AZ91D镁合金半固态加工技术研究进展

半固态加工技术包括半固态浆料或坯料的制备和成形工艺,已经广泛应用于镁合金的加工.AZ91D是镁合金半固态研究及工业应用中最成功的一种镁合金,文中介绍了半固态加工技术及其特点,综述了近年来AZ91D镁合金半固态加工技术的研究现状与进展,包括半固态镁合金的微观组织、成形工艺及其成形件的性能,指出了镁合金半固态加工技术存在的...     

半固态AZ91D流变铸轧正交试验研究

在半固态AZ91D镁合金铸轧工艺试验研究中,选取机械搅拌速度、机械搅拌时间、熔体静置时间和浇铸温度作为试验因子,用正交试验法进行半固态AZ91D镁合金流变铸轧试验;用极差分析法分析了试验结果.结果表明:对半固态AZ91D镁合金组织结构的影响主次顺序为:搅拌速度、静置时间、浇注     

纳米SiC对AZ91D镁合金组织和性能的影响

为了研究不同SiC p含量对AZ91 D镁合金的强化机理,采用扫描电子显微镜测定了各相的微观结构组织形貌和分布特征.同时,结合X射线衍射分析结果,探究其强化机制.结果表明,纳米SiC p加入使基体组织变为柱状晶和树枝晶.纳米SiC p的加入可以显著改善基体结构.在本次实验中,纳米SiCp的含量与晶粒尺寸成反比.当纳米S...     

半固态等温热处理对AZ91D镁合金组织的影响

研究了AZ91D镁合金在半固态等温热处理过程中,等温时间,等温湿度对其组织形态和初生相尺寸的影响。研究发现：在升温过程中,晶界处的共晶组织（δ γ）中的γ相先发生溶解,之后,随着温度进一步升高,δ相又发生熔化分离,并在等温处理过程中逐渐变为球状。当等温时间过长时,球状颗粒有长大的趋势,结果表明：在570℃时保温60min,可得到初生相尺寸在50－80μm的球状组织。     

变形镁合金热压缩变形流变应力研究

由于镁是密排六方晶体结构,纯镁及镁合金在室温下只有很小的延展性,其成形工艺应在中高温下进行.针对AZ91D与ZK60镁合金,采用Gleeble 1500D热模拟试验机对其在不同温度和变形速率下的流变应力进行了实验研究.结果表明,AZ91D与ZK60镁合金具有不同形式的热模拟曲线,不同的流变应力规律.     

压铸镁合金AZ91D钻削力经验公式

采用正交试验的方法对压铸镁合金AZ91D进行了钻削试验，用多元线性回归法对试验结果进行了处理，建立了压铸镁合金AZ91D的钻削力与扭矩的经验公式。由经验公式可以确定：对钻削力和扭矩影响最大的是钻头直径d，进给量f次之，切削速度v的影响最小。因此在实际生产中可以采用提高转速的办法来提高加工效率，减少能耗。     

镁合金手机外壳的半固态压铸成形模拟及工艺参数优化研究

对镁合金手机外壳的半固态压铸成形过程进行了数值模拟,预测了可能产生缩孔、缩松等缺陷产生的部位,分析了其形成原因．根据模拟结果对溢流槽等工艺参数进行了改进,优化了工艺参数．改进的工艺实现了顺序凝固,消除了缩孔、缩松缺陷,保证了压铸件质量．     

SIMA法制备AZ91D镁合金非枝晶组织锭料

研究了利用应变诱发熔体激活法SIMA（Strain-Induced Melt Activation）制备AZ91D镁合金半固态非枝晶时的组织转变过程，实验结果表明：具有树枝晶形态的AZ91D合金经20％及30％的预变形后，在半固态升温（540－580℃）或保温（570℃）过程中，其组织形貌由粗化的等轴晶及短树枝晶依次转变为小块状细晶状→团块状→球状大晶粒，另外，在等温热处理过程中，试样内部体系寻求能量最低状态也是组织转变的一个不可忽略的因素，与未预变形的合金制备的非枝晶组织相比较，经预变形处理的试样是较好的半固态成型材料。     

AZ91D应变状态下低周疲劳行为的研究

对AZ91D镁合金进行了应变控制单轴加载的低周疲劳试验研究,结果表明：AZ91D镁合金在低周载荷下,当循环应变幅值小于0．4％,材料表现出循环软化．随着循环应变幅值的增加,材料表现出明显的循环硬化现象;且随着应变幅值的增加材料的附加强化程度增大．当总应变幅大于1．0％,曲线的斜率基本不变,即循环应变硬化率大致相同．应变幅值对材料低周疲劳寿命有较大影响,随着应变幅值的提高,疲劳寿命降低．运用Coffin-Manson公式进行寿命预测,在高应变幅值下有较好的一致性．     

Analyses of Microarc Oxidation Coating Formed on AZ91D Alloy in Phosphate Electrolytes

This paper studied the appearance transition of microdischarges, the phase composition and the morphology evolution of the oxide film formed by microarc oxidation on AZ91D magnesium alloy. The appearance of microdischarges population experienced apparent changes in size, spatial density and color, which was related with the changes of the type and quantity of the disintegrated gas bubbles generated at the interface between the electrolyte and substrate. Correspondingly, the diameter of micropores together with net-like fine microcracks increased when a higher voltage was employed. The coating was composed of MgO, MgAl2O4 and there existed a fluoride-enriched zone of about 3-5μm at the film/substrate interface.     

