Adherent Carbon Coatings on Quartz

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Numerical Simulation of Damage and Fracture on Typical Interfaces of Plasma Sprayed Thermal Barrier Coatings

Modern thermal barrier coatings (TBC) are required to not only limit heat transfer through the coating but to also protect engine components from thermal cyclic load and oxidation. Failure mechanism of TBC is important for the safety status of components. To obtain a better understanding of the failure mechanism under thermal cyclic load, a new type of interface elements with three nodes which is based on the idea of interface damage mechanics was proposed. Compared with traditional interface elements, thes...     

Thermal Spray Coatings Engineered from Nanostructured Ceramic Agglomerated Powders for Structural,Thermal Barrier and Biomedical Applications: A Review

Thermal spray coatings produced from nanostructured ceramic agglomerated powders were tailored for different applications, some of which required almost completely opposite performance characteristics (e.g., anti-wear and abradable coatings). The influence of nanostructured materials on important areas, such as, thermal barrier coatings (TBCs) and biomedical coatings was also investigated. It was determined that by controlling the distribution and character of the semi-molten nanostructured agglomerated particles (i.e., nanozones) embedded in the coating microstructure, it was possible to engineer coatings that exhibited high toughness for anti-wear applications or highly friable for use as abradables, exhibiting abradability levels equivalent to those of metallic-based abradables. It is shown that nanozones, in addition to being very important for the mechanical behavior, may also play a key role in enhancing and controlling the bioactivity levels of biomedical coatings via biomimetism. This research demonstrates that these nanostructured coatings can be engineered to exhibit different properties and microstructures by spraying nanostructured ceramic agglomerated powders via air plasma spray (APS) or high velocity oxy-fuel (HVOF). Finally, in order to present readers with a broader view of the current achievements and future prospects in this area of research, a general overview is presented based on the main papers published on this subject in the scientific literature.     

热障涂层TGO界面应力分布及裂纹扩展行为的研究进展

热障涂层以其优异的抗氧化? 隔热? 耐腐蚀性而广泛应用于热端部件表面.在超过1000℃高温的服役环境下,外界的氧元素通过陶瓷层扩散到粘接层界面,与其中的金属元素发生氧化反应生成一层热生长高温氧化物(TGO)? 随着服役时间的增加,TGO不断生长,TGO界面产生较大的热应力,导致裂纹的萌生与扩展,使得涂层大面积剥落,因此...     

埋地钢质管道补口材料的选择

介绍了目前国内外运用较多的几种补口材料的性能。阐述了双组分100％固体改性聚氮酯涂料作为一种更为有效的补口材料，所具有的价格低廉及优异的综合性能。     

吸波涂料概述

重点对吸波涂料的吸波机理以及粘结剂和吸收剂种类进行了论述,并对吸波涂料的发展趋势进行了简单描述.     

耐空蚀涂层及其研究进展

螺旋桨、水轮机和水泵等过流部件在高速运转过程中会因空泡腐蚀而损坏,严重时会造成部件提前失效,引发安全事故。所谓空泡腐蚀,是指过流部件附近液体因局部压力下降而引起气泡的形核与长大,当气泡流向高压区时发生溃灭,所产生微射流与冲击波对部件表面造成损伤。目前,在表面制备防护性涂层是部件抵御空蚀损伤较为经济且行之有效的方法。总结了多种国内外用于空蚀防护的涂层材料,并根据抗空蚀原理将其分为两种,一是为通过自身较高的硬度来抵御空泡冲击的高硬度涂层,如大多数的金属、陶瓷材料以及基体的直接硬化改性处理。其中金属涂层及表面硬化改性处理会在抗空蚀领域广泛应用,但仍需要解决腐蚀对空蚀的加剧作用;至于金属陶瓷涂层,热喷涂工艺下的颗粒难以完全熔化,制备的涂层呈现较高的孔隙率,且由于陶瓷颗粒与金属非冶金结合,因此在空蚀的作用下容易剥落。改善金属陶瓷涂层的硬度与韧性,增强涂层与基体间的结合力,降低涂层的孔隙率是未来的研究方向。另外一种是具有良好韧塑性的高弹性涂层,通过吸收空蚀冲击波与微射流的机械冲击能量来延长空蚀孕育期,降低空蚀破坏,如形状记忆合金和聚合物有机涂层。其中有机涂层极大地降低了腐蚀的作用,是未来抗空蚀涂层...     

