聚合物基复合材料用耐高温水溶性芯模性能研究

采用具有良好韧性的聚乙烯醇(PVA)和良好水溶性的聚乙烯吡咯烷酮(PVP)混合溶液作为胶黏剂,以石英砂作为填料,经过高温烘干工艺制备了一种低成本易成型的水溶性芯模。该芯模既能满足树脂基复合材料成型时的温度要求,又能在复合材料成型完成后进行水溶脱除。主要研究了水溶性芯模材料的组成、制备工艺与成型收缩率、耐温性、加工性等相关性能,并对水溶性芯模材料的水溶性作了评价和表征。     

泡沫夹芯结构复合材料VARI工艺模拟研究

提出了一种简单方便的等效建模法,解决了大尺寸夹芯结构或复杂形状夹芯结构真空辅助树脂灌注(VARI)成型工艺模拟仿真计算量大,效率不高的难题。采用等效建模法和细化建模法对矩形泡沫夹芯结构复合材料平板的VARI工艺进行了模拟仿真分析,并结合工艺成型实验进行了验证。结果表明,由两种方法计算得到的理论充模时间与实测树脂充模时间基本一致,采用等效建模法所得树脂流动前锋位置曲线与工艺成型实验测试值更加吻合。     

树脂基复合材料用耐高温水溶性模具材料性能研究

本文采用了耐高温水溶性胶粘剂制备了水溶性模具,通过调节水溶性模具材料各组分配比,研究了水溶性模具的溶解性能和压缩性能,从而确定了制备水溶性模具的最佳工艺条件。另外还对水溶性模具的热性能、热膨胀系数、干燥时间、耐温性等性能进行了研究。研究结果表明:此种水溶性模具材料耐温达220℃,溶解性能和压缩性能能满足树脂基复合材料成型的要求,制备出的复合材料具有空隙率低(空隙率小于0.7%)等优点。     

中空类碳纤维产品的成型工艺

正本发明提供一种中空类碳纤维产品的成型工艺,涉及碳纤维制备技术领域。包括以下步骤:将聚苯乙烯泡沫原料灌入芯模模具内,放置在真空热压炉中成型;将所述芯模套上气袋;根据芯模形状将玻璃布和碳布包覆在芯模上,得到产品     

碳纤维复合材料方管硅橡胶热膨胀成型工艺研究

针对碳纤维复合材料方管,设计制备了硅橡胶热膨胀工艺成型模具,并制备了碳纤维/双马树脂和碳纤维/环氧树脂复合材料方管,研究了成型过程中硅橡胶的温度变化规律,考察了方管的成型质量及其影响因素。结果表明,按照所建立的热膨胀工艺模具尺寸设计公式,可给出硅橡胶芯模的尺寸和工艺间隙;模具内腔的空气对流情况对硅橡胶的温度变化有重要影响;工艺间隙对方管成型质量有很大影响,当工艺间隙与理论计算值相符时,碳纤维/环氧树脂管件的表面和内部质量良好,厚度与设计值一致;碳纤维/双马树脂管件成型时,复合材料内部容易产生孔隙缺陷,采用真空辅助的热膨胀工艺方法,能够有效消除孔隙缺陷。     

水溶性芯模材料的制备与性能研究

采用黄糊精、空心玻璃微珠与尿素等材料,通过共混模压工艺制备了新型的水溶性芯模材料,对其进行了压缩强度、水溶性等性能测试,分析了影响该芯模材料性能的因素。结果表明,将空心玻璃微珠的用量控制在总量的10%左右,尿素的用量控制在总量的6%左右,可获得性能最优的水溶芯模材料;所制得的水溶芯具有强度高、表面光洁、水溶性好、性能稳定、成本低等优点。     

真空辅助树脂灌注配套基体树脂的制备及性能

针对真空辅助成型技术(VARI)对基体树脂的特殊要求,结合航空材料对性能的高要求,研制了BA9912中温固化环氧树脂体系。采用VARI工艺制备了G0827/BA9912复合材料,测试了BA9912树脂浇注料及其复合材料的力学性能和耐热性能,并与国内外同类树脂进行了适当的比较分析。分析测试结果表明,BA9912树脂具有良好的力学性能、耐热性能和工艺性能,能够满足VARI成型工艺要求,适合在航空航天领域中应用。     

基于CAD/CAM的空调面板注塑模设计及数控加工

以空调面板的注塑模设计及其数控加工为例,对塑件的注塑成型工艺进行了分析,详细介绍了模具分型面与浇注系统、脱模复位机构、模温控制系统和模具整体结构的设计,并阐述了模具动模芯的数控加工工艺。实践表明,该模具设计与数控加工工艺合理可靠,所成型的空调面板质量良好,对同类塑件的模具设计与加工具有较好的参考价值。     

