共查询到19条相似文献,搜索用时 78 毫秒
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以三氯硅烷、六甲基二硅氮烷、三氯化硼和甲胺为原料合成聚硼硅氮烷前驱体,对前驱体进行熔融纺丝和不熔化处理,将其高温裂解后制备出SiBN陶瓷纤维。使用FT-IR、NMR、XRD、TEM、TGA等表征手段研究了在不同聚合温度下聚硼硅氮烷前驱体的化学结构特征、SiBN陶瓷纤维的高温热稳定性、介电性能以及力学性能。结果表明:在不同温度下制备的聚硼硅氮烷前驱体的骨架为Si-N-B,均含有HSiN3、BN3及NCH3等结构。在1400℃热处理后SiBN陶瓷纤维仍保持无定形态,直径为14 μm,拉伸强度达到0.91 GPa。在氮气气氛中SiBN陶瓷纤维从室温到1400℃的失重为1.5%,表明这种纤维具有较高的热稳定性。SiBN陶瓷纤维的介电常数为2.6~2.8,损耗角正切的数量级为10-2。 相似文献
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通过甲基乙烯基二氯硅烷及甲基氢二氯硅烷氨解并以NH4C l催化制备了四种含活性基团的有机硅氮烷。对其紫外光(UV)固化性能、机理及热裂解行为进行了研究。结果表明,紫外光可以有效地引发含活性基的有机硅氮烷固化,固化时主要发生N-H、-CH=CH2间的反应;增大低聚物中S i-H含量和硅氮烷的分子量,均可提高其裂解后的陶瓷产率。 相似文献
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为探讨水洗、酸洗以及熔盐等预处理方法对生物质热裂解特性的影响,以橡胶籽壳为原料,使用去离子水(H2O)和质量分数分别为5%、10%和15%的盐酸(HCl)、硫酸(H2SO4)、甲酸(HCOOH)、混合酸溶液(HCl+HCOOH,VHCl∶VHCOOH=1∶1)、KCl以及NaOH对橡胶籽壳进行预处理,采用热重分析法考察了预处理对橡胶籽壳热裂解特性及综合特性指数的影响。结果表明:水洗及酸洗可使橡胶籽壳的热解主反应区热重和微分热重曲线向高温侧移动,最大失重速率和最大失重温度升高,而熔盐则降低;HCl和HCOOH以及HCl+HCOOH溶液浓度对橡胶籽壳热裂解特性的影响较小,而H2SO4浓度的影响显著,并随浓度升高而增大;酸洗有利于橡胶籽壳中挥发分的析出,可以脱除秸秆内的部分钾盐,3种酸脱钾盐的作用依次为H2SO4HClHCOOH;热裂解热性综合特性指数受水洗和酸洗影响显著,并随酸浓度升高而变化。 相似文献
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在锌硼硅玻璃中添加0%~10%(质量分数)的部分稳定氧化锆粉体,在一定温度下烧结后制备成氧化锆/锌硼硅微晶玻璃。采用半圆涂敷法测试微晶玻璃的耐冷热激变炸裂的性能;利用万能试验机测量微晶玻璃遭受热冲击后的残留抗压强度;采用402ES.3电子热膨胀仪和TC-100常温接触式导热系数测定仪测试氧化锆,锌硼硅微晶玻璃的热膨胀系数和导热系数。结果表明,氧化锆可以明显增加微晶玻璃受冷热冲击而炸裂的次数,使微晶玻璃热冲击后残留抗压强度下降的程度大大减小。氧化锆/锌硼硅微晶玻璃的热膨胀系数与导热系数随着氧化锆含量的增加而下降。由此可见,氧化锆可以明显改善锌硼硅微晶玻璃的热震稳定性,从而提高其使用可靠性。 相似文献
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采用氮-磷无卤阻燃剂制备出具有良好阻燃性能的热塑性聚酯弹性体(TPEE)。研究表明阻燃剂对TPEE阻燃性能和热性能都有显著改善,其中三聚氰胺磷酸酯(MP)阻燃剂的阻燃效果最好,氧指数可以达到30%,垂直燃烧达到UL-94V-0级,点燃时间为341s,到达热释放速率峰值的时间为355s的p_(kHRR)达到134KW/m~2,总释放热(THR)最小。电学性能研究表明,由于阻燃剂的加入,抑制了TPEE极性基团的极化和能量损耗,降低了TPEE的介电常数,提高了其绝缘性能。氮-磷无卤阻燃剂的添加对热塑性聚酯弹性体的性能影响很大。 相似文献
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有机硅添加剂对热处理粘胶纤维结构和性能的影响 总被引:1,自引:0,他引:1
借助XPS、SEM等研究了有机硅添加剂对热处理粘胶纤维的结构和性能的影响。结果表明:浸渍有机硅添加剂的粘胶纤维在热处理时,由于有机硅具有耐高温、防粘连,憎水、化学稳定性好等特性,对纤维表面可以起到保护作用;使其在热处理后,表面空洞减少,纤维的分线性得到改善,从而提高了它的抗拉强度。当有机硅添加剂的质量分数为4.79%时,所获炭纤维抗拉强度的增加幅度高达126.3%。浸渍有机硅添加剂的粘胶纤维在热处理后,Si元素主要以SiO2形式存在于纤维表面。 相似文献
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炭黑填充Lyocell纤维的制备及其用于炭纤维原丝的研究初探 总被引:9,自引:3,他引:9
为了提高Lyocell基炭纤维的得率及其力学性能,制备了不同含量炭黑填充的Lyocell纤维用做炭纤维原丝。采用X-衍射(WAXD)、热重分析(TGA)、扫描电镜(SEM)、强度仪等分析了试样的结构与性能。WAXD表明炭黑填充的LyoceH纤维仍然具有纤维素Ⅱ晶型的结构,同时还保留了炭黑的特征衍射峰;TGA表明该纤维热稳定性不变,添加质量分数为10%和30%炭黑的LyoceH纤维在1000℃时的碳得率可分别提高4.4%和17.1%:SEM显示该纤维表面光滑且截面为圆形,符合优质炭纤维原丝的要求;炭黑填充的Lyocell基炭纤维的WAXD图谱与一般Lyocell基炭纤维图谱不同。选择质量分数为10%的炭黑添加量制备出的Lyocell基炭纤维其强度和模量分别比未填充炭黑的Lyocell基炭纤维提高22%和42%,大样实验已制备出强度和模量分别为0.8GPa和70GPa的炭纤维。 相似文献
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《Advanced Powder Technology》2020,31(3):1229-1240
This study is focused on valorizing low value and low quality Indian coals via microwave pyrolysis to produce good quality carbon nanostructures in the heat-treated coal char. The effects of operating conditions such as coal type, coal:susceptor (Fe) mass ratio, and microwave power on product yield and quality are evaluated. The quality of the heat-treated coal char was assessed using different characterization techniques such as electron microscopy, porosimetry, X-ray diffraction, and Raman spectroscopy. The addition of Fe enhanced the heating rates, and led to the formation of carbon nanotubes and nanoparticles. Increasing the proportion of Fe resulted in increase in size of nanotubes and nanoparticles, which is attributed to the fusion of small tubes and particles caused by enhanced localized heating. The yield of carbon nanostructures was more from medium ash (~45%) than from high ash coal (~37%) due to the high fixed carbon and low ash content in the former. In addition to char, coal tar and non-condensable gases were characterized. The major compounds in the coal tar were aromatic hydrocarbons, simple phenols and aliphatic hydrocarbons. Hydrogen and methane were the major gases from medium ash coal, while hydrogen, methane and CO were produced in significant quantities from high ash coal. Microwave-assisted pyrolysis is shown to be a promising process to produce carbon nanostructures in a short time period as compared to conventional thermal processes. 相似文献
