共查询到19条相似文献,搜索用时 156 毫秒
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采用传统固相烧结法,制备了CaBi4Ti(1-x)NbxO1(5x=0.00-0.05,CBT-N)系铋层状结构无铅压电陶瓷。研究了Nb5+掺杂对CBT压电陶瓷压电与介电性能的影响。研究结果表明:添加Nb5+离子,改善了CBT陶瓷的烧结特性,提高了瓷体的致密度。Nb2O5的引入降低了CBT系列陶瓷的介质损耗,改善了陶瓷的压电与介电性能。当掺入量x=0.04(CaBi4Ti0.96Nb0.04O15)时制备的CBT基铋层状压电陶瓷具有优异的压电性能:d33=14pC/N,Qm=3086,εr=212,tanδ=0.0041,kt/kp=1.681。 相似文献
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采用常规电容器陶瓷制备工艺 ,借助正交设计实验法研究了在配方对中温烧结 (12 0 0℃ ) (Ba,Sr)TiO3 (BST)基陶瓷介电性能的影响 ,得到了影响BST基陶瓷介电性能的主次因素以及各因素水平影响其性能的趋势 ,同时得到介电常数最大的配方和介质损耗最小的配方 ,得到了综合性能最佳的适合单片电容器和独石电容器的中温烧结 (12 0 0℃ )BST基陶瓷基方 ,它具有中介 (ε≥ 2 195 )、低损耗 (tanδ≤ 0 .0 15 5 )和高耐压 (大于 4 .5Mv/m)。探讨了各组分对BST基陶瓷介电性能的影响机理 ,为研制中温烧结单片电容器和独石电容器陶瓷提供了依据 相似文献
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研究了V2O5对Mg4Nb2O9陶瓷的烧结温度、相结构和微波介电性能的影响.结果表明,添加1%~8%的V2O5,能使该陶瓷的烧结温度降低到1000~1050℃而对其微波介电性能的影响很小,材料的主晶相为有序型刚玉结构的Mg4 Nb2O9,存在Mg4Nb2O6和Mg5Nb4O15杂相而没有检测到V2O5的存在.陶瓷的密度对微波介电性能起着决定性作用,介电常数e1与密度成线性关系(在99.99%的置信限内,其相关系数为0.98252),Q·f值与密度的关系较复杂.添加1%的v2O5,将Mg4Nb2O9陶瓷的烧结温度降低到了1050℃,得到了εr=12.72,Q·f=151040GHz的优异性能. 相似文献
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研究了CuO-B2O3助剂对Ba4Sm9.33Ti18O54陶瓷的烧结性能和介电性能的影响,结果表明:通过共添加CuO-B2O3助剂(CB),陶瓷的烧结温度可以从1350℃降低到1050℃左右,当CB添加量达到10%时,产生第二相Ba2Cu(BO3)2,研究了CB的添加,对介电性能的影响,当CB的添加量为1wt%时,有以下微波介电性能ε=62.7,Q·f=4 270 GHz,τf=-11.1 ppm/℃. 相似文献
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以Bi2O3和SiO2为原料,利用NaCl-Na2SO4熔盐系统,在850℃保温3 h制成粉体样品,使用XRD对粉体物相进行表征,确定粉体为纯的Bi4Si3O12,然后将该粉体压片烧成Bi4Si3O12陶瓷.通过SEM和阻抗分析仪对陶瓷微观形貌和介电性能进行了分析,研究烧成温度、保温时间对硅酸铋陶瓷介电性能的影响.研究... 相似文献
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BNT(BaO-Nd2O3-TiO2)系统陶瓷是一种介电性能优良的陶瓷材料.在BNT中添加一定量的Bi2O3,可以得到介电性能更优的BNBT(BaO-Nd2O3-Bi2O3 -TiO2)陶瓷.该文分别研究了球磨时间、烧结温度和保温时间对BNBT陶瓷介电性能的影响.结果表明:当球磨时间为10 h、烧结温度为1160 ℃、保温时间为9 h时,BNBT陶瓷的介电性能为:介电常数ε=99.8281,介电损耗tanδ=2.65×10-4,介电常数温度系数αε≤±30 ppm/℃. 相似文献
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主要研究了不同Sm掺杂浓度对Ba4La19.33Ti18O54陶瓷的微波介电性能和微观结构的影响。首先利用常规固相反应技术制备了Sm含量y分别为0.0,0.1,0.3,0.5和0.7的五种Ba4(La1-ySmy)9.33Ti18O54陶瓷样品;室温下在0.3~3.0GHz频率范围内,利用网格分析仪测量了这些样品的介电常数和介电损耗因子;结果表明随着Sm掺杂含量的增大,样品介电损耗明显减小,而介电常数只有微小减少。当Sm掺杂含量y=0.5时,样品的介电性能最好。此外,还利用X射线衍射仪和扫描电子显微镜研究了样品的微观结构及随微波介电性能的变化。 相似文献
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《Ceramics International》2022,48(20):29614-29619
In the 5G era, the dielectric materials used in microwave electronic components must have not only have good microwave dielectric characteristics but also excellent structural characteristics. Li2MgTi3O8 (LMT) ceramics have excellent microwave dielectric properties; however, their low bending strength limits their further applications in the 5G era. In this work, the dielectric properties and bending strength of LMT ceramics were optimized by the addition of Si3N4 reinforcing phase using a solid-phase method, and the effects of Si3N4 addition on the sintering properties, microscopic structure, crystalline phase, dielectric properties and bending strength of ceramics were investigated. The X-ray