Experimental study of the performances of a modified diesel engine operating in homogeneous charge compression ignition (HCCI) combustion mode versus the original diesel combustion mode

Homogeneous charge compression ignition (HCCI) combustion mode provides very low NO_x and soot emissions; however, it has some challenges associated with hydrocarbon (HC) emissions, fuel consumption, difficult control of start of ignition and bad behaviour to high loads. Cooled exhaust gas recirculation (EGR) is a common way to control in-cylinder NO_x production in diesel and HCCI combustion mode. However EGR has different effects on combustion and emissions, which are difficult to distinguish. This work is intended to characterize an engine that has been modified from the base diesel engine (FL1 906 DEUTZ-DITER) to work in HCCI combustion mode. It shows the experimental results for the modified diesel engine in HCCI combustion mode fueled with commercial diesel fuel compared to the diesel engine mode. An experimental installation, in conjunction with systematic tests to determine the optimum crank angle of fuel injection, has been used to measure the evolution of the cylinder pressure and to get an estimate of the heat release rate from a single-zone numerical model. From these the angle of start of combustion has been obtained. The performances and emissions of HC, CO and the huge reduction of NO_x and smoke emissions of the engine are presented. These results have allowed a deeper analysis of the effects of external EGR on the HCCI operation mode, on some engine design parameters and also on NO_x emission reduction.     

双燃料HCCI燃烧的优化策略

对有废气再循环(EGR)的情况下单一二甲基醚(DME)、DME／甲醇(Methanol)和DME/天然气(CNG)双燃料的均质压燃(HCCI)燃烧进行了实验研究．研究结果表明,单一DME的HCCI只能在小负荷下实现．采用DME／甲醇双燃料后,HCCI的负荷范围达到了原柴油机中高负荷水平．EGR能扩大双燃料HCCI的可控燃烧范围,但对扩展双燃料HCCI燃烧的负荷范围作用不大．分层燃烧技术有扩大双燃料发动机的负荷范围到大负荷的潜力．DME／甲醇双燃料HCCI的指示热效率要优于DME／CNG．在低负荷工况,采用单一DME加EGR的HCCI燃烧能获得更好的经济性指标．     

Effects of compression ratio on the combustion characteristics of a homogeneous charge compression ignition engine

The effects of homogeneous charge compression ignition (HCCI) engine compression ratio on its combustion characteristics were studied experimentally on a modified TY1100 single cylinder engine fueled with dimethyl ether. The results show that dimethyl ether (DME) HCCI engine can work stably and can realize zero nitrogen oxides (NO_x) emission and smokeless combustion under the compression ratio of both 10.7 and 14. The combustion process has obvious two stage combustion characteristics at ɛ = 10.7 (ɛ refers to compression ratio), and the combustion beginning point is decided by the compression temperature, which varies very little with the engine load; the combustion beginning point is closely related to the engine load (concentration of mixture) with the increase in the compression temperature, and it moves forward versus crank angle with the increase in the engine load at ɛ = 14; the combustion durations are shortened with the increase in the engine load under both compression ratios. __________ Translated from Chinese Journal Combustion Engine Engineering, 2006, 27(4): 9–12 [译自: 内燃机工程]     

Progress and recent trends in homogeneous charge compression ignition (HCCI) engines

HCCI combustion has been drawing the considerable attention due to high efficiency and lower nitrogen oxide (NO_x) and particulate matter (PM) emissions. However, there are still tough challenges in the successful operation of HCCI engines, such as controlling the combustion phasing, extending the operating range, and high unburned hydrocarbon and CO emissions. Massive research throughout the world has led to great progress in the control of HCCI combustion. The first thing paid attention to is that a great deal of fundamental theoretical research has been carried out. First, numerical simulation has become a good observation and a powerful tool to investigate HCCI and to develop control strategies for HCCI because of its greater flexibility and lower cost compared with engine experiments. Five types of models applied to HCCI engine modelling are discussed in the present paper. Second, HCCI can be applied to a variety of fuel types. Combustion phasing and operation range can be controlled by the modification of fuel characteristics. Third, it has been realized that advanced control strategies of fuel/air mixture are more important than simple homogeneous charge in the process of the controlling of HCCI combustion processes. The stratification strategy has the potential to extend the HCCI operation range to higher loads, and low temperature combustion (LTC) diluted by exhaust gas recirculation (EGR) has the potential to extend the operation range to high loads; even to full loads, for diesel engines. Fourth, optical diagnostics has been applied widely to reveal in-cylinder combustion processes. In addition, the key to diesel-fuelled HCCI combustion control is mixture preparation, while EGR is the main path to achieve gasoline-fuelled HCCI combustion. Specific strategies for diesel-fuelled, gasoline-fuelled and other alternative fuelled HCCI combustion are also discussed in the present paper.     

