Emissions from large-scale medium-speed diesel engines: 2. Influence of fuel type and operating mode

This paper addresses gaseous emissions smoke (soot) and particulate matter in large-scale diesel engine exhaust. The test engine was a large-scale turbocharged, after-cooled mean speed ( 500 rpm) direct-injection diesel engine and the power per cylinder was about 1 MW. Emission measurements were carried out on burning heavy fuel (HFO) and light fuel (LFO) oils. The test modes for the investigation were a propulsion mode (marine application) and a generator mode (power plant application). Gaseous emissions were measured according to the IMO technical code, smoke (soot) emissions were determined optically and particulate matter (PM) was measured by gravimetric impactor designed for five size fractions. In comparison the emissions from HFO and LFO utilisations indicate slightly higher NO and CO emissions for HFO, while LFO gives clearly higher emissions of hydrocarbons (HC). Emissions of soot and CO appeared to correlate very well, being very high for both fuels throughout the propulsion mode and low load, otherwise being similar for both modes. PM emissions are more than three times higher with HFO than with LFO and appear to decrease with the load except for HFO during the generator mode where an increase of PM emissions with the load is seen. Some data on sampled particles is given.     

Particulate emissions from large-scale medium-speed diesel engines: 1. Particle size distribution

This paper addresses particulate matter (PM) size distributions in large-scale diesel engine exhaust. The test engines were multivariable large-scale turbo-charged, after-cooled medium speed (~ 500 rpm, ~ 1 MW power per cylinder) direct injection diesel engines. Emissions measurements were carried out while burning heavy fuel (HFO) and light fuel (LFO) oils. Test modes for investigation were propulsion mode (marine) and generator mode (power plant), with load varying from 25 to 100%. PM was measured using a gravimetric impactor with four impactor stages plus a filter, classifying particles between 0.005 and 2.5 μm (aerodynamic diameter). The results show that HFO firing produces significantly higher PM emissions (more than factor of ~three on mass bases for high load operation) compared to LFO, especially for particles smaller than 0.5 μm. This is mainly due to higher ash-forming elements and sulphur content of HFO. For HFO, the fraction of the finest particles increases with load, more strongly for generator mode than for propulsion mode, with generator mode giving ~ 50% higher PM emissions than propulsion mode. With LFO firing, the largest amount of fine PM was emitted at the lowest load, for propulsion mode being lower and almost independent of load at higher loads, while for generator mode a steady decrease in emissions with increasing load is seen for all PM size classes measured.     

Pilot ignited premixed combustion of dimethyl ether in a turbodiesel engine

This paper describes combustion studies of dimethyl ether in a common rail turbodiesel engine wherein the dimethyl ether was fumigated into the intake air and the conventional diesel injection was used with the intention of igniting the premixed DME-air charge. This combustion process is referred to here as a “mixed mode” process and is similar in some respects to what is commonly referred to as “dual fuel” combustion. In contrast to “dual fuel” combustion, however, in which the gaseous fuel is often natural gas or biogas, in this process with DME the gaseous charge ignites largely independently of the diesel injection. The diesel injection was accomplished with a single, main injection. The engine was operated at a single speed and load. Gaseous and particulate emissions were monitored and heat release analysis was performed to examine how the fuels burn and the impact on emissions formation at various levels of substitution of diesel fuel with fumigated DME, at as high as 44% of the fuel energy from DME. Reductions in NO_x emissions and increases in particulate matter emissions are observed with DME fumigation. The increase in PM emissions is attributed to enrichment of the diesel fuel spray, due to displacement of intake oxygen by the fumigated DME, despite the widely observed soot suppressing effect of DME.     

