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通过雾化干燥法混炼制备纳米氧化锌(ZnO)/天然橡胶复合材料,并对其性能进行研究,同时与传统湿法混炼和传统干法混炼复合材料进行对比。结果表明:与采用传统湿法混炼和传统干法混炼相比,采用雾化干燥法混炼可使纳米ZnO在橡胶基体中分散较均匀,且无明显团聚,硫化胶的交联网络均匀,交联密度较大,物理性能、耐溶剂性能、耐老化性能和导热性能较好;采用雾化干燥法混炼可以减小胶料的纳米ZnO用量,缩短硫化时间,保证硫化胶的各项性能稳定。 相似文献
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针对炭黑与橡胶混炼难度大以及传统干法混炼工艺繁琐、产生粉尘污染等问题,研究全配方(补强填料包括炭黑和白炭黑)湿法连续混炼工艺。结果表明:全配方湿法连续混炼工艺分为4个阶段,分别为补强填料和小料水分散体的制备、炭黑母胶的制备、白炭黑母胶的制备、连续混炼;全配方湿法连续混炼工艺从初期补强填料和小料水分散体的研磨到后期的连续混炼均促进了炭黑在橡胶基体中的分散,使硫化胶的物理性能和动态力学性能比传统干法混炼工艺硫化胶明显提高,同时避免了干法混炼工艺的粉尘飞扬的问题,可实现胶料的清洁化、连续化生产。 相似文献
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根据无机配合剂在橡胶中的分散形态,研究纳米氧化锌在橡胶中的作用机理及其对胶料性能的影响。在硫化过程中氧化锌作为活性剂与有机促进剂、硬脂酸、硫黄等的反应发生在氧化锌粒子的表面。以纳米氧化锌等量替代普通问接法氧化锌,可提高硫化胶的300%定伸应力和耐磨性,减小压缩永久变形,降低压缩疲劳温升;以纳米氧化锌减量50%替代间接法氧化锌,仍可保证硫化胶的性能要求。 相似文献
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原位生成甲基丙烯酸锌对天然橡胶补强的研究 总被引:2,自引:0,他引:2
在天然橡胶(NR)混炼过程中加入氧化锌与甲基丙烯酸(MAA),在橡胶基体中原位生成甲基丙烯酸锌(ZDMA),并在硫化剂过氧化二异丙苯作用下制备NR/ZnO/MAA硫化胶。用扫描电镜、透射电镜研究了硫化胶的形态,并研究了制备条件对硫化胶力学性能的影响,结果表明,在155℃硫化温度,DCP用量为1.5~2 0质量份(phr)条件下,NR硫化胶具有较佳的力学性能。随着ZnO/MAA用量的增加,硫化胶定伸应力、拉伸强度和撕裂强度显著增加,表现出显著的补强作用。 相似文献
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介绍纳米氧化锌替代普通氧化锌在胶鞋胶料中的应用情况。应用纳米氧化锌可以改善胶料的硫化特性和混炼特性等加工性能;在胶料含胶率适当降低的条件下,仍可提高大底和围条硫化胶的物理性能;可使海绵中底胶料的发泡率由85%提高至92%,且泡孔结构小而均匀,从而提高胶鞋的质量。 相似文献
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纳米ZnO在减震器胶料中的应用研究 总被引:1,自引:1,他引:1
探讨了纳米氧化锌对减震器胶料硫化特性和力学性能的影响。结果表明,和普通氧化锌在同等用量时,纳米氧化锌可以缩短胶料的硫化时间,提高胶料的力学性能。台架实验证明,纳米氧化锌用量5份时,橡胶减震器寿命提高20%。 相似文献
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Zhenhua Wang Yonglai Lu Jun Liu Zhimin Dang Liqun Zhang Weimin Wang 《应用聚合物科学杂志》2011,119(2):1144-1155
In this article, nano‐zinc oxide (ZnO) filled ethylene propylene diene monomer (EPDM) composites are prepared, and the mechanical (static and dynamic) properties and thermal conductivity are investigated respectively, which are further compared with the traditional reinforcing fillers, such as carbon black and nano‐silica. Furthermore, influence of in‐situ modification (mixing operation assisted by silane at high temperature for a certain time) with the silane‐coupling agent Bis‐(3‐thiethoxy silylpropyl)‐tetrasufide (Si69) on the nano‐ZnO filled composites is as well investigated. The results indicate that this novel reinforcing filler nano‐ZnO can not only perform well in reinforcing EPDM but can also improve the thermal conductivity significantly. In‐situ modification with Si69 can enhance the interfacial interaction between nano‐ZnO particles and rubber matrix remarkably, and therefore contribute to the better dispersion of filler. As a result, the mechanical properties and the dynamic heat build‐up of the nano‐ZnO filled composites are improved obviously by in‐situ modification, without influencing the thermal conductivity. In comparison with traditioanl reinforcing fillers, in‐situ modified nano‐ZnO filled composites exhibit the excellent performance in both mechanical (static and dynamic) properties and better thermal conductivity. In general, our work indicates that nano‐ZnO, as the novel thermal conductive reinforcing filler, is suitable to prepare elastomer products serving in dynamic conditions, with the longer expected service life. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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Polymethyl methacrylate (PMMA)/zinc oxide (ZnO) composites were prepared using melt mixing process. A nano ZnO-treated with aminopropyl triethoxysilane (APTS) was used as reinforcing particles. PMMA composites were obtained with different ZnO loadings of 0, 0.5, 1 and 2 parts by weight. This research was focused on determination of the influence of different loadings of silane-treated ZnO particles on the morphology, electrical, mechanical and flammable properties of the PMMA composites. Addition of ZnO to the PMMA composite was observed to enhance the thermal properties and char formation. The results from cone calorimeter showed 21% reduction in the peak heat release rate for the composite loaded with 1.5 wt% of ZnO as compared to that of neat PMMA. The surface resistivity, volume resistivity and EMI shielding properties of the composites as a function of ZnO loading were estimated. The results showed that the surface and volume resistivity of the composites reinforced with ZnO particles decreased and the EMI shielding increased almost linearly with increasing ZnO volume content. However, the tensile strength of the composites showed a slight decrease with increase in ZnO content. The SEM micrographs and AFM images showed dispersion of ZnO particles in the PMMA matrix. The nanoparticles were distributed evenly on the surface. Nevertheless the pockets of agglomerates could be seen at higher ZnO loading level. 相似文献
