Microstructure and wear resistance of electro-thermal explosion sprayed stellite coating used for remanufacturing

Electro-thermal explosion directional spraying was used to prepare the stellite coating on substrate of the AISI 1045 steel. The morphologies of cross-section and worn scar, porosity, distribution of elements, micro-hardness and wear resistance of the coating were determined by means of SEM, EDAX, micro-hardness tester and sliding wear tester. Because of the compact construction, good bonding and high hardness, the coating is characterized by good wear resistance. The results show that the mainly failure mode of the stellite coating is micro-plowing. Foundation item: Project(2003AA331130) supported by Hi-tech Research and Development Program of China; Project(50235030) supported by the National Natural Science Foundation of China     

High-temperature corrosion-resistance performance of electro-thermal explosion spraying coating

As a new spraying technology used in the remanufacturing engineering, electro-thermal explosion spraying holds a lot of advantages. Electro-thermal explosion spraying coating aliquation phenomena are reduced and non-crystal, micro-crystal and millimicron-crystal and other microstructure are formed. The corrosion-resistance a bility of electro-thermal explosion spraying coating in high temperature environment was surveyed respectively. SEM equipped with EDS was employed to analyze the microstructure of spraying coating before and after corrosion. The corrosion-resistance mechanism of the spraying coating was discussed.     

High-temperature corrosion-resistance performance of electro-thermal explosion spraying coating

As a new spraying technology used in the remanufacturing engineering, electro-thermal explosion spraying holds a lot of advantages. Electro-thermal explosion spraying coating aliquation phenomena are reduced and non-crystal, micro-crystal and millimicron-crystal and other microstructure are formed. The corrosion-resistance ability of electro-thermal explosion spraying coating in high temperature environment was surveyed respectively. SEM equipped with EDS was employe to analyzed the microstructure of spraying coating before and after corrosion. The corrosion-resistance mechanism of the spraying coating was discussed. Foundation item: Project(2003AA331130) supported by the Hi-tech Research and Development Program of China     

电热爆炸喷涂法制备TiC涂层的特性分析

采用电热爆炸定向喷涂工艺在镍合金基体上制备TiC涂层,借助光学显微镜、显微硬度计分别对涂层显微组织、涂层硬度进行了测试。利用图像分析软件对涂层的晶粒尺寸进行了测量。结果表明,电热爆炸定向喷涂制备的涂层组织晶粒明显细化,涂层组织为典型的快速凝固组织。涂层组织比原始喷涂材料镍合金组织细小、均匀;TiC涂层中大晶粒所占涂层面积为93.6%,小晶粒所占面积为6.4%;大晶粒的弦长平均值为500 nm左右,小晶粒的弦长平均值为81 nm左右;表层有些孔隙;涂层硬度均明显高于基体材料镍合金的硬度,其最高硬度达到了582.5 HV。     

Effect of nano-size nickel particles on wear resistance and high temperature oxidation resistance of ultrafine ceramic coating

1　INTRODUCTIONImprovementsinaerogasturbineengineandartilleryrecoilabsorberperformanceintermsofpower ,efficiencyandmassnecessitatetheuseofhighspecific strengthandlow densitymaterials,whichresultsinthedevelopmentofawiderangeoftitaniumalloysinthecompressorsectionof modern gasturbinesandartilleryrecoilabsorber .Titaniumalloys,ingeneral,easilyabsorboxygen ,leadingtooxidationandalphaphaseformationwhenexposedtohightemperature ( >5 0 0℃ )inair,whichlimitsthehightemperaturecapabilityofalloysdueto…     

TC4合金表面TiN陶瓷激光熔覆层的组织和耐磨性能

为提高TC4合金的耐磨性能，采用连续波CO2激光在其表面熔覆TiN陶瓷涂层，分析了熔覆层的微观组织结构，对熔覆层的硬度和磨损性能进行了测试．结果表明，TiN激光熔覆层分为两个亚层，表层为TiN熔凝层，由TiN棒状树枝晶组成，底层为TiN和钛合金混凝层，由TiN棒状树枝晶、TiN颗粒和钛合金马氏体组成；TiN激光熔覆层的显微硬度在500—900HV之间，明显地改善了TC4合金的磨损性能．     

