Effect of Microstructures on Resistance of a Hot Elevated-Temperature Wear Working Die Steel

 Elevated-temperature wear tests under atmospheric conditions at 400 ℃ were performed for a hot working die steel H21 on a pin-on-disk wear tester. The phase and morphology of worn surfaces were examined using XRD and SEM, and the relation of wear resistance to tempered microstructures was studied for H21 steel. XRD patterns exhibit that oxidative wear is a predominated wear mechanism with Fe3O4 and Fe2O3 on worn surfaces. It is found that with increasing normal load, obvious plastic deformation of substrate appears on worn surfaces. Microstructures start to affect apparently wear resistance of the steel with an increase of load. Under loads of 50-100 N, wear losses of steel retain low values and relatively approach for steels with various microstructures. As loads are increased to 150-200 N, wear losses of steel start to increase obviously and present apparent difference for steel with various microstructures. Wear resistance is found to increase in the sequence as follows: tempered sorbite, tempered martensite, tempered troostite without secondary hardening and tempered troostite with secondary hardening or upcoming one. Higher strength and microstructural stability are required for steels with excellent wear resistance.     

Research on Thermal Wear of Cast Hot Forging Die Steel Modified by Rare Earths

Thermal wear of cast hot-forging die steel modified by rare earths（RE） was studied and compared with commercially used die steels. The function of RE and the mechanism of thermal wear of cast steel modified by RE were discussed. The results showed that with increasing content of RE, the wear rate of cast steel reduced at first and then increased. By adding 0.05% （mass fraction） RE, the cast hot-forging die steel with optimum thermal wear resistance was obtained, which was better than that of H13 and 3Cr2WSV. The large amount of coarse inclusions, （RE）2O2S, resulted from excessive RE, which obviously deteriorated thermal wear resistance. The mechanism of thermal wear of the modified cast die steel is oxidation wear and oxide fatigue delamination. The wear debris are lumps of Fe2O3 and Fe3O4.     

Effect of Alloying Elements on Thermal Wear of Cast Hot-Forging Die Steels

The effect of main alloying elements on thermal wear of cast hot-forging die steels was studied. The wear mechanism was discussed. The results show that alloying elements have significant influences on the thermal wear of cast hot-forging die steels. The wear rates decrease with an increase in chromium content from 3% to 4% and molybdenum content from 2% to 3%, respectively. With further increase of chromium and molybdenum contents, chromium slightly reduces the wear resistance and molybdenum severely deteriorates the wear resistance with high wear rate. Lower vanadium/carbon ratio （1.5-2.5） leads to a lower wear resistance with higher wear rate. With an increase in vanadium/carbon ratio, the wear resistance of the cast steel substantially increases. When vanadium/carbon ratio is 3, the wear rate reaches the lowest value. The predominant mechanism of thermal wear of cast hot-forging die steels are oxidation wear and fatigue delamination. The Fe2O3 and Fe3O4 or lumps of brittle wear debris are formed on the wear surface.     

Effect of Heat Treatment on Structure and Wear Re- sistance of High Chromium Cast Steel ContainingBoron

The microstructure, mechanical properties and wear resistance of high chromium cast steel containing boron after different heat treatments were studied by means of the optical microscopy （OM）, the scanning electron microscopy （SEM）, X-ray diffraction （XRD）, hardness, impact toughness, tensile and pin-on-disc abrasion tests. The results show that as cast microstructures of boron-free high chromium steel consist of martensite and a few （Cr, Fe）_7C_3 carbide, and the macro-hardness of boron-free high chromium steel is 55-57 HRC. After 0.5 mass% B was added into high chromium cast steel, as-cast structure transforms into eutectic （Fe, Cr）2B, （Cr, Fe）7 （C, B）a and martensite, and the macro-hardness reaches 58-60 HRC. High temperature quenching leads to the disconnection and isolated distribution of boride, and there are many （Cr,Fe）_23 （C,B）_6 precipitated phases in the quenching structure. Quenching from 1050 ℃, high chromium steel obtained the highest hardness, and the hardness of high chromium cast steel containing boron is higher than that of boron-free high chromium steel. The change of quenching temperature has no obvious effect on impact toughness of high chromium steel, and the increase of quenching temperature leads to tensile strength having an increasing tendency. At the same quenching temperature, the wear resistance of high chromium cast steel containing boron is more excellent than that of boron-free high chromium steel. High chromium cast steel guide containing boron has good performance while using in steel bar mill.     