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以环己烷为溶剂,苯乙烯(St)、丁二烯(Bd)、异戊二烯(Ip)为单体,正丁基锂为引发剂,采用负离子聚合法合成了集成橡胶———星形苯乙烯-异戊二烯-丁二烯嵌段共聚物(SIBR),考察了星形SIBR的相对分子质量、侧基含量、嵌段比(即Ip的均聚物链段与St-Bd的无规共聚物链段的质量比)与其性能的关系。结果表明,在考察范围内,星形SIBR的拉伸强度和撕裂强度随着其相对分子质量的增加而增大。随着1,2-和3,4-结构含量之和的增加,0℃和60℃时的损耗因子均有所增大。固定St/Bd(质量比)为1/3,随着嵌段比的逐渐降低,所得星形SIBR的门尼黏度逐渐增大;嵌段比为20/80时所得星形SIBR具有较好的力学性能与动态力学性能,且与溶聚丁苯橡胶2300、2305以及天然橡胶相比,具有更好的抗湿滑性和滚动阻力的平衡。 相似文献
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Jongchul Seo Gwonyoung Jeon EUi Sung Jang Sher Bahadar Khan Haksoo Han 《应用聚合物科学杂志》2011,122(2):1101-1108
A series of polypropylene carbonate (PPC)/ZnO nanocomposite films with different ZnO contents were prepared via a solution blending method. The morphological structures, thermal properties, oxygen permeability, water sorption, and antibacterial properties of the films were investigated as a function of ZnO concentration. While all of the composite films with less than 5 wt % ZnO exhibited good dispersion of ZnO in the PPC matrix, FTIR and SEM results revealed that solution blending did not lead to a strong interaction between PPC and unmodified ZnO. As such, poor dispersion was induced in the composite films with a high ZnO content. By incorporating inorganic ZnO filler nanoparticles, the diffusion coefficient, water uptake in equilibrium, and oxygen permeability decreased as the content of ZnO increased. The PPC/ZnO nanocomposite films also displayed a good inhibitory effect on the growth of bacteria in the antimicrobial analysis. The enhancement in the physical properties achieved by incorporating ZnO is advantageous in packaging applications, where antimicrobial and environmental‐friendly properties, as well as good water and oxygen barrier characteristics are required. Furthermore, UV light below ~ 350 nm can be efficiently absorbed by incorporating ZnO nanoparticles into a PPC matrix. ZnO nanoparticles can also improve the weatherability of a PPC film. In future research, the compatibility and dispersion of the PPC matrix polymer and the inorganic ZnO filler nanoparticles should be increased. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011. 相似文献
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Sirirat Wacharawichanant Angsumon Sangkhaphan Niramon Sa‐Nguanwong Vitsarut Khamnonwat Supakanok Thongyai Piyasan Praserthdam 《应用聚合物科学杂志》2012,123(6):3217-3224
The effects of particle size of titanium dioxide (TiO2) on mechanical, thermal, and morphological properties of pure polyoxymethylene (POM) and POM/TiO2 nanocomposites were investigated and compared with the results for nanoparticle ZnO in the same matrix, reported in a previous paper. POM/TiO2 nanocomposites with varying concentration of TiO2 were prepared by the melt mixing technique in a twin screw extruder, the same method that used for blending the homogeneous ZnO nanocomposites. The dispersion of TiO2 particles in POM nanocomposites was studied by scanning electron microscopy (SEM). The agglomeration, as observed by the mechanical properties of TiO2 particles in the polymer matrix, increased with increasing TiO2 content, a result not found for ZnO even at lower particle sizes. Increasing the filler content of POM/TD32.4 and POM/TD130 (130 nm) nanocomposites resulted in a decrease in tensile strength. The Young modulus, stress at break and impact strength of TiO2 nanocomposite did not improve with increasing filler contents, in opposition to the better agglomeration conditions of ZnO nanocomposite even at lower particle sizes. Because of agglomeration, the POM/TD32.4 nanocomposites had lower mechanical properties and lower degradation temperature than the POM/TD130 ones. The sizes of nanoparticles determined the agglomeration, but however, the agglomeration also depended on the type of nanoparticles, even when using the same matrix (POM) and the same mixing method. TiO2 nanoparticles were more difficult to mix and were more agglomerated in the POM matrix as compared to ZnO nanoparticles, regardless of the size of the nanoparticles. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献