液态水对煤吸附甲烷影响的机理分析

为了研究液态水对煤吸附甲烷影响的机理,进行了不同煤级干燥煤样、平衡水煤样和注水煤样等温吸附实验,基于分子间作用力对液态水影响机理进行分析,并用维里方程拟合等温吸附实验结果来验证.结果表明,煤基质的润湿程度是液态水影响煤吸附甲烷的主要因素.干燥煤样中煤与甲烷分子间作用力远大于甲烷分子间作用力,第二维里系数较低,吸附能力强;平衡水煤样中煤与水分子氢键能高于范德华力,气态水分子竞争吸附,第二维里系数偏高,煤基质吸附能力弱;注水煤样中煤与甲烷分子之间长程作用力和甲烷与水分子之间短程作用力之和较小,与甲烷分子间作用力相当,第二维里系数最高,煤基质吸附能力很低.煤级增高,煤基质表面极性及其润湿程度降低,第二维里系数随之降低.     

阳泉3号煤干燥煤样等温吸附-解吸特性实验研究

为了深入研究阳泉3号煤对甲烷的吸附-解吸特性,采用高压容量法对同一干燥煤样进行了2次重复实验,结合吸附理论对实验结果进行分析可知:阳泉3号煤对甲烷具有典型的吸附、解吸过程可逆性和解吸过程滞后性,滞后的主要原因是实验煤样孔径50 nm左右的孔隙发育,易形成经典的毛细凝聚;采用单分子层吸附理论Langmuir方程对实验数据进行处理时发现吸附压力约7MPa时,吸附量大于Langmuir方程对应的吸附量,原因可能是煤中开始向多分子层吸附过渡;吸附-解吸过程造成煤中孔隙体积变化,可能会影响到吸附常数的测试.     

黄陇煤田煤层甲烷解吸滞后规律及解吸滞后定量评价

为研究黄陇煤田低阶煤甲烷解吸滞后规律并定量评价解吸滞后,采集郭家河井田3号煤层煤样(GJH3)、大佛寺井田4号煤层煤样(DFS4)与黄陵二矿井田2号煤层煤样(HL2),采用液氮吸附与等温吸附/解吸试验,分析其孔隙结构特征与吸附/解吸特征,基于Langmuir方程与热力学计算结果,定量评价解吸滞后与吸附/解吸前后吸附热差...     

煤体孔径分布特征及其对瓦斯吸附的影响

利用N2和CO2吸附解吸实验,得到了6个矿井煤样的孔径分布特征,并根据吸附解吸实验曲线分析了不同煤样所含孔形状的差异.同时,对所选煤样进行瓦斯吸附实验,分析瓦斯吸附量随吸附压力的变化情况,以及瓦斯吸附能力与孔径分布的关系.根据工业分析和岩相分析结果,对煤样变质程度和水分含量对瓦斯吸附的影响进行了分析.结果表明:煤对气体的吸附量主要集中在微孔段,同时受到中孔的影响,朗缪尔体积受微孔和中孔分布的共同作用,而朗缪尔压力只与微孔有关.水分子与甲烷分子之间存在竞争吸附,水分的存在不利于瓦斯吸附.煤的变质程度与朗缪尔体积之间呈现"U"型曲线关系,而变质程度的增加使朗缪尔压力降低.在煤矿开采过程中,应当采取措施增大煤体孔隙,使微孔比例降低,促进煤层瓦斯的解吸.     

空气干燥基煤的等温吸附平衡模式分析

针对国标要求的等温吸附测试需时较长,探讨压力随时间变化率平衡模式下所需时间及测试结果的可靠性,为提高实验效率奠定基础.利用Terratek公司IS-300型等温吸附仪,用空气干燥基煤样分别按照每个压力点平衡12 h和压力随时间变化率2种平衡模式进行实验.实验结果表明压力随时间变化率设置为10-8,所测兰氏体积与国标测试结果误差在10%以内,精度可以满足工程的需要,但花费时间缩短50%以上.因此按照斜率模式进行干燥煤样的等温吸附实验,所测结果在工程应用中是可信的且实验效率大幅提高.     

