渗氮—气相沉积硬质膜复合处理技术及其发展

阐述了渗氮－气相沉积硬质膜复合处理的设计思想。从渗氮－气相沉积硬质膜复合处理工艺方法的选择、复合处理层组织结构、性能研究等方面介绍了渗氮－气相沉积硬质膜复合处理技术的发展。     

钢的冲蚀磨损与机械性能的关系及其磨损机理的研究

本文研究了以棕刚玉及玻璃砂为磨粒的钢的冲蚀磨损与机械性能的关系及其磨损机制。结果表明在硬磨粒冲击下,钢的冲蚀磨损受断裂韧性影响较大。而当磨粒硬度接近或低于钢的硬度时,冲蚀磨损由钢的硬度所决定。在硬磨粒冲击下,除了常见的薄片、切削、犁沟等塑性变形机制外,韧性较低的钢会出现开裂机制而造成块状磨屑脱落。软磨粒要依靠多次冲击才能使材料以小片磨屑脱落,而且最大冲蚀率发生在90°冲击角。玻璃砂冲击时,在30°、90°会出现两个冲蚀磨损峰,这是由于玻璃砂在大角度冲击时溅射而产生二次磨损的结果。     

离子氮化—PECVDTiN膜复合处理提高切边模具寿命研究

对用于制作冷作模具的两种高速钢W18Cr4V和W6Mo5Cr4V2Al进行离子渗氮-PECVDTiN复合处理,研究了复合处理层的组织与性能特点,结果表明：较之单一PECVD TiN,离子渗氮-PECVDTiN复合处理改善膜基界面结合,显著提高膜基结合强度与耐磨性;采用优化的复合处理可提高高速钢制不锈钢六角螺栓切边模使用寿命一倍以上。     

The Stress Distribution and Thermal Behavior of TiBN and TiBN／TiN Coatings in Milling AISI H13 Work Tool Steel

The FEM model of TiBN ant TiBNI TiN coated cutting tool in milling of H13 steel was developed. Process variables such as temprature and stress in the coating layer as well as in the substrate were analyzed. The efficacy of the present FEM analysis was verified by conducting controlled milling experiments on AISI H13 to collect the relevant tool life and force data. The results show that the stress in a coated tool can significantly be reduced compared to an uncoated cutting tool, possibly due to surface coatings improving the tribolagical properties of cutting tools. Coatings with good thermal properties also help to improve the thermal behavior of cutting tool.     

Cavitation erosion behavior of WC coatings on CrNiMo stainless steel by laser alloying

The WC powder was precoated on the surface of CrNiMo stainless steel and then made into an alloying layer by using the laser alloying technique.Phases in the layers were investigated by X-ray diffraction (XRD) analysis and surface morphologies after cavitation erosion were observed with the help of scanning electron microscopy (SEM).The cavitation erosion behavior of the CrNiMo stainless steel and WC laser alloying layer in distilled water was tested with the help of ultrasonic vibration cavitation ero-sion equipment.The results showed that the thickness of the laser alloying layer was about 0.13 mm.The layer had a dense micro-structure, metallurgically bonded to the substrate, and no crack had been found.The cavitation erosion mass loss rate of the laser al-loying layer was only 2/5 that of the CrNiMo stainless steel.The layer had better cavitation resistance properties because of its met-allurgical combination and the strengthening effects of the precipitate phases.     

Characterization and wear behavior of WC-0.8Co coating on cast steel rolls by electro-spark deposition

To prepare high wear resistance and high hardness coatings, electro-spark deposition was adopted for depositing an elec trode of a mixture of 92wt%WC+8wt%Co on a cast steel roll substrate. The coating was characterized by classical X-ray diffracto meter (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX). The results indicate that the coating shows nanosized particulate structure and dendritic structure including columnar structure and equiaxed structure. The pri mary phases of the coating contain Fe_3W_3C, Co_3W_3C, Fe_2C and Si_2W. The coating has a low friction coefficient of 0.13, its average wear-resistance is 3.3 times that of the cast steel roll substrate and the main mechanism is abrasive wear. The maximum microhard ness value of the coating is about 1573.9 Hv_(0.3) The study reveals that the electro-spark deposition process has the characteristic of better coating quality and the coating has higher wear resistance and hardness.     

刀具表面涂层技术的研究进展

通过对刀具表面进行涂层处理,可以显著提高刀具的表面硬度和耐磨性,延长刀具的使用寿命.目前刀具涂层制备方法主要包括化学热处理、热喷涂法、溶胶-凝胶法、气相沉积法等.涂层刀具的发展呈现涂层成分多元化、涂层结构多层化、涂层基体梯度化和涂层工艺灵活化的趋势,涂层刀具后处理技术包括热处理、磁化处理及深冷处理等.随着技术的进步,更多更新型的刀具表面涂层技术必将会出现.     

2738模具钢表面激光熔覆Ni基WC复合涂层的摩擦磨损性能

在2738模具钢表面通过CO2激光熔覆制备Ni基WC复合涂层。分别对2738钢基体和Ni-WC激光熔覆层进行干摩擦试验。用三维表面形貌仪测量磨损体积,用扫描电镜观察磨痕的表面形貌。试验结果表明,Ni-WC复合涂层试样的硬度显著提高,表面硬度超过1200HV,保证了Ni-WC熔覆层的耐磨性。熔覆层的平均摩擦因数约为0.24,与2738钢基体的摩擦因数0.43相比,降低了约44%。熔覆试样的比磨损率比基体试样的比磨损率下降了96.7%,WC硬质相提高了摩擦副表面的承载能力。磨粒磨损为Ni-WC复合涂层的主要磨损机理。     

The corrosion behavior of nano-meter embedded phase in Ti implanted H13 steel

On the SEM micrographs of Ti implanted H13 steel, a tree-branch-like structure can be observed. Further investigation with TEM shows that the newly tormed composition is a formation of nann-meter FeTi_2 phase in Ti implanted layer. The layer with a relatively high corrosion resistance has been formed in Ti implanted H13 steel with this structure.The results of electrochemical measurement show that the corrosion current density decreases obviously with an increase of ion dose. The corrosion current density in Ti implanted steel with a dose of 1.3×10~(18)/cm~2 is 8-20 times less than that of Ti implanted steel with a dose of 6×10~(17)/cm~2. The corrosion behavior of Ti implanted steel with a dose of 6×10~(17)/cm~2 could be further improved as the sample was annealed at 500℃ for 20 min and the corrosion current density decreases by 48-80 times compared to that of non-implanted samples. The corrosion trace was not observed on the annealing sample by SEM, after multi-sweep cyclic voltammetry of 40 cycles     

基片预处理对CVD金刚石薄膜形核的影响

微波辅助等离子体化学气相沉积法是目前低压气相合成金刚石薄膜方法中应用最普遍、工艺最成熟的方法,形核是CVD金刚石沉积的第一步．利用微波辅助等离子体化学气相沉积装置,研究了硅基片预处理方式对金刚石薄膜形核密度的影响．在工作气压为5-8kPa,微波功率为2500—5000W,甲烷流量为4-8cm^3／min,氢气流量为200em3／min,沉积温度为500℃-850℃的条件下,在单晶Si基片上沉积金刚石薄膜．通过扫描电子显微镜形貌观察表明,基片预处理能够显著提高金刚石形核密度,同时用拉曼光谱表征了金刚石薄膜的质量,