Boiling enhancement by TiO2 nanoparticle deposition

TiO₂ nanoparticle-coated nickel wires were produced by electrical heating in various nanofluid concentrations ranging from 0.01 to 1 wt.% with various processing heat fluxes from 0 to 1000 kW/m². The experimental results demonstrated up to 82.7% enhancement on critical heat flux (CHF) in condition of coated nickel wire (processed in 1 wt.% with 1000 kW/m²) boiling in pure water. The contact angle measurement revealed that the hydrophilic porous coating formed by vigorous vaporization of TiO₂ nanofluid in nucleate boiling regime enormously modified the wettability of heating surface consequently improving the CHF. Besides, it is evident that the coverage of nanoparticle deposition tended to become more complete as concentration and processing heat flux increased based on SEM and EDS analysis. The nanoparticles dispersed in base fluid exhibited little effect on CHF enhancement and could even hinder the percentage of CHF augmentation from boosting, which demonstrated that one could enhance CHF by using only small amount of nanoparticles just adequate to form surface coatings instead of preparing working fluid with great bulk. However, according to the boiling curves in all cases of coated nickel wires, it is supposed that the nucleate boiling heat transfer coefficient deteriorates as a result of thermal resistance resulted from the occurrence of nanoparticle deposition. In summary, the coated porous structure of nanoparticles leads to enhance CHF and to decrease boiling heat transfer coefficient.     

Effects of high subcooling on two-phase spray cooling and critical heat flux

Experiments were performed with FC-77 using three full-cone spray nozzles to assess the influence of subcooling on spray performance and critical heat flux (CHF) from a 1.0 × 1.0 cm² test surface. The relatively high boiling point of FC-77 (97 °C at one atmosphere) enabled testing at relatively high levels of subcooling. Increasing the subcooling delayed the onset of boiling but decreased the slope of the nucleate boiling region of the spray boiling curve. The enhancement in CHF was relatively mild at low subcooling and more appreciable at high subcooling. CHF was enhanced by about a 100% when subcooling was increased from 22 to 70 °C, reaching values as high as 349 W/cm². The FC-77 data were combined with prior spray CHF data from several studies into a broad CHF database encompassing different nozzles, fluids, flow rates, spray orientations, and subcoolings. The entire CHF database was used to modify the effect of subcooling in a previous CHF correlation that was developed for relatively low subcoolings. The modified correlation shows excellent predictive capability.     

Pool boiling of perfluorocarbon mixtures on silicon surfaces

The need for higher pool boiling critical heat flux (CHF) in electronic cooling applications has turned attention to the use of binary mixtures of dielectric liquids. The available literature demonstrates that the addition of a liquid with higher saturation temperature, higher molecular weight, higher viscosity and higher surface tension can lead to significant enhancement of CHF, beyond what can be achieved through changes in pressure, liquid subcooling, and the product of surface effusivity and heater thickness. The current study focuses on extending the available data on mixture CHF enhancement, as well as pool boiling, on polished silicon surfaces to FC-72/FC-40 mixture ratios of 10%, 15%, and 20% of FC-40 by weight, a pressure range of between 1 and 3 atm, and fluid temperature from 22 to 45 °C, leading to high subcooling conditions. It is found that peak heat flux can be increased to as high as 56.8 W/cm² compared to 25.2 W/cm² for pure FC-72 at 3 atm and 22 °C. It is believed that the increase in the mixture latent heat of evaporation and surface tension, accompanying the depletion of the lower boiling point fluid in the wall region plays the major role in enhancing the critical heat flux for binary mixtures.     

Subcooled flow boiling CHF enhancement with porous surface coatings

The effect of micro/nanoporous inside surface coated vertical tubes on CHF was determined during water flow boiling at atmospheric pressure. CHF was measured for smooth and three different coated tubes, at mass fluxes (100–300 kg/m² s) and two inlet subcooling temperatures (50 °C and 75 °C). Greater CHF enhancement was found with microporous coatings than with nanoporous coatings. Al₂O₃ microporous coatings with particle size <10 μm and coatings thickness of 50 μm showed the best CHF enhancement. Maximum increase in CHF was about 25% for microporous Al₂O₃. A wettability test was performed to study an increase of CHF with microporous coated surfaces.     

