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S. E. Porozova V. Ya. Bekker V. B. Kul’met’eva 《Refractories and Industrial Ceramics》2000,41(2):37-39
The effect of the composition and the method of treatment of mullite-zircon powder on the kinetics of the densification, the strength, and the microstructure of the sintered material is described. It is shown that a fine-grain material with minimum porosity can be obtained based on kaolin by combining the sol-gel method and conventional powder technology with preliminary dry activation of the powder. Translated from Ogneupory i Tekhnicheskaya Keramika, No. 2, pp. 6–8, February, 2000. 相似文献
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《Journal of the European Ceramic Society》2017,37(7):2685-2694
In a MgO/Al2O3/SiO2/ZrO2 glass-ceramic MgO was substituted by equimolar ZnO concentrations. The effect of this substitution on the crystallization behavior, the microstructure and the mechanical properties of the glass-ceramics was studied. The crystal phases and the microstructure were analysed by X-ray diffraction and scanning electron microscopy. Tetragonal ZrO2, a high-/low-quartz solid solution (high-/low-QSS) and spinel/gahnite were observed in the entire bulk of the glass-ceramics. Additionally, indialite or cristobalite are detected at the surface of some glass-ceramics. The substitution of small ZnO concentrations induces an increasing low-QSS concentration and hence higher microhardness and Young’s modulus. By contrast, higher ZnO concentrations lead to a liquid/liquid phase separation in the glass. Moreover, spinel/gahnite is the main crystal phase and the concentration of the low-QSS is smaller in theses glass-ceramics which also do not show as good mechanical properties. However, the biaxial flexural strength of the glass-ceramics is not notably affected by the ZnO concentration. 相似文献
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E. S. Lukin A. S. Vlasov N. M. Astakhova E. V. Bykova 《Refractories and Industrial Ceramics》1987,28(1-2):63-65
Conclusions A highly dense ceramic based on the eutectic composition of the Al2O3-ZrO2 system was obtained using 3 mole % Y2O3 addition. The ceramic has a fine-grained structure and high hardness and strength.Translated from Ogneupory, No. 2, pp. 8–10, February, 1987. 相似文献
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以硝酸铝、正硅酸乙酯、氧氯化锆、钛酸丁酯为前驱体,水和无水乙醇为溶剂,用溶胶-凝胶法制备适合涂膜的复合溶胶。 相似文献
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《Ceramics International》1986,12(1):19-24
The sintering behaviour of refractory compositions in the system Al2O3-Cr2O3-SiO2 was studied. The conditions for densification, the mechanism of densification and the reactions during sintering were investigated. Powders of Al2O3, Cr2O3, mullite and SiO2 were used as a starting material and were sintered in compacted form under different conditions at 1300 to 1550°C. A dense body was obtained by heating in a carbon powder bed at temperatures around 1500°C. The microstructure of the body was skeleton-like and contained rectangular crystals of (Cr, Al)2O3 s.s., which appeared to be desirable for an improvement of the thermal shock resistance. 相似文献
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Phase diagrams of the system Al2O3 - SiO2 as presented in the domestic and foreign literature are analyzed. The congruent and incongruent states of mullite, liquation in the solid phase, and the structures of mullite and sillimanite are discussed.Translated from Ogneupory, No. 8, pp. 11 – 14, August, 1995.A lecture delivered to metallurgists and silicate producers at the Ural State Engineering University. 相似文献