Experimental investigation on dual fuel operation of acetylene in a DI diesel engine

Depletion of fossils fuels and environmental degradation have prompted researchers throughout the world to search for a suitable alternative fuel for diesel engine. One such step is to utilize renewable fuels in diesel engines by partial or total replacement of diesel in dual fuel mode. In this study, acetylene gas has been considered as an alternative fuel for compression ignition engine, which has excellent combustion properties.Investigation has been carried out on a single cylinder, air cooled, direct injection (DI), compression ignition engine designed to develop the rated power output of 4.4 kW at 1500 rpm under variable load conditions, run on dual fuel mode with diesel as injected primary fuel and acetylene inducted as secondary gaseous fuel at various flow rates. Acetylene aspiration resulted in lower thermal efficiency. Smoke, HC and CO emissions reduced, when compared with baseline diesel operation. With acetylene induction, due to high combustion rates, NO_x emission significantly increased. Peak pressure and maximum rate of pressure rise also increased in the dual fuel mode of operation due to higher flame speed. It is concluded that induction of acetylene can significantly reduce smoke, CO and HC emissions with a small penalty on efficiency.     

Potential for reducing emissions in a diesel engine by fuelling with conventional biodiesel and Fischer-Tropsch diesel

A gas-to-liquid (GTL) fuel derived from Low Temperature Fischer-Tropsch process has been tested in an automotive diesel engine fulfilling Euro 4 emissions regulations. Both regulated and non-regulated emissions have been compared with those of a commercial diesel fuel, a commercial biodiesel fuel and a GTL-biodiesel fuel (30% and 70% v/v, respectively) in order to check blending properties, synergistic effects and compatibility between first and second generation production technologies for biofuel consumption in current diesel engines. After presenting a detailed literature review, and confirming that similar efficiencies are attained with the four tested fuels under identical road-like operating conditions (this meaning fuel consumption is inversely proportional to their heating values), significant reductions in smoke opacity, particulate matter emissions and particle number concentration were observed with both GTL and biodiesel fuels, with small changes in NO_x emissions. Compared with the reductions in PM emissions derived from the use of biodiesel fuels, those derived from using GTL fuels were quite similar, despite its lower soot emissions reductions. This can be explained by the lower volatile organic fraction of the PM in the case of GTL. By adequately blending both fuels, a considerable potential to optimise the engine emissions trade-off is foreseen.     

Study of oxygenated biomass fuel blends on a diesel engine

Vegetable methyl ester was added in ethanol–diesel fuel to prevent separation of ethanol from diesel in this study. The ethanol blend proportion can be increased to 30% in volume by adding the vegetable methyl ester. Engine performance and emissions characteristics of the fuel blends were investigated on a diesel engine and compared with those of diesel fuel. Experimental results show that the torque of the engine is decreased by 6%–7% for every 10% (by volume) ethanol added to the diesel fuel without modification on the engine. Brake specific fuel consumption (BSFC) increases with the addition of oxygen from ethanol but equivalent brake specific fuel consumption (EBSFC) of oxygenated fuels is at the same level of that of diesel. Smoke and particulate matter (PM) emissions decrease significantly with the increase of oxygen content in the fuel. However, PM reduction is less significant than smoke reduction. In addition, PM components are affected by the oxygenated fuel. When blended fuels are used, nitrogen oxides (NO_x) emissions are almost the same as or slightly higher than the NO_x emissions when diesel fuel is used. Hydrocarbon (HC) is apparently decreased when the engine was fueled with ethanol–ester–diesel blends. Fuelling the engine with oxygenated diesel fuels showed increased carbon monoxide (CO) emissions at low and medium loads, but reduced CO emissions at high and full loads, when compared to pure diesel fuel.     

Biodiesel engine performance and emissions in low temperature combustion

Engine performance and emission comparisons were made between the use of soy, Canola and yellow grease derived B100 biodiesel fuels and an ultra-low sulphur diesel fuel in the high load engine operating conditions. Compared to the diesel fuel engine-out emissions of nitrogen oxides (NO_x), a high-cetane number (CN) biodiesel fuel produced comparable NO_x while the biodiesel with a CN similar to the diesel fuel produced relatively higher NO_x at a fixed start of injection. The soot, carbon monoxide and un-burnt hydrocarbon emissions were generally lower for the biodiesel-fuelled engine. Exhaust gas recirculation (EGR) was then extensively applied to initiate low temperature combustion (LTC) mode at medium and low load conditions. An intake throttling valve was implemented to increase the differential pressure between the intake and exhaust in order to increase and enhance the EGR. Simultaneous reduction of NO_x and soot was achieved when the ignition delay was prolonged by more than 50% from the case with 0% EGR at low load conditions. Furthermore, a preliminary ignition delay correlation under the influence of EGR at steady-state conditions was developed. The correlation considered the fuel CN and oxygen concentrations in the intake air and fuel. The research intends to achieve simultaneous reductions of NO_x and soot emissions in modern production diesel engines when biodiesel is applied.     

