共查询到20条相似文献,搜索用时 78 毫秒
1.
2.
3.
研究制备中空纤维纳滤复合膜的机器化设备-涂敷机.涂敷机应用可编程控制器(PLC)来控制喂丝辊、干燥管、反应管、受丝辊等各个部件,对喷淋时间、卷绕速度、有机相浓度等因素进行控制.试验以截流分子量为20000的聚砜中空纤维超滤膜为基膜,哌嗪水相浓度质量分数为2.0%,均苯三甲酰氯有机相浓度质量分数为0.5%,水相处理时间为40min,涂敷装置的卷绕速度控制在1.356m·min~(-1),界面反应温度控制在45℃,能够连续制备性能优良的中空纤维复合膜.以质量分数0.2%的硫酸镁水溶液,在0.4MPa下测试膜的性能,其脱盐率91.85%,通量30.08L·m~(-2)·m~(-2)h~(-1). 相似文献
4.
5.
6.
现阶段国内纳滤膜的制备方法主要集中在相转化法和复合法。由于技术的限制,中空纤维纳滤膜的制备还处于实验室阶段。本文主要介绍了现阶段国内中空纤维纳滤膜的制备方法,以及国外中空纤维纳滤膜制备新方法——共挤出一步成型技术。 相似文献
8.
9.
10.
以新型杂萘联苯聚醚砜酮(PPESK)为膜材料,N-甲基-2-吡咯烷酮(NMP)为溶剂,乙二醇甲醚(EGME)、冰醋酸(AA)以及AA/EGME作为复合添加剂,采用干-湿相转化技术制备了中空纤维非对称纳滤膜,重点考察了非溶剂添加剂对中空纤维膜结构和性能的影响。结果表明非溶剂添加剂的加入导致了中空纤维膜孔结构由指状转变为海绵状,从而引起中空纤维膜性能的变化。当聚合物质量分数为23%,铸膜液溶剂体系为m(AA)∶m(EGME)∶m(NMP)=5.7∶16.5∶54.8时,中空纤维膜对PEG600的截留率高于96%,纯水通量为211 L/(m2.h)。 相似文献
11.
New asymmetric hollow fiber reverse osmosis (RO) membrane was developed from a new chlorine‐resistant copolyamide [4T‐PIP(30)] with a piperazine moiety by a conventional phase‐separation method. The new 4T‐PIP(30) hollow fiber membrane has the same low‐pressure RO performance as cellulose triacetate hollow fiber membrane (FR = 205 L/m2 day, Rj = 99.6%) and superior chlorine resistance as well as pH resistance to conventional aramid RO membranes. Structural analysis and viscoelastic study revealed that the new hollow fiber consisted of a top skin, dense layer, and microporous layer, and that it began to decrease its elasticity at 80°C in water, which is possibly related to its good and stable RO performance around room temperature. Several kinds of RO modules were made from the new hollow fiber membranes, for which RO performances were stable for 2 years in chlorinated feed water desalination (the free residual chlorine ranged from 0.l to 1.1 mg/L). © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 79: 517–527, 2001 相似文献
12.
13.
14.
Carlos Echaide-Górriz Magdalena Malankowska Carlos Téllez Joaquín Coronas 《American Institute of Chemical Engineers》2020,66(6):e16970
The inner and outer surfaces of a porous hollow fiber polysulfone support are compared as substrates for the synthesis of polyamide thin-film composite (TFC) membranes by interfacial polymerization. While both surfaces have pores common of microfiltration membranes, the inner surface has a larger pore diameter than the outer surface (2,700 nm compared to 950 nm). The inner TFC membrane showed higher water nanofiltration permeance than the outer (2.20 ± 0.17 compared to 0.13 ± 0.03 L m−2 hr−1 bar−1). This was due to the influence of the porosity and roughness, which were different on both support surfaces. These membranes are interesting because they were synthesized in a hollow fiber support with a high membrane area per volume unit (~6,900 m2/m3) and the substrate used was commercial, which means that the TFC membrane obtained is suitable for industrial application. A mathematical simulation of the nanofiltration run with COMSOL Multiphysics 5.3 software confirmed the experimental trends observed. 相似文献
15.
