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1.
The objective of this investigation was to study the effect of dilution with CO2 on the laminar burning velocity and flame stability of syngas fuel (50% H2–50% CO by volume). Constant pressure spherically expanding flames generated in a 40 l chamber were used for determining unstretched burning velocity. Experimental and numerical studies were carried out at 0.1 MPa, 302 ± 3 K and ? = 0.6–3.0 using fuel-diluent and mixture-diluent approaches. For H2–CO–CO2–O2–N2 mixtures, the peak burning velocity shifts from ? = 2.0 for 0% CO2 in fuel to ? = 1.6 for 30% CO2 in fuel. For H2–CO–O2–CO2 mixtures, the peak burning velocity occurred at ? = 1.0 unaffected by proportion of CO2 in the mixture. If the mole fraction of combustibles in H2–CO–O2–CO2 mixtures is less than 32%, then such mixtures are supporting unstable flames with respect to preferential diffusion. The analysis of measured unstretched laminar burning velocities of H2–CO–O2–CO2 and H2–CO–O2–N2 mixtures suggested that CO2 has a stronger inhibiting effect on the laminar burning velocity than nitrogen. The enhanced dilution effect of CO2 could be due to the active participation of CO2 in the chemical reactions through the following intermediate reaction CO + OH ? CO2 + H.  相似文献   

2.
This paper reported a numerical study on the NOx emission characteristics of opposed-jet syngas diffusion flames. A narrowband radiation model was coupled to the OPPDIF program, which used detailed chemical kinetics and thermal and transport properties to enable the study of 1-D counterflow syngas diffusion flames with flame radiation. The effects of syngas composition, pressure and dilution gases on the NOx emission of H2/CO synthetic mixture flames were examined. The analyses of detailed flame structures, chemical kinetics, and nitrogen reaction pathways indicate NOx are formed through Zeldovich (or thermal), NNH and N2O routes both in the hydrogen-lean and hydrogen-rich syngas flames at normal pressure. Zeldovich route is the main NO formation route. Therefore, the hydrogen-rich syngas flames produce more NO due to higher flame temperatures compared to that for hydrogen-lean syngas flames. Although NNH and N2O routes also are the primary NO formation paths, a large amount of N2 will be reformed from NNH and N2O species. For hydrogen-rich syngas flames, the NO formation from NNH and N2O routes are lesser, where NO can be dissipated through the reactions of NH + NO  N2 + OH and NH + NO  N2O + H more actively. At a rather low pressure (0.01 atm), NNH-intermediate route is the only formation path of NO. Increasing pressure then enhances NO formation reactions, especially through Zeldovich mechanisms. However, at higher pressures (5–10 atm), NO is then converted back to N2 through reversed N2O route for hydrogen-lean syngas flames, and through NNH as well for hydrogen-rich syngas flames. In addition, the dilution effects from CO2, H2O, and N2 on NO emissions for H2/CO syngas flames were studied. The hydrogen-lean syngas flames with H2O dilution have the lowest NO production rate among them, due to a reduced reaction rate of NNH + O  NH + NO. But for hydrogen-rich syngas flames with CO2 dilution, the flame temperatures decrease significantly, which leads to a reduction of NO formation from Zeldovich route.  相似文献   

3.
This study examines the airside performance of the wavy fin-and-tube heat exchangers having a larger diameter tube (Dc = 16.59 mm) with the tube row ranging from 1 to 16. It is found that the effect of tube row on the heat transfer performance is quite significant, and the heat transfer performance deteriorates with the rise of tube row. The performance drop is especially pronounced at the low Reynolds number region. Actually more than 85% drop of heat transfer performance is seen for Fp  1.7 mm as the row number is increased from 1 to 16. Upon the influence of tube row on the frictional performance, an unexpected row dependence of the friction factor is encountered. The effect of fin pitch on the airside performance is comparatively small for N = 1 or N = 2. However, a notable drop of heat transfer performance is seen when the number of tube row is increased, and normally higher heat transfer and frictional performance is associated with that of the larger fin pitch.  相似文献   

