Numerical analysis of an air condenser working with the refrigerant fluid R407C

As CFC (clorofluorocarbon) and HCFC (hydrochlorofluorocarbon) refrigerants which have been used as refrigerants in a vapour compression refrigeration system were know to provide a principal cause to ozone depletion and global warming, production and use of these refrigerants have been restricted. Therefore, new alternative refrigerants should be searched for, which fit to the requirements in an air conditioner or a heat pump, and refrigerant mixtures which are composed of HFC (hydrofluorocarbon) refrigerants having zero ODP (ozone depletion potential) are now being suggested as drop-in or mid-term replacement. However also these refrigerants, as the CFC and HCFC refrigerants, present a greenhouse effect.The zeotropic mixture designated as R407C (R32/R125/R134a 23/25/52% in mass) represents a substitute of the HCFC22 for high evaporation temperature applications as the air-conditioning.Aim of the paper is a numerical–experimental analysis for an air condenser working with the non azeotropic mixture R407C in steady-state conditions. A homogeneous model for the condensing refrigerant is considered to forecast the performances of the condenser; this model is capable of predicting the distributions of the refrigerant temperature, the velocity, the void fraction, the tube wall temperature and the air temperature along the test condenser. Obviously in the refrigerant de-superheating phase the numerical analysis becomes very simple. A comparison with the measurements on an air condenser mounted in an air channel linked to a vapour compression plant is discussed. The results show that the simplified model provides a reasonable estimation of the steady-state response and that this model is useful to design purposes.     

Boiling heat transfer coefficient of R22 and an HFC/HC refrigerant mixture in a fin‐and‐tube evaporator of a window air conditioner

The commonly used refrigerant in unitary type air conditioners is R22 and its phase out schedule in developing countries is to commence from 2015. Many alternatives to R22 are found in published literature in which R407C has similar characteristics to those of R22 except for its zeotropic nature. However, R407C which is an HFC is made compatible with the mineral oil lubricant in the system compressor by the addition of 20% of HC. This HFC/HC mixture called the M20 refrigerant mixture is reported to be a retrofit refrigerant for R22. Though its latent heat value is greater than that of R22, its refrigerating capacity is lower when it is used to retrofit R22 window air conditioners. Hence, a heat transfer analysis was conducted in the evaporator of a room air conditioner, for practically realized heat flux conditions during standard performance testing. The tests were conducted as per the BIS and ASHRAE standards. Kattan–Thome–Favrat maps are used to confirm the flow patterns, which prevail inside the fin‐and‐tube evaporator in the tested operating conditions. It is revealed that the heat transfer coefficient/heat fluxes are poorer for M20 because of the lower mass flow rate and higher vapor fraction at the entry of the evaporator than that of R22 in the prevailing operating conditions. The heat transfer coefficients of the M20 refrigerant mixture under various test conditions are lower in the range of 14% to 56% than those of R22. © 2010 Wiley Periodicals, Inc. Heat Trans Asian Res; Published online in Wiley Online Library ( wileyonlinelibrary.com ). DOI 10.1002/htj.20299     

Energy efficiency analysis of a new ternary HFC alternative

In this paper, energy efficiency results are presented for a new HFC ternary blend proposed as a substitute for CFC 502 and HCFC 22. The blend is composed of R-23/R-32/R-125. Performance evaluation test results were obtained after an experimental heat pump set up with a 3 kW rotary compressor. The refrigerants tested in this study under different conditions were HCFC-22, as a reference base refrigerant and R-410a (HFC-32/HFC-125), R-407c (HFC-32/HFC-125/HFC-134a), as well as quaternary mixture; HFC-32/HFC-125/HFC-143a/HFC-134a. The experimental data showed that our proposed HFC ternary blend R-23/R-32/R-125 has superior performance compared to other proposed HFC alternatives such as R-410a and R-407c, under the same conditions. Pressure ratios and head pressures were compatible with new compressors to be used in new systems. Furthermore, experimental results demonstrated that the ternary blend R-23/R-32/R-125 is the best performing replacement for R-22 in heat pump applications and low temperature equipment. Experiments also showed that the heat pump system using R-23/R-32/R-125 was stable and experienced reasonable head pressures. © 1997 John Wiley & Sons, Ltd.     