煤储层条件下平衡湿度测定方法研究

根据水与饱和硫酸钾溶液、粒度、时间等对平衡湿度的影响,分析了各因素对平衡湿度影响的原因,并在大量煤样测试研究基础上,修改完善了平衡湿度测定方法的技术参数,确定了实验的合理条件,为等温吸附实验提供了准确、可靠的保证,提出了相应的试验参数及误差范围.     

煤储层条件下平衡湿度测定方法研究

根据水与饱和硫酸钾溶液、粒度、时间等对平衡湿度的影响,分析了各因素对平衡湿度影响的原因,并在大量煤样测试研究基础上,修改完善了平衡湿度测定方法的技术参数,确定了实验的合理条件,为等温吸附实验提供了准确、可靠的保证,提出了相应的试验参数及误差范围.     

高含水煤样的多元混合气体的吸附分析

对高含水煤样进行了三元混合气体（CH4,CO2,N2均为33．3％）的高压等温吸附试验,得出等温吸附曲线,并分析了三元混合气体在吸附过程中各组分体积分数的变化规律．结果表明,吸附曲线在煤样含水量高于5％时不遵循超出煤样平衡水分范围曲线不再变化的规律,而是吸附量低得多;吸附过程中各组分的体积分数是实时变化的,吸附能力强的气体吸附速率先快后慢,吸附能力弱的气体吸附速率先慢后快;在高压时吸附曲线没有明显变化．为更科学地计算煤层气资源量和可采潜力提供参考．     

页岩吸附能力与温度的关系及吸附模型比较

页岩的吸附能力是评价页岩储层的关键参数。选取渝东南地区龙马溪组的页岩样品,利用磁悬浮称重法测量其甲烷吸附能力;使用非线性拟合方法模拟页岩的等温吸附曲线,得到不同温度下页岩的吸附差异;利用扫描电镜观察页岩的孔隙结构特征,综合分析温度对孔隙结构与页岩吸附能力的影响。测试结果发现,页岩的吸附能力受温度影响较大,随着温度的增加,页岩的吸附量下降明显。对比拟合结果表明,考虑了温度影响的指数模型比经典的Langmuir模型有更好的拟合效果。计算页岩吸附能力时应当考虑温度的影响。     

煤粒瓦斯解吸扩散规律实验

进行了不同粒径煤样、不同温度和不同吸附平衡压力条件下的等温吸附-解吸实验.通过对解吸实验前600s实验数据的甲烷解吸率和槡t线性拟合,并结合计算得到了煤粒甲烷的初始有效扩散系数和扩散动力学参数.结果表明:吸附平衡压力越大,初始有效扩散系数越大,瓦斯解吸率越大;温度越高,初始有效扩散系数和扩散动力学参数也越大;煤样的粒径愈大初始有效扩散系数愈大,而动力学扩散参数越小,相同解吸时间内的甲烷解吸率越小.通过Arrhenius方程得到了甲烷解吸扩散活化能的表达式,通过处理数据得到1#和3#煤样的解吸扩散活化能分别为14.38kJ/mol和9.99kJ/mol.     

CO2 isothermal adsorption models of coal in the Haishiwan Coalfield

Since the capacity of CO2 adsorption of coal is a key factor in coal and CO2 outbursts,an experimental study was carded out on CO2 isothermal adsorption with high-pressure volumetry with dry coal samples from the No.2 coal seam in the Haishiwan Coalfield.Four different equations (Langmuir,BET,D-R and D-A) were used to fit the experimental data.We discuss adsorption mechanisms.The results show that the amount of CO2 adsorption increases rapidly under low relative pressure,i.e.,the ratio of equilibrium pressure and saturated vapor pressure,which indicates that molecular layer adsorption or micropore filling may occur in coal.No clear equilibrium state was observed on the isothermal adsorption curves under relative pressure (P/P0) ranging from 0 to 0.8.The fitted results show that the accuracy of the D-A equation is highest with n=1.Micropores are more developed in coal by comparing the BET equation with a pressure mercury injection method on the surface area.The D-A equation (n=l) provides the best fit.By comparing the calculated specific surface area of the BET equation and the mercury intrusion method,it is found that micropore adsorption of CO2 occupies a dominant position.     