4.
This study investigated the effect of fin thickness on the air-side performance of wavy fin-and-tube heat exchangers under dehumidifying conditions. A total of 10 samples were tested with associated fin thickness (δf) of 0.115 mm and 0.25 mm, respectively. For a heat exchanger with two rows (N = 2) and fin pitch Fp of 1.41 mm, the effect of fin thickness on the heat transfer coefficient is more pronounced. The heat transfer coefficients for δf = 0.25 mm is about 5–50% higher than those for δf = 0.115 mm whereas the pressure drop for δf = 0.25 mm is about 5–20% higher. The unexpected difference in heat transfer coefficient subject to fin thickness is attributable to better interactions between the directed main flow and the swirled flow caused by the condensate droplet for δf = 0.25 mm. The maximum difference in heat transfer coefficients for N = 2 and Fp = 2.54 mm subject to the influence of fin thickness is reduced to about 20%, and there is no difference in heat transfer coefficient when the frontal velocity is above 3 m/s. For N  4 and Fp = 2.54 mm, the influence of fin thickness on the heat transfer coefficients diminishes considerably. This is because of the presence of tube row, and the unsteady/vortex shedding feature at the down stream of wavy channel. Based on the present test results, a correlation is proposed to describe the air-side performance for wavy fin configurations, the mean deviations of the proposed heat transfer and friction correlations are 7.9% and 7.7%, respectively.  相似文献   

5.
Thermal management of distributed electronics similar to data centers is studied using a bi-disperse porous medium (BDPM) approach. The BDPM channel comprises heat generating micro-porous square blocks, separated by macro-pores. Laminar forced convection cooling fluid of Pr = 0.7 saturates both the micro- and macro-pores. Bi-dispersion effect is induced by varying the macro-pore volume fraction ?E, and by changing the number of porous blocks N2, both representing re-distribution of the electronics. When 0.2 ? ?E ? 0.86, the heat transfer Nu is enhanced twice (from ~550 to ~ 1100) while the pressure drop Δp1 reduces almost eightfold. For ?E < 0.5, Nu reduces quickly to reach a minimum at the mono-disperse porous medium (MDPM) limit (?E  0). Compared to N2 = 1 case, Nu for BDPM configuration is high when N2 ? 1, i.e., the micro-porous blocks are many and well distributed. The Nu increase with Re changes from non-linear to linear as N2 increases from 1 to 81, with corresponding insignificant pumping power increase.  相似文献   

6.
The characteristics of transient double-diffusive convection in a vertical cylinder are numerically simulated using a finite element method. Initially the fluid in the cavity is at uniform temperature and solute concentration, then constant temperature and solute concentration, which are lower than their initial values, are imposed along the sidewall and bottom wall, respectively. The time evolution of the double-diffusive convection is investigated for specific parameters, which are the Prandtl number, Pr = 7, the Lewis number, Le = 5, the thermal Grashof number, GrT = 107, and the aspect ratio, A = 2, of the enclosure. The objective of the work is to identify the effect of the buoyancy ratio (the ratio of solutal Grashof to thermal Grashof numbers: N = GrS/GrT) on the evolution of the flow field, temperature and solute field in the cavity. It is found that initially the fluid near the bottom wall is squeezed by the cold flow from the sidewall, a crest of the solute field forms and then pushed to the symmetry line. In the case of N > 0, a domain with higher temperature and weak flow (dead region) forms on the bottom wall near the symmetry line, and the area of dead region increases when N varies from 0.5 to 1.5. More crests of the solute field are formed and the flow near the bottom wall fluctuates continuously for N < 0. The frequency of the fluctuation increases when N varies from −0.5 to −1.5. Corresponding to the variety of the thermal and solutal boundary layers, the average rates of heat transfer (Nu) at the sidewall remain almost unchanged while the average rates of mass transfer (Sh) at the bottom wall change much in the cases of N = 1, 0, −1.  相似文献   