Ozone friendly binary blends R 32/R 134a and the ternary R 407b

The objective of this paper is to present thermodynamic properties and characteristics of the binary refrigerant mixtures R 32/R 134a in compositions 20/80%, 30/70%, 40/60% by mass and of the ternary mixture R 407b: 10 wt% R 32+70 wt% R 125+20 wt% R 134a. A computer code has been developed and by use of a Peng–Robinson type equation of state, PVT data for all working fluids are determined. Based on the thermodynamics theory, analytical relationships for the enthalpy, entropy, constant pressure and constant volume specific heats as well as for k-type isentropic change exponents are given. Furthermore, comparisons are provided by means of diagrams illustrating the influence of state conditions on the k-type exponents k_p,V, k_T,V, k_p,T, and classical k (k=c_P/c_V). A systematic study has also been carried out and the data obtained are plotted for a better physical feeling related to the sound velocity of real gas for the R 32/R 134a blend in composition 20/80%. The results are compared with corresponding ones of the ternary R 407b.     

Experimental investigation of R290/R600a mixture as an alternative to R134a in a domestic refrigerator

R134a is the most widely used refrigerant in domestic refrigerators. It must be phased out soon according to Kyoto protocol due to its high global warming potential (GWP) of 1300. In the present work, an experimental investigation has been made with hydrocarbon refrigerant mixture (composed of R290 and R600a in the ratio of 45.2:54.8 by weight) as an alternative to R134a in a 200 l single evaporator domestic refrigerator. Continuous running tests were performed under different ambient temperatures (24, 28, 32, 38 and 43 °C), while cycling running (ON/OFF) tests were carried out only at 32 °C ambient temperature. The results showed that the hydrocarbon mixture has lower values of energy consumption; pull down time and ON time ratio by about 11.1%, 11.6% and 13.2%, respectively, with 3.25–3.6% higher coefficient of performance (COP). The discharge temperature of hydrocarbon mixture was found to be 8.5 to 13.4 K lower than that of R134a. The overall performance has proved that the above hydrocarbon refrigerant mixture could be the best long term alternative to phase out R134a.     

含R227ea的混合制冷剂替代R22研究

由于R410，R407系列混合制冷剂在替代R22方面的不足，更多新型的制冷剂列入了研究。R227ea具有良好的环境性能，最典型的特点是具有很好的阻燃性。文章对含R227ea各种混合物进行了理论计算和比较，并对其安全性进行了分析。计算结果表明，混合物R32／R134a／R227ea及R32／R125／R227ea不论是COP还是Qv值，都能和R22相匹配，而且优于R410A的最大特点是其冷凝压力大大降低，甚至低于R22，非常有利于原装置替代。     

R407c as an alternative to R22 in refrigeration systems

A refrigeration test facility was constructed to examine the performance of potential alternatives to R22. For the purpose of this paper, the performance of R407c (a zeotropic mixture of R134a, R125 and R32 in a 52% 25% 23% composition by mass) was compared to that of R22. It was found that the performance of R407c approached that of R22 at higher evaporator temperatures, but reductions in evaporator capacity and COPc were found with decreasing evaporator temperature. The effects on evaporator performance of a 32 cSt polyol ester compressor lubricating oil were also noted. It was seen that while R22 and this oil responded in typical fashion for a soluble refrigerant-oil pair (reduced capacity, increased evaporator pressure drop and fall-off in capacity at low superheats), R407c displayed a two-stage performance decline occurring over a greater range of superheat. The combined effect of differential solubility of the individual components of the mixture in conjunction with a more gradual solubility effect due to the presence of a temperature glide in the evaporator lead to a minor change in composition of the circulating refrigerant mixture resulting in a drop in evaporator capacity and COPc.     