Correlation of critical heat flux and two-phase friction factor for subcooled convective boiling in structured surface microchannels

Critical heat flux (CHF) and pressure drop of subcooled flow boiling are measured for a microchannel heat sink containing 75 parallel 100 μm × 200 μm structured surface channels. The heated surface is made of a Cu metal sheet with/without 2 μm thickness diamond film. Tests and measurements are conducted with de-ionized water, de-ionized water +1 vol.% MCNT additive solution, and FC-72 fluids over a mass velocity range of 820–1600 kg/m² s, with inlet temperatures of 15(8.6)°C, 25(13.6)°C, 44(24.6)°C, and 64(36.6)°C for DI water (FC-72), and heat fluxes up to 600 W/cm². The CHF of subcooled flow boiling of the test fluids in the microchannels is measured parametrically. The two-phase pressure drop is also measured. Both CHF and the two-phase friction factor correlation for one-side heating with two other side-structured surface microchannels are proposed and developed in terms of the relevant parameters.     

Enhancement of pool boiling critical heat flux in dielectric liquids by microporous coatings

An experimental investigation into the effects of pressure and subcooling on the pool boiling critical heat flux from a bare silicon chip-like heater and from a silicon heater coated with microporous layers, is reported. The dual inline heater package was immersed in FC-72, a dielectric fluid, and the experiments were performed in the horizontal orientation, with subcooling varying between 0 K and 72 K, and the pressure between 101.3 kPa and 303.9 kPa. The maximum CHF values on the diamond-base microporous-coated silicon heater were found to reach 47 W/cm², at 3 atm and nearly 50 K of subcooling, and to provide an average enhancement of approximately 60% over the values attained with un-treated silicon surfaces. An available CHF correlation, with a reported standard deviation of 12.5% for un-treated surfaces over a large range of pressures, subcoolings, and surface conditions, was shown to predict the pressure and subcooling effects on CHF from the surface-enhanced chip with a standard deviation of 12%.     

Stabilizer effect on CHF and boiling heat transfer coefficient of alumina/water nanofluids

We measured the critical heat flux (CHF) and boiling heat transfer coefficient (BHTC) of water-based Al₂O₃ (alumina) nanofluids. To elucidate the stabilizer effect on CHF and BHTC of alumina/water nanofluids, a polyvinyl alcohol (PVA) was used as a stabilizer. The plate copper heater (10 × 10 mm²) is used as the boiling surface and the concentration of alumina nanoparticle varies 0–0.1 vol.%. The results show that the BHTC of the nanofluids becomes lower than that of the base fluid as the concentration of nanoparticles increases while CHF of it becomes higher. It is found that the increase of CHF is directly proportional to the effective boiling surface area and the reduction of BHTC is mainly attributed to the blocking of the active nucleation cavity and the increase of the conduction resistance by the nanoparticle deposition on the boiling surface.     

Effects of carbon nanotube arrays on nucleate pool boiling

Experiments were performed to assess the impact coating silicon and copper substrates with nanotubes (CNTs) have on pool boiling performance. Different CNT array densities and area coverages were tested on 1.27 × 1.27 mm² samples in FC-72. The CNT preparation techniques used provided strong adherence of CNTs to both substrate materials. Very small contact angle enabled deep penetration of FC-72 liquid inside surface cavities of smooth uncoated silicon surfaces, requiring unusually high surface superheat to initiate boiling. Fully coating the substrate surface with CNTs was highly effective at reducing the incipience superheat and greatly enhancing both the nucleate boiling heat transfer coefficient and critical heat flux (CHF). Efforts to further improve boiling performance by manipulating CNT area coverage of the substrate surface proved ineffective; best results were consistently realized with full surface coverage. Greater enhancement was achieved on silicon than on copper since, compared to uncoated copper surfaces, the uncoated silicon surfaces were very smooth and void of any sizeable nucleation sites to start with. This study is concluded with detailed metrics to assess the enhancement potential of the different CNT array densities and area coverages tested.     