7.
Flat premixed burner-stabilized H2 + O2 + N2 flames, neat or doped with 300–1000 ppm of NO or NH3, were studied experimentally using molecular-beam mass-spectrometry and simulated numerically. Spatial profiles of temperature and concentrations of stable species, H2, O2, H2O, NO, NH3, and of H and OH radicals obtained at atmospheric pressure in lean (? = 0.47), near-stoichiometric (? = 1.1) and rich (? = 2.0) flames are reported. Good agreement between measured and calculated structure of lean and near-stoichiometric flames was found. Significant discrepancy between simulated and measured profiles of NO concentration was observed in the rich flames. Sensitivity and reaction path analyses revealed reactions responsible for the discrepancy. Modification to the model was proposed to improve an overall agreement with the experiment.  相似文献   

8.
Mixed convection heat transfer from longitudinal fins inside a horizontal channel has been investigated for a wide range of modified Rayleigh numbers and different fin heights and spacings. An experimental parametric study was made to investigate effects of fin spacing, fin height and magnitude of heat flux on mixed convection heat transfer from rectangular fin arrays heated from below in a horizontal channel. The optimum fin spacing to obtain maximum heat transfer has also been investigated. During the experiments constant heat flux boundary condition was realized and air was used as the working fluid. The velocity of fluid entering channel was kept nearly constant (0.15 ? win ? 0.16 m/s) using a flow rate control valve so that Reynolds number was always about Re = 1500. Experiments were conducted for modified Rayleigh numbers 3 × 107 < Ra1 < 8 × 108 and Richardson number 0.4 < Ri < 5. Dimensionless fin spacing was varied from S/H = 0.04 to S/H = 0.018 and fin height was varied from Hf/H = 0.25 to Hf/H = 0.80. For mixed convection heat transfer, the results obtained from experimental study show that the optimum fin spacing which yields the maximum heat transfer is S = 8–9 mm and optimum fin spacing depends on the value of Ra1.  相似文献   

9.
Electrochemically driven steady convective diffusion is analyzed for electrodiffusion friction probes of arbitrary convex shape in a stream of microdisperse liquid, assuming non-linear velocity profiles ranging from simple shear flow (p = 1) to ideal slip motion (p = 0). Correction on the edge effects due to spatial diffusion at medium Peclet numbers is given, using the recent numerical data about the strip-like probes by Wein [25] Simple correction formulas are presented for the disk-like probes.  相似文献   

10.
The effect of enhanced geometry (pore diameter, gap width) is investigated on the pool boiling of R-123/oil mixture for the enhanced tubes having pores with connecting gaps. Tubes having different pore diameters (and corresponding gap widths) are specially made. Significant heat transfer degradation by oil is observed for the present enhanced tubes. At 5% oil concentration, the degradation is 26–49% for Tsat = 4.4 °C. The degradation increases 50–67% for Tsat = 26.7 °C. The heat transfer degradation is significant even with small amount of oil (20–38% degradation at 1% oil concentration for Tsat = 4.4 °C), probably due to the accumulation of oil in sub-tunnels. The pore size (or gap width) has a significant effect on the heat transfer degradation. The maximum degradation is observed for dp = 0.20 mm tube at Tsat = 4.4 °C, and dp = 0.23 mm tube at Tsat = 26.7 °C. The minimum degradation is observed for dp = 0.27 mm tube for both saturation temperatures. It appears that the oil removal is facilitated for the larger pore diameter (along with larger gap) tube. The highest heat transfer coefficient with oil is obtained for dp = 0.23 mm tube, which yielded the highest heat transfer coefficient for pure R-123. The optimum tube significantly (more than 3 times) outperforms the smooth tube even with oil. The heat transfer degradation increases as the heat flux decreases.  相似文献   

