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MMA/纳米TiO_2改性白乳胶的研制 总被引:1,自引:1,他引:0
为提高白乳胶的粘接性能和耐水性,采用硅烷偶联剂(KH-570)和甲基丙烯酸甲酯(MMA)对纳米TiO2(nano-TiO2)进行改性;以MMA和改性nano-TiO2为白乳胶的改性剂,比较了不同改性方法对改性白乳胶的固含量、黏度、硬度、粘接强度和耐水性等影响。结果表明:各种改性方法制成的适量改性nano-TiO2,均能改善白乳胶的相关性能;当m(MMA)∶m(等质量的MMA和KH-570共同改性nano-TiO2)∶m(过硫酸钾)=4∶2∶0.1时,改性白乳胶的黏度(15.72 Pa.s)、硬度(2H)、粘接强度(9.6 MPa)和耐水性(20、80℃水中的开胶时间分别为57、39 h)均达到最大值。 相似文献
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综述了Al2O3包覆LiNi(1/3)Co(1/3)Mn(1/3)O2锂离子电池正极材料的研究现状与进展,并评述了其制备方法和包覆改性;讨论了包覆改善该正极材料性能的机理;提出了这种正极材料的研发过程中的一些问题并对其未来的发展前景作了展望。 相似文献
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使用以氧化丙烯甲基铝改性的Nd(OCOR)3-AlH(iso-C4H9)2-C6H4(CCl3)2催化体系聚合丁二烯。研究了聚合的动力学参数及聚丁二烯的分子特性。此种改性催化体系具有高活性,由此合成的聚丁二烯橡胶硫化胶的力学性能可满足工业上的需要。。 相似文献
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尿素作为沉淀剂,采用均相沉淀技术制备了Ni2+-Fe3+-CO2-3-LDHs层状材料.以Ni2+-Fe3+-CO2-3-LDHs作为前驱体,分别与NaCl、十二烷基磺酸钠(CH3(CH2)11SO3Na)进行离子交换反应得到Ni2+-Fe3+-CH3(CH2)11SO-3-LDHs新型吸附剂材料,成功实现了将CH3(CH2)11SO-3负载到Ni2+-Fe3+-LDHs层状材料,对Ni2+-Fe3+-CO2-3-LDHs进行亲油改性,研究表明该改性后的材料为介孔材料,其比表面积为196.2m2/g,平均孔径为18.3nm.利用Ni2+-Fe3+-CH3(CH2)11SO-3-LDHs复合材料对含油污水进行处理,实验表明十二烷基磺酸根离子插层Ni2+-Fe3+-LDHs后的产物增强了LDHs的亲油吸附性能,其饱和吸附量为6.57μL/g. 相似文献
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研究了不同表面改性对活性炭吸附废水中Cr(Ⅵ)的影响,将活性炭AC0在2 mol.L-1的HNO3、HCl、H2O2溶液中静置12 h并经过马弗炉煅烧后制得改性活性炭AC1、AC2、AC3。分别考察溶液的pH、吸附时间、温度对废水中Cr(Ⅵ)离子去除率的影响,采用滴定法定量检测活性炭表面的离子交换容量。结果表明:活性炭经过HNO3、HCl改性后,其Cr(Ⅵ)的吸附容量和吸附速度均显著改变,AC1、AC2阳离子交换容量分别为2.21、1.66 mmol.g-1,是AC0的1.7倍、1.28倍。活性炭对Cr(Ⅵ)离子的去除率强烈地依赖于溶液的pH,当溶液pH值控制在2.0~3.0时,Cr(Ⅵ)离子的去除率达到99%左右,随后骤然降低,但是AC1、AC2对Cr(Ⅵ)离子的去除率还能保持在一个较高的水准。 相似文献
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三聚氰胺甲醛树脂改性P(VAC-MMA)乳液的合成 总被引:3,自引:0,他引:3
本文报道了P(VAC-MMA)乳液及三聚氰胺甲醛树脂的合成及其共混。考察了乳液粘度、稳定性及其成膜耐水性等。结果表明,所得P(VAC-MMA)乳液的耐水性、防冻性及PH值适应范围较PVAC均聚物乳液均有所改善。而乳液中三聚氰胺树脂的加入可明显增稠,其成膜耐水性较传统乳白胶有明显改善。 相似文献
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An organic/inorganic hybrid nanocomposite membrane, poly(vinyl alcohol)/clay (PVAC), was prepared. The morphology of PVAC nanocomposite membranes were characterized using transmission electron microscopy (TEM), X‐ray diffraction (XRD), and atomic force microscopy (AFM). The crystallinity and surface roughness increases with an increasing clay content in the PVAC nanocomposite membrane. Compared with the pure poly(vinyl alcohol) (PVA) membrane, the hybrid nanocomposite membrane (PVAC) shows an improvement in the thermal stability and the prevention of the water‐soluble property. The oxygen permeability and the water‐vapor permeation rate decreases with an increasing clay content (1–3 wt %) in the PVAC nanocomposite membranes. In addition, the effects of the clay content on the vapor‐permeation performance of an aqueous ethanol solution through the PVAC nanocomposite membranes was also investigated. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 3632–3638, 2003 相似文献
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聚合物乳液改性含钛高炉渣免烧砖 总被引:2,自引:0,他引:2