吸波涂料的研究现状

重点对吸波涂料的种类进行了论述，并对吸波涂料的应用情况和发展趋势进行了简单描述。     

重防腐涂料及其应用

本文简要介绍了重防腐涂装技术、重防腐涂料，列举了一些重防腐涂装的典型实例。     

绿色防腐涂料的研究与发展

由于环保和节约资源的需要,一些具有环境友好性、使用安全性的绿色防腐涂料逐渐成为研究热点。本文对几种绿色防腐涂料(高固体分涂料、水性涂料、粉末涂料及辐射固化涂料)进行简要介绍,并展望了绿色防腐涂料的发展方向。     

Quality Considerations for the Evaluation of Thermal Spray Coatings

Revealing the true structural and mechanical properties is of utmost importance for the optimized use of thermal sprayed coatings. Only the true properties can be expected to correlate to the spray parameters. During the recent decade, the gas turbine industry has experienced a focus on the laboratory procedures being the weakest link in a frozen and robust process. This article will show several results indicating that the laboratory procedures are more essential to the evaluation results than the spray parameters themselves. With new and robust laboratory techniques, the true properties of thermal spray coatings are revealed, causing a major problem with respect to the quality standards developed 30-40 years ago. In many cases, these old specifications need updates, which is a difficult task from a cost, time, and quality perspective for OEM’s. Coatings that have been successfully used for almost half a century no longer conform to the specification they were optimized to, because of these new appropriate laboratory techniques and procedures. What is actually meant when stating the following? (1) The coating has 5% porosity; (2) No cracks are allowed; (3) Tensile bond is 50 Mpa; (4) Hardness is 1000 HV; and (5) Coating thickness is 100 μm. This article also initiates a discussion on the measurement inaccuracies, for testing of thermally sprayed coatings, with respect to the commonly used general international standards (such as QS9000, ISO17025, AS9003, and ISO10012), as well as with respect to recommendations from the Six Sigma methodology.     

Gas detonation spray forming of Fe-Al coatings in the presence of interlayer

The present paper reports that gas detonation sprayed (GDS) NiAl and NiCr intermediate layers underneath of the intermetallic Fe-Al type coatings on plain carbon steel substrate form bilayer coating system interacting with external environment and/or metal elements. The interface layers are responsible for hardness, bond strength, thermal stability and adhesive strength of the whole GDS structure. The physical-chemical properties of the intermediate layers, combined with unique, very dense and pore free intermetallic Fe-Al coating obtained from self-decomposing powders resulted in new, beneficial features of the whole GDS structure which became more complex, enabled independent control of its functional properties and considerably reduced negative gradients of stress and temperature influencing the substrate and increasing adhesion strength.The achievement of homogenous and refined structure (comprising of small (< 1 µm) and equiaxed sized grains) creates a thermal barrier based on high-melting point intermetallic phases containing Al₂O₃ ceramics which is responsible for properties of the GDS bilayer coatings. The application properties were investigated and the specific multilayer structure of the GDS coating was analyzed such as the phase composition, the degree of order, grain morphology, the quality of substrate/interlayer/external coating bonds, and first of all the influence of hardness of the NiAl or NiCr intermediate layers on the hardness and thermal stability of the FeAl coating after gas detonation spraying and additional heating at 750 °C and 950 °C for 10 h.     

SiO2气凝胶涂料的制备及应用研究进展

SiO2气凝胶自1931年由美国科学家Kistler制备问世以来,因其热导率低、比表面积大、孔隙率大等优异性能一直被研究者所青睐.随着研究的深入,SiO2气凝胶的制备加工工艺得到了优化,使用性能在一定程度上得到了较大提升,研究方向也从早期的制备、性能研究发展到现在的应用研究.现已研制开发出许多具有特殊功能的全新产品,并通过与其他材料的复合得到性能更优越的SiO2气凝胶复合材料,使其在航天航空、军事、建筑、医学等领域得到越来越广泛的应用.在SiO2气凝胶众多应用领域中,其在涂料中的运用是极为重要的一个分支.针对目前SiO2气凝胶涂料推广应用难等现实情况,先对SiO2气凝胶及其涂料制备过程中存在的主要问题做简要阐述,再将利用SiO2气凝胶在某些方面的突出性质而制成的功能涂料进行分类,并从SiO2气凝胶在各种功能涂料中的作用机理出发,对不同功能的SiO2气凝胶涂料的研究进展情况进行归纳总结,在此基础上,展望了未来SiO2气凝胶涂料的发展方向.     