11.
《Biomass & bioenergy》2007,31(8):593-598
This work is focused on the influence of dilution rate (0.08⩽D⩽0.32 d−1) on the kinetics of continuous cultivation of Spirulina platensis at two different concentrations of ammonium chloride (N0=1.0 and 10 mM) as nitrogen source. Cell productivity increased in both series of runs up to D≅0.12–0.16 d−1, and then decreased. While at N0=1.0 mM biomass washing was certainly the cause of progressive cell concentration decrease, a combination of this phenomenon with the toxic effect of excess ammonia was responsible, at N0=10 mM and D⩾0.20 d−1, for quick stop of cell growth just beyond the achievement of maximum cell productivity (92.4 mg l−1 d−1). Similar profile was observed for protein productivity, that achieved a maximum value of 67.0 mg l−1 d−1, because of the very high protein content (72.5%) of biomass produced under these conditions. The yield of nitrogen-to-biomass was much higher at the lower N0, because of the low protein content, and reached a maximum value of 9.7 g g−1 at D=0.08–0.12 d−1. The yield of nitrogen-to-protein showed less marked difference, being most of the nitrogen present in the cell as proteins or free amino-acids.  相似文献   

12.
This work uses an optimization procedure consisting of a simplified conjugate-gradient method and a three-dimensional fluid flow and heat transfer model to investigate the optimal geometric parameters of a double-layered microchannel heat sink (DL-MCHS). The overall thermal resistance RT is the objective function to be minimized, and the number of channels N, channel width ratio β, lower channel aspect ratio αl, and upper channel aspect ratio αu are the search variables. For a given bottom area (10 × 10 mm) and heat flux (100 W/cm2), the optimal (minimum) thermal resistance of the double-layered microchannel heat sink is about RT = 0.12 °C/m2W. The corresponding optimal geometric parameters are N = 73, β = 0.50, αl = 3.52, and, αu = 7.21 under a total pumping power of 0.1 W. These parameters reduce the overall thermal resistance by 52.8% compared to that yielded by an initial guess (N = 112, β = 0.37, αl = 10.32, and αu = 10.93). Furthermore, the optimal thermal resistance decreases rapidly with the pumping power and then tends to approach an constant value. As the pumping power increases, the optimal values of N, αl, and αu increase, whereas the optimal β value decreases. However, increasing the pumping power further is not always cost-effective for practical heat sink designs.  相似文献   

13.
Thermal management of heat generating electronics using the Bi-Disperse Porous Medium (BDPM) approach is investigated. The BDPM channel comprises heat generating micro-porous square blocks separated by macro-pore gaps. Laminar forced convection cooling fluid of Pr = 0.7 saturates both the micro- and macro-pores. Bi-dispersion effect is induced by varying the porous block permeability DaI and external permeability DaE through variation in number of blocks N2. For fixed Re, when 10?5 ? DaI ? 10?2, the heat transfer Nu is enhanced four times (from ~200 to ~800) while the pressure drop Δp1 reduces almost eightfold. For DaI < 10?5, Nu decreases quickly to reach a minimum at the Mono-Disperse Porous Medium (MDPM) limit (DaI  0). Compared to N2 = 1 case, Nu for BDPM configuration is high when N2 ? 1, i.e., the micro-porous blocks are many and well distributed. The pumping power increase is very small for the entire range of N2. Distributing heat generating electronics using the BDPM approach is shown to provide a viable method of thermo-hydraulic performance enhancement χ.  相似文献   

14.
In this article, double-diffusive mixed convection in a vertical pipe under local thermal non-equilibrium state has been investigated. The non-Darcy Brinkman–Forchheimer-extended model has been used and solved numerically by spectral collocation method. Special attention is given to understand the effect of buoyancy ratio (N) and thermal non-equilibrium parameters: inter phase heat transfer coefficient (H) as well as porosity scaled thermal conductivity ratio (γ) on the flow profiles as well as on rates of heat and solute transfer. Judged from the influence of buoyancy ratio on velocity profile, when both the buoyancy forces: thermal as well as solutal are in favor of each other and for given any value of H considered in this study, it has been found that for N equal to 10 as well as 100, the basic velocity profile shows back flow for small subdomain of the domain of the flow. When two buoyancy forces are opposing to each other (RaT = ?1000), velocity profile possesses a kind of distortion, in which the number of zeroes increases on increasing N. Corresponding variation of heat transfer rate in the (N,  Nuf)-plane shows a sinusoidal pattern. The flow separation on the flow profile dies out on increasing H for N = 0. It has been also found that for each N, when N < 0.7, there exists a minimum value of H such that the velocity profile becomes free from flow separation. Influence of H on the profiles of solid temperature as well as solute, in both situations are similar. Overall, the impact of LTNE parameters, specially γ, on heat transfer rate of double-diffusive convection is not straight forward.  相似文献   