晋城无烟煤煤中CH4和CO2运移规律研究

基于三轴应力条件下,煤岩有效应力、吸附膨胀量和渗透率的一体测试,研究了晋城无烟煤吸附甲烷和二氧化碳后,渗透性随有效应力改变和煤岩吸附膨胀效应的变化规律.认为煤岩吸附膨胀量和孔隙压力的关系可用兰氏方程描述;煤岩渗透性同有效应力、吸附膨胀量均呈负指数函数关系,同时结果表明:甲烷和二氧化碳在晋城无烟煤中的扩散方式不同,煤岩对甲烷的吸附膨胀符合单孔气体扩散模型,而对二氧化碳的吸附膨胀符合双孔气体扩散模型,且甲烷的吸附膨胀速率小于二氧化碳的吸附膨胀速率;煤岩饱和吸附后,各孔隙压力条件下的初始渗透率与孔隙压力呈幂函数关系减小.针对晋城无烟煤,同等条件下煤岩吸附甲烷后的渗透率为吸附二氧化碳后渗透率的1.14～1.51倍,大部分在1.30倍左右.     

华北重点矿区煤储层吸附特征及其影响因素

研究华北地区煤储层吸附特征及主要影响因素，对9个重点矿区42件煤样进行了平衡水法等温吸附分析．实验表明：研究区原煤兰氏体积在6．22～43．57m^3／t之间，分布特征受区域煤变质的三带分布规律控制，在中带的沁水盆地最高，焦作、安鹤、永夏和荥巩煤田其次，而在南、北两带的平顶山、大同和两淮地区最低；全区域兰氏压力在0．20～3．83MPa之间，以大同和沁水最高，平顶山次之，其他矿区较低．研究表明，煤级是影响该区煤储层吸附能力的主要因素，随煤级增大，煤储层吸附能力呈多项式关系增强．煤吸附能力随煤中镜质组和惰质组含量总和的增高而增强，其中惰质组的影响较大．煤储层吸附能力随煤中碳组分含量的增高和氢组分含量的降低而增高．煤中水分和灰分的存在会降低煤的吸附性能．     

Methane adsorption behavior on coal having different pore structures

The adsorption of methane onto five dry coal samples was measured at 298 K over the pressure range from 0 to 3.5 MPa using a volumetric method. The isotherm data were fitted to the Langmuir and the Freundlich equations. The kinetic data were fitted to a pseudo second order equation, the linear driving force equation (LDF), and an intra-particle diffusion model. These results showed that higher methane adsorption is correlated with larger micro-pore volumes and specific surface areas. The adsorption was related to the narrow micro-pore size distribution when the previous two parameters are large. The kinetics study showed that the kinetics of methane adsorption onto these five dry coal samples followed a pseudo second order model very well. Methane adsorption rates are controlled by intra-particle diffusion. The faster the intra-particle diffusion, the faster the methane adsorption rate will be.     

Construction of high-pressure adsorption isotherm: A tool for predicting coalbed methane recovery from Jharia coalfield,India

Adsorption isotherm relates the gas storage capacity as a function of pressure at constant temperature. In this paper, adsorption isotherm of two dry borehole samples was constructed in the laboratory using the manometric method. Isotherm was measured for two gases, i.e., CH_4 and CO_2 to pressure up to 8.4 MPa.Before the construction of sorption isotherm, coal was characterized by proximate, ultimate and petrographic analysis. Coalbed gas content of these two samples was found 2.29 m~3/t and 2.75 m~3/t. SEM images were obtained for the pore size distribution of coal using pore image analysis. Prediction of coalbed methane recovery from CH_4 adsorption isotherm showed that these coalbeds are under saturated. CO_2 isotherm was constructed to estimate enhanced coalbed methane(ECBM) recovery. Volume wise CO_2/CH_4 sorption ratio was found 2.09 times to 2.75 times respectively. This paper presents the interpretation of isotherm data to find the recovery factor of methane production from Jharia coalfield.     