A new mechanistic model for pool boiling CHF on horizontal surfaces

This work proposes a new mechanistic model for predicting the critical heat flux (CHF) in horizontal pool boiling systems. It is postulated that when the vapor momentum flux is sufficient to lift the liquid macrolayer from the heating surface, wetting is no longer feasible, and a transition from nucleate to film boiling occurs. This is the same mechanism that has found success in predicting CHF in flow boiling systems. An experimental investigation of CHF with pentane, hexane, and FC-72 in saturated horizontal pool boiling with chamber pressures of 150, 300, and 450 kPa provides evidence that the new model captures the variation of CHF with pressure reasonably well compared with other well known models. The new model is also compared with existing data from the literature over a reduced pressure range of 2 × 10^?5–2 × 10^?1. The mean deviation between the predicted and measured CHF is typically within 20% over the parameter space covered.     

Boiling time effect on CHF enhancement in pool boiling of nanofluids

Using TiO₂–water nanofluids as the test liquid, pool boiling experiments were carried out to investigate the dependence of the nucleate boiling heat transfer, surface wettability and critical heat flux (CHF) on the boiling time in nanofluids. In the experiments performed at sufficiently high nanoparticle concentrations, the boiling heat transfer first degraded, then improved, and finally reached an equilibrium state. It was hence supposed that the present nanofluids had competing effects to deteriorate and enhance the nucleate boiling heat transfer. As for the surface wettability and CHF, the static contact angle asymptotically decreased whilst the CHF asymptotically increased with an increase in the boiling time. The maximum CHF enhancement measured in the present experiments was 91%, and strong correlation was found between the contact angle and the CHF. Although the boiling time needed to achieve the maximum CHF enhancement was less than a minute at high particle concentrations, a longer time of the order of 1 h was necessary at the lowest particle concentration tested in this work. This experimental result indicated that sufficient attention should be paid to the boiling time effect particularly in industrial applications of nanofluids to emergency cooling.     

Effects of heater size and working fluids on nucleate boiling heat transfer

The present study is an experimental investigation of nucleate boiling heat transfer mechanism in pool boiling from wire heaters immersed in saturated FC-72 coolant and water. The vapor volume flow rate departing from a wire during nucleate boiling was determined by measuring the volume of bubbles from the wire utilizing the consecutive-photo method. The effects of the wire size on heat transfer mechanism during a nucleate boiling were investigated, varying 25 μm, 75 μm, and 390 μm, by measuring vapor volume flow rate and the frequency of bubbles departing from a wire immersed in saturated FC-72. One wire diameter of 390 μm was selected and tested in saturated water to investigate the fluid effect on the nucleate boiling heat transfer mechanism. Results of the study showed that an increase in nucleate boiling heat transfer coefficients with reductions in wire diameter was related to the decreased latent heat contribution. The latent heat contribution of boiling heat transfer for the water test was found to be higher than that of FC-72. The frequency of departing bubbles was correlated as a function of bubble diameters.     

Flow condensation in parallel micro-channels – Part 1: Experimental results and assessment of pressure drop correlations

In this first part of a two-part study, experiments were performed to investigate condensation of FC-72 along parallel, square micro-channels with a hydraulic diameter of 1 mm and a length of 29.9 cm, which were formed in the top surface of a solid copper plate. The condensation was achieved by rejecting heat to a counter flow of water through channels brazed to the underside of the copper plate. The FC-72 entered the micro-channels slightly superheated, and operating conditions included FC-72 mass velocities of 68–367 kg/m² s, FC-72 saturation temperatures of 57.2–62.3 °C, and water mass flow rates of 3–6 g/s. Using high-speed video imaging and photomicrographic techniques, five distinct flow regimes were identified: smooth-annular, wavy-annular, transition, slug, and bubbly, with the smooth-annular and wavy-annular regimes being most prevalent. A detailed pressure model is presented which includes all components of pressure drop across the micro-channel. Different sub-models for the frictional and accelerational pressure gradients are examined using the homogenous equilibrium model (with different two-phase friction factor relations) as well as previous macro-channel and mini/micro-channel separated flow correlations. Unexpectedly, the homogenous flow model provided far more accurate predictions of pressure drop than the separated flow models. Among the separated flow models, better predictions were achieved with those for adiabatic and mini/micro-channels than those for flow boiling and macro-channels.     

