Productive energy in the US economy

In this paper, methods of separation of primary work _EP$E_{\mathrm{P}}$, which is needed to provide the genuine work of production equipment, from the total amount of primary energy E$E$ are proposed. Direct estimates of primary work of production equipment _EP$E_{\mathrm{P}}$ on the base of available data for the US economy for the 20th century are compared with alternative evaluations of the same quantity calculated from time series for consumption of labour and primary energy. The relationship among primary energy E$E$, primary work of production equipment _EP$E_{\mathrm{P}}$, and genuine work of production equipment P$P$ (productive energy) is considered. The results allow one to estimate coefficient of efficiency of primary work of production equipment.     

Second law analysis of forced convection in a circular duct for non-Newtonian fluids

The second law characteristics of fluid flow and heat transfer inside a circular duct under fully developed forced convection for non-Newtonian fluids are presented. Heat flux is kept constant at the duct wall. Analytical expressions for dimensionless entropy generation number (_NS$N_{\mathrm{S}}$), irreversibility distribution ratio (Φ  ), and Bejan number (Be$\mathit{Be}$) are obtained as functions of dimensionless radius (R$R$), Peclet number (Pe$\mathit{Pe}$), modified Eckert number (Ec$\mathit{Ec}$), Prandtl number (Pr), dimensionless temperature difference (Ω  ), and fluid index (m$m$ or n$n$). Spatial distributions of local and average entropy generation number, irreversibility ratio, and Bejan number are presented graphically. For a particular value of fluid index, n=1$n=1$ (or m=2$m=2$), the general entropy generation number expression for a non-Newtonian power-law fluid reduces to the expression for Newtonian fluid as expected. Furthermore, entropy generation minimization is applied to calculate an optimum fluid index (_nEGM$n_{\mathrm{EGM}}$). A correlation is proposed that calculates _nEGM$n_{\mathrm{EGM}}$as a function of group parameter (Ec×Pr/Ω$\mathit{Ec}\times \mathit{Pr}/\Omega$) and Peclet number (Pe$\mathit{Pe}$) within ±5% accuracy. Finally, for some selected fluid indices, the governing equations are solved numerically in order to obtain Nusselt number. It is observed that the numerically obtained asymptotic Nusselt number shows excellent agreement with the analytically obtained Nusselt number.     

Effect of the equivalence ratio,Damköhler number,Lewis number and heat release on the stability of laminar premixed flames in microchannels

The effect of the equivalence ratio on the stability and dynamics of a premixed flame in a planar micro-channel with a step-wise wall temperature profile is numerically investigated using the thermo-diffusive approximation. To characterize the stability behavior of the flame, we construct the stability maps delineating the regions with different flame dynamics in the inlet mass flow rate m   vs. the equivalence ratio ?$?$ parametric space. The flame stability is analyzed for fuels with different diffusivity by changing the Lewis numbers in the range 0.3?_LeF?1.4$0.3?{\mathit{Le}}_F?1.4$. On the other hand, the Lewis number of the oxidizer is kept constant and equal to unity _LeO=1${\mathit{Le}}_O=1$. Our results show that, for very diffusive fuels, the stability of the flame varies significantly with the equivalence ratio, transitioning from stable flames for lean mixtures to highly unstable flames when ?>1$?>1$. As the fuel Lewis number approaches unity, the stability behavior of the flame for lean and rich mixtures becomes more similar to give, in the equidiffusional case _LeF=1${\mathit{Le}}_F=1$, a symmetric stability map around the stoichiometric mixture ?=1$?=1$. In all cases considered, the most stable flames are always found around the stoichiometric mixtures ?=1$?=1$, when the flame instabilities are completely suppressed for very diffusive fuels _LeF<1${\mathit{Le}}_F<1$, or are reduced to a narrow range of inflow velocities for fuel Lewis numbers equal or greater than unity.     