diffraction pattern indicates that all ceramics exhibit spinel structure. Combined with the phenomenon of grain reduction in the SEM graph, it indicates that the addition of Si3N4 can inhibit the grain growth and achieve the purpose of fine-grain strengthening. The dispersion enhancement of second phase particles is also one of the reasons for the increase of bending strength. LMT ceramics doped with 0.5 wt% Si3N4 exhibited the maximum bending strength after sintering at 1050 °C for 4 h, which was 76.97% higher than that of pure LMT ceramics. In addition, the ceramics exhibited outstanding dielectric properties: a dielectric constant of 23.20, quality factor of 49344 GHz, and temperature coefficient of ?5.90 ppm/°C. The high bending strength and good microwave dielectric properties indicate that Si3N4-added LMT ceramics can be effectively applied in the 5G era. 相似文献
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本文利用固态反应法制备了CaCu3-xMnxTi4O12(x=0,0.2,0.4,0.6,0.8,1.0)陶瓷,并分析探讨了MnO添加量对其介电性能的影响。研究结果表明,MnO的添加有助于CaCu3Ti4O12相生成,且在高MnO添加的情况下所得陶瓷晶粒尺寸较小。MnO的添加对CaCu3Ti4O12的介电性能有非常不好的影响,少量的添加就会导致其介电常数由10000多降至只有数百。在1000Hz前MnO的添加会使陶瓷的介电损耗大幅上升,这表明MnO添加有降低电阻的效果。 相似文献
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Microwave dielectric properties of low temperature fired Ba5Nb4O15 ‐ BaWO4 ceramics supplemented with their own nanoparticles for LTCC applications
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Chikkala Anil Kumar Dobbidi Pamu 《International Journal of Applied Ceramic Technology》2017,14(2):191-199
Polycrystalline Ba5Nb4O15 (BNO) ‐ BaWO4 (BWO) composite ceramics are prepared by adding their own nanoparticles as a sintering aid. The prepared samples exhibited the maximum relative density of 98.2% at 900°C. The complex dielectric response of these composite ceramics are analysed by Havriliak ‐ Negami (HN) equation. The BNO ‐ BWO composite added with x=3 wt% of their nanoparticles, fired at 900oC displayed the best microwave dielectric properties; εr=39 and Q×f0=59.8 THz at 9.44 GHz. The obtained results of BNO ‐ BWO composite makes this material as a potential candidate for LTCC applications. 相似文献
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Linsheng Sheng Xin Du Qingyuan Chao Peng Zheng Wangfeng Bai Lili Li Fei Wen Wei Wu Liang Zheng 《Ceramics International》2018,44(15):18316-18321
Lead-free piezoelectric material with excellent piezoelectric properties and high Curie temperature is necessary for practical applications. In this work, (Nd, Ce) co-doped CaBi4Ti4O15 (CBT) ceramics were prepared by the conventional solid-state reaction technique. The effect of (Nd, Ce) co-doping on the structure and resulting electrical properties of CBT ceramics was systematically investigated. The optimized comprehensive performances were obtained at x?=?0.075 with a large piezoelectric coefficient (19 pC/N), a low dielectric loss (0.073%) and a high Curie temperature (794?°C). More importantly, the ceramic also maintained a very high resistance and a low dielectric loss even at 400?°C (ρ?=?2.5?×?108 Ω?cm, tan δ?=?1.96%) and the d33 showed no sign of waning after annealed at 400?°C, which shows great potential for high temperature piezoelectric device applications. Related mechanisms for the enhancement of electrical properties were discussed. 相似文献