Multi-dimensional modeling of the application of catalytic combustion to homogeneous charge compression ignition engine

The detailed surface reaction mechanism of methane on rhodium catalyst was analyzed.Comparisons betweennumerical simulation and experiments showed a basic agreement.The combustion process of homogeneouscharge compression ignition(HCCI)engine whose piston surface has been coated with catalyst(rhodium andplatinum)was numerically investigated.A multi-dimensional model with detailed chemical kinetics was built.The effects of catalytic combustion on the ignition timing,the temperature and CO concentration fields,and HC,CO and NO_x emissions of the HCCI engine were discussed.The results showed the ignition timing of the HCCIengine was advanced and the emissions of HC and CO were decreased by the catalysis.     

Experimental study of combustion and emission characteristics of ethanol fuelled port injected homogeneous charge compression ignition (HCCI) combustion engine

The homogeneous charge compression ignition (HCCI) is an alternative combustion concept for in reciprocating engines. The HCCI combustion engine offers significant benefits in terms of its high efficiency and ultra low emissions. In this investigation, port injection technique is used for preparing homogeneous charge. The combustion and emission characteristics of a HCCI engine fuelled with ethanol were investigated on a modified two-cylinder, four-stroke engine. The experiment is conducted with varying intake air temperature (120–150 °C) and at different air–fuel ratios, for which stable HCCI combustion is achieved. In-cylinder pressure, heat release analysis and exhaust emission measurements were employed for combustion diagnostics. In this study, effect of intake air temperature on combustion parameters, thermal efficiency, combustion efficiency and emissions in HCCI combustion engine is analyzed and discussed in detail. The experimental results indicate that the air–fuel ratio and intake air temperature have significant effect on the maximum in-cylinder pressure and its position, gas exchange efficiency, thermal efficiency, combustion efficiency, maximum rate of pressure rise and the heat release rate. Results show that for all stable operation points, NO_x emissions are lower than 10 ppm however HC and CO emissions are higher.     

EGR对汽油机HCCI燃烧过程的影响机理

以甲苯掺比燃料作为汽油燃料替代混合物,利用零维单区化学动力学模型,在EGR率为20％时,分析和研究EGR中添加不同摩尔分数的CO、NO和CH2O对汽油机HCCI燃烧的化学作用,进而分析添加物对生成物中有害物质的影响.通过模拟分析可知,不同摩尔分数的添加物可以使气缸内的温度和压力有一定程度的提高,同时能够降低废气中的CO、NOx和UHC等有害物质的排放.     

废气再循环对二甲基醚均质压燃燃烧过程影响的试验研究

在一台单缸发动机上进行了废气再循环(EGR)对二甲基醚(DME)均质压燃(HCCI)燃烧过程影响的试验研究。结果表明，EGR比例小于20％对运行最大负荷工况范围影响不大；采用高比例EGR可以拓宽DME均质压燃运行工况范围，随着EGR率增大，HCCI运行的最大负荷工况增大，着火燃烧时刻推迟，燃烧放热率降低，缸内最大爆发压力降低，发动机热效率增大；EGR率小于75％，HC排放略有降低或相当，EGR率为75％时，HC排放显著增加；EGR率大于25％，随着EGR率增加，CO排放增大，小负荷工况尤其明显，在中高负荷工况，EGR率对CO排放影响较小。     

Control of homogeneous charge compression ignition combustion in a two-cylinder gasoline direct injection engine with negative valve overlap