煤基活性炭比表面积表征研究

为了建立适用于不同类型及孔结构煤基活性炭比表面积的科学计算方法,用物理吸附分析法对宁夏煤基活性炭比表面进行表征,通过研究Langmuir比表面积和BET比表面积理论模型,探讨了两种比表面积表征结果的特点和原因．结果表明,同一材料的Langmuir比表面积大于BET比表面积,本质上是由于依据Langmuir方程得到的单层吸附量大于依据BET理论所求得的单层吸附量．     

Improved analytic methods for coal surface area and pore size distribution determination using 77 K nitrogen adsorption experiment

77 K nitrogen adsorption was the most widely used technique for determining surface area and pore size distribution of coal. Brunauer–Emmett–Teller (BET) and Barrett–Joyner–Halenda (BJH) model are commonly used analytic methods for adsorption/desorption isotherm. A Chinese anthracite coal is tested in this study using an improved experimental method and adsorption isotherm analyzed by three adsorption mechanisms at different relative pressure stages. The result shows that the micropore filling adsorption predominates at the relative pressure stage from 6.8E−7 to 9E−3. Theoretically, BET and BJH model are not appropriate for analyzing coal samples which contain micropores. Two new analytic procedures for coal surface area and pore size distribution calculation are developed in this work. The results show that BET model underestimates surface area, and micropores smaller than 1.751 nm account for 35.5% of the total pore volume and 74.2% of the total surface area. The investigation of surface area and pore size distribution by incorporating the influence of micropore is significant for understanding adsorption mechanism of methane and carbon dioxide in coal.     

The impact of depositional environment and tectonic evolution on coalbed methane occurrence in West Henan,China

A deeper understanding of the mechanisms by which geological factors(depositional environment and tectonic evolution) control the occurrence of coalbed methane(CBM) is important for the utilization of CBM resources via surface-drilled wells and the elimination of coal-methane outbursts, the latter of which is a key issue for coal mine safety. Based on drill core data, high-pressure isothermal adsorption experiments, scanning electron microscopy experiments, mercury intrusion porosimetry, and X-ray diffraction experiments, the impact of the depositional environment and tectonic evolution on CBM occurrence of the II-1 coal seam of the Shanxi Formation in West Henan was analyzed. Results showed that the depositional environment led to the epigenetic erosion of tidal flat coal-accumulating structures by shallow-delta distributary channel strata. This resulted in the replacement of the original mudstonesandy mudstone coal seam immediate roof with fine-to-medium grained sandstones, reducing methane storage capacity. Epigenetic erosion by the depositional environment also increased coal body ash content(from 6.9% to 21.4%) and mineral content, filling the cleat system and reducing porosity, reducing methane storage capacity. The maximum methane adsorption capacity of the coal body reduced from35.7 cm3/g to 30.30 cm3/g, and Langmuir pressure decreased from 1.39 MPa to 0.909 MPa. Hence, the methane adsorption capacity of the coal body decreased while its capacity for methane desorption increased. Owing to the tectonic evolution of West Henan, tectonically deformed coal is common; as it evolves from primary cataclastic coal to granulitic coal, the angle of the diffraction peak increases, d002 decreases, and La, Lc, and Nc increase; these traits are generally consistent with dynamic metamorphism.This is accompanied by increases in the total pore volume and specific surface area of the coal body, further increasing the capacity for methane storage. Increases in micropore volume and specific surface area also increase the ability of the coal body to adsorb methane.