Kinetic study on nonisothermal dehydrogenation of TiH2 powders

The nonisothermal dehydrogenation of TiH₂ powders was studied using thermogravimetry and differential scanning calorimetry. The reaction model was established by estimating the activation energy. The results show the nonisothermal dehydrogenation occurred in a four-step process. The hydrogen released from the TiH_1.5∼2$\text{Ti}{\mathrm{H}}_{1.5\sim 2}$ phase in the first step, which led to the decrease of activation energy. The second step was derived from the formation of βH${\beta }_H$ in δ$\delta$ phase and the reaction model was Phase boundary reaction. In the third step, the hydrogen started to release from the βH${\beta }_H$ phase, and then the βH→αH${\beta }_{\mathrm{H}}\to {\alpha }_{\mathrm{H}}$ phase transformation happened. So the activation energy Eα$E_{\alpha }$ underwent a decrease followed by a quick increase. The fourth step corresponded to the formation of αH${\alpha }_H$ in βH${\beta }_H$ phase, and the slight oxidation resulted in the small fluctuation of activation energy.     

Kinetic characteristics of sodium borohydride formation when sodium meta-borate reacts with magnesium and hydrogen

Sodium borohydride is attracting considerable interests as a hydrogen storage medium. In this paper, we investigated the effects of hydrogen pressure, reaction temperature and transition metal addition on sodium borohydride synthesis by the reaction of sodium meta-borate with Mg and _H2${\mathrm{H}}_2$. It was found that higher _H2${\mathrm{H}}_2$ pressure was beneficial to _NaBH4${\mathrm{NaBH}}_4$ formation. The increase in reaction temperature first improved _NaBH4${\mathrm{NaBH}}_4$ formation kinetics but then impeded it when the temperature was raised to near the melting point of Mg. It was also found that some additions of transition metals such as Ni, Fe and Co in the _NaBO2+Mg+_H2${\mathrm{NaBO}}_2+\mathrm{Mg}+{\mathrm{H}}_2$ system promoted the _NaBH4${\mathrm{NaBH}}_4$ formation, but Cu addition showed little effect. The activation energy of the _NaBH4${\mathrm{NaBH}}_4$ formation from Mg, _NaBO2${\mathrm{NaBO}}_2$ and _H2${\mathrm{H}}_2$ was estimated to be 156.3 kJ/mol _NaBH4${\mathrm{NaBH}}_4$ according to Ozawa analysis method.     

H2 production with ultra-low CO selectivity via photocatalytic reforming of methanol on Au/TiO2 catalyst

_H2${\mathrm{H}}_2$ with ultra-low CO concentration was produced via photocatalytic reforming of methanol on Au/_TiO2$\mathrm{Au}/{\mathrm{TiO}}_2$ catalyst. The rate of _H2${\mathrm{H}}_2$ production is greatly increased when the gold particle size is reduced from 10 to smaller than 3 nm. The concentration of CO in _H2${\mathrm{H}}_2$ decreases with reducing the gold particle size of the catalyst. It is suggested that the by-product CO is mostly produced via decomposition of the intermediate formic acid species derived from methanol. The smaller gold particles possibly switch the HCOOH decomposition reaction mainly to _H2${\mathrm{H}}_2$ and _CO2${\mathrm{CO}}_2$ products while suppress the CO and _H2${\mathrm{H}}_2$O products. In addition, some CO may be oxidized to _CO2${\mathrm{CO}}_2$ by photogenerated oxidizing species at the perimeter interface between the small gold particles and _TiO2${\mathrm{TiO}}_2$ under photocatalytic condition.     

CO2 reforming of CH4 by combination of thermal plasma and catalyst

Experiments on synthesis gas preparation from dry reforming of methane by carbon dioxide with thermal plasma only and cooperation of thermal plasma with commercial catalysts have been performed. In all experiments, nitrogen gas was used as the plasma gas to form a high-temperature jet injected into a tube reactor. A mixture of _CH4${\mathrm{CH}}_4$ and _CO2${\mathrm{CO}}_2$ was fed vertically into the jet. Both kinds of experiments were conducted in the same conditions, such as total flux of feed gases, the molar ratio of _CH4/_CO2${\mathrm{CH}}_4/{\mathrm{CO}}_2$, and the plasma power except with or without catalysts in the tube reactor. Higher conversion of _CH4${\mathrm{CH}}_4$ and _CO2${\mathrm{CO}}_2$, higher selectivity of _H2${\mathrm{H}}_2$ and CO, and higher specific energy of the process were achieved by thermal plasma with catalysts. For example, the conversions of _CH4${\mathrm{CH}}_4$ and _CO2${\mathrm{CO}}_2$ were high to 96.33% and 84.63%, and the selectivies of CO and _H2${\mathrm{H}}_2$ were also high to 91.99% and 74.23%, respectively. Both were 10–20%$10–20\%$ higher than those by thermal plasma only.     