Enhanced flow boiling heat transfer of FC-72 on micro-pin-finned surfaces

For the purpose of cooling electronic components with high heat flux efficiently, some experiments were conducted to study the flow boiling heat transfer performance of FC-72 on silicon chips. Micro-pin-fins were fabricated on the chip surface using a dry etching technique to enhance boiling heat transfer. Three different fluid velocities (0.5, 1 and 2 m/s) and three different liquid subcoolings (15, 25 and 35 K) were performed, respectively. A smooth chip (chip S) and four micro-pin-finned chips with the same fin thickness of 30 μm and different fin heights of 60 μm (chip PF30–60) and 120 μm (chip PF30–120), respectively, were tested. All the micro-pin-finned surfaces show a considerable heat transfer enhancement compared to the smooth one, and the critical heat flux increases in the order of chip S, PF30–60 and PF30–120. For a lower ratio of fin height to fin pitch and/or higher fluid velocity, the fluid velocity has a positive effect on the nucleate boiling curves for the micro-pin-finned surfaces. At the velocities lower than 1 m/s, the micro-pin-finned surfaces show a sharp increase in heat flux with increasing wall superheat, and the wall temperature at the critical heat flux (CHF) is less than the upper limit, 85 °C, for the reliable operation of LSI chips. The CHF values for all surfaces increase with fluid velocity and subcooling. The maximum CHF can reach nearly 150 W/cm² for chip PF30–120 at the fluid velocity of 2 m/s and the liquid subcooling of 35 K.     

An experimental study on CHF enhancement in flow boiling using Al2O3 nano-fluid

The critical heat flux (CHF) is one of the most important thermal hydraulic parameters in heat transfer system design and safety analyses. CHF enhancement allows higher limits of operation conditions such that heat transfer equipment can be operated safely with greater margins and better economy. The application of nano-fluids is thought to have strong potential for enhancing the CHF. In this study, zeta potentials of Al₂O₃ nano-fluids were measured and flow boiling CHF enhancement experiments using Al₂O₃ nano-fluids were conducted under atmospheric pressure. The CHFs of Al₂O₃ nano-fluids were enhanced up to ～70% in flow boiling for all experimental conditions. Maximum CHF enhancement (70.24%) was shown at 0.01 vol% concentration, 50 °C inlet subcooling, and a mass flux of 100 kg/m² s. Inner surfaces of the test section tube were observed by FE–SEM and the zeta potentials of Al₂O₃ nano-fluids were measured before and after the CHF experiments.     

Critical heat flux on flow boiling of methanol–water mixtures in a diverging microchannel with artificial cavities

This study constitutes an experimental investigation into the convective boiling heat transfer and critical heat flux (CHF) of methanol–water mixtures in a diverging microchannel with artificial cavities. Flow visualization shows that bubbles are generally nucleated at both the artificial cavities and side walls of the channel. This confirms the proper functioning of such artificial cavities. Consequently, the wall superheat of the onset nucleate boiling is significantly reduced. Experimental results show that the boiling heat transfer and CHF are significantly influenced by the molar fraction (x_m) as well as the mass flux. The CHF increases with an increase in mass flux at the same molar fraction. On the other hand, the CHF increases slightly from x_m = 0 to 0.3, and then decreases rapidly from x_m = 0.3 to 1 at the same mass flux. The maximum CHF is reached at x_m = 0.3, particularly for a mass flux of 175 kg/m² s, due to the Marangoni effect. Flow visualization confirms that the Marangoni effect helps a region with a liquid film breakup persist to a higher heat flux, and therefore a higher CHF. Moreover, a new empirical correlation involving the Marangoni effect for the CHF on the flow boiling of methanol–water mixtures is developed. The present correlation prediction shows excellent agreement with the experimental data, and further confirms that the present correlation may predict the Marangoni effect on the CHF for the convective boiling heat transfer of binary mixtures.     