消失模铸造用超细粉涂料的实验研究

通过实验测试系统研究消失模超细粉涂料流变性能、悬浮性以及透气特性，结果表明，一定粒度范围的超细粉涂料所具有较好的悬浮性、涂挂性与致密性。超细粉涂料在实际中的应用，不仅满足消失模连续生产对涂料的要求，而且提高所生产消失模铸件的表面质量。     

CHT‘2001北京国际热处理展览会技术报告会日程通知

介绍了一种用射频磁控溅射方法制备Ni/Al复合涂层的新工艺,该涂层由30层平均厚度为900nm的Ni层和200nm的Al层交替组合而成,厚约15μm.试验结果表明,由于层间距离较小,而使相界面增加,位错不易滑动,塑变抗力提高;而且该复合涂层能在Ni层和Al层间形成亚稳相(Al9Ni2),层间化合物相的存在,可使涂层的强度、硬度较大幅度地提高.     

消失模铸造涂料的配制和使用

分析了消失模铸造涂料的技术要求、种类及其组成,介绍了消失模水基涂料和醇基涂料的基本配方,阐述了消失模涂料的涂挂和干燥工艺,指出消失模涂料的配制使用是决定铸件品质的关键因素之一。     

水性铝塑复合板涂料的研制

以水性丙烯酸酯树脂为原料,以六甲氧基三聚氰胺树脂作交联剂,配制了不同的水性铝塑复合板涂料.讨论了水性丙烯酸酯树脂的分子量、玻璃化转变温度(Tg)及交联剂的配比对涂膜力学性能和耐水性能的影响.实验结果表明,水性丙烯酸酯的分子量越大,玻璃化转变温度越低,涂膜的柔韧性越好,但其硬度、耐溶剂性能和耐腐蚀性能越差;交联剂的用量在7%左右时,涂膜的耐腐蚀性能最优.     

金刚石复合镀层的研究现状

综述了化学复合镀、复合电沉积法制备金刚石复合镀层的研究现状。阐述了复合镀层制备的机理。应用及制备中存在的主要问题，并为今后的研究提出了建议。     

Tensile Test Specimens with a Circumferential Precrack for Evaluation of Interfacial Toughness of Thermal-Sprayed Coatings

A new testing procedure to evaluate the interfacial toughness of thermal-sprayed coatings has been developed. The newly designed test specimen is a modification of the pin test with an artificially introduced weak interface, which is expected to open up easily under tensile loading and act as a circumferential precrack along the interface between a coating and the substrate. This configuration makes it possible to calculate the stress intensity factor K _Int at the tip of the precrack, which can be expressed as , where σ₀ is the apparent average stress, a the crack length, R the specimen radius, and F _I the geometrical correction function. Finite-element analysis was carried out to calculate the correction function F _I for various values of a/R. In the experiments, the flat surface of a pin was grit-blasted and a ring-shaped area from the periphery was covered with carbon using a pencil and set into a mating dice. SUS316L stainless steel was plasma-sprayed onto the flat surface of the pin and the dice. Then, tensile load was applied to the pin to break the weak interface containing the carbon and finally the unmodified coating-substrate interface. The load required to pull out the pin was measured for various specimen parameters such as a and R. The results indicate that the adhesion of the tested coatings can be represented by interface toughness of 1.9 ± 0.1 MPa m^1/2. As a consequence, this testing procedure can be considered as a viable method to evaluate adhesion of a thermal-sprayed coating on a substrate.     

金属表面耐高温防腐涂料的研究进展

长时间处于高温环境中,金属易发生氧化腐蚀,从而丧失机械性能直至破坏,严重影响了使用效能的发挥。在金属表面涂覆耐高温涂层,因施工简便、成本较低、耐热性能好等优点而获得广泛应用,对于防止材料高温腐蚀、节约资源等具有重要的经济意义。对目前常用的耐高温涂料进行分类,包括有机耐高温涂料和无机耐高温涂料两大类,重点介绍了有机硅树脂耐高温涂料和无机耐高温涂料,并简单描述了有机-无机复合耐高温涂料的有关情况。对不同类别耐高温涂料的化学组成、物理性能和耐热机理等进行了阐述,并结合涂料的结构特点对各自优缺点进行了分析与比较。根据耐高温涂料在现代工业发展中的重要作用,介绍了国内外关于耐高温涂料的研究进展和应用情况,指出了不同类别耐高温涂料在使用过程中存在的问题。最后结合当前工业社会向信息化社会转变的时代背景以及研究耐高温涂层的技术意义,对耐高温涂料的发展趋势进行了展望。