Experimental investigation on the effect of natural gas composition on performance of autothermal reforming

This paper presents experimental study on catalytic autothermal reforming (ATR) of natural gas (NG) for hydrogen (_H2${\mathrm{H}}_2$) production over sulfide nickel catalyst supported on gamma alumina. The experiments are conducted on a cylindrical reactor of 30 mm in diameter and 200 mm in length with “simulated” NG of different composition under thermal-neutral conditions and fed with different molar air to fuel ratio (A/F$A/F$) and molar water to fuel ratio (W/F)$(W/F)$. The results showed that reforming performance is significantly dependent on A/F$A/F$, W/F$W/F$ and concentration of _C2+${\mathrm{C}}_{2+}$ hydrocarbons in inlet fuel. Fuels containing higher _C2+${\mathrm{C}}_{2+}$ hydrocarbons concentration have optimum performance in terms of more _H2${\mathrm{H}}_2$ at higher A/F$A/F$ and W/F$W/F$ but lower conversion efficiency. Good performance for ATR of fuel containing 15%–20% _C2H6${\mathrm{C}}_2{\mathrm{H}}_6$ can be achieved at A/F=5–7$A/F=5–7$ and W/F=4–6$W/F=4–6$, much higher than that for optimum performance of ATR of methane (A/F=3,W/F=2–2.5$A/F=3,W/F=2–2.5$). _CO2${\mathrm{CO}}_2$ in the inlet fuel does not have significant effect on the reversed water–gas shift reaction. Its effect on reforming performance is mainly due to the dilution of inlet fuel and products.     

Measurements and kinetic study on ignition delay times of propane/hydrogen in argon diluted oxygen

Measurements on ignition delay times of propane/hydrogen mixtures in argon diluted oxygen were conducted for hydrogen fractions in the fuel mixtures (XH₂)$\left(X_{{\text{H}}_2}\right)$ from 0 to 100%, pressures of 1.2, 4.0 and 10 atm, and temperatures from 1000 to 1600 K using the shock-tube. Results show that for XH₂$X_{{\text{H}}_2}$ less than 70%, ignition delay time shows a strong Arrhenius temperature dependence and it decreases with the increase of pressure, while for XH₂$X_{{\text{H}}_2}$ larger than 90%, there is a crossover pressure dependence of the ignition delay time with increasing temperature. Numerical studies were made using the selected kinetic mechanisms and results show that the predicted ignition delay time gives a reasonable agreement with the measurements. Both measurements and predictions show that for XH₂$X_{{\text{H}}_2}$ less than 70%, the ignition delay time is only moderately decreased with the increase of XH₂$X_{{\text{H}}_2}$, indicating that hydrogen addition has weak effect on ignition enhancement. Sensitivity analysis reveals the key reactions that control the simulation of ignition delay time. Kinetic study is made to interpret the ignition delay time dependence on pressure and XH₂$X_{{\text{H}}_2}$.     

Effects of bluff-body shape on LPG–H2 jet diffusion flame

The effects of bluff-body lip thickness on the several physical parameters like flame length, radiant fraction, gas temperature and _NOx${\mathrm{NO}}_x$ emissions in liquefied petroleum gas (LPG)–H₂ jet diffusion flame are investigated experimentally. Results indicate that the flame length reduces with the addition of hydrogen in the bluff-body stabilized flame, which can be attributed to the enhanced reactivity and residence time of the mixture gases. Moreover, with increasing lip thickness of the bluff body, the flame length also gets reduced. The soot free length fraction (SFLF) is observed to be enhanced with H₂ addition to the fuel stream. In contrast, the SFLF gets reduced with increasing lip thickness repetition, which is due to the reduced induction period of soot formation. The emission index of _NOx${\mathrm{NO}}_x$ (_EINOx${\mathrm{EINO}}_x$) is found to be attenuated in coaxial burner with hydrogen addition. In contrast it is observed to be enhanced in bluff-body stabilized flame. The former is due to the reduction in residence time of gas mixture, whereas the latter can be explained on the basis of increased flame temperature. Besides this, _NOx${\mathrm{NO}}_x$ emission level is also found to be enhanced with increasing lip thickness due to enhanced residence time.     