等离子熔覆铁基堆焊合金显微组织与耐磨性

为了提高在严峻工况条件下工作的机械零件的耐磨性,采用等离子熔覆技术,在20g钢表面制备了一系列Fe-15Cr-x-V-0.8C堆焊合金.借助光学显微镜、扫描电镜和x-射线衍射等分析手段研究了合金组织和碳化物形貌.结果表明：堆焊合金显微组织由马氏体、铁素体、少量奥氏体、M₇C₃和VC组成.合金中加入一定数量的V,可诱发基体的马氏体转变,改善合金的耐磨性.随着V的质量分数的增加,VC的数量增加,堆焊合金晶粒显著细化.此外,考察了V的质量分数对堆焊合金硬度及耐磨性的影响.耐磨粒磨损实验结果表明：堆焊合金耐磨性优良,当合金中存在较多数量的硬质相且硬质相分布均匀、晶粒大小适中时,能有效阻止磨粒的显微切削运动,显著提高材料的耐磨性.     

真空熔覆原位自生WC/Ni基复合涂层的组织及耐磨性能x

为了提高煤油泵的使用寿命,利用真空熔覆技术在316L不锈钢表面原位合成了W_{C/Ni基复合涂层.采用扫描电子显微镜、能谱仪、X射线衍射仪研究了复合涂层的显微组织和相组成,并对其进行了硬度测量和摩擦性能试验.结果表明,复合涂层组织细密且与基材呈冶金结合.复合涂层主要由γ-Ni固溶体、原位生成的WC、(Cr,Fe)7C3和Cr7C3相组成,且WC相弥散分布在γ-Ni固溶体中.复合涂层的硬度约为316L不锈钢基材的4倍,相对耐磨性约为基材的37倍.xx}x     

热喷涂HA复合涂层的组织分析

为了制备羟基磷灰石（HA）复合涂层,采用化学沉淀法制备羟基磷灰石粉末,对制备的超细粉末加入PVA溶液充分搅拌、干燥、研磨和过筛,制备出微米级、近似球状的、在等离子送粉器中容易流动的羟基磷灰石粉末.利用等离子喷涂和电弧喷涂的复合喷涂方法制备出羟基磷灰石不锈钢复合涂层和氧化铝不锈钢复合涂层,并通过扫描电镜分析了涂层的组织形态.结果表明,羟基磷灰石粉末比重很轻,不易进入等离子弧中心而被融化,等离子弧将羟基磷灰石粉末加热并载入电弧喷涂气流中,由不锈钢雾化液滴一并打在基体上形成复合涂层.对于氧化铝/不锈钢涂层和复合涂层,2种粒子虽然分布不均匀,但却获得了良好的冶金结合.     

电弧喷涂锡基巴氏合金层的磨损性能

针对电弧喷涂巴氏合金涂层组织的特殊性,研究在润滑条件下巴氏合金涂层的摩擦磨损性能,对该涂层的工程应用具有重要的参考价值.利用环块摩擦磨损试验分别对比了电弧喷涂、铸造以及堆焊方法制备的巴氏合金层与碳钢和铸铁构成摩擦副的磨损表现.借助于扫描电子显微镜、x 射线能谱以及x 射线衍射,分析了巴氏合金涂层的微观组织结构和磨损表面形貌,研究了其组织变化与耐磨性能之间的关系.实验结果表明：在润滑条件下,电弧喷涂巴氏合金涂层具有比铸造巴氏合金更好的减磨性能;选择合适的工艺参数可以制备组织致密、结合强度高,且具有很好磨损性能的巴氏合金涂层.     

