XeCl Excimer laser annealing used in the fabrication of poly-Si TFT's

Mo-gate n-channel poly-Si thin-film transistors (TFT's) have been fabricated for the first time at a low processing temperature of 260°C. A 500-1000-A-thick a-Si:H was successfully crystallized by XeCl excimer laser (308nm) annealing without heating a glass substrate. TFT's were fabricated in the crystallized Si film. The channel mobility of the TFT was 180cm²/V.s when the a-Si:H was crystallized by annealing with a laser having an energy density of 200 mJ/cm². This result shows that high-speed silicon devices can be fabricated at a low temperature using XeCl excimer laser annealing.     

A poly-Si TFT fabricated by excimer laser recrystallization onfloating active structure

This letter reports a. new excimer laser annealing (ELA) method to produce large polycrystalline silicon (poly-Si) lateral grains exceeding 4 μm. A selectively floating amorphous silicon (a-Si) flint with a 50 nm-thick air-gap was irradiated by a single-pulse XeCl excimer laser and uniform lateral grains were grown due to the lateral thermal gradient caused by the low thermal conductivity of the air. A poly-Si thin-film transistor (TFT) with two high-quality 4.6 μm-long lateral grains was fabricated by employing the proposed ELA and high field-effect mobility of 331 cm²/Vsec was obtained due to. the high-quality grain structure     

High performance poly-Si TFTs fabricated using pulsed laserannealing and remote plasma CVD with low temperature processing

Key technologies for fabricating polycrystalline silicon thin film transistors (poly-Si TFTs) at a low temperature are discussed. Hydrogenated amorphous silicon films were crystallized by irradiation of a 30 ns-pulsed XeCl excimer laser. Crystalline grains were smaller than 100 nm. The density of localized trap states in poly-Si films was reduced to 4×10¹⁶ cm^-3 by plasma hydrogenation only for 30 seconds. Remote plasma chemical vapor deposition (CVD) using mesh electrodes realized a good interface of SiO ₂/Si with the interface trap density of 2.0×10¹⁰ cm^-2 eV^-1 at 270°C. Poly-Si TFTs were fabricated at 270°C using laser crystallization, plasma hydrogenation and remote plasma CVD. The carrier mobility was 640 cm²/Vs for n-channel TFTs and 400 cm²/Vs for p-channel TFTs. The threshold voltage was 0.8 V for n-channel TFTs and -1.5 V for p-channel TFTs. The leakage current of n-channel poly-Si TFTs was reduced from 2×10^-10 A/μm to 3×10^-13 A/μm at the gate voltage of -5 V using an offset gate electrode with an offset length of 1 μm     

KrF excimer laser annealed TFT with very high field-effect mobilityof 329 cm2/V-s

A thin-film transistor (TFT) with a maximum field-effect mobility of 320 cm²/V-s, an on/off current ratio of 7.6×10⁷ , a threshold voltage of 6.7 V and a subthreshold slope of 0.37 V/decade was fabricated by using pulse laser annealing processes. Amorphous silicon films (a-Si:H) with a very low impurity concentration of 4×10¹⁸ cm^-3 for oxygen, 1.5×10¹⁸ cm^-3 for carbon, and 2×10¹⁷ cm^-3 for nitrogen were deposited by a plasma chemical vapor deposition (CVD) method and annealed by KrF excimer laser (wavelength of 248 nm). The Raman spectroscopy technique was a useful tool for optimizing laser annealing conditions. Experimental results show that two factors are very important for fabricating very-high mobility TFTs: (1) utilizing high-purity as-deposited a-Si:H film; and (2) performing whole laser annealing processes sequentially in a vacuum container and optimizing illumination conditions     

An investigation of laser annealed and metal-induced crystallizedpolycrystalline silicon thin-film transistors