用聚苯乙烯乳液、聚乙酸乙烯酯乳液和苯丙乳液等改性含钛高炉渣浆分别得到免烧免蒸砖试样. 考察了影响试样性能的主要因素和改性机理. 结果表明,聚乙酸乙烯酯乳液改性渣浆试样性能较好,苯丙乳液改性效果最好. 当含钛高炉渣为72%(w,下同)、苯丙乳液为10%、添加剂为18%、成型压力为30 MPa、养护时间为7 d时,渣浆试样的抗压强度和抗折强度分别达到37.7和13.9 MPa. 机理探索表明,苯丙乳液中酸根离子与渣浆中金属离子交联生成了金属络合物. 相似文献
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IR laser-induced modification of poly(vinyl acetate) (PVAC) was examined through ablative and non-ablative thermal processing of bulk PVAC. Both laser-induced processes differ remarkably from conventional heating of PVAC, which yields acetic acid and non-polar carbonaceous residue. The non-ablative treatment at low-fluence irradiations results in the formation of volatile vinyl acetate and acetone and leaves the remaining irradiated polymer having an almost identical structure. The ablative treatment at high-fluence irradiations yields a multitude of volatile compounds (methane, ethane, vinyl acetate, acetone, acetic acid, benzene, H2, CO and CO2) and affords deposition of thin polymeric films that contain reactive conjugated CC bonds and half of the initially present acetate groups. Residual reactivity of the CC bonds leads to polymer crosslinking, substantial decrease in solubility and some increase in thermal stability. The low fluence-induced decomposition stands for the first example of the thermal decomposition of polyvinyls into the monomer and the high-fluence ablative deposition represents a one-step approach to crosslinked (intractable), thermally stable and polar polymeric films from linear-chain polymers with pending functional groups. 相似文献
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Jihui Li Yongshen Li Shuai Niu Jie Liu Lizhen Wang 《Journal of Porous Materials》2017,24(6):1595-1604
In this article, the low toxicity of polyvinyl alcohol (PVA) and dimethyl carbonate (DMC) were used to synthesize polyvinyl alcohol carbonate (PVAC) sponge via a simple transesterification-foaming approach, and the structure and morphology of PVAC sponge were characterized; moreover, the influence of dosage of K2CO3, PVA, distilled water and n-pentane on the water retention capacity of PVAC sponge were investigated, and the influence of reaction temperature and reaction time on the water retention capacity of PVAC sponge were also surveyed. Based on those, it was confirmed that 9.00 g PVA and 5.00 mL DMC in the presence of 2.00 g K2CO3 and 50.00 mL water could be used to synthesize PVAC polymer at 75?°C and for 2.5 h via the transesterification approach, and PVAC polymer in the presence of 5.00 mL n-pentane could be used to synthesize PVAC sponge at 55?°C and for 10 h via the foaming approach, and PVAC sponge owned the structure of six-membered lactone ring and the polyporous morphology, and the maximal water retention capacity was 21.50 g/g. 相似文献