Homogeneous charge compression ignition (HCCI) has challenges in ignition timing control, combustion rate control, and operating range extension. In this paper, HCCI combustion was studied in a two-cylinder gasoline direct injection (GDI) engine with negative valve overlap (NVO). A two-stage gasoline direct injection strategy combined with negative valve overlap was used to control mixture formation and combustion. The gasoline engine could be operated in HCCI combustion mode at a speed range of 800–2 200 r/min and load, indicated mean effective pressure (IMEP) range of 0.1–0.53 MPa. The engine fuel consumption is below 240 g/(kW⁻¹·h⁻¹), and the NO _x emission is below 4 × 10⁻⁵ without soot emission. The effect of different injection strategies on HCCI combustion was studied. The experimental results indicated that the coefficient of variation of the engine cycle decreased by using NVO with two-stage direct injection; the ignition timing and combustion rate could be controlled; and the operational range of HCCI combustion could be extended. Translated from J Tsinghua Univ (Sci & Tech), 2006, 46(5): 720–723 [译自: 清华大学学报]     

Homogeneous charge compression ignition (HCCI) combustion of diesel fuel with external mixture formation

HCCI (Homogeneous Charge Compression Ignition) has been touted for many years as the alternate technology of choice for future engines, preserving the inherent efficiency of CIDI (Compression Ignition Direct Injection) engines while significantly reducing emissions. The current direction for all published diesel HCCI research is mixture preparation using the direct injection – system, referred to as internal mixture formation. The benefit of internal mixture formation is that it utilizes an already available direct injection system. Direct injected diesel HCCI can be divided into two areas, early injection (early in the compression stroke) and late injection (usually after Top Dead Center (aTDC)). Early direct injection HCCI requires carefully designed fuel injector to minimize the fuel wall-wetting that can cause combustion inefficiency and oil dilution. Late direct injection HCCI requires a long ignition delay and rapid mixing rate to achieve the homogeneous mixture. The ignition delay is extended by retarding the injection timing and rapid mixing rate was achieved by combining high swirl with toroidal combustion-bowl geometry. There is a compromise between Direct Injection (DI) and HCCI combustion regimes. Even under ideal conditions, it can prove difficult to form a truly homogeneous charge, which leads to elevated emissions when compared to true homogenous charge combustion and also strongly contribute to the high sensitivity of the combustion phasing to external parameters. The alternative to the internal mixture formation is, predictably, external mixture formation. By introducing the fuel external to the combustion chamber one can use the turbulence intake process to create a homogeneous charge regardless of engine conditions. This eliminates the need for combustion system changes which were necessary for the internal mixture formation method. With this method, the combustion system remains fully optimized for direct injection and also capable of running in HCCI combustion mode with nearly ideal mixture preparation. The key to the external mixture formation with diesel fuel is proper mixture preparation.     

Experimental study and chemical analysis of n-heptane homogeneous charge compression ignition combustion with port injection of reaction inhibitors

The control of ignition timing in the homogeneous charge compression ignition (HCCI) of n-heptane by port injection of reaction inhibitors was studied in a single-cylinder engine. Four suppression additives, methanol, ethanol, isopropanol, and methyl tert-butyl ether (MTBE), were used in the experiments. The effectiveness of inhibition of HCCI combustion with various additives was compared under the same equivalence ratio of total fuel and partial equivalence ratio of n-heptane. The experimental results show that the suppression effectiveness increases in the order MTBE < isopropanol ? ethanol < methanol. But ethanol is the best additive when the operating ranges, indicated thermal efficiency, and emissions are considered. For ethanol/n-heptane HCCI combustion, partial combustion may be observed when the mole ratio of ethanol to that of total fuel is larger than 0.20; misfires occur when the mole ratio of ethanol to that of total fuel larger than 0.25. Moreover, CO emissions strongly depend on the maximum combustion temperature, while HC emissions are mainly dominated by the mole ratio of ethanol to that of total fuel. To obtain chemical mechanistic informations relevant to the ignition behavior, detailed chemical kinetic analysis was conducted. The simulated results also confirmed the retarding of the ignition timing by ethanol addition. In addition, it can be found from the simulation that HCHO, CO, and C₂H₅OH could not be oxidized completely and are maintained at high levels if the partial combustion or misfire occurs (for example, for leaner fuel/air mixture).     