Boiling characteristics of ternary mixtures inside enhanced surface tubing

Two phase flow characteristics such as coefficient of heat transfer and pressure drop observed during boiling of ternary azeotropic refrigerant mixtures R-404A (R-125/RR--134a/R-143a:44/4/52), R-407B (R-32/R-125/R-134a: 10/70/20), R-407C (R-32/R-125/R-134a:23/25/52) and R-408A (R-22/R-125/R-143a:46/7/47) are presented and analyzed in this paper.Experiments showed that for Reynolds numbers higher than 4.5 E04, R-408A and R-404A appear to have greater heat transfer rates than the other blends under investigation. Furthermore, it is quite evident from this data that at higher Reynolds number R-404A and R-408A have the highest pressure drop while R-407 experiences the lowest pressure drop among the refrigerants under investigation.     

Performance evaluation of heat exchanger using alternative refrigerant R407C

R22 (HCFC22) has been widely used as the refrigerant in air conditioners. According to the Montreal protocol for ozone layer protection, the total production of HCFCs has been capped since the beginning of 1996. Zeotropic refrigerant mixture R407C and nearly azeotropic refrigerant mixture R410A have been selected as alternatives to R22. We examined refrigerant passages in heat exchangers used in heat pump‐type room air conditioners using zeotropic refrigerant R407C through simulation, and obtained the following conclusions. In an indoor heat exchanger, a counter flow configuration when operating as a condenser has higher temperature efficiency. When an outdoor heat exchanger operates as an evaporator, a configuration that suppresses the temperature glide by partially reducing the refrigerant passage not only produces high efficiency, but also reduces the frost formation on fins. © 2002 Wiley Periodicals, Inc. Heat Trans Asian Res, 31(8): 626–638, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.10064     

Performance prediction of a refrigerating machine using R‐407C: the effect of the circulating composition on system performance

This article presents a steady‐state model of a vapour compression refrigerating machine using a ternary refrigerant mixture R‐407C. When using a zeotropic mixture in a refrigerant cycle, the circulating composition does not agree with the composition of the original charged mixture. It is mainly due to the temperature glide and the vapour–liquid slip ratio. As a result of the composition shift and its magnitude, the system performance changes depending on the system design, especially the presence of liquid receiving vessels. In this paper, a method that predicts the circulating composition has been associated to a refrigerating machine model. The results obtained with this model show an enrichment in the most volatile components of about 1% for the circulating composition, which is sufficient to decrease the system performance by about 3%. Factors affecting the overall performance have been investigated. The results show a very strong performance dependence on the refrigerant charge. The COP can decrease by 25% when the refrigerant charge is insufficient. An initial charged composition variation of 2% involves variations of the cooling capacity of about 5%. Furthermore, our model was employed to compare the performance for both R‐22 and R‐407C. The cooling capacity for R‐22 is slightly greater in comparison to R‐407C and the COP is almost constant. Copyright © 2002 John Wiley & Sons, Ltd.     

An experimental evaluation of the vapour compression plant performances in presence of R407C leaks using an electronic expansion valve

Chlorofluorocarbons and hydrofluorocarbons (HFCs) used as working fluids in the vapour compression plants, have to be replaced by new substances because of their ozone depletion potential. Zeotropic mixture of HFCs refrigerants that are environment-friendly substances are often employed. The zeotropic mixtures with a large glide temperature could cause problems in the refrigeration control system when a leak occurs because their composition modifies. This paper presents a comparison of the energetic performances, in presence of leaks, when a thermostatic valve and an electronic expansion valve are used in a refrigeration plant, working with the zeotropic mixture designated as R407C (R32/R125/R134a 23/25/52% in mass)—this is the most suitable substitute of the HCFC22. The vapour leaks are simulated at the inlet of the evaporator and at the liquid receiver. Experimental results show that a good adaptability to mixture leaks is related to the electronic expansion valve, while better energetic performances are obtained using the thermostatic expansion valve as long as it is usable.     