We report results on thin-film transistors (TFTs) made from a new hybrid process in which amorphous silicon (a-Si) is first converted to polycrystalline silicon (poly-Si) using Ni-metal-induced lateral crystallization (MILC), and then improved using excimer laser annealing (laser MILC or L-MILC). With only a very low shot laser process, we demonstrate that laser annealing of MILC material can improve the electron mobility from 80 to 170 cm²/Vs, and decrease the minimum leakage current by one to two orders of magnitude at a drain bias of 5 V. Similar trends occur for both p- and n-type material. A shift in threshold voltage upon laser annealing indicates the existence of a net positive charge in Ni-MILC material, which is neutralised upon laser exposure. The MILC material in particular exhibits a very high generation state density of ~10¹⁹ cm^-3 which is reduced by an order of magnitude in L-MILC material. The gate and drain field dependences of leakage current indicate that the leakage current in MILC transistors is related to this high defect level and the abruptness of the channel/drain junction. This can be improved with a lightly doped drain (LDD) implant, as in other poly-Si transistors     

A new polycrystalline silicon TFT with a single grain boundary inthe channel

A new excimer laser annealing method, which results in large lateral polysilicon grains exceeding 1.5 μm, has been proposed and polycrystalline silicon thin film transistors (poly-Si TFTs) with a single grain boundary in the channel have been successfully fabricated. The proposed method employs a lateral grain growth phenomenon obtained by excimer laser irradiation on an amorphous silicon layer with pre-patterned aluminum film. The aluminum patterns act as a masking layer of the incident laser beam for the selective melting of the amorphous silicon layer. Uniform and large grains are obtained near the edge of the aluminum patterns. When two aluminum patterns are separated by a 2 μm space, the solidified region (i.e., poly-Si channel) exhibits a single grain boundary. The n-channel poly-Si TPT fabricated by the proposed method shows considerably improved I-V characteristics, such as high field effect mobility exceeding 240 cm²/Vs     

Low temperature poly-Si thin-film transistor fabrication bymetal-induced lateral crystallization

A new low temperature crystallization method for poly-Si TFTs was developed: Metal-Induced Lateral Crystallization (MILC). The a-Si film in the channel area of a TFT was laterally crystallized from the source/drain area, on which an ultrathin nickel layer was deposited before annealing. The a-channel poly-Si TFTs fabricated at 500°C by MILC showed a mobility of 121 cm²/V·s, a threshold voltage of 1.2 V, and an on/off current ratio of higher than 10⁶ . These electrical properties are much better than TFTs fabricated by conventional crystallization at 600°C     

Fabrication of high-mobility p-channel poly-Si thin filmtransistors by self-aligned metal-induced lateral crystallization

High-mobility p-channel poly-Si TFTs were fabricated using a new low-temperature process (⩽500°C): self-aligned metal-induced lateral crystallization (MILC). With a one-step annealing at 500°C, activation of dopants in source/drain/gate a-Si films as well as the crystallization of channel a-Si films was achieved. The TFTs showed a threshold voltage of -1.7 V, and an on/off current ratio of ~10⁷ without post-hydrogenation. The mobility was measured to be as high as 90 cm²/V·s, which is two to three times higher than that of the poly-Si TFTs fabricated by conventional solid-phase crystallization at around 600°C     

Inverse staggered poly-Si and amorphous Si double structure TFT'sfor LCD panels with peripheral driver circuits integration

Inverse staggered polycrystalline silicon (poly-Si) and hydrogenated amorphous silicon (a-Si:H) double structure thin-film transistors (TFT's) are fabricated based on the conventional a-Si:H TFT process on a single glass substrate. After depositing a thin (20 nm) a-Si:H using the plasma CVD technique at 300°C, Ar⁺ and XeCl (300 mJ/cm²) lasers are irradiated successively, and then a thick a-Si:H (200 nm) and n⁺ Si layers are deposited again. The field effect mobilities of 10 and 0.5 cm ²/V·s are obtained for the laser annealed poly-Si and the a-Si:H (without annealing) TFT's, respectively     

Improvement of electrical characteristics for fluorine-ion-implanted poly-Si TFTs using ELC

The fluorine ion implantation applied to the polycrystalline silicon thin-film transistors (poly-Si TFTs) is investigated in this letter. Experimental results have shown that fluorine ion implantation effectively minimized the trap state density, leading to superior electrical characteristics such as high field-effect mobility, low threshold voltage, and high ON/OFF current ratio. Furthermore, the fluorine ions tended to segregate at the interface between the gate oxide and poly-Si layers during the excimer laser annealing, even without the extra deposition of pad oxide on the poly-Si film. The presence of fluorine obviously enhanced electrical reliability of poly-Si TFTs.     

