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利用废聚苯乙烯泡沫塑料制备改性乳液型胶粘剂 总被引:4,自引:1,他引:3
废聚苯乙烯泡沫塑料经洗净、干燥、粉碎、溶解、改性、乳化等步骤制备一种性能优异的木材纸张胶粘剂.对原料的用量、低毒性混合剂的选择和配比、改性剂的选择、乳化剂的选择、反应温度和反应时间的选择进行了优化试验.以乙酸乙酯、甲苯、丙酮为溶剂其最佳配比为:m(乙酸乙酯):m(甲苯):m(丙酮)=3:2:0.5.采用顺酐、丙烯酸对废聚苯乙烯进行改性试验.对酚醛树脂改性和邻苯而甲酸二丁酯增塑对其粘接性能的影响进行了探讨,确定酚醛树脂的最佳用量为3.0%~4.0%,邻苯二甲酸二丁酯的用量为8%~10%.用阴离子表面活性剂十二烷基硫酸钠和非离子表面活性剂OP-10作为乳化剂对废聚苯乙烯进行乳化改性.改性温度为(80±2)℃,反应时间为3~4h;乳化温度为70℃,反应时间为1~2h. 相似文献
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宋凯杰万红敬 《高分子材料科学与工程》2018,(5):170-176
以丙烯酸(AA)为改性剂,采用无皂乳液聚合的方法将其聚合接枝于聚苯乙烯(PS)微粒表面。使用红外光谱仪、热分析仪分析了其物性结构,使用扫描电子显微镜观察了粒子直径及阵列,使用接触角测量仪对比测试了PS粒子改性前后的接触角,分析了表面接枝基团对粒子亲水性能的影响。结果表明,改性后的PS粒子平均粒径为250 nm,表面富含羧基,亲水性得以改善。通过高能球磨法将合成的羧基化PS粒子分散在聚乙二醇200中,得到一种有机高分子体系的剪切增稠液(STF),分别采用动态流变仪和扩散波谱仪对其机械流变性能和微流变性能进行了测试,二者所测数据均表明流体具有显著的剪切增稠特性。 相似文献
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以丙烯酸(AA)为改性剂,采用无皂乳液聚合的方法将其聚合接枝于聚苯乙烯(PS)微粒表面。使用红外光谱仪、热分析仪分析了其物性结构,使用扫描电子显微镜观察了粒子直径及阵列,使用接触角测量仪对比测试了PS粒子改性前后的接触角,分析了表面接枝基团对粒子亲水性能的影响。结果表明,改性后的PS粒子平均粒径为250 nm,表面富含羧基,亲水性得以改善。通过高能球磨法将合成的羧基化PS粒子分散在聚乙二醇200中,得到一种有机高分子体系的剪切增稠液(STF),分别采用动态流变仪和扩散波谱仪对其机械流变性能和微流变性能进行了测试,二者所测数据均表明流体具有显著的剪切增稠特性。 相似文献
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利用废聚苯乙烯泡沫塑料制备乳液型防水涂料 总被引:1,自引:0,他引:1
以废聚苯乙烯泡沫塑料为主要原料,甲苯、乙酸乙酯作为混合溶剂,用丙烯酸和丙烯酸丁酯对聚苯乙烯进行接枝改性,制备乳液型防水涂料.通过试验分别考察了混合溶剂的配比及用量、改性剂的选择、复合乳化剂的用量及增塑剂的用量对涂料性能的影响,并对涂料的质量进行了测试. 相似文献
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通过乳液接枝聚合技术合成不同聚丁二烯(PB)含量的聚丁二烯接枝聚苯乙烯(PB-g-PS)共聚物, 共混改性聚苯乙烯(PS), 使PB含量控制在20wt%。通过对接枝共聚物PB-g-PS接枝度的测定, 分析了不同接枝度对橡胶粒子分散状态以及橡胶粒子内部结构的影响, 考察了不同接枝度对改性聚苯乙烯力学性能的影响。通常认为橡胶粒子只有在1~3μm时才能对聚苯乙烯进行有效增韧, 然而实验结果表明, 使用粒径约为300nm的核壳橡胶粒子改性聚苯乙烯冲击韧性提高很大。此时, 接枝共聚物具有最佳核壳比PB/PS为70/30, 橡胶粒子呈均匀分散状态, 且最大冲击强度为124.9J/m, 相当于纯聚苯乙烯冲击强度的10倍。 相似文献
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纳米SiO2制备及改性 总被引:1,自引:0,他引:1
为了改善纳米SiO2的分散性,用溶胶-凝胶技术制备了纳米SiO2凝胶,并用不同改性剂对粉末进行了表面改性.采用透射电子显微镜(TEM)、X射线衍射(XRD)、粒度分析仪(PSA)、紫外-可见光分光光度计(UV-VS)等分析了纳米SiO2的粒径及分散性.结果表明,正硅酸乙酯的水解和缩合反应条件直接影响纳米SiO2粉体的粒径大小.KH-550硅烷偶联改性剂用量、改性时间等因素对改性效果有明显的影响.当改性剂用量为4.1%(质量分数),改性时间为2h时,可得到高分散性的纳米SiO2粉体.纳米SiO2粉末易发生团聚,只有对其进行表面改性,才能得到疏水性纳米SiO2粉末. 相似文献
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《International journal for numerical methods in engineering》2018,113(9):1488-1506
In this paper, we present a new method for inserting several triangulated surfaces into an existing tetrahedral mesh generated by the meccano method. The result is a conformal mesh where each inserted surface is approximated by a set of faces of the final tetrahedral mesh. First, the tetrahedral mesh is refined around the inserted surfaces to capture their geometric features. Second, each immersed surface is approximated by a set of faces from the tetrahedral mesh. Third, following a novel approach, the nodes of the approximated surfaces are mapped to the corresponding immersed surface. Fourth, we untangle and smooth the mesh by optimizing a regularized shape distortion measure for tetrahedral elements in which we move all the nodes of the mesh, restricting the movement of the edge and surface nodes along the corresponding entity they belong to. The refining process allows approximating the immersed surface for any initial meccano tetrahedral mesh. Moreover, the proposed projection method avoids computational expensive geometric projections. Finally, the applied simultaneous untangling and smoothing process delivers a high‐quality mesh and ensures that the immersed surfaces are interpolated. Several examples are presented to assess the properties of the proposed method. 相似文献
