激光熔敷合金层组织和腐蚀磨损特性的研究

研究了在４５钢表面进行激光熔敷镍基合金，镍基Ｃｒ２Ｏ３合金和镍基ＷＣ合金的熔敷层的组织结构、耐蚀性及不同冲击速度和不同浓度的腐蚀介质下的腐蚀磨损特性。结果表明，激光熔敷合金层不论耐性还是抗腐蚀磨损性能都优于不锈钢，产根据组织分析，显微硬度测试及腐蚀磨损后的表面形貌观察，探讨了熔敷合金层的腐蚀磨损过程。     

CeO2对激光熔敷合金层组织和腐蚀磨损性能的影响

用Ｘ射线衍射仪、ＳＥＭ、ＴＥＭ和电子控针研究了稀土氧化物ＣｅＯ２对Ｎｉ６０－ＷＣ激光熔敷层的相结构、显微组织以及腐蚀磨损性能的影响,试验结果表明Ｎｉ６０＋２０％ＷＣ＋０．５％ＣｅＯ２熔敷层的抗腐蚀磨损性能最好。     

激光熔敷合金层的组织结构和凝固过程

运用ＳＥＭ，Ｘ射线衍射仪，ＴＥＭ等先进设备，对不同成分合金激光熔敷层到基体显微组织形貌的连续变化，熔敷层的相结构，取向关系和微观缺陷进行了深入系统的研究，根据试验结果和凝固理论，探讨了激光熔敷层的凝固过程，研究结果可以作为激光熔敷技术深入研究和发展的参考。     

激光熔覆IMC涂层的热疲劳性能

研究了激光熔覆和Ｎｉ－Ａｌ合金涂层及（Ｎｉ－Ａｌ）＋ＷＣ复合涂层的热疲劳性能。结果表明，涂层疲劳损伤形式为沿晶应力（氧化）腐蚀。腐蚀产物为Ａｌ２Ｏ３。每次热循环后，熔覆层中的最终残余应力是残余热应力和相变应力共同作用的结果。由于复合涂层中的残余应力为压应力，而合金涂层中的残余应力为拉应力，因此前热疲劳性能优于后者。     

高端液压支架用激光熔覆Fe基粉末设计与性能研究

为了实现在液压支架表面有效控制材料、工艺成本的基础之上制备出高性能激光熔覆层，满足现代化采煤对高端液压支架的需求，设计并制备了三种高端液压支架用激光熔覆Fe基粉末，通过金相观察、硬度实验、磨损实验、盐雾腐蚀实验对粉末的激光熔覆层性能展开研究。研究得出：设计的三种粉末经激光熔覆后熔覆层组织致密，耐磨性、耐蚀性相比基材有了不同程度的提升，均为基材的2倍以上，应用前景广阔。     

采用激光熔敷Ni—WC技术修复破碎辊的工艺研究

熔敷Ni—WC技术采用自重送粉法，在ZG35CrMo基体表面用圆光斑激光熔敷Ni—WC复合涂层，其过程中要严格控制激光功率、扫描速度、送粉量、光斑进给量及基材的温度。这种方法可有效地减少表面裂纹、气孔，并能降低基体材料对熔敷材料的稀释，有效地提高熔敷层的硬度和耐磨性，延长破碎辊的使用寿命。     

NiCrBSiC合金大面积激光熔覆层性能研究

采用CO2激光器及LASERCELL-1005六轴六联动三维激光加工机床在40Cr钢上进行激光熔覆处理。利用扫描电镜、X射线衍射仪、显微硬度计、电化学测试系统、磨料磨损试验机等设备对熔覆层组织、硬度、磨损、腐蚀性能进行研究。结果表明:大面积激光熔覆层主要由Cr23C6,Ni3B,(Fe,Ni),Ni等相组成。激光熔覆层的显微硬度值在420~1 320 HK之间。熔覆层的硬度、耐磨性和耐蚀性与基体相比均有较大的提高;大面积激光熔覆层的显微硬度、耐磨性、耐蚀性均不及单道激光熔覆层;多层叠加熔覆层的耐蚀性能优于     