The influence of n-butanol/diesel fuel blends utilization on a small diesel engine performance and emissions

Nitrogen oxides and smoke emissions are the most significant emissions for the diesel engines. Especially, fuels containing high-level oxygen content can have potential to reduce smoke emissions significantly. The aim of the present study is to evaluate the influence of n-butanol/diesel fuel blends (as an oxygenation additive for the diesel fuel) on engine performance and exhaust emissions in a small diesel engine. For this aim five-test fuels, B5 (contains 5% n-butanol and 95% diesel fuel in volume basis), B10, B15, B20 and neat diesel fuel, were prepared to test in a diesel engine. Tests were performed in a single cylinder, four stroke, unmodified, and naturally aspirated DI high speed diesel engine at constant engine speed (2600 rpm) and four different engine loads by using five-test fuels. The experimental test results showed that smoke opacity, nitrogen oxides, and carbon monoxide emissions reduced while hydrocarbon emissions increased with the increasing n-butanol content in the fuel blends. In addition, there is an increase in the brake specific fuel consumption and in the brake thermal efficiency with increasing n-butanol content in fuel blends. Also, exhaust gas temperature decreased with increasing n-butanol content in the fuel blends.     

Effect of Biofuels on Catalyzed Diesel Particulate Filter Regeneration

Under the terms of the Renewable Energy Directive, EU member states are required to use 10 % of transport energy sourced from renewable sources, mainly biofuels, by 2020. The purpose is to reduce greenhouse gas (GHG) emissions from the transport sector. However, biodiesel used as fuel has a significant impact on emissions, as related by most of the literature on the subject. In particular, nitric oxides (NOx) and particulate matter (PM) emissions from current diesel technologies are critical factors because they are already close to the limits permitted by regulations and both limits will be even more stringent in the near future. Soot particles are trapped on a diesel particulate filter (DPF). If the DPF is catalyzed like in this study, the soot is then burned by reaction with NO₂ (CDPF continuous regeneration) which occurs at lower temperatures than reaction with O₂ (active regeneration). Tests of ultra-low sulfur diesel blended with rapeseed-biodiesel at 30 % (B30) and Fischer–Tropsch diesel (FT30) were conducted. The Fischer–Tropsch diesel was chosen to represent a biomass-to-liquid fuel. This work investigated the impact of these two biofuels on engine polluting emissions and the resulting CDPF ability to regenerate. When compared with similar inlet conditions on a synthetic gas bench, an impact of fuel was observed on soot reactivity: the CDPF loaded with FT30 soot regenerated slightly faster. Engine bench tests were also performed to combine the effects of fuel on engine emissions and soot reactivity and to evaluate the CDPF. The increase in NOx and decrease in PM emissions observed for B30 appeared to significantly improve CDPF continuous regeneration by NO₂.     

Characterization of Particulate Matter Morphology and Volatility from a Compression-Ignition Natural-Gas Direct-Injection Engine