混合工质R134a/R23替代R22的可行性研究

叙述了基于新型环保型混合制冷剂R134a/R23替代制冷剂R22的问题,以及通过REFPROP7.5,对混合工质R134a/R23从物性和热力学特性进行的理论计算分析,指出,由质量分数为70%的R134a和质量分数为30%的R23组成的混合制冷剂与R22性能最为接近,在变工况运行条件下,其COP值比R22高8%左右,其冷凝压力比同条件下用R22作为循环工质低21%～36%,理论上完全具有替代R22的可能性。     

R407C as an alternative to R22 in vapour compression plant: an experimental study

The problem of HCFC22 phase-out in refrigeration plants is analysed. A comparison is performed between R22 and R407C. The latter seems a promising drop-in substitute. Indeed, its use in existing plants would only require discharge of mineral oil and refilling with a compatible polyolester oil. The experimental tests are performed in a plant consisting in a water-cooled vapor-compression circuit employed for cooling a water–glycol mixture in a closed-loop system. Both the thermodynamic properties and general performance of R407C are comparable with those of R22. The COP, however, is 5–17% lower. As a consequence, in order to provide the same refrigerating load, a plant working with R407C requires higher electric-power consumption. The operational behaviour of R407C is increasingly better with increasing condensation and evaporation temperature. Therefore, R407C is a good R22 substitute in all applications requiring high evaporation temperatures, such as air-conditioning plants. © 1997 John Wiley & Sons, Ltd.     

Pool boiling heat transfer of refrigerant mixtures R32/R125

Nucleate pool boiling heat transfer of new, environmentally harmless refrigerant mixtures R32/R125 has been systematically investigated in a wide range of pressure and heat flux under saturation conditions using a horizontal platinum wire (d = 0.1 mm). The platinum wire served as both heating element and resistance thermometer. The experimental results are compared with calculated values using a modified Jungnickel correlation. The comparison between all calculated data and experimental data shows good agreement. Most of the data fall within ±20% of the correlation. The mean average deviation is ±8.25%.     

Flow boiling heat transfer of HFO1234yf and R32 refrigerant mixtures in a smooth horizontal tube: Part I. Experimental investigation

HFO1234yf has been proposed for mobile air-conditioners due to its low global warming potential (GWP) and performance comparable to that of R134a. However, its performance is inferior to that of R410A. This makes it difficult to be applied to residential air-conditioners. In order to apply the low-GWP refrigerant to residential air-conditioners, refrigerant mixtures of HFO1234yf and R32 are proposed, and their flow boiling heat transfer performances were investigated at two mass fractions (80/20 and 50/50 by mass%) in a smooth horizontal tube with an inner diameter of 2 mm. The experiments were conducted under heat fluxes ranging from 6 to 24 kW/m² and mass fluxes ranging from 100 to 400 kg/m² s at the evaporation temperature of 15 °C. The measured heat transfer coefficients were compared with those of pure HFO1234yf and R32. The results showed that the heat transfer coefficients of the mixture with an R32 mass fraction of 20% were 10–30% less than those of pure HFO1234yf for various mass and heat fluxes. When the mass fraction of R32 increased to 50%, the heat transfer coefficients of the mixture were 10–20% greater than those of pure HFO1234yf under conditions of large mass and heat fluxes. Moreover, the heat transfer coefficients of the mixtures were about 20–50% less than that of pure R32. The performances of the mixtures were examined at different boiling numbers. For refrigerant mixture HFO1234yf and R32 (80/20 by mass%), the nucleate boiling heat transfer was noticeably suppressed at low vapor quality for small boiling numbers, whereas the forced convective heat transfer was significantly suppressed at high vapor quality for large boiling numbers. This indicates that the heat transfer is greatly influenced by the mass diffusion resistance and temperature glide of the mixture.     