High performance poly-crystalline silicon thin film transistorsfabricated using remote plasma chemical vapor deposition of SiO2

A remote plasma chemical vapor deposition (RPCVD) of SiO₂ was investigated for forming an interface of SiO₂/Si at a low temperature below 300°C. A good SiO₂/Si interface was formed on Si substrates through decomposition and reaction of SiH₄ gas with oxygen radical by confining plasma using mesh plates. The density of interface traps (D_it) was as low as 3.4×10¹⁰ cm^-2eV^-1. N- and p-channel Al-gate poly-Si TFTs were fabricated at 270°C with SiO₂ films as a gate oxide formed by RPCVD and laser crystallized poly-crystalline films formed by a pulsed XeCl excimer laser. They showed good characteristics of a low threshold voltage of 1.5 V (n-channel) and -1.5 V (p-channel), and a high carrier mobility of 400 cm²/Vs     

Fabrication of SOS MOSFETs using two-step doping with excimer laser

Using two-step doping with excimer laser, p-channel MOSFETs were fabricated in thin silicon films on sapphire (SOS). Source and drain p ⁺ layers were formed using two-step doping with only one melting pulse of excimer laser. Devices were processed at room temperature except for the LPCVD gate oxide deposition at 450°C. High-quality thin film transistors (TFTs) were fabricated with on/off current ratio of 7 and a field effect hole mobility of 145 cm²/V s     

High-mobility poly-Si TFTs fabricated on flexible stainless-steelsubstrates

High mobility polycrystalline Si thin-film transistors (poly-Si TFTs) are firstly fabricated on flexible stainless-steel substrates 100 μm thick through low-temperature processes where both active Si and gate SiO₂ films are deposited by glow-discharge sputtering and the Si films are crystallized by KrF excimer laser irradiation. The gate SiO₂ films are sputter-deposited in oxygen atmosphere from the SiO₂ target. Resulting poly-Si TFTs show excellent characteristics of mobility of 106 cm²/V·s and drain current on-off ratio of as high as 1×10⁶. Thus, the poly-Si TFTs are very promising for realizing novel flat panel displays of lightweight and rugged LCDs and LEDs     

Excimer-laser crystallized poly-Si TFT's with transparent gate

A new poly-crystal silicon thin-film transistor (poly-Si TFT) with a transparent bottom-gate electrode has been fabricated by XeF excimer-laser light irradiation from the glass substrate side. Compared with poly-Si TFTs made by XeF or ArF excimer-laser light irradiation to the top Si surface, the new TFT shows a higher electron mobility of about 100 cm²/Vs, independent of the Si film thickness. Therefore, poly-Si driver TFTs and amorphous-silicon (a-Si) TFTs for the matrix can be formed with the same channel-etch type bottom-gate structure simultaneously on the same glass substrate by using the same starting materials. This is expected to open the way for making driver monolithic and active matrix liquid crystal displays     

A high-performance multichannel dual-gate poly-Si TFT fabricated by excimer laser irradiation on a floating a-Si thin film

A new excimer laser annealing (ELA) process that uses a floating amorphous-Silicon (a-Si) thin film with a multichannel structure is proposed for high-performance poly-Si thin-film transistors (TFTs). The proposed ELA method produces two-dimensional (2-D) grain growth, which can result in a high-quality grain structure. The dual-gate structure was employed to eliminate the grain boundaries perpendicular to the current flow in the channel. A multichannel structure was adapted in order to arrange the grain boundary to be parallel to the current flow. The proposed poly-Si TFT exhibits high-performance electrical characteristics, which are a high mobility of 504 cm/sup 2//Vsec and a low subthreshold slope of 0.337 V/dec.     