45 钢表面激光熔覆铁基合金粉末研究

针对 45 钢基材设计了 Fe55 激光熔覆合金粉末, 并进行了工艺验证, 获得了高硬度、 表面无裂纹的激光熔 覆层。 利用金相显微镜、 显微硬度计、 摩擦磨损试验、 中性盐雾试验研究了熔覆层的组织、 结构、 磨损和耐腐蚀 性能。 结果表明： 熔覆层硬度可达 HV1640, 与基体的结合为冶金结合, 显微组织为树枝状等轴晶, 耐磨性和耐 腐蚀性能优异。     

提高板坯连铸机结晶器铜板寿命

连铸机结晶器铜板损坏的主要形式及原因：（１）弯月面处（高温钢液引起）的热裂纹;（２）调节结晶器宽度时造成的擦伤;（３）表面镀层磨损后露出铜板基体;（４）结晶器下部铜板的机械磨损及腐蚀。提高结晶器铜板寿命的措施：（１）改变表面处理材质。ＮｉＣｏ合金镀层的导热系数（６８．９Ｗ／ｍ·ｋ）比原来采用ＦｅＮｉ镀层（６２．７Ｗ／ｍ·ｋ）高,抗剪切强度更好,而熔蚀则仅有１／２;ＮｉＣｒ合金喷镀层硬度（ＨＶ＝６００）比ＦｅＮｉ合金（ＨＶ＝５００）高,热胀系数更小,熔蚀则为１／３以下。因此,结晶器宽边铜板…     

Co－Cr_3C_2合金与WC润湿性的观察和分析

采用实况采相观察了Ｃｏ－Ｃｒ３Ｃ２合金与ＷＣ的润湿现象，采用ＪＣＸＡ－７３３型电子探针显微分析仪和３０１４型Ｘ射线衍射仪研究了Ｃｏ－Ｃｒ３Ｃ２合金熔渗ＷＣ所形成的组织，为ＷＣ－Ｃｏ合金中添加Ｃｒ３Ｃ２的作用机理提供解释依据。     

高锰钢表面激光熔覆Fe-WC复合涂层的组织与性能

采用激光熔覆技术在高锰钢基体上制备了不同WC含量的Fe-WC复合熔覆层,研究了WC添加量对熔覆层组织和性能的影响.试验结果表明,不同WC含量的Fe-WC熔覆层均含有马氏体、M7C3碳化物和未熔WC颗粒,当加入20wt.％的WC时,熔覆层中出现了残余奥氏体,共晶碳化物呈鱼骨状沿晶界析出.Fe-WC熔覆层的硬度和耐磨性随着...     

“双层金属布”硬质涂层耐磨性能的研究

对复合在钢基体上的WC-Ni-Fe-Co系“双层金属布”硬质涂层的相对耐磨系数ε进行了测定,对比耐磨件是HRC60的高速钢,实验采用磨粒磨损和摩擦磨损,实验结果表明WC-Ni-Fe-Co系“双层金属布”涂层耐磨性明显优于高速钢（HRC60）,涂层耐磨性主要与WC相含量有关。     

TC4钛合金表面激光熔覆Ni包WC复合涂层研究

为了提高钛合金的耐磨性能及使用性能,采用激光熔覆法在TC4钛合金基体上制备了Ni与WC混合粉末涂层,研究了不同WC添加量对熔覆层的物相组成、显微组织、硬度及耐磨性能的影响。结果表明,三组不同的熔覆材料经过激光熔覆后,都可以使材料表面硬度和耐磨性能较基材大幅度增加。但是随着WC含量的增加,熔覆层均匀性降低,出现小颗粒的WC团,并且组织开始多样化,且硬度分布均匀性也有所下降。     

Effect of Laser Power on Microstructure and Wear Resistance of WCP/Ni Cermet Coating

Laser cladding nickel-based alloy coating （Ni60） and nickel-based composite coating doped with WC particles by 35 % （WCp/Ni） were produced on the low-carbon steel substrate by CO2 continuous wave laser with power of 5 kW using the injected powder technique. The effect of laser power on microstructure and wear resistance of laser cladding WCp/Ni cermet coating was investigated. The WCp/Ni alloy coating with evenly distributed WC ceramic phases and the better bond with the substrate alloy was obtained at a power of 2.2 kW. Diffusion solution reaction happened between WC particles and the substrate alloy during laser cladding, and led to the formation of block rich-tungsten carbide on the edges of the WC particles, especially at higher power. The WCp/Ni alloy coating consists of the undissolved WC particles, the block or dendritic rich-tungsten carbide, the bar-like rich-chromium carbide, and dendrite solid solution and eutectic structure among the carbides. Microhardness and wear resistance of the WCp/Ni coating at different powers were much higher or better than those of Ni60 alloy coating, and the best results were obtained at power of 2.2 kW.     