The particulate matter (PM) emitted from a single-cylinder compression-ignition, natural-gas engine fitted with a High-Pressure Direct-Injection (HPDI) system distinctly different from a duel fuel engine was investigated, and characterized by size distribution, morphology, mass-mobility exponent, effective density, volatility, mixing state, and primary particle size using transmission electron microscopy (TEM), and tandem measurements from differential mobility analyzers (DMA) and a centrifugal particle mass analyzer (CPMA). Six engine conditions were selected with varying load, speed, exhaust gas recirculation (EGR) fraction, and fuel delivery strategy. An increase in engine load increased both the number concentration and the geometric mean diameter of the particulate. The fraction of the number of purely volatile particles to total number of particles (number volatile fraction, NVF) was found to decrease as load increased, although at the lower speed, partially premixed mode, the lowest NVF. All size distributions were also found to be unimodal. The size-segregated ratio of the mass of internally mixed volatile material to total particle mass (mass volatile fraction, MVF) decreased with load and with particle mobility-equivalent diameter. A roughly constant amount of volatile material is likely produced at each engine mode, and the decrease in MVF is due to the increase in PM number with load. Effective density and mass-mobility exponent of the non-volatile soot at the different engine loads were the same or slightly higher than soot from traditional diesel engines. Denuded effective density trends were observed to collapse to approximately the same line, although engine modes with higher MVFs had slightly higher effective densities suggesting that the soot structures have collapsed into more dense shapes—a suspicion that is confirmed with TEM images. TEM results also indicated that primary particle size first decreases from low to medium load, then increases from medium to high load. An increase in EGR was also seen to increase primary particle size. Coefficients were determined for a relation that gives primary particle diameter as a function of projected area equivalent diameter. A decrease in load or speed results in a stronger correlation.

Copyright 2015 American Association for Aerosol Research     

Performance and combustion characteristics of a DI diesel engine fueled with waste palm oil and canola oil methyl esters

This study discusses the performance and combustion characteristics of a direct injection (DI) diesel engine fueled with biodiesels such as waste (frying) palm oil methyl ester (WPOME) and canola oil methyl ester (COME). In order to determine the performance and combustion characteristics, the experiments were conducted at the constant engine speed mode (1500 rpm) under the full load condition of the engine. The results indicated that when the test engine was fueled with WPOME or COME, the engine performance slightly weakened; the combustion characteristics slightly changed when compared to petroleum based diesel fuel (PBDF). The biodiesels caused reductions in carbon monoxide (CO), unburned hydrocarbon (HC) emissions and smoke opacity, but they caused to increases in nitrogen oxides (NO_x) emissions.     

Experimental study of n-butanol additive and multi-injection on HD diesel engine performance and emissions

Experimental study was conducted to investigate the influence of the diesel fuel n-butanol content on the performance and emissions of a heavy duty direct injection diesel engine with multi-injection capability. At fixed engine speed and load, exhaust gas recirculation rates were adjusted to keep NO_x emission at 2.0 g/kW h. Diesel fuels with different amounts (0%, 5%, 10% and 15% by volume) of n-butanol were used. The results show that the n-butanol addition can significantly improve soot and CO emissions at constant specific NO_x emission without a serious impact on the break specific fuel consumption and NO_x. The impacts of pilot and post injection on engine characteristics by using blended fuels are similar to that found by using pure diesel. Early pilot injection reduces soot emission, but results in a dramatic increase of CO. Post injection reduces soot and CO emissions effectively. Under each injection strategy, the increase of fuel n-butanol content leads to further reduction of soot. A triple-injection strategy with the highest n-butanol fraction used in this study offers the lowest soot emission.     

Effect of variation in LPG composition on emissions and performance in a dual fuel diesel engine

This paper investigates the effect of variation in LPG composition on emissions and performance characteristics in a dual fuel engine run on diesel fuel and five gaseous fuel of LPG with different composition. To quantify the best LPG composition for dual fuel operation especially in order to improve the exhaust emissions quality while maintaining high thermal efficiency comparable to a conventional diesel engine, a two-cylinder, naturally aspirated, four-stroke, DI diesel engine converted to run as pilot-injected dual fuel engine. The tests and data collection were performed under various conditions of load at constant engine speed. From the results, it is observed that the exhaust emissions and fuel conversion efficiency of the dual fuel engine are found to be affected when different LPG composition is used as higher butane content lead to lower NO_x levels while higher propane content reduces CO levels. Fuel #3 (70% propane, 30% butane) with mass fraction 40% substitution of the diesel fuel was the best LPG composition in the dual fuel operation except that at part loads. Also, tests were made for fuel #3-diesel blend in the dual fuel operation at part loads to improve the engine performances and exhaust emissions by using the Exhaust Gas Recirculation (EGR) method.     