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Ba2Ti3Nb4O18是BaO-TiO2-Nb2O5体系中一种新型的介质材料,具有优良的微波介电性能.为满足低温共烧陶瓷技术(low temperature cofired ceramics,LTCC)对微波介质陶瓷材料的低温烧结要求,实现在900℃与银电极共烧,添加了质量分数为5%的ZnO-B2O3玻璃作助融剂,并研究了机械球磨时间对粉料粒径、陶瓷样品的烧结密度、显微结构和介电性能的影响.机械球磨6h的粉体粒径适中(约90nm),用该粉料制备的陶瓷样品可以在900℃致密烧结(大于理论密度的95%).且高频介电性能为(1MHz下测试):介电常数εt≈36,介电损耗tanδ≈2× 10-4,电容温度系数αc≈2.5×10-6/℃.同时微波介电性能良好:εt=33.3,品质因数和频率的乘积Qf=14274GHz.可与银电极共烧结作为LTCC介质瓷料. 相似文献
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The LiNiPO4 ceramic for the LTCC technology was prepared via the traditional solid-state reaction route and its dielectric properties were investigated for the first time. The best dielectric properties of LiNiPO4 ceramics with a εr of 7.18, Q×f value of 27,754?GHz and τf of ?67.7?ppm/°C were obtained in samples sintered at 825?°C for 2?h. Rietveld refinement was firstly employed to study the crystal structure and dielectric properties of LiNiPO4 ceramics. Unfortunately, the relatively large negative τf was unfavorable to practical applications. Therefore, we introduced TiO2, which possessed a considerable positive τf, to obtain a desired τf value. The prepared LiNiPO4 ceramics with 15?wt% TiO2 sintered at 900?°C for 2?h exhibited excellent dielectric properties of εr~11.49, Q×f~10,792?GHz, τf~?2.8?ppm/°C. The Ag co-fired experiments confirmed the excellent chemical compatibility with LiNiPO4-TiO2 ceramics which might be potential dielectric LTCCs for high frequency applications. 相似文献
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Junqi Chen Weishuang Fang Yifan Zhai Feihu Li Ying Tang Jie Li Huanhuan Guo Liang Fang 《Journal of the European Ceramic Society》2021,41(8):4473-4477
Orthorhombic-structured CaIn2O4 ceramics with a space group Pca21 were synthesized via a solid-state reaction method. A high relative density (95.6 %) and excellent microwave dielectric properties (εr ~11.28, Qf = 74,200 GHz, τf ~ ?4.6 ppm/°C) were obtained when the ceramics were sintered at 1375 °C for 6 h. The dielectric properties were investigated on the basis of the Phillips–Van Vechten–Levine chemical bond theory. Results indicated that the dielectric properties were mainly determined by the InO bonds in the CaIn2O4 ceramics. These bonds contributed more (74.65 %) to the dielectric constant than the CaO bonds (25.35 %). Furthermore, the intrinsic dielectric properties of the CaIn2O4 ceramics were investigated via infrared reflectivity spectroscopy. The extrapolated microwave dielectric properties were εr ~10.12 and Qf = 112,200 GHz. Results indicated that ion polarization is the main contributor to the dielectric constant in microwave frequency ranges. 相似文献