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桑枝基活性炭的制备及其对多环芳烃菲的吸附 总被引:1,自引:0,他引:1
以废弃桑枝为原料,以磷酸氢二铵为活化剂制备活性炭,考察了浸渍比、炭化温度、炭化时间、活化温度和活化时间对活性炭的亚甲基蓝吸附值的影响,确定了制备桑枝基活性炭的最佳工艺条件。研究了桑枝基活性炭对水中多环芳烃菲的吸附性能。结果表明制备活性炭的最佳工艺条件:浸渍比为2:1、炭化温度为400℃、炭化时间为90min、活化温度为800℃、活化时间为120min。制备的活性炭对多环芳烃菲具有较好的吸附效果,初始浓度为1000μg/L的菲在桑枝活性炭上吸附去除率可达71.7%,吸附平衡时间为240min。Freundlich吸附模型可较好地模拟菲在桑枝基活性炭上的吸附等温线。菲的吸附以物理吸附为主,吸附较易进行。 相似文献
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污泥衍生活性炭制备与性能表征 总被引:3,自引:1,他引:2
通过对青岛海泊河污水处理厂的污泥性质和组成分析,研究了以城市污水厂污泥为基本原料,采用CO2活化法制备活性炭吸附剂.选取炭化温度、炭化时间、CO2流量、活化温度和活化时间等因素,通过正交实验确定最佳工艺条件.通过亚甲基蓝吸附值、电镜照片对制备的污泥活性炭进行性能评价,结果表明:最佳工艺条件炭化温度为550 ℃、炭化时间90min、二氧化碳流量250 mL/min、活化温度950 ℃、活化时间120 min,污泥衍生活性炭亚甲基蓝吸附值245 mg/g. 相似文献
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以重质沥青为原料,采用空气热聚合法-物理活化法协同制备重质沥青基活性炭。通过正交设计法系统研究了预氧化升温速率、恒温温度、恒温时间、活化时间、活化温度、炭化时间、炭化温度等因素对重质沥青基活性炭的影响。利用扫描电镜、碘吸附值等对活性炭的表面形态及吸附特性进行表征。结果表明,空气热聚合法-物理活化法协同制备重质沥青基活性炭的优化条件为:预氧化升温速率为2℃/min、预氧化恒温温度为300℃、预氧化恒温时间为1 h、炭化温度为500℃、炭化时间为120 min、活化温度为850℃、活化时间为90 min,该工艺条件下制备的活性炭具有较为发达的微孔结构,碘吸附值为689.33 mg/g。 相似文献
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水蒸气活化法制备稻壳活性炭的研究 总被引:1,自引:0,他引:1
研究了水蒸气活化法制备稻壳活性炭的工艺条件,探讨了炭化温度、活化温度、活化时间和水蒸气用量对活化效果的影响。最佳工艺条件为:炭化温度 450℃、活化温度 900℃、活化时间 90 min和水蒸气用量为炭化料的1.5倍,制备的活性炭碘吸附值 844 mg/g,亚甲基蓝吸附值 138 mL/g,产品得率 13.9%。这些指标与木质活性炭相当。且投资少,能耗低,具有良好的经济效益与社会效益。 相似文献
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研究了不黏煤配合气煤制备压块活性炭的工艺条件,探讨了活性炭吸附性能,实验得到最佳的工艺条件为炭化温度550℃,炭化恒温时间30min,活化温度900℃,活化时间4h。压块活性炭的碘吸附值可达1041mg/g,亚甲基蓝吸附值为190mg/g,均符合工业生产的要求。 相似文献
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在煤基球形活性炭的制备过程中,生球预氧化条件很大程度上决定了球形炭的球形度和物化特性。以山西柳林华晋焦煤集团焦煤为原料,研究了活性炭制备过程中预氧化、炭化、活化等工艺参数对活性炭质量的影响。结果表明:预处理温度为200℃,预处理时间3 h,炭化终温700℃,炭化升温速率4℃/min,活化温度800℃,活化时间7 h时,制得的活性炭球形度完整,物化性能优良,活性炭的碘值为770.18 mg/g,亚甲基蓝值为64.24 mg/g。随着预处理时间的增加,活性炭的强度和产率都增大。试验结果对煤基球形活性炭的生产具有一定的指导意义。 相似文献
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Mechanical behavior of two-dimensional carbon/carbon composites with interfacial carbon layers 总被引:1,自引:0,他引:1
Effect of interfacial carbon layers on the mechanical properties and fracture behavior of two-dimensional carbon fiber fabrics reinforced carbon matrix composites were investigated. Phenolic resin reinforced with two-dimensional plain woven carbon fiber fabrics was used as starting materials for carbon/carbon composites and was prepared using vacuum bag hot pressing technique. In order to study the effect of interfacial bonding, a carbon layer was applied to the carbon fabrics in advance. The carbon layers were prepared using petroleum pitch with different concentrations as precursors. The experimental results indicate that the carbon/carbon composites with interfacial carbon layers possess higher fracture energy than that without carbon layers after carbonization at 1000°C. For a pitch concentration of 0.15 g/ml, the carbon/carbon composites have both higher flexural strength and fracture energy than composites without carbon layers. Both flexural strength and fracture energy increased for composites with and without carbon layers after graphitization. The amount of increase in fracture energy was more significant for composites with interfacial carbon layers. Results indicate that a suitable pitch concentration should be used in order to tailor the mechanical behavior of carbon/carbon composites with interfacial carbon layers. 相似文献