High-performance poly-Si TFTs made by Ni-mediated crystallization through low-shot laser annealing

High-performance polycrystalline silicon (poly-Si) thin-film transistors (TFTs) have been fabricated using metal-induced crystallization followed by laser annealing (L-MIC). Laser annealing after MIC was found to yield a major improvement to the electrical characteristics of poly-Si TFTs. At a laser fluence of 330 mJ/cm/sup 2/, the field effect mobility increased from 71 to 239 cm/sup 2//Vs, and the minimum leakage current reduced from around 3.0/spl times/10/sup -12/ A//spl mu/m to 2.9/spl times/10/sup -13/ A//spl mu/m at a drain voltage of 5 V. In addition, the dependence of the TFT characteristics on the laser energy density was much weaker than that for conventional excimer laser annealed poly-Si TFTs.     

A novel germanium doping method for fabrication of high-performance p-channel poly-Si/sub 1-x/Ge/sub x/ TFT by excimer laser crystallization

In this letter, a novel process for fabricating p-channel poly-Si/sub 1-x/Ge/sub x/ thin-film transistors (TFTs) with high-hole mobility was demonstrated. Germanium (Ge) atoms were incorporated into poly-Si by excimer laser irradiation of a-Si/sub 1-x/Ge/sub x//poly-Si double layer. For small size TFTs, especially when channel width/length (W/L) was less than 2 /spl mu/m/2 /spl mu/m, the hole mobility of poly-Si/sub 1-x/Ge/sub x/ TFTs was superior to that of poly-Si TFTs. It was inferred that the degree of mobility enhancement by Ge incorporation was beyond that of mobility degradation by defect trap generation when TFT size was shrunk to 2 /spl mu/m/2 /spl mu/m. The poly-Si/sub 0.91/Ge/sub 0.09/ TFT exhibited a high-hole mobility of 112 cm/sup 2//V-s, while the hole mobility of the poly-Si counterpart was 73 cm/sup 2//V-s.     

High-mobility poly-Si thin-film transistors fabricated by a novelexcimer laser crystallization method

High-mobility poly-Si thin-film transistors (TFTs) were fabricated by a novel excimer laser crystallization method based on dual-beam irradiation. The new method can reduce the solidification velocity of the top Si layer by heating the bottom Si layer of the Si/SiO₂/Si/glass substrate structure by means of laser irradiation not only from the front side but also from the back side. The grain size of poly-Si film was enlarged up to 2 μm. The field-effect mobilities of the TFT exceeded 380 cm²/V-s for electrons and 100 cm²/V-s for holes     

High-quality polycrystalline Si TFTs fabricated on stainless-steelfoils by using sputtered Si films

We have developed a low-temperature fabrication process (⩽ 200°C for high-quality polycrystalline Si thin-film transistors (poly-Si TFTs) on flexible stainless-steel foils. The fabrication processes is realized through sputter deposition of thin films, including active-Si and gate-SiO₂ films, crystallization of Si films by KrF excimer laser irradiation, and inductively coupled plasma hydrogenation. High-quality n- and p-channel poly-Si TFTs are successfully fabricated without suffering from problems of substrate bending, film ablation, or cracking in films. The resulting n- and p-channel poly-Si TFTs showed mobilities of 106 and 122 cm²/V·s, respectively. This paper describes the deposition and properties of the sputtered Si films and the fabrication process and electrical characteristics of the poly-SiTFTs     

A high performance thin-film transistor using a low temperaturepoly-Si by silicide mediated crystallization

Electric field enhanced silicide mediated crystallization (SMC) was introduced for low-temperature polycrystalline silicon thin-film transistors (TFTs) on glass substrates. The amorphous silicon (a-Si) film having an average Ni thickness of 0.15 Å, was completely crystallized at a temperature of 480°C within 30 min in the presence of an electric field of 40 V/cm. The poly-Si is composed of needlelike crystallites with a few μm length and about 50 nm width. The poly-Si TFT using the SMC exhibited a field effect mobility of 86 cm²/Vs, a threshold voltage of -0.6 V, and a subthreshold slope of 0.6 V/dec