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聚合物熔体在异型材三维动态挤出口模内的停留时间分布 总被引:1,自引:1,他引:1
利用ANSYS软件对受口模入口处周期性振动的压力驱动的聚合物熔体在“Y”形和“L”形异型材挤出口模内的停留时间分布进行了数值模拟。设熔体流动为三维等温广义牛顿幂律流动,在求得速度场后,应用路线示踪法跟踪流场中任一粒子的流动轨迹,进而求得熔体在口模中的停留时间分布。通过改变振动参数再重复计算,总结出振动参数对停留时间分布的影响规律。结果表明:压力的振动能有效地缩短熔体在口模内的停留时间,振幅和频率越高则停留时间越短,而且在靠近口模流道壁面处停留时间的缩短最明显,表明振动的引入可以降低壁面附近的流动阻力,使截面上的流速更平稳,从而改善挤出制品的表观质量。 相似文献
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介绍了立式液压振动注射机的工作原理。在立式液压振动注射机上进行振动参数不同的注射成型实验,制取线性低密度聚乙烯(LLDPE)圆盘试样。利用自制的压力传感器及数据采集系统对脉动压力注射过程中的充模压力进行实时采集。实验结果表明,充模压力的波动频率与柱塞杆的振动频率相同;随着柱塞杆振动频率、振幅的增大,充模压力的波动幅度增大,平均充模压力也增大,模腔最大压力也增大。 相似文献
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振动场作用下聚合物熔体在异型材挤出口模内的前沿推进跟踪 总被引:2,自引:0,他引:2
利用ANSYS软件对受口模入口处周期性振动的压力驱动的非牛顿幂律聚合物熔体在“L”形异型材挤出口模内的前沿推进过程进行了三维等温数值模拟。求得不同时刻熔体前沿位置,从而得到熔体前沿推进过程。通过改变振动参数而重复计算,总结出振动参数对前沿推进的影响规律。结果表明:在入口压力的振幅恒定时,其振频越高,则熔体前沿移动越快;在振频恒定时,随着振幅的提高,熔体前沿的推进则先变慢后变快。 相似文献
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建立了同向旋转三螺杆挤出机计量段实际流道真实尺寸的三维非牛顿模型,利用ANSYS软件中的FLOTRAN CFD分析功能对该流场进行数值模拟,分析了振动力场作用下挤出机计量段内的黏度分布、压力分布、速度分布以及振幅对流量的影响,同时与无振动状态的挤出特性进行了比较。研究结果表明:振动力场的引入使熔体黏度和流量呈周期性变化,熔体黏度降低,螺棱两侧压差随振幅增大而增大,剪切作用增强,分散性混合能力和分布性混合能力提高。 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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D. G. Gordeev L. F. Gudarenko M. V. Zhernokletov V. G. Kudel’kin M. A. Mochalov 《Combustion, Explosion, and Shock Waves》2008,44(2):177-189
A semi-empirical equation of state for metals is described. Its capabilities are demonstrated by the example of the equation
of state for aluminum. New experimental data are presented on the location of the isentrope of aluminum for unloading from
the state at p = 229.71 GPa on the shock adiabat to an aerogel (SiO2) of density 0.08 g/cm3.
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Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 2, pp. 61–75, March–April, 2008. 相似文献
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Jorge Marcelo Romero Soledad Bustillo Hugo Enrique Ramirez Maisuls Nelly Lidia Jorge Manuel Eduardo Gómez Vara Eduardo Alberto Castro Alicia H. Jubert 《International journal of molecular sciences》2007,8(7):688-694
A thermochemical rather simple experimental technique is applied to determine the enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented with suitable theoretical calculations at the semiempirical and ab initio levels. A particular satisfactory agreement between both ways is found for the ab initio calculation at the 6–311G basis This set level. Some possible extensions of the present procedure are pointed out. 相似文献
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The objective of the study was to explore the effect of the degree of deacetylation (DD) of the chitosan used on the degradation rate and rate constant during ultrasonic degradation. Chitin was extracted from red shrimp process waste. Four different DD chitosans were prepared from chitin by alkali deacetylation. Those chitosans were degraded by ultrasonic radiation to different molecular weights. Changes of the molecular weight were determined by light scattering, and data of molecular weight changes were used to calculate the degradation rate and rate constant. The results were as follows: The molecular weight of chitosans decreased with an increasing ultrasonication time. The curves of the molecular weight versus the ultrasonication time were broken at 1‐h treatment. The degradation rate and rate constant of sonolysis decreased with an increasing ultrasonication time. This may be because the chances of being attacked by the cavitation energy increased with an increasing molecular weight species and may be because smaller molecular weight species have shorter relaxation times and, thus, can alleviate the sonication stress easier. However, the degradation rate and rate constant of sonolysis increased with an increasing DD of the chitosan used. This may be because the flexibilitier molecules of higher DD chitosans are more susceptible to the shear force of elongation flow generated by the cavitation field or due to the bond energy difference of acetamido and β‐1,4‐glucoside linkage or hydrogen bonds. Breakage of the β‐1,4‐glucoside linkage will result in lower molecular weight and an increasing reaction rate and rate constant. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3526–3531, 2003 相似文献