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In order to determine the activities of phosphorus and iron in liquid {Cu‐Fe‐P} alloys, the two coexisting phases of liquid {Cu‐Fe‐P} alloys + <Cu‐Fe‐P> solid solutions were brought into equilibrium with a mixture of Al2O3 + AlPO4 + FexAl2O4 at temperatures of 1416K and 1526K. The oxygen partial pressures were measured with the aid of a solid‐oxide galvanic cell of the type: (+)Mo / Mo + MoO2/ ZrO2(MgO) / {Cu‐Fe‐P} + <Cu‐Fe‐P> + <Al2O3> + <AlPO4> + <FeAl2O4> / Fe(‐) The equilibrium reactions underlying the experiments can be expressed by 2[P]cu + (5/2) (O2) + <Al2O3> = 2 <AlPO4> and x[Fe]Cu + (1/2) (O2) + <Al2O3> = <FexAl2O4> The Henrian activity coefficient referred to 1 wt pct solution in pure liquid copper could be well expressed by the formula log fP° = (4.46±0.40) ‐ (8.67±0.59)/(T/K). The iron activities referred to pure solid iron could be formulated as log aFe =‐ (0.37 ± 0.12) + (500 ±200) /(T/K). 相似文献
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基于遗传算法的MIVM预测合金溶液组元活度 总被引:2,自引:0,他引:2
在求解分子相互作用体积模型(MIVM)中的分子对位能参数B(ij),B(ji)时,为避免出现计算超量问题,基于遗传算法,提出了一种新算法--多个体参与交叉遗传算法,并给出了新算法的实现方案.在新算法中,采用了轮盘选种法与优秀个体保存、多个体参与交叉和多点变异等策略;选择B(ij),B(ji)个体时,按照适应度函数值愈大,个体被选中的概率愈大的原则,选择二元合金溶液中一组元活度的计算值与实验测定值之间偏差(σ)建立的适应度函数f(x)最大为优化目标.采用Matlab软件编制新算法下的B(ij),B(ji)计算程序,并分别求算了Cd-Bi,Cd-Pb,Cd-Sn,Bi-Pb,Bi-Sn,Pb-Sn等6组二元合金溶液在773 K下合金溶液的参数B(ij),B(ji)优化值.由B(ij),B(ji)计算优化值和其他一些资料数据,使用MIVM进一步预测773 K下Cd-Bi-Pb,Cd-Bi-Sn,Cd-Pb-Sn,Cd-Bi-Pb-Sn多元合金溶液中组元Cd的活度,模型预测值与实验测定值之间的相对误差低于4.6%,偏差低于0.022,两者吻合很好.结果表明,所提出的多个体参与交叉遗传算法为求解MIVM中的参数B(ij),B(ji)提供了一种有力工具,从而也能提高MIVM对多元合金溶液中组元活度的预测效果. 相似文献
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Pan Qingchun Shan Bingquan Tian Yun Liu GuangzuCentral Iron Steel Research Institute MMI Beijing 《钢铁研究学报(英文版)》1998,(1)
CorrosionBehaviorofOxideDispersionStrengthenedFeriticAloysinLiquidSodiumPanQingchun,ShanBingquan,TianYun,LiuGuangzu①ABSTRACTC... 相似文献
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真空液相烧结法制备三元硼化物硬质合金覆层材料 总被引:3,自引:0,他引:3
采用液相烧结法在钢基体表面制备三元硼化物硬质合金覆层,将三元硼化物硬质合金的优异性能赋予钢基体表面,获得了耐磨抗蚀、界面结合强度高的新型硬质覆层材料。同时确定了硬质合金覆层的化学配比(B、Fe、Mo元素成分的配比)和C、Cr、Ni合金元素的添加量。对硬质合金覆层的洛氏硬度的测量结果表明,覆层的硬度明显高于钢基体的硬度,其中5Cr2Ni0.8C材料试样的硬度最大;对硬质合金覆层以及覆层与钢基体的界面结合处的扫描电镜观察和能谱分析表明,铬加入后部分进入陶瓷硬质相,加强了其硬度,而镍元素只在铁基粘结相中存在,并且覆层与钢基体之间形成了致密的冶金结合。 相似文献
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According to the ion and molecule coexistence theory, the activity model of Fe Si B ternary system was established, and the influence of ratio xSi/xFe, boron content and temperature, etc on the activity of the melt compound was investigated. The results show that the FeB activity is high in the liquid iron, when xSi/xFe is 05; the activity of boron increases with increasing the boron content for different contents of xFe and xSi, and the activity of boron at the ratio xFe=04 is about one order of magnitude higher than that for the xFe=08; The activities of the melt compound were also affected by temperature, but the influencing extent was little. The equal activity diagrams of silicon and boron were drawn for the first time according to the model results. 相似文献
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WANG Xin-hong ZOU Zeng-da QU Shi-yao 《钢铁研究学报(英文版)》2006,13(4):51-55
Mierostrueture of the Fe-based alloy hardfaeing coating reinforced by TiC-VC particles was investigated by means of SEM, TEM, XRD and EPMA. The thermodynamics and effect of elements on the carbides were discussed. The result shows that TiC-VC carbides can be formed during arc welding. Carbides with particle size of 2 ~4μm are uniformly dispersed in the matrix. Evidently the covering components and their amount affect the microstrueture and hardness of the coatings. An excellent microstructure and hardness of hardfacing coating were obtained, while the amount of graphite, FeTi and FeV was controlled within the range of 8%- 10%, 15%- 18% and 8%- 12%, respectively. 相似文献
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For accurately forecasting the liquid steel temperature in ladle furnace (LF), a novel temperature prediction model based on optimally pruned Bagging combined with modified extreme learning machine (ELM) is proposed. By analyzing the mechanism of LF thermal system, a thermal model with partial linear structure is obtained. Subsequently, modified ELM, named as partial linear extreme learning machine (PLELM), is developed to estimate the unknown coefficients and undefined function of the thermal model. Finally, a pruning Bagging method is proposed to establish the aggregated prediction model for the sake of overcoming the limitation of individual predictor and further improving the prediction performance. In the pruning procedure, AdaBoost is adopted to modify the aggregation order of the original Bagging ensembles, and a novel early stopping rule is designed to terminate the aggregation earlier. As a result, an optimal pruned Bagging ensemble is achieved, which is able to retain Bagging′s robustness against highly influential points, reduce the storage needs as well as speed up the computing time. The proposed prediction model is examined by practical data, and comparisons with other methods demonstrate that the new ensemble predictor can improve prediction accuracy, and is usually consisted compactly. 相似文献
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Becker Jens Ulrik ) Oeters Franz ) ) Thyssen Krupp Stahl GmbH Dortmund Germany ) Technical University Berlin Berlin Germany 《钢铁研究学报(英文版)》1999,6(2)
Fromthepresentknowledgeofmelting[1-3]itisknownthatthefirsteventatimmersingacoldsolidbodyintoahotmeltistheformationofashelloffrozenmeltaroundthebody.Shellformationdoesalsooccur,ifapieceofacoldalloyisthrownintoahotmelt.Inthecasethatthealloyhasalowerliq… 相似文献
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Zhang Hua Mo Shuai Yang Ling Liu Tao Wu Yi-Nan Ni Hong-Wei 《Metallurgical and Materials Transactions A》2022,53(10):3565-3572
Metallurgical and Materials Transactions A - Fe-based amorphous alloys generally suffer from deteriorated glass forming ability and soft magnetic properties due to the impurities in industrial raw... 相似文献