Diesel and rapeseed methyl ester (RME) pilot fuels for hydrogen and natural gas dual-fuel combustion in compression-ignition engines

This paper presents experimental results of rapeseed methyl ester (RME) and diesel fuel used separately as pilot fuels for dual-fuel compression-ignition (CI) engine operation with hydrogen gas and natural gas (the two gaseous fuels are tested separately). During hydrogen dual-fuel operation with both pilot fuels, thermal efficiencies are generally maintained. Hydrogen dual-fuel CI engine operation with both pilot fuels increases NO_x emissions, while smoke, unburnt HC and CO levels remain relatively unchanged compared with normal CI engine operation. During hydrogen dual-fuel operation with both pilot fuels, high flame propagation speeds in addition to slightly increased ignition delay result in higher pressure-rise rates, increased emissions of NO_x and peak pressure values compared with normal CI engine operation. During natural gas dual-fuel operation with both pilot fuels, comparatively higher unburnt HC and CO emissions are recorded compared with normal CI engine operation at low and intermediate engine loads which are due to lower combustion efficiencies and correspond to lower thermal efficiencies. This could be due to the pilot fuel failing to ignite the natural gas-air charge on a significant scale. During dual-fuel operation with both gaseous fuels, an increased overall hydrogen-carbon ratio lowers CO₂ emissions compared with normal engine operation. Power output (in terms of brake mean effective pressure, BMEP) as well as maximum engine speed achieved are also limited. This results from a reduced gaseous fuel induction capability in the intake manifold, in addition to engine stability issues (i.e. abnormal combustion). During all engine operating modes, diesel pilot fuel and RME pilot fuel performed closely in terms of exhaust emissions. Overall, CI engines can operate in the dual-fuel mode reasonably successfully with minimal modifications. However, increased NO_x emissions (with hydrogen use) and incomplete combustion at low and intermediate loads (with natural gas use) are concerns; while port gaseous fuel induction limits power output at high speeds.     

Comparison of emissions of a direct injection diesel engine operating on biodiesel with emulsified and fumigated methanol

Biodiesel is an alternative fuel for internal combustion engines. It can reduce carbon monoxide (CO), hydrocarbon (HC) and particulate matter (PM) emissions, compared with diesel fuel, but there is also an increase in nitrogen oxides (NO_x) emission. This study is aimed to compare the effect of applying a biodiesel with either 10% blended methanol or 10% fumigation methanol. The biodiesel used in this study was converted from waste cooking oil. Experiments were performed on a 4-cylinder naturally aspirated direct injection diesel engine operating at a constant speed of 1800 rev/min with five different engine loads. The results indicate a reduction of CO₂, NO_x, and particulate mass emissions and a reduction in mean particle diameter, in both cases, compared with diesel fuel. It is of interest to compare the two modes of fueling with methanol in combination with biodiesel. For the blended mode, there is a slightly higher brake thermal efficiency at low engine load while the fumigation mode gives slightly higher brake thermal efficiency at medium and high engine loads. In the fumigation mode, an extra fuel injection control system is required, and there is also an increase in CO, HC and NO₂ (nitrogen dioxide) and particulate emissions in the engine exhaust, which are disadvantages compared with the blended mode.     

Emission characteristics using methyl soyate–ethanol–diesel fuel blends on a diesel engine

A blend of 20% (v/v) ethanol/methyl soyate was prepared and added to diesel fuel as an oxygenated additive at volume percent levels of 15 and 20% (denoted as BE15 and BE20). We also prepared a blend containing 20% methyl soyate in diesel fuel (denoted as B20). The fuel blends that did not have any other additive were stable for up to 3 months. Engine performance and emission characteristics of the three different fuels in a diesel engine were investigated and compared with the base diesel fuel. Observations showed that particulate matter (PM) emission decreased with increasing oxygenate content in the fuels but nitrogen oxides (NO_x) emissions increased. The diesel engine fueled by BE20 emitted significantly less PM and a lower Bosch smoke number but the highest NO_x among the fuel blends tested. All the oxygenate fuels produced moderately lower CO emissions relative to diesel fuel. The B20 blend emitted less total hydrocarbon (THC) emissions compared with base diesel fuel. This was opposite to the fuel blends containing ethanol (BE15, BE20), which produced much higher THC emission.     