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结构炭/炭复合材料力学性能及微观结构研究 总被引:13,自引:1,他引:13
采用四向编织、快速化学气相渗透致密化新工艺制备了炭/炭复合材料,其弯曲强度达320MPa。分析研究了这种材料的力学性能特征。利用SEM和高分辨TEM分析了基体炭、炭纤维/基体灰界面的精细结构,发现炭纤维呈单根被基体炭包围,基体现灰呈层片状,为二维有序的乱层石墨结构;在炭纤维与基体炭之间存在着过渡相,这一过渡相厚度的约几十纳米,随着与炭纤维之间距离的增大,它们之间形成的夹角由小变大,这一过渡相即为炭 相似文献
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The catalytic behaviour of potassium carbonate doped onto active carbon was investigated with respect to reduction of carbon dioxide. The distribution of potassium on the carbon surface was found by an X-ray microanalyzer to be uniform. The amount of oxygen trapped on the carbon surface during reaction was nearly proportional to the surface concentration of potassium. The catalytic activity with carbon doped with less than 2% potassium carbonate was proportional to the amount of trapped oxygen, while excessive doping by potassium was found to form trapped oxygen independently of the gasification of carbon. Disproportionation of carbon monoxide into carbon dioxide and carbon was found to take place readily at 700 °C, with carbon doped with 4.0 wt % potassium carbonate. 相似文献
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Yong Deng Ran Liu Kexin Jiao Yanbo Chen 《Journal of the European Ceramic Society》2021,41(11):5740-5749
Wetting behavior between hot metal and carbon brick is the first step to explore the erosion of carbon brick. In order to investigate the wetting behavior, wetting experiments between hot metal (with carbon content 2.87, 3.47, 4.12, 4.51, and 4.96 mass%) and carbon brick were carried out. The wetting angle under different conditions was measured, the reaction interface morphology and carbon structure were analyzed, the mechanism of hot metal wetting carbon brick was clarified based on interfacial energy and scaling law. The results show that: The wetting angle decreased gradually with the increase of wetting time for all initial carbon content experiments, the wetting angle increased with the increase of initial carbon content in hot metal. The dissolution of carbon occurred during the wetting process, which left a concave on carbon brick. The graphitization degree of carbon in carbon brick increased after the wetting behavior. In the initial stage of the wetting reaction, the change of interfacial energy caused by carbon dissolution reaction was the essential reason for the change of wetting angle. In the final stage of the wetting reaction, the wetting angle mainly depended on the concave shape after the concave was formed. The wetting model was established to explore the wetting behavior with dissolution reaction, the scaling relationship between the spreading radius of iron drop and time was obtained, which was convenient to evaluate the wetting behavior between hot metal and carbon brick. 相似文献
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以石墨片微元构建的多孔碳材料作为活性炭的结构模型,采用巨正则蒙特卡罗方法(GCMC)和分子动力学方法(MD),从分子层面研究甲烷和甲苯在活性炭中的吸附和扩散特性. 结果表明,石墨片微元大小对多孔碳材料吸附甲烷和甲苯有一定影响,37个碳环构成的多孔碳材料是最佳的吸附结构;甲烷气体在活性炭材料中扩散较快,甲苯在活性炭中扩散较慢,随碳环碳原子数增加,气体在多孔碳材料中的自扩散系数逐渐增大;引入基团会使最优密度向高密度方向偏移,用不同基团表面改性的吸附量顺序为羟基>氨基>羧基>未改性,基团引入会改善材料的孔结构,有利于吸附量的增加. 相似文献