Experimental study of an ammonia–water bubble absorber using a plate heat exchanger for absorption refrigeration machines

The development of absorption chillers activated by renewable heat sources has increased due mainly to the increase in primary energy consumption that causes problems such as greenhouse gases and air pollution among others. These machines, which could be a good substitute for compression systems, could be used in the residential and food sectors which require a great variety of refrigeration conditions. Nevertheless, the low efficiency of these machines makes it necessary to enhance heat and mass transfer processes in the critical components, mainly the absorber, in order to reduce their large size.This study used ammonia–water as the working fluid to look at how absorption takes place in a plate heat exchanger operating under typical conditions of absorption chillers, driven by low temperature heat sources. Experiments were carried out using a corrugated plate heat exchanger model NB51, with three channels, where ammonia vapor was injected in bubble mode into the solution in the central channel. The results achieved for the absorption flux were in the range of 0.0025–0.0063 kg m^?2 s^?1, the solution heat transfer coefficient varied between 2.7 and 5.4 kW m^?2 K^?1, the absorber thermal load from 0.5 to 1.3 kW. In addition, the effect of the absorber operating conditions on the most significant efficiency parameters was analyzed. The increase in pressure, solution and cooling flow rates positively affect the absorber performance, on the other hand an increase in the concentration, cooling, and solution temperature negatively affects the absorber performance.     

Experimental characterization and performance study of an ammonia–water–hydrogen refrigerator

We present in this paper an experimental study of a commercial diffusion-absorption refrigeration machine (DAR) operating on the Platen and Munters cycle. The temperatures at the inlet and outlet of every component of the machine, as well as the cabinet and ambient temperature are measured continuously. The tests are repeated for various electric power inputs to the refrigerator. The global heat transfer coefficient of the cabinet (UA)_cab is determined using both theoretical and experimental methods. This coefficient is found equal to 0.2 W/°C. The global heat transfer coefficient of the evaporator (UA)_evap is deduced using dynamic and steady state methods. This global heat transfer coefficient (UA)_evap is found equal to 0.3 W/°C. Finally the cooling capacity of the unit and the coefficient of performance are evaluated. The heating power supply to the generator necessary to ensure the desired state of this machine is found to be in the range of 35 W–45 W.     

Analysis of the process characteristics of an absorption heat transformer with compact heat exchangers and the mixture TFE–E181

In the project described in this paper an experimental rig for a one-stage absorption heat transformer was designed and constructed. One aim of the project was to reduce the investment costs for the apparatus. This incorporates new and less expensive compact brazed plate heat exchangers for generator, evaporator, condenser and solution heat exchanger. The absorber was designed as a helical coil pipe absorber, where the weak solution trickles down as a falling film outside of the coil. The tests of the equipment involved measurements using a mixture of trifluorethanol (TFE) and tetraethyleneglycoldimethylether (E181). The process characteristics were investigated for different temperatures of the rich solution leaving the absorber. Experimental results are presented and compared with the results of a computer simulation model. Additionally the model was used to compare the COP of the heat transformation process with the mixtures lithium bromide–water (LiBr–H₂O) and ammonia–water (NH₃–H₂O). Furthermore, the overall heat and mass transfer coefficients for the plate heat exchangers and the falling film absorber were evaluated and compared with those of shell and tube heat exchangers.     

Simultaneous heat and mass transfer of a packed distillation column for ammonia–water absorption refrigeration systems

This paper presents a study on the NH₃–H₂O distillation process using a packed column with liquid reflux from the condenser in an absorption refrigeration system. A differential mathematical model has been developed on the basis of mass and energy balances and the heat and mass transfer equations. A net molar flux between the liquid and vapour phases has been considered in the mass transfer equation, which obviates the need to assume equimolar counter-diffusion. The model equations have been solved using the finite-difference method. Results obtained for a specific application are shown, including parameter distributions along the column length. The influence of rectifying and stripping lengths, mass and heat transfer coefficients and volumetric heat rejection from the column, on the distillate ammonia concentration has been analysed.     