Effect of Waste Cooking Oil Biodiesel on the Properties of Particulate from a DI Diesel Engine

The present work focuses on the effect of waste cooking oil biodiesel on the particulate mass, number concentration, nanostructure, and oxidative reactivity under different engine speeds and engine loads. Particulate samples were collected from the diluted exhaust of a medium-duty direct injection diesel engine and were used to analyze the physico-chemical properties via the transmission electron microscope (TEM) and the thermogravimetric analyzer/differential scanning calorimeter (TGA/DSC). The TEM images reveal that smaller primary particles are formed at higher engine speed, lower engine load, or using biodiesel. Quantitative analysis of the nanostructures indicates more soot with more disordered configuration, in which shorter and more curved graphene layer is prevailing at lower engine load or when using biodiesel. Furthermore, the TGA results infer that the soot oxidative reactivity is closely related to the nanostructure properties and the effect of engine load is more pronounced than the effect of engine speed. Also biodiesel soot has faster oxidative reactivity than diesel soot. Moreover, results obtained for B30 (30% biodiesel and 70% diesel fuel) lie in between those for biodiesel and diesel fuel.

Copyright 2015 American Association for Aerosol Research     

Experimental investigation on the combustion and exhaust emission characteristics of biogas-biodiesel dual-fuel combustion in a CI engine

An experimental investigation was performed to study the influence of dual-fuel combustion characteristics on the exhaust emissions and combustion performance in a diesel engine fueled with biogas-biodiesel dual-fuel. In this work, the combustion pressure and the rate of heat release were evaluated under various conditions in order to analyze the combustion and emission characteristics for single-fuel (diesel and biodiesel) and dual-fuel (biogas-diesel and biogas-biodiesel) combustion modes in a diesel engine. In addition, to compare the engine performances and exhaust emission characteristics with combustion mode, fuel consumption, exhaust gas temperature, efficiency, and exhaust emissions were also investigated under various test conditions. For the dual-fuel system, the intake system of the test engine was modified to convert into biogas and biodiesel of a dual-fueled combustion engine. Biogas was injected during the intake process by two electronically controlled gas injectors, which were installed in the intake pipe.The results of this study showed that the combustion characteristics of single-fuel combustion for biodiesel and diesel indicated the similar patterns at various engine loads. In dual-fuel mode, the peak pressure and heat release for biogas-biodiesel were slightly lower compared to biogas-diesel at low load. At 60% load, biogas-biodiesel combustion exhibited the slightly higher peak pressure, rate of heat release (ROHR) and indicated mean effective pressure (IMEP) than those of diesel. Also, the ignition delay for biogas-biodiesel indicated shortened trends compared to ULSD dual-fueling due to the higher cetane number (CN) of biodiesel. Significantly lower NO_x emissions were emitted under dual-fuel operation for both cases of pilot fuels compared to single-fuel mode at all engine load conditions. Also, biogas-biodiesel provided superior performance in reductions of soot emissions due to the absence of aromatics, the low sulfur, and oxygen contents for biodiesel.     

Regulated and unregulated emissions from a light-duty diesel engine with different sulfur content fuels

Five different sulfur content fuels were used on a light-duty diesel engine to study the effect of fuel sulfur on emissions. Four regulated emissions: smoke, nitrogen oxide (NO_x), unburned hydrocarbon (HC) and carbon monoxide (CO) emissions of the engine were investigated, as well as three unregulated emissions: formaldehyde (HCHO), acetaldehyde (MECHO) and sulfur dioxide (SO₂). The smoke emission decreases continuously and remarkably with the fuel sulfur content, and the fuel sulfur has more influence on smoke emission at lower engine load. The concentration of NO_x emissions did not change significantly with the different sulfur content fuels. As the fuel sulfur content decreases, the concentrations of HC and CO emissions have distinct reduction. The HCHO emission values are very low. The MECHO emission decreases with increasing engine load, and it continuously decreases with the fuel sulfur content and it could not be detected at higher engine load with 50 ppm sulfur fuel. The SO₂ emission increases continuously with the engine load, and obviously decreases with the fuel sulfur contents.