紧固件表面锰系磷化膜的制备及摩擦磨损性能

为了提高核主泵紧固件的摩擦磨损性能,采用三种磷化工艺在40Ni Cr Mo7钢表面制备了锰系磷化膜.采用多功能材料表面性能测试仪进行了往复摩擦磨损试验,并研究了在有无润滑条件下,不同工艺对磷化膜摩擦磨损性能的影响.采用扫描电子显微镜和能谱仪表征了磨损前后磷化膜表面的组织形貌和化学成分,并分析了其磨损失效机制.结果表明,通过工艺Ⅱ制备的磷化膜具有最优的摩擦磨损性能.磷化膜特有的孔隙结构具有储油能力,有利于改善其摩擦学性能.随着法向载荷的增加,磷化膜的塑性变形增大,抗剪切强度降低,且摩擦系数呈先缓慢下降后急剧上升的趋势.     

Corrosion resistance of plasma sprayed NiCrAl (ZrO_2 Y_2O_3) thermal barrier coating on 18-8 steel surface

1INTRODUCTION Austeniticstainlesssteelisdevelopedtocom pensateforpoorcorrosionresistanceofmartensite stainlesssteelandoverlargebrittlenessofferrite stainlesssteel.Basicconstituentsofitstypicalal loyare18%Crand8%Ni(massfraction),which isusuallycalledas188s…     

等离子喷涂复合陶瓷涂层及其耐磨性能

用等离子喷涂技术制取了ＭＯ＋Ａｌ２Ｏ３－ＴｉＯ２、ＭＯＳ２＋Ａｌ２Ｏ３、ＴｉＯ２＋Ｃｒ３Ｃ２ＮｉＣｒ和ＭｏＳ２＋Ｃｒ３Ｃ２－ＮｉＣｒ复合涂层．利用ＳＥＭ、ＸＲＤ、和ＸＰＳ等技术．观察和分析了涂层的显微结构和喷涂过程中的物相变化及添加成分对涂层耐磨性能的影响．在ＭＭ－２００型磨损试验机上测定了涂层的滑动摩擦系数和磨损率．结果表明；Ｍｏ、ＭｏＳ２与Ａｌ２Ｏ３－ＴｉＯ２的结合性能较好，ＴｉＯ２、ＭｏＳ２在Ｃｒ３Ｃ２－ＮｉＣｒ涂层的气孔和裂纹处偏聚；添加ＭｏＳ２对Ａｌ２Ｏ３－ＴｉＯ２涂层的物相组成有明显的影响；适量的ＭＯ、ＭＯＳ２加入Ａｌ２Ｏ３－ＴｉＯ２中，可以降低涂层的摩擦系数和磨损率；而ＴｉＯ２、ＭｏＳ２加入Ｃｒ３Ｃ２－ＮｉＣｒ中，对涂层的摩擦磨损性能影响不大     

药芯焊丝明弧堆焊Fe-Cr-C-B合金组织及耐磨性

为了提高堆焊合金的耐磨性,利用明弧堆焊方法将自保护耐磨堆焊药芯焊丝熔覆在Q235基体金属表面,制备得到Fe-Cr-C-B耐磨堆焊合金.采用金相显微镜、扫描电子显微镜、X射线衍射仪、硬度计和磨料磨损试验机对堆焊层的组织、硬度和耐磨性进行了分析.结果表明,堆焊层主要由马氏体、少量残余奥氏体、M₃(C,B)、M₂₃(C,B)6和M₇(C,B)3相组成.随着B质量分数的增大,基体组织转变为马氏体,共晶硬质相增多,并呈连续网状分布在基体组织周围.当B的质量分数为3%时,堆焊层的耐磨性达到最佳,其硬度为61. 5 HRC,磨损量为0. 362 9 g.     