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用SO24-物质的量相同的H2SO4和Al2(SO4)3分别对Al-MCM-41进行改性,得到样品SO42-/Al-MCM-41和Al/SO24-/Al-MCM-41。采用X射线多晶衍射(XRD)、红外光谱(FTIR)、N2吸附-脱附和NH3程序升温脱附(NH3-TPD)等测试技术对样品进行表征。分别用H2SO4、MCM-41、Al-MCM-41、SO42-/Al-MCM-41和Al/SO24-/Al-MCM-41催化合成丙酸香叶酯,比较了它们的催化性能。结果表明,H2SO4和Al2(SO4)3改性对Al-MCM-41中孔分子筛结构影响不明显,都可提高其酸性,改性后中孔分子筛的骨架仍保持着六方介孔结构,孔径、孔容和比表面积有所降低,但用Al2(SO4)3改性的分子筛酸性和催化性能更强;SO42-/Al-MCM-41的酸催化活性主要源于SO42-与分子筛表面硅羟基作用形成的双齿螯合配位结构,而Al/SO42-/Al-MCM-41的酸催化活性一方面来自SO24-与分子筛表面硅羟基作用形成的双齿螯合配位结构,另一方面,也来自与分子筛骨架接枝的铝,使其产生了更多的Brnsted酸中心。 相似文献
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A. Ali Fathima Sabirneeza S. Subhashini 《Journal of Adhesion Science and Technology》2013,27(12):1268-1294
Parametric optimization for better synergism between polyvinyl alcohol (PVA) and l-cysteine was optimized using Taguchi design, a statistical approach. The corrosion inhibition property of poly(vinyl alcohol-cysteine) (PVAC) on mild steel corrosion was continuously monitored using electrochemical techniques such as polarization and impedance methods. Continuous monitoring of the system reveals the formation of stable film on the metal surface. Temperature effect on the inhibition properties of PVAC was studied using electrochemical measurements. Calculated kinetic and thermodynamic parameters supported the spontaneous adsorption of PVAC. Atomic force microscopic and laser profiler analysis confirmed the adsorption of PVAC on mild steel surface. Theoretical calculations using Hyperchem 7.0 proved the better corrosion mitigation properties of PVAC compared to PVA. 相似文献
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3-异烷氧基噻吩的合成 总被引:2,自引:0,他引:2
以CuB r为催化剂,NMP为溶剂,在110℃下,3-溴噻吩与过量的甲醇钠反应2.5 h生成3-甲氧基噻吩,产率为82%。再以无水NaHSO4为催化剂,在108~115℃下,3-甲氧基噻吩分别与异丁醇、异戊醇、异辛醇发生取代反应合成了3-(2-甲基丙氧基)噻吩、3-(3-甲基丁氧基)噻吩、3-(2-乙基己氧基)噻吩,反应时间分别为:3、3.5、4h,收率分别为72%、67%、63%。这些化合物结构都通过IR、1HNMR和MS进行了表征,并对其进行了初步香味评价,结果表明,它们都具有基本肉香味的特征。 相似文献
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The poly(vinyl acetate) (PVAC) film was obtained by electropolymerization on the copper electrode using cyclic voltammetry performed in mixed electrolyte based on water/ethyl alcohol/acetic acid containing vinyl acetate (VAc) and benzoyl peroxide as polymerization initiator. The coatings were characterized by optical microscopy, scanning electron microscopy (SEM) and infrared (IR) spectroscopy. The corrosion was induced in hydrochloric acid solution using potentiodynamic measurements and electrochemical impedance spectroscopy (EIS). The microscopic and SEM images revealed the PVAC coating formation and IR spectroscopy confirmed that it exhibits the same characteristic bands as a standard PVAC sample. From the potentiodynamic polarization, the PVAC protective performance of 78% was computed. The EIS measurements showed the occurrence of the surface adsorbed layer with a higher impedance response to the frequency and a phase angle maximum shifted to lower values than those of uncoated samples. In addition, the VAc electropolymerization mechanism was discussed and the PVAC adsorption mechanism on the copper surface was proposed. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47320. 相似文献