共查询到18条相似文献,搜索用时 203 毫秒
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柴油低温流动改进剂的研究 总被引:1,自引:0,他引:1
介绍了一种新研制的复配型柴油低温流动改进剂,并与公司目前使用的TS型低温流动改进剂进行了比较。结果表明,复配型柴油低温流动改进剂对不同批次、不同组成的柴油具有较好的感受性,当加剂量为400mg/kg,柴油冷滤点的降低值都在10个单位以上,好于目前使用的TS改进剂。同时考察了改进剂对柴油质量的影响,用复配剂由0^#柴油调成的-10^#柴油产品完全符合轻柴油的质量指标。 相似文献
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《化学反应工程与工艺》2018,(4)
为更好地了解生物柴油组分对其低温流动性的影响,探究组分与生物柴油低温流动性的关系,采用碱催化酯交换法制备生物柴油,对生物柴油进行低温流动性检测以及气相色谱-质谱联用仪(GC-MS)分析,同时利用多元回归的方法建立组分与低温流动性的关联式。结果表明,生物柴油之间低温流动性具有很大差异,菜籽油生物柴油的冷滤点和凝点温度最低,分别为-13和-10℃,棕榈油生物柴油的冷滤点和凝点温度最高分别为12和16℃,生物柴油的低温流动性主要由其组分的含量以及组分自身性质决定。通过GC-MS分析,生物柴油主要由5种脂肪酸甲酯构成,含量达90%以上;采用多元回归的方法,分析生物柴油组分对低温流动性影响,建立基于生物柴油主要组分(硬脂酸甲酯、棕榈酸甲酯、油酸甲酯、亚油酸甲酯、亚麻酸甲酯)的凝点、冷滤点、运动黏度的预测模型,相关系数均在0.95以上,可以很好地预测生物柴油的低温流动性。 相似文献
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GC/MS法测定五种生物柴油中脂肪酸甲酯的研究 总被引:4,自引:0,他引:4
选用菜籽油、葵花籽油、玉米油、棕桐油、麻疯果油快速甲酯化制得生物柴油,通过气相色谱-质谱联用仪测定5种生物柴油的脂肪酸甲酯成分及其含量,共分析鉴定了14种脂肪酸甲酯,发现5种生物柴油主要由油酸、亚油酸、棕榈酸、硬脂酸的甲酯组成,并比较分析了它们的异同点,提出了研究脂肪酸甲酯成分和含量对生物柴油理化性能指标影响的必要性. 相似文献
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Kiril Kazancev Violeta Makareviciene Valdas Paulauskas Prutenis Janulis 《European Journal of Lipid Science and Technology》2006,108(9):753-758
The aims of the present study were to evaluate the cold temperature behavior of methyl esters of vegetable and animal origin and of their mixtures with fossil diesel fuel, as well as to investigate the effectiveness of different depressants. Various blends of rapeseed oil methyl esters, linseed oil methyl esters, pork lard methyl esters and fossil diesel fuel were prepared, and both cloud point and cold filter plugging point (CFPP) were analyzed. It was found that mixtures with CFPP values of –5 °C and lower may contain up to 25% of pork lard methyl esters; whereas the ratio of summer fossil diesel fuel and rapeseed oil methyl esters may vary over a wide range, i.e. such mixtures can be used in a diesel engine in the summer. In the transitory periods it is possible to use up to 20% animal and vegetable ester blends (3 : 7) with winter fossil diesel, whereas only up to 5% of esters can be added to the fuel used in winter. In order to improve the cold properties of rapeseed oil, pork lard and linseed oil methyl ester mixtures, various additives were tested. Depressant Viscoplex 10–35 with an optimal dose of 5000 mg/kg was found to be the most effective. 相似文献
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柴油降凝剂感受性研究 总被引:2,自引:0,他引:2
针对镇海炼化公司生产加剂柴油的需要,对柴油加剂感受性进行研究,论述了影响柴油降凝剂的主要因素,如基础油组成,馏分,馏程,蜡含量,添加剂品种等,找出降低柴油冷滤点的规律,同时初步探索了降凝剂的机理. 相似文献
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Biodiesel fuel is gaining more and more importance because of the depletion and uncontrollable prices of fossil fuel resources. The use of vegetable oil and their derivatives as alternatives for diesel fuel is the best answer and as old as Diesel Engine. Chemically biodiesel fuel is the mono alkyl esters of fatty acids derived from renewable feed stocks like vegetable oils and animal fats. Safflower oil contains 75-80% of linoleic acid; the presence of this unsaturated fatty acid is useful in alleviating low temperature properties like pour point, cloud point and cold