15.
The optimization of total solids in the feed (%TS) and alkalinity ratio (γ) for H2 production from organic solid wastes under thermophilic regime was carried out using response surface methodology based on a central composite design. The total solids levels were 20.9, 23.0, 28.0, 33.0 and 35.1% whereas the levels of alkalinity ratio (defined as g phosphate alkalinity/g dry substrate) were 0.15, 0.20, 0.30, 0.41 and 0.45. High levels of TS and γ affected in a negative way the H2 productivity and yield; both response variables significantly increased upon decreasing the TS content and alkalinity ratio. The highest H2 productivity and yield were 463.7 N mL/kg-d and 54.8 N mL/g VSrem, respectively, predicted at 20.9% TS and alkalinity ratio 0.25 (0.11 g CaCO3/g dry substrate). The alkalinity requirements for hydrogenogenic processes were lower than those reported for methanogenic processes (0.11 vs. 0.30 g CaCO3/g COD). Adequate alkalinity ratio was necessary to maintain optimal biological activity for hydrogen production; however, excessive alkalinity negatively affected process performance probably due to an increase of osmotic pressure. Interestingly, reactor pH depended only on the alkalinity ratio, thus the buffer capacity was able to maintain a constant pH independently of TS levels. At γ = 0.15–0.30 the pHs were in the range 5.56–5.95, which corresponded to the highest hydrogen productivities and yields. Finally, the highest metabolite accumulation corresponded with the highest removal efficiencies but not with high H2 productivities and yields. Therefore, it seems that organic matter removal was channeled toward solvent generation instead of hydrogen production at high TS and γ levels. This is the first study that shows the requirements of alkalinity in solid substrate fermentation conditions for H2 production processes and their interaction with the content of total solids in the feed.  相似文献   

16.
Thermodynamic equilibrium of methanol steam reforming (MeOH SR) was studied by Gibbs free minimization for hydrogen production as a function of steam-to-carbon ratio (S/C = 0–10), reforming temperature (25–1000 °C), pressure (0.5–3 atm), and product species. The chemical species considered were methanol, water, hydrogen, carbon dioxide, carbon monoxide, carbon (graphite), methane, ethane, propane, i-butane, n-butane, ethanol, propanol, i-butanol, n-butanol, and dimethyl ether (DME). Coke-formed and coke-free regions were also determined as a function of S/C ratio.Based upon a compound basis set MeOH, CO2, CO, H2 and H2O, complete conversion of MeOH was attained at S/C = 1 when the temperature was higher than 200 °C at atmospheric pressure. The concentration and yield of hydrogen could be achieved at almost 75% on a dry basis and 100%, respectively. From the reforming efficiency, the operating condition was optimized for the temperature range of 100–225 °C, S/C range of 1.5–3, and pressure at 1 atm. The calculation indicated that the reforming condition required from sufficient CO concentration (<10 ppm) for polymer electrolyte fuel cell application is too severe for the existing catalysts (Tr = 50 °C and S/C = 4–5). Only methane and coke thermodynamically coexist with H2O, H2, CO, and CO2, while C2H6, C3H8, i-C4H10, n-C4H10, CH3OH, C2H5OH, C3H7OH, i-C4H9OH, n-C4H9OH, and C2H6O were suppressed at essentially zero. The temperatures for coke-free region decreased with increase in S/C ratios. The impact of pressure was negligible upon the complete conversion of MeOH.  相似文献   