Methods for in-cylinder EGR stratification and its effects on combustion and emission characteristics in a diesel engine

The effects of in-cylinder EGR stratification on combustion and emission characteristics are investigated in a single cylinder direct injection diesel engine. To achieve in-cylinder EGR stratification, external EGR rates of two intake ports are varied by supplying EGR asymmetrically using a separated intake runner. The EGR stratification pattern is improved using a 2-step bowl piston and an offset chamfer at the tangential intake port. When high EGR gas is supplied to the left (tangential) port, a high EGR region is formed at the central upper region of the combustion chamber. Consequently, combustion is initiated in the low EGR region, and PM is reduced significantly. When high EGR gas is supplied to the right (helical) port, a high EGR region is formed at the lower periphery of the combustion chamber. Therefore, combustion is initiated in the high EGR region, and NO_x is reduced without PM penalty. Stratified EGR potentially reduces NO_x by maximum 45%, without penalties of performance and other emissions. A proper in-cylinder swirl with stratified EGR maximizes the effects and achieves simultaneous reduction of NO_x by 7% and PM by 23%. Moreover, the robustness of stratified EGR is evaluated under various operating conditions and injection strategies.     

Impact of nitrogen oxides (NO,NO2, N2O) on the formation of soot

The emission of both nitrogen oxides and soot from combustion processes is still a matter of concern. When a flue gas recirculation (FGR) technique is applied, the presence of a given nitrogen oxide in the recirculated mixture can affect the emissions of other pollutants, such as soot, and be used for its control in a combustion process. In this context, the present work is focused on the identification of the effect of the main nitrogen oxides (NO, NO₂ and N₂O) present in combustion systems on soot and main product gases formation from the pyrolysis of ethylene, at atmospheric pressure and in the 975–1475 K temperature range. The experimental results are examined to assess the effectiveness of each nitrogen oxide in suppressing or boosting soot formation, to achieve the possible nitrogen oxides reduction, and to identify the elementary steps involved in the nitrogen oxides and ethylene conversion as function of the different nitrogen oxides. This analysis is supported on model calculations.     

Experimental investigation of varying composition of HCNG on performance and combustion characteristics of a SI engine

With rapid depletion of petroleum resources, researchers are investigating alternate fuels to meet global transportation energy demand. Gaseous fuels such as compressed natural gas (CNG) and hydrogen are of special interest because of their cleaner combustion characteristics compared to liquid petroleum based fossil fuels. However both these gaseous fuels have some technical issues when they are used as stand-alone alternate fuel in conventional spark ignition (SI) engines. CNG suffers from lower energy density and narrow flammability range whereas backfiring tendency is highly pronounced in hydrogen fueled engines. Hydrogen enriched compressed natural gas (HCNG) mixtures are observed to be good alternative to these individual fuels since these mixtures do not pose the issues experienced by the constituent fuels i.e. CNG and hydrogen. In this study, experiments were conducted in a spark ignited gas engine using various compositions of HCNG mixtures having 0, 10, 20, 30, 50, 70 and 100% (v/v) hydrogen fraction. The performance and combustion characteristics of these test fuels were compared with that of baseline CNG, in order to find an optimum HCNG mixture composition for a single cylinder gas engine. Results obtained showed that 30HCNG mixture delivered superior engine performance compared to other HCNG mixtures and baseline CNG, which is in sharp contrast to 15HCNG being advocated globally.     

Progress in the production and application of n-butanol as a biofuel

Butanol is a very competitive renewable biofuel for use in internal combustion engines given its many advantages. In this review, the properties of butanol are compared with the conventional gasoline, diesel fuel, and some widely used biofuels, i.e. methanol, ethanol, biodiesel. The comparison of fuel properties indicates that n-butanol has the potential to overcome the drawbacks brought by low-carbon alcohols or biodiesel. Then, the development of butanol production is reviewed and various methods for increasing fermentative butanol production are introduced in detailed, i.e. metabolic engineering of the Clostridia, advanced fermentation technique. The most costive part of the fermentation is the substrate, so methods involved in renewed substrates are also mentioned. Next, the applications of butanol as a biofuel are summarized from three aspects: (1) fundamental combustion experiments in some well-defined burning reactors; (2) a substitute for gasoline in spark ignition engine; (3) a substitute for diesel fuel in compression ignition engine. These studies demonstrate that butanol, as a potential second generation biofuel, is a better alternative for the gasoline or diesel fuel, from the viewpoints of combustion characteristics, engine performance, and exhaust emissions. However, butanol has not been intensively studied when compared to ethanol or biodiesel, for which considerable numbers of reports are available. Finally, some challenges and future research directions are outlined in the last section of this review.