Alloying Design for High Wear-Resistant Cast Hot-Forging Die Steels

The alloying design of cast hot-forging die steels was analyzed. The relationship of the life of cast hot-forging dies with the failure patterns was studied. The thermal wear resistance was believed to be the key property for the alloying design of cast hot-forging die steels. The alloying design parameters were selected and optimized for the cast hot-forging die steel with high wear resistance. The wear resistance of the optimized cast die steel was evaluated in comparison with commercial H13 steels and 3Cr2WSV steel. In the new cast hot-forging die steel, VC is predominant carbide with Cr and Mo as the main solution elements in α-Fe. It is found that the cast die steel has significantly lower wear rate than normal H13 steel and 3Cr2W8V steel, almost the same as that of high purity H13 steel. The high wear resistance of the new cast hot-forging die steel can be attributed to its reasonable alloying design and nonsensibility to the detrimental function of S and P.     

冲击载荷对10Mn钢磨损性能的影响及耐磨机制分析

通过水韧处理配合450℃时效热处理工艺,研究10Mn钢在2和5 J冲击载荷下耐磨性能.结果表明,10Mni钢在5J冲击载荷下失重量更少,加工硬化的速率更快,并且在不同冲击载荷下磨损失重量都出现了周期性变化.磨损表面SEM结果表明,表面存在犁削磨损、凿削磨损、裂纹.通过XRD数据对亚表面奥氏体和马氏体体积分数进行定量计算...     

0Cr17Ni7Al钢的摩擦磨损行为研究

采用销盘式高温磨损试验机对0Cr17Ni7Al钢进行干滑动摩擦磨损试验,研究了该材料不同热处理状态、不同工况下的摩擦磨损行为,采用EDS、XRD、SEM分析磨损表面成分、形貌和磨面剖面结构,探讨0Cr17Ni7Al钢的磨损机理。结果表明:磨损率随着载荷的增加而增加,随环境温度的升高而升高。其中在环境温度25℃和200℃低载时,磨损形式主要以磨粒磨损为主,随着载荷增加变成由粘着磨损和磨粒磨损混合作用机制。200℃高载时候磨损形式主要以粘着磨损为主,400℃时开始出现疲劳磨损。环境温度25℃和200℃低载时固溶处理试样的耐磨性最好,而在400℃时最差。     

微钒Cr-B系NM400耐磨钢的热处理工艺

 采用在Cr-B系中添加微量钒的低成本设计思路来确定NM400耐磨钢的合金成分,详细研究了不同淬火温度和回火温度对NM400耐磨钢显微组织和力学性能的影响,获得了适合工业生产的热处理工艺制度。通过光学显微镜、SEM和TEM观察,分析了经不同温度回火后马氏体组织精细结构的演变规律。结果表明：试验钢具有良好的淬透性,经900~930℃淬火、250℃保温90min回火后得到均匀细小的回火板条马氏体组织;TEM分析表明,回火板条马氏体的宽度在0.1~0.2μm,板条内分布细小均匀的碳化物析出粒子（主要是10~20nm碳氮化钒）,提高钢的综合力学性能。     

新型低合金高强韧性耐磨钢的研究

采用多元合金化及变质处理设计了一种新型低合金高强度高韧性耐磨钢。研究了钢的基本特性、显微组织、断口形貌以及热处理工艺对钢的力学性能和耐磨性的影响。研究结果表明,该钢的过冷奥氏体的稳定性高,具有高淬透性及高回火稳定性,经８８０～９２０℃淬火及２５０～３００℃回火后获得回火板条马氏体组织,使钢具有高强韧性及高耐磨性     

