailings are strongly diluted (approximately 100:1) by the Macraes tailings, and adsorption of Sb to iron oxyhydroxides in the tailings piles ensures that there has been no increase in the Sb content of the tailings water since the Reefton concentrate has been added at Macraes.  相似文献   

18.
Water quality regulations recently adopted by states in the western USA have increasingly stringent limitations on allowable changes in the quality of surface water and groundwater. The “nondegradation of water” provisions in state regulations require accurate predictions and control of the quantity and quality of acid mine water and strictly limit the entry of acid water into natural water systems. Long-term water quality impacts from mine waste rock, spent ore from heap leaching, tailings and open pits must be considered in design, operation and reclamation of proposed or expanded mining operations. Acid-base testing, humidity cells, column testing and shake flask tests have been used with mixed success to predict the extent of acid water production. The types and forms of sulfide minerals present, bacterial catalysis of the sulfide oxidation reaction and configuration of the reclaimed facilities are all important elements in accurately predicting acid mine drainage. A critical factor in prediction of acid mine impacts is a pathway and fate analysis which includes geochemical reactions with aquifer materials and dilution and dispersion of parameters in the leachate plume. Of particular concern is the production and transport of arsenic, metals and residual cyanide from mined areas. Evaluation of three major operating gold mines in the northwestern United States shows the relationship between production of acidic water, movement of this water in aquifers and impacts on groundwater and surface water. Column testing showed reduction in concentrations of most metals by 50 to over 90 percent during travel through aquifers. Clays and silt zones were very effective in adsorbing metals. Operational control of water/rock reactions and reclamation design can significantly reduce or eliminate acid drainage. Soil cover, revegetation and slope are the major components that limit long-term acid drainage and metal contamination of surface water and groundwater. Compliance with water quality limits can be achieved only by design and operation of mining facilities to minimize the formation of acidic waters.  相似文献   

19.
遥感技术在探查峰峰矿区奥灰水中的应用   总被引:2,自引:0,他引:2  
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20.
夏冬  常宏 《金属矿山》2015,44(12):157-160
为保护地下水资源,合理开发矿产资源,采用全封闭的注浆堵水帷幕堵截地下水是保证大水矿山正常开采的一种有效的技术措施。在井巷施工及矿体开采过程中,需对帷幕内围岩进行疏干排水,随着疏干排水的进行,势必会在帷幕内外形成一定的水力梯度,这将对帷幕的稳定性产生很大的不利影响。结合中关铁矿注浆堵水帷幕工程,根据矿区的水文地质资料、工程地质资料和钻孔资料,建立堵水帷幕区域的三维地质模型、三维可视化模型和三维力学计算模型,并对帷幕内围岩疏干排水引起的应力响应进行分析。结果表明:疏干排水使堵水帷幕区域的应力场发生了明显的改变,疏干排水对西侧和西南侧帷幕的扰动较为明显。  相似文献   

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