17.
《Journal of power sources》2006,154(1):290-297
The crystal structure, hydrogen storage property and electrochemical characteristics of the La0.7Mg0.3Ni3.5  x(Al0.5Mo0.5)x (x = 0–0.8) alloys have been investigated systematically. It can be found that with X-ray powder diffraction and Rietveld analysis the alloys are of multiphase alloy and consisted of impurity LaNi phase and two main crystallographic phases, namely the La(La, Mg)2Ni9 phase and the LaNi5 phase, and the lattice parameter and the cell volume of both the La(La, Mg)2Ni9 phase and the LaNi5 phase increases with increasing Al and Mo content in the alloys. The PC isotherms curves indicate that the hydrogen storage capacity of the alloy first increases and then decreases with increasing x, and the equilibrium pressure decreases with increasing x. The electrochemical measurements show that the maximum discharge capacity first increases from 354.2 (x = 0) to 397.6 mAh g−1 (x = 0.6) and then decreases to 370.4 mAh g−1 (x = 0.8). The high-rate dischargeability of the alloy electrode increases lineally from 55.7% (x = 0) to 73.8% (x = 0.8) at the discharge current density of 1200 mA g−1. Moreover, the exchange current density of the alloy electrodes also increases monotonously with increasing x. The hydrogen diffusion coefficient in the alloy bulk increases with increasing Al and Mo content and thus enhances the low-temperature dischargeability of the alloy electrode.  相似文献   

18.
In this paper we present the results on experimental investigation of the local opposing mixed convection heat transfer in the vertical flat channel with symmetrical heating in a laminar–turbulent transition region. The experiments were performed in airflow (p = 0.1–1.0 MPa) in the range of Re from 1.5 × 103 to 6.6 × 104 and Grq up to 1 × 1011 at the limiting condition qw1 = qw2 = const. The analysis of the results revealed significant increase in the heat transfer with increasing of air pressure (Gr number). Also sharp increase in heat transfer was noticed in the region with vortex flow in comparison with the turbulent flow region.  相似文献   

19.
《Journal of power sources》2006,161(2):1161-1168
The transient behavior of a proton exchange membrane fuel cell (PEMFC) with porosity is investigated in this study using a two-phase, half-cell model. The thin film agglomerate approach is used to model the catalyst layer. Both vapor transport and liquid water transport in the PEMFC are examined in this study. Proton transport is much faster than the gaseous and liquid water transport. The ionic potential reaches a steady state level in ∼10−1 s but liquid water transport takes ∼10 s. The variation of the ionic potential loss reaches a critical value, decreasing to a steady state, and is not monotonic. The gas diffusion layer (GDL) and the catalyst layer (CL) porosity, which can affect cell performance, have been carefully investigated. The current density rises rapidly within 10−2 s, then remaining constant. After 1 s, this is affected by the cell voltage, GDL porosity, and CL porosity, and if the GDL porosity is below 0.4, the current density drops. For the gas diffusion layer porosity, the current density increases between ɛGDL = 0.2 and ɛGDL = 0.5, with increased GDL porosity. For the catalyst layer porosity, the optimum value appears between ɛCL = 0.06 and ɛCL = 0.1.  相似文献   

20.
An experimental investigation has been carried out to study the heat transfer coefficient and friction factor by using artificial roughness in the form of specially prepared inverted U-shaped turbulators on the absorber surface of an air heater duct. The roughened wall is uniformly heated while the remaining three walls are insulated. These boundary conditions correspond closely to those found in solar air heaters.The experiments encompassed the Reynolds number range from 3800 to 18000; ratio of turbulator height to duct hydraulic mean diameter is varied from, e/Dh = 0.0186 to 0.03986 (Dh = 37.63 mm and e = 0.7 to 1.5 mm) and turbulator pitch to height ratio is varied from, p/e = 6.67 to 57.14 (p = 10 to 40 mm). The angle of attack of flow on turbulators, α = 90° kept constant during the whole experimentation. The heat transfer and friction factor data obtained is compared with the data obtained from smooth duct under similar geometrical and flow conditions. As compared to the smooth duct, the turbulator roughened duct enhances the heat transfer and friction factor by 2.82 and 3.72 times, respectively. The correlations have been developed for area averaged Nusselt number and friction factor for turbulator roughened duct.  相似文献   

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