Electric-spark hardening of VT3-1 titanium alloy with tungsten-free composite ceramics

The mass transfer and wear resistance of both monolayer and multilayer coatings on VT3-1 alloy are examined. The coatings are deposited by electrospark alloying (ESA) with composite titanium and zirconium refractory ceramics. It is shown that the wear resistance of these electrospark-deposited coatings is 1.6 to 3 times higher in fretting corrosion in unlubricated friction as compared with the conventional WC + 3% Co coating. In addition, the multilayer structure permits four-to fivefold increase in the coating thickness as opposed to the monolayer WC + 3% Co ESA coating.     

激光熔覆WC/Ni60B复合涂层在水润滑滑动摩擦环境下的磨损特性

采用激光熔覆技术制备了Ni60B镍基合金涂层以及微米WC、纳米WC和微-纳米WC颗粒增强的Ni60B基复合涂层（分别称为WCm、WCn和WCmn复合涂层）.对制备涂层在Amsler200磨损试验机上进行了不同载荷和滑动距离的水润滑滑动磨损试验.结果表明:WC颗粒的加入显著提高了Ni60B涂层的耐磨性.WCm复合涂层和纳米WCn复合涂层的耐磨性差别不大,但磨损形貌不同.涂层在水润滑环境下的磨损量均远远低于干滑动摩擦,其原因是水膜的支撑或隔离作用降低了涂层与磨轮之间的接触应力,水的冷却作用减少了摩擦热引起的温度升高,降低了涂层摩擦表面的温升和热软化.水润滑摩损条件下,WCm和WCn复合涂层中过饱和W元素发生扩散和聚集.      

激光熔覆涂层的浆体磨损特性及其应用研究

采用激光熔覆技术在４５钢试样表面获得镍基合金和ＷＣ颗粒增强的镍基合金复合材料涂层。研究了激光涂层工艺、熔覆层的组织结构和水平－煤－石英砂浆体的磨损特性,并将研究成果成功地应用于矿用渣浆泵平衡盘等零件。     

Laser Processing of Fe-Based Bulk Amorphous Alloy Coatings on Titanium

Laser Engineered Net Shaping (LENS?), a solid freeform fabrication technique, was employed for the processing of Fe-based bulk amorphous alloy (Fe BAA) powder on titanium. One and two layers of the Fe BAA were deposited with the same processing parameters. SEM and XRD analyses of the Fe BAA coatings revealed the retention of the feedstock powder’s amorphous nature. The mixing of the feedstock powder in the titanium substrate was very small. A crystalline-amorphous composite microstructure evolved from the laser processing in all types of coatings. The coatings were further laser remelted. The amorphous character was found to increase and the crystallites were found to grow during remelting. The Fe BAA coatings showed higher hardness and smaller wear volume compared to the Ti substrate. A further increase in these properties was observed after laser remelting treatment. During the wear testing in NaCl solution, Ti substrate showed intergranular corrosion, whereas the Fe BAA coatings showed signs of low and localized fretting corrosion in a saline environment. Our results demonstrate that using LENS?, amorphous coatings can be deposited on metallic substrates.     

电沉积Ni-W-WC复合镀层摩擦磨损性能

为了提高Ni-W合金镀层的硬度,改善其耐磨性,在镀层中添加WC颗粒作为硬质相,采用乙醇作为分散剂,利用超声波分散和机械搅拌相结合使WC颗粒均匀地分散于镀液中. 初步探究WC的添加量对镀层硬度及耐磨性能的影响. 结果表明:其他工艺条件不变的情况下,在一定范围内添加WC颗粒,可以较大幅度地提高镀层的硬度及耐磨性;WC添加量为1 g/L时,镀层的综合力学性能最好.