基于VARI工艺的J型加筋壁板成型工艺研究

对VARI成型工艺进行了简介,并提供了一种高性能VARI工艺成型J型加筋壁板的出胶结构和方法。采用阴阳模结构取代传统单面模具,同时阴模本体上设计有多排均布圆形导口,用于导出气体,提高树脂沿长度方向的流动性,增加树脂的浸润能力,保证树脂能够完全浸润预制体。在Z型本体的上表面两端分别设置注胶口和出胶口,注胶口设置在大Z端,出胶口设置在小Z端,从模具上部注胶有利于借助重力作用提高树脂沿高度方向的流动性。该出胶结构和方法最终保证获得了高性能的复合材料产品。     

新型水溶性芯模材料的研制

将磷酸酯淀粉与刚性填料,通过共混制备了新型的水溶性芯模材料。并对其压缩强度、水溶性等进行了测试,分析了影响性能的各种因素。实验结果表明,在磷酸酯淀粉中加入质量分数10%的刚性填料所制得的水溶性芯模材料,具有强度高、表面光洁、水溶性好等特点。     

VARI成型不同处理方法泡沫夹芯复合材料工艺及性能研究

采取泡沫芯刻槽和泡沫芯导孔两种处理方法预制备泡沫芯材,采用VARI工艺成型泡沫夹芯复合材料,对复合材料进行无损检测,并对其成型效率、质量和力学性能进行研究。结果表明:刻槽和导孔处理可以有效地提高泡沫夹芯复合材料的成型效率,且其表面质量良好;三种泡沫夹芯复合材料泡沫与复合材料面板间均结合紧密,不存在贫胶、分层等缺陷;经刻槽处理后,泡沫夹芯复合材料的剥离强度有所下降,而弯曲强度和侧压强度略有上升;经导孔处理后,泡沫夹芯复合材料的剥离强度、弯曲强度和侧压强度均小幅下降。总的来看,不同处理工艺对VARI泡沫夹芯结构力学性能影响不大。     

水溶性砂芯模材料在成型复合材料壳体中的应用

以聚乙烯醇(PVAL)水溶液与聚乙烯吡咯烷酮(PVP)水溶液的混合溶液作为基体材料,以石英砂为增强材料,经过高温烘干工艺制作了一种水溶性砂芯模材料,分析了影响其水溶性的因素并对各因素设置不同的水平,通过正交试验发现,PVP水溶液的质量浓度为38%且占混合溶液的质量分数为60%、胶砂质量比为0.08时,制作的砂芯模水溶性最好,在室温条件下经过水的冲刷可快速溃散。为解决金属模具成型小开口、大长径比复合材料壳体造成的脱模困难、模具设计复杂的缺点,将研制的水溶性砂芯模材料应用于某复合材料壳体的成型,成型后的壳体其爆破强度、环向应变、容器特性指数与金属模具成型的复合材料壳体相差不大,符合使用要求。     

Research on a New Variotherm Injection Molding Technology and its Application on the Molding of a Large LCD Panel

The polymer injection products produced by using the current injection molding method usually have many defects, such as short shot, jetting, sink mark, flow mark, weld mark, and floating fibers. These defects have to be eliminated by using post-processing processes such as spraying and coating, which will cause environment pollution and waste in time, materials, energy and labor. These problems can be solved effectively by using a new injection method, named as variotherm injection molding or rapid heat cycle molding (RHCM). In this paper, a new type of dynamic mold temperature control system using steam as heating medium and cooling water as coolant was developed for variotherm injection molding. The injection mold is heated to a temperature higher than the glass transition temperature of the resin, and keeps this temperature in the polymer melt filling stage. To evaluate the efficiency of steam heating and coolant cooling, the mold surface temperature response during the heating stage and the polymer melt temperature response during the cooling stage were investigated by numerical thermal analysis. During heating, the mold surface temperature can be raised up rapidly with an average heating speed of 5.4°C/s and finally reaches an equilibrium temperature after an effective heating time of 40 s. It takes about 34.5 s to cool down the shaped polymer melt to the ejection temperature for demolding. The effect of main parameters such as mold structure, material of mold insert on heating/cooling efficiency and surface temperature uniformity were also discussed based on simulation results. Finally, a variotherm injection production line for 46-inch LCD panel was constructed. The test production results demonstrate that the mold temperature control system developed in this study can dynamically and efficiently control mold surface temperature without increasing molding cycle time. With this new variotherm injection molding technology, the defects on LCD panel surface occurring in conventional injection molding process, such as short shot, jetting, sink mark, flow mark, weld mark, and floating fibers were eliminated effectively. The surface gloss of the panel was improved and the secondary operations, such as sanding and coating, are not needed anymore.     