Numerical and experimental analysis of falling-film exchangers used in a LiBr–H2O interseasonal heat storage system

This paper investigates heat and mass transfer occurring in an interseasonal absorption heat storage system using LiBr/H₂O as the sorption couple. It focuses on the poor performances of the falling film exchangers with vertical tubes, which are characterized by low flow rate compared to conventional absorption machines. A numerical model was developed for the study and validated with specific experimental results. Comparison of the numerical model to experimental results from the heat storage prototype shows the presence of abnormally high thermal resistance between the falling films and the exchanger surfaces. The deterioration in performance appears to originate in the low wetting rate of the surfaces. A new design of the exchangers is proposed to solve this problem and thus attain the desired performance.     

Laminar convective heat transfer and viscous pressure loss of alumina–water and zirconia–water nanofluids

Laminar convective heat transfer and viscous pressure loss were investigated for alumina–water and zirconia–water nanofluids in a flow loop with a vertical heated tube. The heat transfer coefficients in the entrance region and in the fully developed region are found to increase by 17% and 27%, respectively, for alumina–water nanofluid at 6 vol % with respect to pure water. The zirconia–water nanofluid heat transfer coefficient increases by approximately 2% in the entrance region and 3% in the fully developed region at 1.32 vol %. The measured pressure loss for the nanofluids is in general much higher than for pure water. However, both the measured nanofluid heat transfer coefficient and pressure loss are in good agreement with the traditional model predictions for laminar flow, provided that the loading- and temperature-dependent thermophysical properties of the nanofluids are utilized in the evaluation of the dimensionless numbers. In other words, no abnormal heat transfer enhancement or pressure loss was observed within measurement errors.     

Experimental investigation on the thermal efficiency and performance characteristics of a flat plate solar collector using SiO2/EG–water nanofluids

Application of nanofluids in thermal energy devices such as solar collectors is developing day by day. This paper reports the results of experiments on a flat plate solar collector where the working fluid is SiO₂/ethylene glycol (EG)–water nanofluid with volume fractions up to 1%. The thermal efficiency and performance characteristics of solar collector are obtained for mass flow rates between 0.018 and 0.045 kg/s. The curve characteristics of solar collector indicate that the effects of particle loading on the thermal efficiency enhancement are more pronounced at higher values of heat loss parameter. The results of this work elucidate the potential of SiO₂ nanoparticles to improve the efficiency of solar collectors despite its low thermal conductivity compared to other usual nanoparticles.     

Residential solar air conditioning: Energy and exergy analyses of an ammonia–water absorption cooling system

Large scale heat-driven absorption cooling systems are available in the marketplace for industrial applications but the concept of a solar driven absorption chiller for air-conditioning applications is relatively new. Absorption chillers have a lower efficiency than compression refrigeration systems, when used for small scale applications and this restrains the absorption cooling system from air conditioning applications in residential buildings. The potential of a solar driven ammonia–water absorption chiller for residential air conditioning application is discussed and analyzed in this paper. A thermodynamic model has been developed based on a 10 kW air cooled ammonia–water absorption chiller driven by solar thermal energy. Both energy and exergy analyses have been conducted to evaluate the performance of this residential scale cooling system. The analyses uncovered that the absorber is where the most exergy loss occurs (63%) followed by the generator (13%) and the condenser (11%). Furthermore, the exergy loss of the condenser and absorber greatly increase with temperature, the generator less so, and the exergy loss in the evaporator is the least sensitive to increasing temperature.     

Numerical investigation of heat transfer and pressure drop characteristics of tube–fin heat exchangers in ice slurry HVAC system

This paper analyzes the heat transfer and pressure drop characteristics of a tube–fin heat exchanger in ice slurry HVAC system. Ice slurry is a suspension of crystallized water based - ice solution with a freezing point depressant like ethylene glycol. The ice- slurry is pumpable, hence it is also called pumpable ice. The composition of ice slurry considered for analysis is 14% ice fraction, 16% ethylene glycol, and 70% water by volume. It is deduced that the ice slurry HVAC system results in 7.4% increase in temperature drop over the conventional chilled water system The latent heat absorbed by ice slurry on melting makes it an attractive choice for achieving high degree of cooling. The numerical analysis was conducted by simulating the ice slurry tube flow region and air flow region of tube–fin heat exchanger in the air-handling unit of HVAC system. For the simulation six different louver patterns with 10 to 55 louver angle were considered. The design of the tube–fin heat exchanger for optimal heat transfer and pressure drop characteristics was also determined with the optimization parameter like louver angle, fin pitch, and ice slurry flow velocity.     