无热处理高硬度高耐磨性化学镀镍磷合金

研究了一种无需后续热处理且具有高硬度、高耐磨性的化学镀镍磷合金镀层.采用乳酸和乙酸钠作为络合剂，在理论上完全络合镍离子的前提下，通过改变化学镀镍溶液中乳酸和乙酸钠之间的比例，研究了镀速、镀层表面显微硬度以及镀层耐磨性的变化情况,结果表明,随着乳酸比例的增加，镀速出现先升高后下降的现象，并在n(乳酸提供的配位原子)：n(乙酸钠提供的配位原子)为4∶6时，镀速达到最大值，由此溶液得到的镀层，其表面显微硬度在热处理前达到了HV820，且镀层表面平整、致密，具有很高的耐磨性.     

Characterization and wear behavior of WC-0.8Co coating on cast steel rolls by electro-spark deposition

To prepare high wear resistance and high hardness coatings, electro-spark deposition was adopted for depositing an elec trode of a mixture of 92wt%WC+8wt%Co on a cast steel roll substrate. The coating was characterized by classical X-ray diffracto meter (XRD) and scanning electron microscopy (SEM) with energy dispersive X-ray analysis (EDX). The results indicate that the coating shows nanosized particulate structure and dendritic structure including columnar structure and equiaxed structure. The pri mary phases of the coating contain Fe_3W_3C, Co_3W_3C, Fe_2C and Si_2W. The coating has a low friction coefficient of 0.13, its average wear-resistance is 3.3 times that of the cast steel roll substrate and the main mechanism is abrasive wear. The maximum microhard ness value of the coating is about 1573.9 Hv_(0.3) The study reveals that the electro-spark deposition process has the characteristic of better coating quality and the coating has higher wear resistance and hardness.     

加热扩散对电弧喷涂Al涂层的影响

为了提高Al涂层的抗高温氧化性及硬度,采用电弧喷涂方法在Q235碳钢基体上制备了Al涂层.结果表明,经过加热扩散处理后Al涂层和基体之间形成了扩散层.涂层厚度、加热温度与加热时间对扩散层具有一定影响.当加热温度为800℃和900℃时,Al涂层主要形成相为Fe Al、Fe Al2、Fe Al3和Fe2Al5.经过加热扩散处理后Al涂层具有优良的抗高温氧化性,且平均硬度相比未经加热扩散处理的Al涂层提高了10倍以上,利用扩散系数求出的扩散层深度与实际扩散层深度相近.     

铜表面气体渗硅后的滑动摩擦磨损研究

本文对用硅烷－氢（ＳｉＨ４／Ｈ２）混合气体在铜表面进行化学热处理获得的含硅表层进行了摩擦磨损研究．结果表明，在铜表面生成的含硅层可以降低摩擦系数；在低负荷干摩擦条件下，含硅表层的磨损率有较大程度的改善     

Microstructure and wear resistance of in situ NbC particles reinforced Ni-based alloy composite coating by laser cladding

The in situ synthesized NbC particles reinforced Ni-based alloy composite coating was produced by laser cladding a precursor mixture of Ni-based alloy powder,graphite and niobium powders on a steel substrate.The microstructure,phase composition and wear property of the composite coating were investigated by means of scanning electron microscopy(SEM),X-ray diffraction(XRD)and dry sliding wear test.The experiment results show that the composite coating is homogeneous and free from cracks,and about 0.8 mm thick.The microstructure of the composite coating is mainly composed of NbC particles,CrB type chromium borides,γ-Ni primary dendrites,and interdendritic eutectics.CrB phases often nucleate and grow on the surface of NbC particles or in their close vicinity.NbC particles are formed via in situ reaction between niobium and graphite in the molten pool during the laser cladding process and they are commonly precipitated in three kinds of morphologies,such as quadrangle,cluster,and flower-like shape.Compared with the pure Ni-based alloy coating,the microhardness of the composite coating is increased about 38%,giving a high average hardness of HV0.21000,and the wear rate of the composite coating is decreased by about 32%,respectively.These are attributed to the presence of in situ synthesized NbC particles and their well distribution in the coating.