热处理工艺对Cr12MoV钢组织、硬度及耐磨性的影响

本试验研究了不同淬火和回火工艺热处理对Cr12MoV钢组织、硬度和磨损性能的影响。实验结果表明:当在1050~1100℃范围内淬火、520℃回火时,得隐针马氏体+少量残余奥氏体组织,材料硬度与耐磨性均较好;当在1100℃淬火,各温度二次回火硬度均较一次回火高,当在550℃回火时,试验钢实现二次硬化,且残余奥氏体大量转变,硬度和耐磨性达最大值,材料性能最优。     

热处理工艺对100mm特厚07MnCrMoVR水电钢板组织性能的影响

对07MnCrMoR水电钢板的淬透性曲线进行了测定,利用淬火机和热处理炉对100 mm厚试验钢板进行了淬火和回火试验,并对试验钢进行了组织观察和力学性能测定。结果表明,随着试验钢距水冷端的距离增大,淬火组织由马氏体转变为粒状贝氏体,距离端部50 mm处转变为铁素体和粒状贝氏体的混合组织。试验钢板利用淬火机淬火后得到板条贝氏体+粒状贝氏体+先共析铁素体,回火后转变为铁素体+粒状贝氏体,同时大量的碳化物在铁素体基体和晶界处析出。试验钢最合理的热处理工艺为930℃ 30min水冷淬火,660℃ 60min空冷回火。     

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Effect of heat treatment process on corrosion performance of plastic die steel P20 and mechanism for corrosion were studied by electrochemical test, electrochemical impedance spectrum test, weight loss test, neutral salt spray test, SEM, EDS and XRD. It is found that the steels with bainite/martensite quenched at 860?? by air cooling or martensite quenched at 860?? by oil cooling have better corrosion resistance than the steel with ferritic/martensitic quenched at 785?? by oil cooling. After the samples with bainite/martensite or martensite are tempered at 450 and 620?? respectively, martensite and bainite decompose and a lot of carbides precipitate, leading to a poor corrosion resistance. After electrochemical test, the outer layer of corrosion product on the surface of the samples is loose FeOOH and the inner layer is relatively dense Fe3O4. The anode reaction is mainly dissolution of Fe and the cathode reaction is generation of hydrogen. Pitting mainly occurs around inclusions in NaCl solution of 0. 5mol/L.     

Wear Behavior and Mechanism of a Cr-Mo-V Cast Hot-Working Die Steel

The wear behavior and mechanisms of a Cr-Mo-V cast hot-working die steel with three microstructures (tempered martensite, troostite, and sorbite) were studied systematically through the dry-sliding wear tests within a normal load range of 50 to 300 N and an ambient temperature range of 298 K to 673 K (25 °C to 400 °C) by a pin-on-disk high-temperature wear machine. Five different mechanisms were observed in the experiments, namely adhesive, abrasive, mild oxidative, oxidative, and extrusive wear; one or more of those mechanisms would be dominant within particular ranges of load and temperature. The transition of wear mechanisms depended on the formation of tribo-oxides, which was related closely to load and temperature, and their delamination, which was mainly influenced by the matrix. By increasing the load and ambient temperature, the protective effect of tribo-oxides first strengthened, then decreased, and in some cases disappeared. Under a load ranging 50 to 300 N at 298 K (25 °C) and a load of 50 N at 473 K (200 °C), adhesive wear was the dominant wear mechanism, and abrasive wear appeared simultaneously. The wear was of mild oxidative type under a load ranging 100 to 300 N at 473 K (200 °C) and a load ranging 50 to 150 N at 673 K (400 °C) for tempered martensite and tempered troostite as well as under a load of 100 N at 473 K (200 °C) and a load ranging 50 to 100 N at 673 K (400 °C) for tempered sorbite. At the load of 200 N or greater, or the temperatures above 673 K (400 °C), oxidative wear (beyond mild oxidative wear) prevailed. When the highest load of 300 N at 673 K (400 °C) was applied, extrusive wear started to dominate for the tempered sorbite.     