Effects of Cattaneo–Christov heat flux analysis on heat and mass transport of Casson nanoliquid past an accelerating penetrable plate with thermal radiation and Soret–Dufour mechanism

In this analysis, the effect of Catteneo–Christov model on heat alongside mass transport magnetohydrodynamics of a Casson nanoliquid with thermal radiation and Soret–Dufour mechanism is considered. The fluid flow is considered through porous media as the thermophysical attributes such as viscosity along with thermal conductivity are considered to be constant. Suitable similarity transformations were employed on the governing coupled flow equation to yield total differential equations (ODE). An accurate and newly developed spectral method called spectral homotopy analysis method (SHAM) was employed to provide solution to the simplified equations. The numerical method of homotopy analysis method (HAM) is SHAM. SHAM portrays the division of nonlinear equations into linear as well as nonlinear parts. The findings in this study show that an increment in the Casson parameter is seen to elevate the velocity plot at the wall and lessen the velocity far away from the plate. An increase in the Brownian motion and thermophoresis term is observed to speed up the local skin friction coefficient.     

Finite time thermodynamics study and exergetic analysis of ammonia–water absorption systems

This paper presents an optimization study of a single stage absorption machine operating with an ammonia–water mixture under steady state conditions. The power in the evaporator, the temperatures of the external fluids entering the four external heat exchangers as well as the effectiveness of these heat exchangers and the efficiency of the pump are assumed fixed. The results include the minimum value of the total thermal conductance UA_tot as well as the corresponding mean internal temperatures, overall irreversibility and exergetic efficiency for a range of values of the coefficient of performance (COP). They show the existence of three optimum values of the COP: the first minimises UA_tot, the second minimises the overall irreversibility and the third maximises the exergetic efficiency. They also show that these three COP values are lower than the maximum COP which corresponds to the convergence of the internal and external temperatures towards a common value. The influence of various parameters on the minimum thermal conductance of the heat exchangers and on the corresponding exergy efficiency has also been evaluated. From an exergetic viewpoint it is interesting to reduce the temperature at the desorber and at the evaporator and to raise the values of that parameter at the condenser and the absorber. However these changes must be accompanied by an important increase in the total UA if it is desired to conserve a constant COP. The internal heat exchangers between the working fluid and the solution improve both the overall exergy efficiency and the coefficient of performance of the absorption apparatus.     

Thermal performance of an oscillating heat pipe with Al2O3–water nanofluids

An experimental investigation was performed on the thermal performance of an oscillating heat pipe (OHP) charged with base water and spherical Al₂O₃ particles of 56 nm in diameter. The effects of filling ratios, mass fractions of alumina particles, and power inputs on the total thermal resistance of the OHP were investigated. Experimental results showed that the alumina nanofluids significantly improved the thermal performance of the OHP, with an optimal mass fraction of 0.9 wt.% for maximal heat transfer enhancement. Compared with pure water, the maximal thermal resistance was decreased by 0.14 °C/W (or 32.5%) when the power input was 58.8 W at 70% filling ratio and 0.9% mass fraction. By examining the inner wall samples, it was found that the nanoparticle settlement mainly took place at the evaporator. The change of surface condition at the evaporator due to nanoparticle settlement was found to be the major reason for the enhanced thermal performance of the alumina nanofluid-charged OHP.     

Prediction of heat transfer due to presence of copper–water nanofluid using resilient-propagation neural network

Heat transfer due to laminar natural convection of copper–water nanofluid in a differentially heated square cavity has been predicted by Artificial Neural Network (ANN). The nanofluid has been considered as non-Newtonian. The ANN has been trained by a resilient-propagation (RPROP) algorithm. The required input and output data to train the ANN has been taken from the results of numerical simulation that was performed simultaneously where the transport equations has been solved numerically using finite volume approach incorporating SIMPLER algorithm. Results from simulation and resilient-propagation (RPROP) based ANN have been compared. It has been observed that the ANN predicts the heat transfer correctly within the given range of training data. It is further observed that resilient-propagation (RPROP) based ANN is an efficient tool to predict the heat transfer than simulation, which takes much longer time to compute.     