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Sol-Gel法制备Al2O3-SiO2-TiO2-ZrO2复合陶瓷膜的研究 总被引:3,自引:0,他引:3
将Sol-Gel法应用于无机膜的制备,成功的研制出一种新型的膜面平整、膜厚均匀且无宏观缺陷的Al2O3-SiO2-TiO2-ZrO2复合陶瓷膜,复合膜含有γ-Al2O3、SiO2、TiO2、ZrO2和Al2SiO5等晶相,改变体系组成含量,晶相组成和含量随之变化,从而引起膜的显微结构的变化。利用XRD、SEM、AFM、EPMA等测试手段重点研究了膜的表面形貌和显微结构,并分析了添加剂、热处理方式等对膜的表面形貌和显微结构影响。 相似文献
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V. L. Balkevich A. V. Belyakov E. R. Men'kova 《Refractories and Industrial Ceramics》1984,25(1-2):23-28
Conclusions The congruence or incongruence of mullite's melting is not finally explained, and requires further study; apparently, it depends on the conditions in which the experiments are carried out, and also on the presence of stabilizing impurities in the lattice of the mullite and the partial pressure of the oxygen.The phase diagram for A12O3-SiO2 system contains only one compound — mullite, of the composition 3Al2O3·2SiO2, with a completely ordered lattice. Solid solutions having a mullitelike structure can be obtained in the compositional range from Al2O3·SiO2 to 2Al2O3· SiO2 with the use of special additives.Translated from Ogneupory, No. 1, pp. 23–27, January, 1984. 相似文献
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研究了利用无机原料以反应烧结法合成Al2O3-ZrO2系无收缩的陶瓷的可能性。为使收缩率达到零,作为活性反应组分,除了ZrAl3金属间相之外,还利用了超细铝粉,后者是采用导线通过电爆破法制取的。查明,由于加入15%金属铝,使试样的几何尺寸变化几乎为零,此时制取的试样的气孔率<1.5%,强度达750MPa。 相似文献
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以铝镁浇注料钢包衬为母体,主要研究渣线部位预防性Al2O3-ZrO2-SiO2系陶瓷保护涂层作用机理,以期钢包各部位寿命同步,进而提高其寿命节材降耗。通过试验,取得了可喜的进展。 相似文献
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研究了水玻璃、磷酸二氢铝、硫酸铝及磷酸二氢铝+硫酸铝复合结合剂对Al2O3-SiO2系浇注料强度和热震稳定性的影响.利用X射线衍射、红外光谱(IR)等分析手段,对磷酸二氢铝和磷酸二氢铝+硫酸铝复合结合剂的作用机理进行了探讨.认为磷酸二氢铝和磷酸二氢铝+硫酸铝复合结合剂能使材料获得较高的抗热震性和强度. 相似文献
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采用二乙三胺五乙酸(DTPA)为配合剂,以简易的液相法合成出微纳米纤维状Al和Al-Zr前体,煅烧处理制备了棒状α-Al2O3和Al2O3-ZrO2复合陶瓷粉体。同时研究了DPTA∶Al3+质量比、反应温度与时间对陶瓷粉体形态的影响。利用X射线衍射(XRD)、热分析(TG/DSC)以及扫描电子显微镜(SEM)对粉体进行了表征。结果表明:较高的DTPA∶Al3+质量比以及较长的反应时间有利于制备高长径比的纤维棒状Al和Al-Zr配合物前体。合成纳米纤维状α-Al2O3和Al2O3-ZrO2前体的最优条件是反应温度60℃,反应时间5.5h,DTPA∶Al3+比例为1.2∶1。相应地,该前体煅烧后可以制备出棒状α-Al2O3和Al2O3-ZrO2复合陶瓷粉体。 相似文献
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《应用陶瓷进展》2013,112(2):91-94
AbstractTernary Al2O3-ZrO2-Y2O3 samples with a eutectic composition were prepared by slow cooling. The microstructural evolution was observed with X-ray diffraction (XRD), scanning electron microscopy (SEM).The SEM observation of the ternary samples agreed with the XRD with a completion of crystallisation by slow cooling. The target materials commonly have ‘cantaloupe skin’ microstructures as shown in the previous studies by Han et al. The nanocomposite may have experienced different cooling rates with two different microstructures, near the surface having experienced optimal conditions for the eutectic reaction during their cooling and thus formed the eutectic microstructure, near the centre having experienced a slower cooling rate. The crystallised eutectic ternary Al2O3-ZrO2-Y2O3 system had three different phases with a 3Y2O3-5Al2O3 (yttrium-aluminium garnet phase), an alumina phase formed by the eutectic reaction, and a solid solution of ZrO2 and Y2O3. 相似文献