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采用阳极氧化法对炭纤维进行连续表面改性,并在其表面进行电镀镍处理,利用扫描电子显微镜(SEM)、X射线衍射(XRD)、热重分析和酸碱滴定等方法研究了炭纤维阳极氧化前后的物理化学结构及对炭纤维电镀镍镀层的影响。结果表明:经过阳极氧化处理后,炭纤维表面的总酸性官能团提高约10倍;炭纤维拉伸强度降低先慢后快;阳极氧化可以改善镀层的生长过程,使镍镀层的生长由(V-W)模式转变为(F-M)模式,并且促使镀层晶粒细晶化,N i晶粒尺寸由14.5nm降为11.2nm,提高了镀镍炭纤维的抗氧化性以及镀层与炭纤维的结合力,阳极氧化后镀镍的炭纤维初始氧化温度较镀镍炭纤维提高了50℃。 相似文献
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The tribological behaviors of polyetheretherketone (PEEK) composite reinforced by carbon fiber (CF) and potassium titanate whiskers (PTW) have been investigated using the pin-on-disk configuration at different applied loads under water lubricated condition. The effects of micrometer carbon fiber and sub-micrometer PTW on the wear properties of the hybrid composite have been discussed. It was found that the PEEK/PTW/CF composite showed excellent tribological performance in water condition. High wear resistance and low friction coefficient were achieved under a wide range of loads. It was revealed that the two fillers worked synergetically to enhance the wear resistance of the hybrid reinforced PEEK composite. The carbon fiber carried the main load between the contact surfaces and protected the matrix from further severe abrasion of the counterpart. At the same time, the exposed PTW out of the polymer matrix around the fiber inhibited the direct scraping between the fiber edge and counterpart tip in some degree, so that the fibers could be less directly impacted during the subsequent sliding process and they were protected from severe damage. In addition, the reinforcement effect of PTW on PEEK could reduce the stress concentration on the carbon fiber-matrix interface, and thereby reduce the CF failure/damage. The reinforcement effect of PTW on PEEK might also restrict the crack initiation and propagation on the surface and subsurface of the composite, and therefore to protect the matrix from fatigue failure during the sliding process. 相似文献
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Ran Qin Yu Tian Linbao Zheng Jianjie Qin Yu Tao Chao Song 《Fullerenes, Nanotubes and Carbon Nanostructures》2017,25(3):156-162
A special electrochemical anodic oxidation (EAO) method was applied to modify the surface of carbon fibers (CFs) with fatty alcohol polyoxyethylene ether phosphate (O3P), triethanolamine (TEA), fatty alcohol polyoxyethylene ether ammonium phosphate (O3PNH4), and ammonium bicarbonate (NH4HCO3) used as the electrolyte respectively. Then different catalysts, including Ni, Co, and Cu, were used to catalyze the growth of carbon nanotubes (CNTs) on the surface of CFs. The variation regulation of structure and property of CNTs on CFs surface was investigated by different methods. The results showed that the optimal effect of surface modification of CFs was achieved when O3PNH4 served as an electrolyte and the optimal electrochemical treatment intensity (ETI) was 100C/g. Also, with temperature variety, there are different microstructure changes for CNTs that adopt different catalysts. Through the experiment, a uniform catalyst coating was obtained on the surface of CFs after reduction process, which laid the foundation for the growth of uniform and regular CNTs. 相似文献