Measurements of thermal conductivity and thermal diffusivity of alternative refrigerants in liquid phase with a transient short‐hot‐wire method

A transient short‐hot‐wire method has been proposed to simultaneously measure the thermal conductivity and thermal diffusivity of liquids. The method has been applied to the refrigerant HCFC‐22, alternative refrigerants HFC‐32, HFC‐125, HFC‐134a and refrigerant mixtures HFC‐32/125 [35/65, 50/50 (HFC‐410A), 68/32 wt%], HFC‐32/125/134a [23/25/52 (HFC‐407C) wt%]. From the present study, it is shown that the measured results agree well with the literature values on thermal conductivity and those on thermal diffusivity obtained from NIST's thermophysical property database, REFPROP Ver. 6.0. © 2004 Wiley Periodicals, Inc. Heat Trans Asian Res, 33(8): 540–552, 2004; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/htj.20032     

Prediction of the condensation and boiling characteristics of R12 substitutes R22/r152a/R114 and R22/R152a/R124 inside enhanced-surface tubing

In this paper, the heat-transfer behaviour of two ternary refrigerant blends proposed as an R12 substitute, has been studied during condensation and boiling inside horizontal enhanced surface tubing. Correlations are proposed to predict the average heat transfer coefficients as well as pressure drops of newly proposed ternary refrigerant blends flow, inside enhanced surface tubing.     

Performance of heat pumps charged with R170/R290 mixture

In this study, thermodynamic performance of R170/R290 mixture is measured on a heat pump bench tester in an attempt to substitute R22. The bench tester is equipped with a commercial hermetic rotary compressor providing a nominal capacity of 3.5 kW. All tests are conducted under the summer cooling and winter heating conditions of 7/45 °C and −7/41 °C in the evaporator and condenser, respectively. During the tests, the composition in R170/R290 mixture is varied from 0% to 10% with an interval of 2%. Test results show that the coefficient of performance (COP) and capacity of R290 are up to 15.4% higher and 7.5% lower, respectively than those of R22 for two conditions. For R170/R290 mixture, the COP decreases and the capacity increases with an increase in the composition of R170. The mixture of R170/R290 mixture at 4%/96% composition shows the similar capacity and COP as those of R22. For the mixture, the compressor discharge temperature is 17–28 °C lower than that of R22. For R170/R290 mixture, there is no problem with mineral oil since the mixture is composed of hydrocarbons. The amount of charge is reduced up to 58% as compared to R22. Overall, R170/R290 mixture is a good long term ‘drop-in’ candidate from the view point of energy efficiency and greenhouse warming to replace R22 in residential air-conditioners and heat pumps.     

Performance of alternative refrigerant R430A on domestic water purifiers

In this study, performance of R430A is examined numerically and experimentally in an effort to replace HFC134a used in refrigeration system of domestic water purifiers. Even though HFC134a is used predominantly in such a system these days, it needs to be phased out in near future in most of the developed countries due to its high global warming potential. To solve this problem, cycle simulation and experiments are carried out with a new refrigerant mixture of 76%R152a/24%R600a using actual water purifiers. This mixture is numbered and listed as R430A by ASHRAE recently. Test results show that the system performance is greatly influenced by the amount of charge due to the small internal volume of the refrigeration system in water purifiers. With the optimum amount of charge of 21–22 g, about 50% of HFC134a, the energy consumption of R430A is 13.4% lower than that of HFC134a. The compressor dome and discharge temperatures and condenser center temperature of R430A are very similar to those of HFC134a for the optimum charge. Overall, R430A, a new long term environmentally safe refrigerant, is a good alternative for HFC134a in domestic water purifiers requiring no major change in the system.     

Analysis on the adiabatic flow of R407C in capillary tube

In this paper the adiabatic flow in the capillary tube is analyzed and modeled for R407C, which is a non-azeotropic mixed refrigerant and one of the alternatives to R22. The equations of energy, continuity and pressure drop through a capillary tube are presented. A mathematical model of the sub-cooled flow region and the two-phase flow region is developed. The results of the calculation show that this numerical model is capable of providing an effective means to analyze components’ performance in optimizing and controlling a R407C air-conditioning system.