稀土对低合金耐磨铸钢组织和性能的影响

采用扫描电镜分析,硬度测试和摩擦性能测试等手段,研究了稀土对低合金耐磨铸钢组织和性能的影响。结果表明,在低合金耐磨铸钢中添加0.15%稀土,可细化合金铸态组织,增加铸态组织中的铁素体数量,减少珠光体数量,同时可细化热处理后合金的贝氏体组织,使铁素体形态和大小分布均匀,马氏体数量减少。添加稀土后可使铸态合金硬度提高9.4%,摩擦系数由0.136 9减小为0.081 9。     

组织形态对718塑料模具钢切削性能的影响

通过热处理制备出具有回火马氏体组织、下贝氏体组织以及粒状贝氏体组织的718钢,利用光学显微镜、扫描电子显微镜、X射线衍射仪、万能拉伸实验机比较其显微组织及力学性能。同时借助高速铣削实验及光学轮廓仪,研究力学性能以及组织结构对切削性能的影响。结果表明,当切削速度低于145 m·min?1时,贝氏体组织类型比回火马氏体组织更易切削,切削贝氏体组织比切削回火马氏体组织的刀具使用寿命高30%～40%。当切削速度高于165 m·min?1时,马氏体组织发生了加工软化现象,刀具使用寿命提高,切削性能上升。粒状贝氏体组织加工表面因为严重的刀具黏附而出现背脊纹路,马氏体组织具有最佳的切削表面粗糙度。综合考虑之下,三种组织的综合切削性能从高到低排序为:下贝氏体组织、马氏体组织、粒状贝氏体组织,采用300 ℃等温淬火工艺可以有效提升718塑料模具钢的综合切削性能。      

Effects of Alloying Elements on Microstructure,Hardness, Wear Resistance,and Surface Roughness of Centrifugally Cast High-Speed Steel Rolls

A study was made of the effects of carbon, tungsten, molybdenum, and vanadium on the wear resistance and surface roughness of five high-speed steel (HSS) rolls manufactured by the centrifugal casting method. High-temperature wear tests were conducted on these rolls to experimentally simulate the wear process during hot rolling. The HSS rolls contained a large amount (up to 25 vol pct) of carbides, such as MC, M₂C, and M₇C₃ carbides formed in the tempered martensite matrix. The matrix consisted mainly of tempered lath martensite when the carbon content in the matrix was small, and contained a considerable amount of tempered plate martensite when the carbon content increased. The high-temperature wear test results indicated that the wear resistance and surface roughness of the rolls were enhanced when the amount of hard MC carbides formed inside solidification cells increased and their distribution was homogeneous. The best wear resistance and surface roughness were obtained from a roll in which a large amount of MC carbides were homogeneously distributed in the tempered lath martensite matrix. The appropriate contents of the carbon equivalent, tungsten equivalent, and vanadium were 2.0 to 2.3, 9 to 10, and 5 to 6 pct, respectively.     

Microstructure and Abrasive Wear Behavior of Medium Carbon Low Alloy Martensitic Abrasion Resistant Steel

The effect of processing parameters such as hot rolling and heat treatment on microstructure and mechanical properties was investigated for a new 0.27mass% C and Ni,Mo-free low alloy martensitic abrasion resistant steel.The three-body impact abrasive wear behavior was also analyzed.The results showed that two-step controlled rolling besides quenching at 880℃and tempering at 170℃could result in optimal mechanical property:the Brinell hardness,tensile strength,elongation and-40 ℃impact toughness were 531,1 530 MPa,11.8% and 58J,respectively.The microstructure was of fine lath martensite with little retained austenite.Three-body impact abrasive wear results showed that wear mechanism was mainly of plastic deformation fatigue when the impact energy was 2J, and the relative wear resistance was 1.04times higher than that of the same grade compared steel under the same working condition.The optimal hardness and toughness match was the main reason of higher wear resistance.     