Saturated flow boiling heat transfer and associated bubble characteristics of FC-72 on a heated micro-pin-finned silicon chip

An experiment is carried out here to investigate flow boiling heat transfer and associated bubble characteristics of FC-72 on a heated micro-pin-finned silicon chip flush-mounted in the bottom of a horizontal rectangular channel. Besides, three different micro-structures of the chip surface are examined, namely, the smooth, pin-finned 200 and pin-finned 100 surfaces. The pin-finned 200 and 100 surfaces, respectively, contain micro-pin-fins of size 200 μm × 200 μm × 70 μm (width × length × height) and 100 μm × 100 μm × 70 μm. The pitch of the fins is equal to the fin width for both surfaces. The effects of the FC-72 mass flux, imposed heat flux, and surface micro-structures of the silicon chip on the FC-72 saturated flow boiling characteristics are examined in detail. The experimental data show that an increase in the FC-72 mass flux causes a delay in the boiling incipience. However, the flow boiling heat transfer coefficient is not affected by the coolant mass flux. But adding the micro-pin-fin structures to the chip surfaces can effectively enhance the single-phase convection and flow boiling heat transfer. Moreover, the mean bubble departure diameter and active nucleation site density are reduced for a rise in the FC-72 mass flux. A higher coolant mass flux results in a higher mean bubble departure frequency. Furthermore, larger bubble departure diameter, higher bubble departure frequency, and higher active nucleation site density are observed at a higher imposed heat flux. We also note that adding the micro-pin-fins to the chips decrease the bubble departure diameter and increase the bubble departure frequency. However, the departing bubbles are larger for the pin-finned 100 surface than the pin-finned 200 surface but the bubble departure frequency exhibits an opposite trend. Finally, empirical equations to correlate the present data for the FC-72 single-phase liquid convection and saturated flow boiling heat transfer coefficients and for the bubble characteristics are provided.     

Boiling heat transfer and critical heat flux of ethanol–water mixtures flowing through a diverging microchannel with artificial cavities

This paper presents an experimental study on the convective boiling heat transfer and the critical heat flux (CHF) of ethanol–water mixtures in a diverging microchannel with artificial cavities. The results show that the boiling heat transfer and the CHF are significantly influenced by the molar fraction (x_m) as well as the mass flux. For the single-phase convection region except for the region near the onset of nucleate boiling with temperature overshoot, the single-phase heat transfer coefficient is independent of the wall superheat and increases with a decrease in the molar fraction. After boiling incipience, the two-phase heat transfer coefficient is much higher than that of single-phase convection. The two-phase heat transfer coefficient shows a maximum in the region of bubbly-elongated slug flow and deceases with a further increase in the wall superheat until approaching a condition of CHF, indicating that the heat transfer is mainly dominated by convective boiling. A flow-pattern-based empirical correlation for the two-phase heat transfer coefficient of the flow boiling of ethanol–water mixtures is developed. The overall mean absolute error of the proposed correlation is 15.5%, and more than 82.5% of the experimental data were predicted within a ±25% error band. The CHF increases from x_m = 0–0.1, and then decreases rapidly from x_m = 0.1–1 at a given mass flux of 175 kg/m² s. The maximum CHF is reached at x_m = 0.1 due to the Marangoni effect, indicating that small additions of ethanol into water could significantly increase the CHF. On the other hand, the CHF increases with increasing the mass flux at a given molar fraction of 0.1. Moreover, the experimental CHF results are compared with existing CHF correlations of flow boiling of the mixtures in a microchannel.     

