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用笔者研制的改性钛酸酯催化剂TAV—B,合成了苯多羧酸(DOP)型增塑剂,并确定了生产DOP的最佳工艺条件。过滤极容易;产品质量好,酸值低;不用氮气作保护。 相似文献
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本文以CTA氧化残事分离出来的混合单元苯羧酸为原料,和二甘醇进行酯化反应,合成铂混合单元苯酸酸二某醇酯增塑剂,考察了反应温度,催化剂用量,反应时间,醇/酸经对反应的影响,得出最佳工艺条件为:反应温度210℃,反应时间7h,催化剂量0.4%,醇/酸为1.5/2(摩尔比)。 相似文献
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采用密度泛函理论方法,在B3LYP/6 31G(d)水平下,计算了35种苯砜基羧酸酯化合物的量子化学参数。采用统计学软件Statistic 6.0进行多元线性回归,得到描述此类化合物对发光菌急性毒性的预测模型:-lgEC50=-0.01×P 1.92×q1-5.63×q10-0.087×μ 2.34,模型的相关性分析如下:R=0.92,r2ad j=0.82,F=40.96,q2=0.837。得到以下结论:苯砜基羧酸酯类化合物急性毒性随着亲水性的增强而减弱;分子越大,毒性越小;取代基的电负性越大,毒性越小。该研究为探讨化合物急性毒性的机理起到借鉴作用。 相似文献
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氢化葵花油脂肪酸蔗糖酯的合成 总被引:3,自引:0,他引:3
以氢化葵花油为原料 ,采用两步法合成了氢化葵花油脂肪酸蔗糖酯。探讨了反应温度、时间、压力、催化剂用量、助熔剂等对蔗糖酯收率的影响规律。结果表明 :当助熔剂和催化剂分别为 30 %和 2 .1%时 ,在 15 0℃下反应 6h ,产物收率达 4 5 %以上。 相似文献
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高级脂肪酸酯-醋酸乙烯酯共聚改性研究 总被引:5,自引:0,他引:5
介绍了醋酸乙烯酯。在丙烯酸类单体共聚改性的基础上,引入一种高级脂肪酸酯类单体参与共聚.探讨了共聚合成乳液及其粘接强度和耐水性。研究结果表明,改性后的胶粘剂降低了最低成膜温度,并经胶合板的JAS2类检测标准耐温水试验显示,试件的耐水性和粘接强度得到提高。 相似文献
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Setiyo Gunawan Shaik Ramjan Vali Yi-Hsu Ju 《Journal of the American Oil Chemists' Society》2006,83(5):449-456
Fatty acid steryl esters (FASE) and wax esters (WE) of rice bran oil (RBO) have potential applications in cosmetic, nutraceutical,
and pharmaceutical formulations. FASE and WE were extracted from RBO by a modified Soxhlet extraction using hexane as the
solvent. FASE and WE were then separated by storage in acetone at 10°C for 24 h. The FASE fraction was further purified by
silica, gel column chromatography. The contents and compositions of FASE and WE, as well as their saponified products, were
identified by GC and GC-MS. The identification of FASE and WE was carried out by comparing the retention time of GC peaks
and mass spectral analysis with standards synthesized in our laboratory. FASE and WE accounted for ca. 4.0% of crude RBO,
of which 2.8–3.2% and 1.2–1.4% are FASE and WE, respectively. GC-MS of FASE showed five major peaks. Major FA in the FASE
fraction were linoleic acid and oleic acid, which were esterified with 4-desmethyl, 4-monomethyl, and 4,4-dimethyl sterols.
The contents of 4-desmethylsterol, 4-monomethylsterol, and 4,4-dimethylsterol esters in crude RBO were 76.1, 8.7, and 15.1%,
respectively. WE of RBO consisted of both even and odd carbon numbers ranging from C44 to C64. The major constituents were, saturated esters of C22 and C24 FA and C24 to C40 aliphatic alcohols, with C24 and C30 being the predominant FA and fatty alcohol, respectively. The advantages of using a modified Soxhlet extraction over column
chromatography are less solvent usage and larger sample size per batch with shorter operation time. 相似文献
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通过浸渍法结合液相还原法将金属Pt,Ni和Sn负载在活性炭上制备了多组分Pt/C催化剂,并应用于催化氧化直接制备醇醚羧酸的反应中,考察了催化剂组分不同对脂肪醇聚氧乙烯醚(AEO9)氧化法制备醇醚羧酸(AE9C)过程中催化性能的影响;采用TEM,XRD和XPS对催化剂进行了表征。结果表明,在Pt/C催化剂中加入Ni和Sn后,Pt的颗粒粒径变小,分散性更好,Pt0的含量增加,从而提高了催化剂的活性。多组分Pt/C催化剂与单一组分Pt/C催化剂相比,AE9C产率提高了27.54百分点。 相似文献
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