filter plugging point. In this paper we studied the effect of various parameters such as temperature, molar ratio (oil to alcohol), and concentration of catalyst on synthesis of biodiesel fuel from safflower oil. The better suitable conditions of 1:6 molar ratio (oil to alcohol), 60 degrees C temperature and catalyst concentration of 2% (by wt. of oil) were determined. The finally obtained biodiesel fuel was analyzed for fatty acid composition by GLC and some other properties such as flash point, specific gravity and acid value were also determined. From the results it was clear that the produced biodiesel fuel was with in the recommended standards of biodiesel fuel with 96.8% yield. 相似文献
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柠檬酸-新戊二醇-柠檬酸-环烷酸-十八醇爪形大分子的合成、表征与降滤性质 总被引:1,自引:0,他引:1
以新戊二醇、柠檬酸为原料,以对甲苯磺酸为催化剂,甲苯为溶剂,在120℃油浴中反应,合成了以新戊二醇为核的多羟基多酸爪状物小分子柠檬酸-新戊二醇-柠檬酸(CNC);再利用酯化反应依次与带有功能化基团的环烷酸、十八醇分别在140℃和180℃油浴中接枝,合成了新型的多元酯类爪形大分子柠檬酸-新戊二醇-柠檬酸-环烷酸-十八醇(CNC-NO)。用1HNMR及IR对合成的两种化合物进行了结构表征;结果表明,合成的CNC和CNC-NO与所设计的分子结构吻合。用元素分析确定了CNC的化学组成为C17H24O14。合成的CNC-NO不溶于水,溶于非极性的有机溶剂。将CNC-NO按600μg/g添加到轻柴油中,柴油的冷滤点可降低6℃。 相似文献
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Production of biodiesel through optimized alkaline-catalyzed transesterification of rapeseed oil 总被引:1,自引:0,他引:1
Umer Rashid 《Fuel》2008,87(3):265-273
Present work reports an optimized protocol for the production of biodiesel through alkaline-catalyzed transesterification of rapeseed oil. The reaction variables used were methanol/oil molar ratio (3:1-21:1), catalyst concentration (0.25-1.50%), temperature (35-65 °C), mixing intensity (180-600 rpm) and catalyst type. The evaluation of the transesterification process was followed by gas chromatographic analysis of the rapeseed oil fatty acid methyl esters (biodiesel) at different reaction times. The biodiesel with best yield and quality was produced at methanol/oil molar ratio, 6:1; potassium hydroxide catalyst concentration, 1.0%; mixing intensity, 600 rpm and reaction temperature 65 °C. The yield of the biodiesel produced under optimal condition was 95-96%. It was noted that greater or lower the concentration of KOH or methanol than the optimal values, the reaction either did not fully occur or lead to soap formation.The quality of the biodiesel produced was evaluated by the determinations of important properties such as density, specific gravity, kinematic viscosity, higher heating value, acid value, flash point, pour point, cloud point, combustion point, cold filter plugging point, cetane index, ash content, sulphur content, water content, copper strip corrosion value, distillation temperature and fatty acid composition. The produced biodiesel was found to exhibit fuel properties within the limits prescribed by the latest American Standards for Testing Material (ASTM) and European EN standards. 相似文献
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为降低大豆油生物柴油的冷滤点,合成了马来酸酐-丙烯酰胺-苯乙烯醇解衍生物(AAS)以及助剂环己醇脂肪酸酯(CF),并对其进行红外表征。通过正交实验,优化了三元共聚物(AAS)的工艺条件,同时考察了自制AAS分别与助剂CF以及德国蜡晶分散剂的复配效果。实验结果表明,合成AAS的最佳工艺条件为:单体配比2:1.5:0.75,引发剂(BPO)用量1.5%,催化剂加量1.0%,共聚温度75℃,共聚时间5 h,醇解时间3 h,酐醇比7:12。当AAS添加量为0.3%时,可使大豆油生物柴油冷滤点降低4℃。与助剂CF以1:1质量配比复配可使大豆油生物柴油冷滤点降低6℃,并可使菜籽油生物柴油降低5℃。 相似文献