界面聚合工艺条件对反渗透复合膜性能的影响 总被引:1,自引:2,他引:1
以聚砜超滤膜为支撑膜,间苯二胺(MPD)为水相功能单体,均苯三甲酰氯(TMC)为油相功能单体,通过界面聚合法制备了反渗透复合膜。研究了功能单体浓度、界面聚合反应时间、界面聚合成膜后热处理时间和温度等条件对复合膜分离性能的影响;并对在水相中添加相转移催化剂对复合膜分离性能的影响和相转移催化机理进行了初步探讨。首先在单因素实验条件下确定工艺条件的优化范围,然后经过正交实验得到最佳工艺条件,实验结果表明, 油相中TMC浓度为3 g8226;L-1、水相中MPD浓度为20 g8226;L-1、界面聚合反应时间为30 s、界面聚合成膜后热处理温度为90 ℃、后处理时间15 min时,所制备的反渗透复合膜表现出良好的分离性能,通量达14.91 L8226;m-28226;h-1,截留率为0.951(测试条件: 压力1.6 MPa, 温度25 ℃, NaCl浓度20000 mg8226;L-1);当水相中MPD浓度较低时,加入适量的相转移催化剂,能有效地改善膜的分离性能。 相似文献
16.
The presently used hollow fiber membrane modules consist of a bundle of fibers in a cylindrical polymer or metal shell parallel to the shell axis. The feed solution flows either through the lumen or at the outside parallel to the fibers. This paper compares the performance of these modules with a new transverse flow module where the hollow fibers are positioned perpendicularly to the flow direction. For both types of modules the product costs are calculated for desalination by reverse osmosis and Dextran concentration by ultrafiltration. These calculations are based on literature data. The main conclusion is that the application of the tr‘ansverse flow module is only attractive if the permeation resistance is mainly determined by the hydrodynamics (ultrafiltration) and not attractive if the membrane permeability is the main resistance (reverse osmosis). 相似文献
17.
In this study, reverse osmosis (RO) composite membrane with extra‐thin separation layer was prepared by the interfacial polymerization (IP) of metaphenylene diamine (MPD) with trimesoyl chloride (TMC) on the surface of polysulfone (PS) support membrane. The properties and structures of skin layer of RO composite membranes were characterized by FTIR and SEM, it was found that IP had occurred and the separation layer was formed. The effects of the monomer concentration on membrane flux and salt rejection were investigated, and the optimum concentration of MPD and TMC were 2 and 0.3% (w/v), respectively. To improve flux, the phase‐transfer catalyst was added to the water phase, and the effects were remarkable when the concentration of MPD was low, in which both salt rejection and flux increased by 20% than initial results. When some of the hydrophilic additives such as alcohols and phenols were added into water phase, the flux of the prepared membrane increased from 13.03 to 33.42 L/(m2 h) without loss in salt rejection. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
18.
Shih‐Hsiung Chen Dong‐Jang Chang Rey‐May Liou Ching‐Shan Hsu Shiow‐Shyung Lin 《应用聚合物科学杂志》2002,83(5):1112-1118
Utilizing an interfacial polymerization technique for the preparation of a polymeric composite nanofiltration membrane, both high permeation flux of water and high salt rejection can be achieved. Synthesis conditions, such as concentration of monomer, reaction time, and swelling agent, significantly affected the separation performance of composite membranes. The composite polyamide membrane had a permeation rate of ~2–5 gallon/ft2/day (gfd) and a salt rejection rate of ~94–99% when 2000 ppm aqueous salt solution was fed at 200 psi and 25°C. Also, a higher performance nanofiltration membrane could be prepared by suitably swelling the support matrix in the period of polymerization. The results of various feed concentrations showed that permeate flux decreased with increasing salt concentration in the feed solution. This result may be due to concentration polarization on the surface of polyamide membranes. The separation performance of polyamide membranes showed an almost independent relationship with operation pressure until it was up to 200 psi. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1112–1118, 2002 相似文献
19.
20.
The performance of different nanofiltration (NF) and reverse osmosis (RO) membranes was studied in treating the toxic metal effluent from metallurgical industry. The characteristics and filtration behavior of the processes including the wastewater flux, salt rejection and ion rejection versus operating pressure were evaluated. Then the wastewater flux of RO membrane was compared with theoretical calculation using mass transfer models, and good consistency was observed. It was found that a high rejection rate more than 95% of metal ions and a low Chemical Oxygen Demand (COD) value of 10 mg·L^-1 in permeate could be achieved using the RO composite membrane, while the NF rejection of the salt could be up to 78.9% and the COD value in the permeate was 35 mg·L^-1. The results showed that the product water by both NF and RO desalination satisfied the State Reutilization Qualification, but NF would be more suitable for large-scale industrial practice, which offered significantly higher permeate flux at low operating pressure. 相似文献