Flow boiling CHF enhancement with surfactant solutions under atmospheric pressure

Surfactant effect on CHF (critical heat flux) was determined during water flow boiling at atmospheric pressure in closed loop filled with solution of tri-sodium phosphate (TSP, Na₃PO₄ · 12H₂O). TSP was added to the containment sump water to adjust pH level during accident in nuclear power plants. CHF was measured for four different water surfactant solutions in vertical tubes, at different mass fluxes (100–500 kg/m² s) and two inlet subcooling temperatures (50 °C and 75 °C). Surfactant solutions (0.05–0.2%) at low mass flux (～100 kg/m² s) showed the best CHF enhancement. CHF was decreased at high mass flux (500 kg/m² s) compared to the reference plain water data. Maximum increase in CHF was about 48% as compared to the reference data. Surfactant caused a decrease in contact angle associated with an increase of CHF from surfactant addition.     

Pool boiling heat transfer on horizontal rectangular fin array in saturated FC-72

The flow patterns and pool boiling heat transfer performance of copper rectangular fin array surfaces immersed in saturated FC-72 were experimentally investigated. The effects of the geometry parameters (fin spacing and fin length) on boiling performance were also examined. The test surfaces were manufactured on a copper block with a base area of 10 mm × 10 mm with three fin spacing (0.5 mm, 1.0 mm and 2.0 mm) and four fin lengths (0.5 mm, 1.0 mm, 2.0 mm and 4.0 mm). All experiments were performed in the saturated state at 1 atmospheric condition. A plain surface was used as the reference standard and compared with the finned surfaces. The photographic images showed different boiling flow patterns among the test surfaces at various heat fluxes. The test results indicated that closer and higher fins yielded a greater flow resistance that against the bubble/vapor lift-off in the adjacent fins. Moreover, as the heat flux approached to critical heat flux (CHF), numerous vapor mushrooms periodically appeared and extruded from the perimeter of the fin array, causing dry-out in the center of the fin array. Closer and higher fins provide more heat transfer. The results also showed that overall heat transfer coefficient decayed rapidly as the fin spacing decreased or the fin length increased. The maximum value of CHF on the base area was 9.8 × 10⁵ W m⁻² for the test surface with a 0.5 mm fin spacing and a 4.0 mm fin length, which has a value five times greater than that of the plain surface.     

Efficient spreaders for cooling high-power computer chips

Investigated is the performance of composite spreaders, consisting of a top layer of porous graphite (⩾0.4 mm), for enhanced cooling by nucleate boiling of FC-72 dielectric liquid, and a copper substrate (⩽1.6 mm), for efficient spreading of the dissipated thermal power by the underling 10 × 10 mm or 15 × 15 mm high-power computer chips. The analysis assumes uniform thermal power dissipation by the chips and calculates the square surface area of the spreader, along with the spreading, boiling and total thermal resistances, the maximum chip temperature, and the removed thermal power from the spreader surface by saturation or subcooled nucleate boiling of FC-72 liquid. These performance parameters are determined as functions of the thickness of the copper substrate and the size of the underlying chip. When compared with those of copper and porous graphite spreaders of the same total thickness, 2.0 mm, the performance of the composite spreaders is superior for cooling high-power computer chips. When cooled by nucleate boiling of 30 K subcooled FC-72 liquid, the composite spreader removes 160.3 W and 98.4 W of dissipated thermal power by the underlying 10 × 10 mm and 15 × 15 mm chips, at total thermal resistances of 0.29 and 0.48 °C/W. When the same spreader is cooled by saturation boiling of FC-72, the removed thermal power decreases to 85.6 W and 53.4 W, and the total thermal resistances also decrease to 0.12 and 0.20 °C/W, respectively. Although the calculated surface temperatures of the chips are not uniform, the maximum temperatures are <71 °C and the temperature differential across the chips is <8 °C. For the same cooling condition, the calculated surface area of the copper spreaders, the total thermal resistance, and the maximum chip temperature are much higher, but the removed thermal powers from the surface of spreaders are much lower than with composite spreaders. The calculated surface areas of the porous graphite spreaders are smaller, the thermal powers removed from surface of these spreaders are much lower and both the total thermal resistance and the maximum chip temperature are higher than those with composite spreaders.