Demonstration of sustained hydrogen photoproduction by immobilized,sulfur-deprived Chlamydomonas reinhardtii cells

It was demonstrated that immobilized, sulfur-deprived algal cultures can photoproduce H₂${}_2$. After identifying the optimal material and procedures for immobilization of Chlamyodomonas reinhardtii   at high cell density, we examined the effect of liquid mixing, sulfate content, acetate levels and light intensity on the H₂${}_2$-production activity of the culture. Our results indicate that (a) liquid mixing is important to provide homogeneous conditions for the immobilized culture; (b) sulfur deprivation is necessary for hydrogen production by immobilized cultures; and (c) high light intensity decreases H₂${}_2$ production. The maximum total volume of H₂${}_2$ produced by the system (160 ml of reactor volume) was 380 ml over 23 days, and the highest rate of H₂${}_2$ production observed was 45 ml day^-1${}^{-1}$. Cell immobilization significantly increased the duration of the H₂${}_2$-photoproduction phase (up to 4 weeks), maintained specific rates of H₂${}_2$ photoproduction similar to those of suspension cultures and showed potential for large increases in H₂${}_2$ production.     

Nanostructured hematite for photoelectrochemical generation of hydrogen

With the advent of nanotechnology there has been a resurge of interest in α$\alpha$-Fe₂O₃, as suitable candidate for photoelectrochemical (PEC) splitting of water to generate hydrogen. This paper describes the enhanced PEC behaviour of nanostructured α$\alpha$-Fe₂O₃ thin films modified by various techniques. Nanostructured thin film/pellets of α$\alpha$-Fe₂O₃ prepared by various techniques and various dopants were investigated for their photoelectrochemical response. Thin films prepared by spray pyrolysis having particle size of 20–30 nm exhibited better photoresponse as compared to the films prepared by sol–gel methods, which further improved on doping with Zn. These films were further modified by (i) depositing Zn dots on the surface of α$\alpha$-Fe₂O₃ films using thermal evaporation method and (ii) irradiating it with 170 MeV Au¹³⁺${\mathrm{Au}}^{13+}$ ions. When used as electrode in photoelectrochemical cell, a significant increase in the photoresponse of these modified films were observed, details of which are discussed.     

Intake charge dilution effects on control of nitric oxide emission in a hydrogen fueled SI engine

Though hydrogen fueled spark ignition engine can operate at high thermal efficiency with almost zero emission of HC and CO, the high level of _NOx${\mathrm{NO}}_x$ poses problems. The high combustion temperature and lean mixtures used are the reasons. In this work, the effect of _N2${\mathrm{N}}_2$, _CO2${\mathrm{CO}}_2$ and hot EGR gas as diluents in the intake charge to suppress NO emission in a manifold injected hydrogen fueled SI engine was studied. Nitrogen as a diluent is not so effective at low loads while inducting smaller amounts, but very effective at higher loads where the mixture becomes richer and the dilution effect (oxygen depletion) is significant. On other hand, carbon dioxide is a good diluent with relatively better thermal effect and diluent effect and effectively controls NO emission at all output regions. However this is at the expense of thermal efficiency. Recirculating hot exhaust gas which contains both _N2${\mathrm{N}}_2$ and steam comes in between _N2${\mathrm{N}}_2$ and _CO2${\mathrm{CO}}_2$ in terms of its effectiveness. On the whole _N2${\mathrm{N}}_2$ is the most effective as it has minimum impact on thermal efficiency for a given level of permissible NO emission. Thus it is felt that cold EGR could be a good option. In all cases, a good control system is necessary to supply correct quantity of diluent.