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Standards are the basis for production enterprises to organize production ex-factory inspection trade 《中国标准化(英文版)》2008,25(1):24-25
Standards are the basis for production enterprises to organize production, ex-factory inspection, trade (delivery) and technical exchanges, product certification, quality arbitration and supervision.…… 相似文献
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A flow calorimeter for enthalpy increment measurements on condensed gases is presented. A better knowledge of the properties of the liquefied natural gas is needed, and therefore a liquid loop has been designed for our flow calorimeter. The fluid loop in the calorimeter is designed in order to avoid the two-phase region, since two phases would give compositional disturbances in the measurements. The avoidance of the two-phase region is made possible by increasing the pressure of the test fluid after the measurement section, then heating the fluid at super-critical pressure past the critical point. Finally, the fluid is throttled to the low-pressure gas state at the inlet condition of the compressor that circulates the fluid. To perform the pressure increase, a new cryogenic pump has been designed. To evaluate the new equipment, measurements were taken on liquid ethane over the temperature range 146–256 K at pressure between 0.9 and 5.1 MPa. 相似文献
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Steffen Müller-Probandt 《材料科学与工程:中英文B版...》2018,(4):161-177
We associate a variety of innovations with the term "Industry 4.0". The pioneer of many 4.0 modifications forms the basisfor the trend towards the integrated di... 相似文献
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On November 30, 2007, the China Association for Standardization (CAS) held a press conference at Beijing Diaoyutai State Guest House. Leaders from the China Household Electric Appliance Research Institute, the China Household Electric Appliance Association, and the China Consumers' Association attended and made speeches.…… 相似文献
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Zusammenfassung Bei der Gestaltung von Ernteprozessen — beispielsweise des Prozesses Mähdrusch, Körnertransport und -abnahme — als transportverbundene Fließarbeitsverfahren mit mindestens zwei verschiedenen Arbeitsmitteln gibt es einen großen Optimierungsspielraum. Solche Prozesse sind mehrstufige Bedienungsprozesse mit gemischter Anordnung der Bedienungseinrichtungen. Außerdem besitzen sie stark ausgeprägte räumliche Aspekte. Es wird vor allem gezeigt, welche Merkmale solcher Prozesse in Simulationsmodellen abgebildet sein müssen, welche Zielgrößen in Abhängigkeit von welchen Einflußgrößen unter Berücksichtigung welcher Prozeßbedingungen ermittelt werden sollten und wie der Bewertungsprozeß zur Ermittlung der gewünschten Informationen gestaltet werden muß. 相似文献
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Janet Lang 《Materials and Manufacturing Processes》2017,32(7-8):857-866