不同冲击载荷下10Mn钢和NM500的磨损性能及机理

为了给不同类型耐磨钢的实际使用环境提供可靠试验依据,研究不同微观组织的磨损性能和机理,分别在低载荷2 J和高载荷5 J下测试NM500马氏体钢和10Mn奥氏体钢的冲击磨损性能。NM500马氏体耐磨钢以板条状马氏体为主,板条内部存在高密度位错亚结构,同时存在少量残余奥氏体和一些棒状碳化物(TiC);奥氏体10Mn耐磨钢以奥氏体为主,还有少量马氏体和碳化物(NbC、VC)。结果表明,在低冲击载荷(2 J)下,NM500耐磨性高于10Mn钢(160 min的磨损量分别为109和181 mg),归因于NM500比10Mn钢具有更高的硬度,磨料对表面的破坏更小;在高冲击载荷(5 J)下,磨损初期,NM500耐磨性高于10Mn钢(120 min的磨损量分别为140和145 mg),但长时间磨损,NM500耐磨性低于10Mn钢(160 min的磨损量分别为222和173 mg),归因于10Mn钢发生了充分加工硬化,具有更优异的耐磨性。10Mn钢磨损后亚表面微观形貌中存在大量的高密度位错、形变孪晶、应变马氏体,优异的加工硬化能力使10Mn在5 J冲击载荷下更耐磨。     

等温淬火温度对超细贝氏体钢组织及耐磨性的影响

设计了一种0.7C的低合金超细贝氏体钢,并通过膨胀仪、二体磨损实验、光学显微镜、扫描电镜、X射线衍射、激光扫描共聚焦显微镜及能谱仪,研究了不同等温淬火温度对超细贝氏体钢的贝氏体相变动力学、微观组织以及干滑动摩擦耐磨性的影响,揭示超细贝氏体钢在二体磨损条件下的耐磨性能和磨损机理.研究结果表明,不同等温温度下的超细贝氏体钢都由片层状贝氏体铁素体和薄膜状以及块状的残留奥氏体组成;随着等温温度的升高,超细贝氏体的相变速率提高,相变孕育期及相变完成时间缩短,但贝氏体铁素体板条厚度增加,残留奥氏体含量增加,硬度值有所降低;超细贝氏体钢磨损面形貌以平直的犁沟为主,主要的磨损机理为显微切削;不同等温温度下所获得的超细贝氏体的耐磨性能都优于回火马氏体,且随着等温温度的降低,耐磨性能提高.其中在250℃等温所获得的超细贝氏体钢具有最优的耐磨性能,其相对耐磨性为回火马氏体的1.28倍.这主要与超细贝氏体钢中贝氏体铁素体板条的细化及磨损过程中残留奥氏体的形变诱导马氏体相变（TRIP）效应有关.      

高铬白口铸铁低速重载条件下的干滑动摩擦磨损特性

研究了不同类型碳化物和不同基体组织的高铬白口铸铁在低速（滑动速度为0.4187～1.0467m/s），重载（接触应力为1～21MPa）条件下与淬火40Cr钢（硬度HRC51～53）配副的干滑动摩擦磨损特性，结果表明，在（Fe,Cr)7C3、（Fe,Cr）3C和（Fe,Cr）33C63种碳化物中，（Fe,Cr）7C3有利于提高高铬白口铸铁的耐磨性，（Fe,Cr）3C有利于降低摩擦系数，共析组织，奥氏体和马氏体3种基体相比，共析组织基体使合金具有较高的摩擦系数，而奥氏体基体合金的耐磨性最好，存在一个临界摩擦应力，当摩擦应力大于此值时，磨损率急剧上升。