纤维增强复合材料的力学性能预测的数值模拟

纤维增强复合材料的力学性能和热物理性能依赖于纤维的取向状态.在注射成型过程中纤维最终的取向状态依赖于充填过程的速度场,因此最终的产品性质依赖于成型的详细过程.研究发现,注塑成型制品的结构呈层状分布,层数依赖于模具几何和成型条件,不过大多数的结构在成型表面为沿流动方向取向,而在中心层为横向排列,有时在制件表面还有一层薄的介于二者之间排列的取向层.本文主要给出两个简单模型中纤维取向预测的理论和数值方法,这两个模型分别为:中心浇口圆盘和边浇口长条.     

电风扇壳体多重倒扣成型注塑模具设计

针对某款落地电风扇后壳的结构特点,对此塑料产品的分型面做了合理设计。由于该产品内侧存在多个形状各异、方向不同的倒扣难以脱模,因此设计了四组斜导柱抽芯机构和四组斜顶机构组合的单型腔注塑模具,从而保证成型的同时能够顺利脱模。该壳体作为大众消费品有较高外观质量要求,因此采用侧浇口进浇以保证产品外观质量。对产品进行注塑模具设计的同时,利用CAE技术对所设计的注塑模具进行了注塑成型过程的模流分析,提高了注塑模具的设计效率、优化了模具的设计结构和注射成型工艺参数的设置,降低了模具制造成本。经验证,该模具结构可靠,运动顺畅,产品注塑成型效果良好,为类似结构特点模具的设计提供了良好的借鉴。     

Analysis of the effects of internal heating and cooling during the rotational molding of plastics

In rotational molding, shortening the cycle time is one of the most important requirements for increasing production rates and reducing product cost. A characteristic feature of the process is that the mold and plastic powder are heated from room temperature to the melting temperature of the plastic and then back to room temperature. In addition, in the vast majority of cases the heat input and subsequent heat extraction occur at the outside surface. In order to improve the heat transfer, this paper considers the effects of internal heating and cooling. A mathematical model has been developed in which an internal heating term can be incorporated. The experiments with rotomolding powders show that the predictions made by the model are accurate. In particular, it is found that the introduction of internal heating is very effective in shortening the cycle time and that the introduction of internal cooling in rotational molding provides a more uniform structure and less likelihood of warpage.     

复合材料热膨胀成型工艺研究与应用

简要叙述热膨胀工艺的原理和成型工艺过程，对热膨胀芯模的材料性能和设计、制造进行试验，分析影响膨胀压力的因素，并与热压罐成型工艺进行性能对比。以硅橡胶材料制作的芯模与钢模组合使用制备碳纤维复合材料制件，应用效果较好。研究表明，该工艺适用于多腔体复合材料制件的整体共固化成型。     

Electromagnetic Field-Aided Magnetic Soft Mold Reverse Imprinting Technology Applied in Microstructure Replication

This paper proposes an advanced microstructure embossing replication technology that combines an electromagnetic-field-aided magnetic soft mold and a reverse imprinting technology to replicate microstructure. The main advantage of this technology is low pressure, low cost, and quick and easy forming. The entire imprinting process can be completed at room temperature using a ultraviolet (UV) curing technique. This study applied a compound casting technique to fabricate a magnetic poly(dimethylsiloxane) (PDMS) soft mold, with an electromagnetic chuck for even imprinting pressure, and reverse imprinting molding technology. Microstructure cavity of the mold was fully filled with photoresist before imprint replication, and improved microstructure transfer ratio. Examination of the results showed that, the magnetic PDMS soft mold integrated electromagnetic-field-aided reverse imprinting process developed by this study, can successfully replicate microstructure at room temperature, low pressure, and avoid deformation and residual stress problems due to heating and cooling.     

汽车JST连接器注塑模设计

根据汽车JST连接器的结构特点和注射成型工艺要求,提出了型芯采用镶拼式结构的注塑成型模具结构设计方案。首先,分析了ABS材料的性能和成型工艺;然后采用Moldflow软件对塑件进行模流分析,从而得到优化的工艺参数组合。模具设计采用单分型面,一模八腔,潜伏式浇口形式。实践证明：该模具结构设计合理,满足成型工艺要求,产品质量好。