ABSTRACTThe production of ferrous metal increased during the Roman Late Republican period, Principate and Empire. The direct bloomery process was used to extract the metal from its ores using slag-tapping and slag-pit furnaces. The fuel was charcoal and an air blast was introduced by bellows-operated tuyères. Iron formed as a bloom, often as a spongy mass of metal, which contained impurities from the smelting process, including unreacted ore, fuel, slag and fragments from the furnace walls, while the metal was often inhomogeneous with varied carbon contents. Blooms were either smithed directly into bars or ingots or they were broken up, which also allowed the removal of gross impurities and a selection of pieces with similar properties to be made. These could then be forge-welded together and formed into characteristically shaped ingots. Making steel in the furnace seems to have been achieved: it depended on the ore and the furnace and conditions within it. Surface carburization was also carried out. Iron and steel were used extensively in construction and for tools and weapons. Fire welding was often used to add pieces of steel to make the edges of tools and weapons, which could be heat-treated by quenching to harden them. 相似文献
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C. Qihong W. Zhan‐Wen J. Yi J. Yehua L. Fei F. Hanguang 《Materialwissenschaft und Werkstofftechnik》2014,45(7):582-590
In the present study a high‐boron high speed steel (HSS) roll material was designed. Many expensive alloy elements have been substituted by cheap boron alloy, and high‐boron high speed steel roll has been manufactured by centrifugal casting method. The microstructures, mechanical properties and wear resistance of centrifugal casting high‐boron high speed steel roll have been investigated by optical microscopy (OM), scanning electron microscopy (SEM), and X‐ray diffraction (XRD) analysis, hardness test, impact test and wear test. The results indicated that the solidification microstructures of high‐boron high speed steel roll consisted of M2(B,C), (W,Mo)2(B,C), M3(B,C), M23(B,C)6 type borocarbides and martensite, a small amount of retained austenite. Borocarbides were continuously distributed over the grain boundary. After quenching from 1050 °C, local broken network appeared in partial borocarbides, and fine secondary borocarbide precipitated from the matrix. After tempering from 525 °C, the amount of precipitated borocarbide increased significantly. After heat treatment, the hardness of high‐boron high speed steel roll excelled 60 HRC, and its impact toughness excelled 8.0 J/cm2. The single groove steel rolling amount of high‐boron high speed steel rolls increases by 500% than that of bainite cast iron roll, when the rolls are used in K1 mill housing of bar mill. 相似文献
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《中国标准化(英文版)》2014,(4)
正Responding to ISO’s appeal for survey for the to-be-developed ISO Strategy Plan for 2016-2020,SAC hosted a special workshop over the needs and comments of various fi elds on June 8 in Beijing.The workshop was attended by ISO President-elect and Ansteel General Manager Zhang Xiaogang,SAC Vice-Administrator Yu Xinli,and 30 experts from 相似文献