Mitigation of ice crystallization fouling in stationary and circulating liquid–solid fluidized bed heat exchangers

Liquid–solid fluidized bed heat exchangers are attractive ice crystallizers since they are able to mitigate ice crystallization fouling and exhibit high heat transfer coefficients. Experiments show that the fouling removal ability of stationary fluidized beds increases with decreasing bed voidage (95–80%) and increasing particle size (2–4 mm). The removal of ice crystallization fouling appears to be more effective in circulating fluidized beds, especially at high circulation rates. Fouling removal is realized by both particle–wall collisions and pressure fronts induced by particle–particle collisions. A comparison between ice crystallization experiments and impact characteristics shows that the removal rate is proportional to the impulse exerted on the wall. A model based on these phenomena is discussed and predicts the transition temperature difference for ice crystallization fouling in both stationary and circulating fluidized beds with an average absolute error of 9.2%.     

An experimental study of forced convective heat transfer for fully developed Al2O3–water nanofluid in an annulus tube

Nanofluids have been known as practical materials to ameliorate heat transfer within diverse industrial systems. The current work presents an empirical study on forced convection effects of Al₂O₃–water nanofluid within an annulus tube. A laminar flow regime has been considered to perform the experiment in high Reynolds number range using several concentrations of nanofluid. Also, the boundary conditions include a constant uniform heat flux applied on the outer shell and an adiabatic condition to the inner tube. Nanofluid particle is visualized with transmission electron microscopy to figure out the nanofluid particles. Additionally, the pressure drop is obtained by measuring the inlet and outlet pressure with respect to the ambient condition. The experimental results showed that adding nanoparticles to the base fluid will increase the heat transfer coefficient (HTC) and average Nusselt number. In addition, by increasing viscosity effects at maximum Reynolds number of 1140 and increasing nanofluid concentration from 1% to 4% (maximum performance at 4%), HTC increases by 18%.     

Marangoni convection flow and heat transfer characteristics of water–CNT nanofluid droplets

ABSTRACT

The heat transfer characteristics of liquid droplets are influenced by the hydrophobicity of the surfaces. Fluid properties and surface energy play important roles in heat transfer assessment. In the present study, the influence of the contact angle on the flow field developed inside a nanofluid droplet consisting of a mixture of water and carbon nanotubes (CNT) is investigated. Flow field and heat transfer characteristics are simulated numerically in line with the experimental conditions. It is found that the flow velocity predicted numerically is in good agreement with the experimental data. Nusselt and Bond numbers increase at large contact angles and Marangoni force dominates over buoyancy force.     

Effects of particle volume fraction on spray heat transfer performance of Al2O3–water nanofluid

An experimental investigation is conducted into the effects of the particle volume fraction on the spray heat transfer performance of a nanofluid comprising de-ionized water and Al₂O₃ particles with a diameter of 35 nm. The tests are performed with a flat, horizontal heated surface using a nozzle with an orifice diameter of 0.7 mm and a nozzle-to-heated surface distance of 17 mm. The spray mass flux is varied in the range of 26.433–176.751 kg/m² s, while the particle volume fraction is specified as 0%, 0.001%, 0.025%, or 0.05%. It is found that the optimal heat transfer performance is obtained using a particle volume fraction of 0.001%. The surface compositions of the sprayed samples are observed using scanning electron microscopy. The results show that the surfaces sprayed with a nanofluid containing 0.025 Vol% or 0.05 Vol% of nanoparticles contain a small amount of Al. However, those cooled using a nanofluid with a particle volume fraction of 0% or 0.001% show no traces of Al.     

Enhancing the performance of Mg–Al brine water batteries using conductive polymer-PEDOT:PSS

In this paper, the effect of the conductive additive, poly (3, 4-ethylenedioxythiophene)-poly (styrene sulfonate) (PEDOT:PSS) on brine water batteries was investigated. Brine water batteries were produced using magnesium powder mixed with aluminum powder, activated carbon and carbon nanotubes, which functioned as the anode with aluminum foil as the current collector. The aluminum current collector also took part in the anodic reaction after the magnesium was used up in the brine water battery reaction. AgCl mixed with activated carbon and carbon nanotubes functioned as the cathode. Platinum mesh was used as current collector for the cathode. The binder used was a mixture of poly vinyl alcohol and poly-acrylic acid. To this binder, the conductive binder PEDOT:PSS was added. The brine water battery consisted of five cells in series connection and each cell had an anode and cathode either with or without PEDOT:PSS. The brine water batteries were operated in a 3.5% NaCl which mimics seawater.