SIMA法制备AZ91半固态坯料枝晶衍变规律的研究

研究了应变诱发熔化激活法(SIMA)制备AZ91半固态坯料枝晶演变规律.挤压后,AZ91组织结构为白亮拉长的初生α相和分布在其间的黑色共晶相.由于变形不充分,在试棒中心垂直于挤压方向仍有较大的初生α相存在.575℃等温重熔过程中,首先发生再结晶,伴随液相向再结晶产生的晶界渗透,导致枝晶破碎.随着等温保温时间的增加,组织转变为细小的球状α相,均匀分布在液相中.等温保温10m in时,α相由于组织的球化和粗化过程而变得更为圆整粗大.     

Microstructural formation of semi-solid AZ91D alloy stirred by electromagnetic field

With the help of an electromagnetic stirring device, alloy melt quenching and EBSD (electron back scatter diffraction)analysis technology, the microstructure of the semi-solid AZ91D magnesium alloy slurry stirred by rotational electromagnetic field under different stirring power conditions has been studied. The results show that the size of primary α-Mg phase is reduced obviously when the solidifying alloy melt is stirred by rotational electromagnetic field, moreover, the primary α-Mg grains are changed to fine rosette grains or spherical grains which are proved to belong to the different grains in three-dimension by the EBSD analysis technology. The results also show that the stirring power is an important processing parameter in the preparation of the semi-solid AZ91D magnesium alloy slurry. The larger the stirring power, the finer the primary α-Mg grains, the less the rosette primary α-Mg grains, and the more the spherical primary α-Mg grains. Theoretical analysis indicates that a stronger flow motion leads to a more even temperature field and solute field and a stronger man-made temperature fluctuation in the alloy melt so that the specially fine rosette and/or spherical primary α-Mg grains are formed in the semi-solid AZ91D magnesium alloy slurry.     

Surface nanocrystallization of magnesium alloy AZ91D by high-energy shot peening

High-energy shot peening (HESP), a method to produce severe plastic deformation by high velocity flying balls, was applied on die cast magnesium alloy AZ91D. Effects of surface nanocrystallization by HESP and heat treatment at different temperatures were investigated. The microstructure evolution was conducted using X-ray diffraction (XRD) and field emission scanning electronic microscopy (FESEM). The hardness was measured by microhardness tester. The experimental results show that surface nanocrystrallization of AZ91D obtained by HESP would lead to the increase of microhardness. Low temperature heated at 100 °C for 1 h do not change the property obviously. However, both the microstructure and microhardness vary greatly after heat treatment at 400 °C for 1 h. Funded by the National Ministry of Education (No.207095) and Beijing Key Laboratory for Corrosion Erosion and Surface Technology     

Sr Microalloying for Refining Grain Size of AZ91D Magnesium Alloy

The grain refining process of an AZ91D Mg alloy by Sr addition was studied and the heterogeneous nucleating particles of α-Mg were investigated by electron probe microanalysis （EPMA）. With 0.6 wt% Sr addition, the mean grain size of AZ91D alloy was refined from 235.4μm to 52.5 μm at the one-half radius of the ingot. The morphology of primary crystal changed from a sixford symmetrical shape to a petallike shape, Mg-Sr-Al-Fe-Mn heterogeneous nucleating particles were observed at the grain centers and Sr solute atoms presented segregation along the grain boundaries. Grain refinement was facilitated by both the Mg-Sr-Al- Fe-Mn nucleating particles and the Sr solute atoms, and the former played a dominate role in the process.     

Effect of RE on the ignition-proof, microstructure and properties of AZ91D magnesium alloy

The magnesium alloy is prone to burn during die-casting, which limits its applications severely, so the effect of adding rare earth （RE） on the ignition-proof of AZ91D Mg alloy is studied. The results indicate that the addition of mischmetal RE elements has a remarkable influence on the ignition-proof property of the magnesium alloy. It is found that the ignition temperature of the magnesium alloy can be greatly raised by adding a proper amount of RE. When the amount is 0.1wt%, the ignition temperature reaches 877℃ which is 206℃ higher than that of AZ91D without RE and the mechanical properties of the alloy are also improved, However, the amount of RE must be properly controlled because too much RE would induce grain coarsening and reduce the mechanical properties.     

Effects of rare earth elements on the microstructure and properties of magnesium alloy AZ91D

The effects of rare earth elements on the microstructure and properties of Magnesium alloy AZ91D alloy were studied.The different proportion of rare earth elements was added to the AZ91D and the tensile tests were carried out at different temperatures.The experimental results show that at room temperature or at 120℃ the AZ91D‘s decrease with the increasing amount of the rare earth elements.however,the ductility is improved.The influence of 0.14%Sb(mass fraction)on the AZ91D‘s strength is like that of rare earth elements(0.2%-0.4%)(mass fraction).Microstructure graphs demonstrate that appropriate amount of rare earth elements (0.1%-0.2%) can fine AZ91D‘s grain and improve its ductility.     

Gd对AZ91D-0.4%Ca-0.3%Sr镁合金低周疲劳性能的影响

通过运用控制总应变幅的方法,在应力比R=-1条件下施加拉-压载荷,测试了合金元素Gd复合添加对金属型铸造镁合金AZ91D-0.4%Ca-0.3%Sr的低周疲劳性能的影响,并利用光学电子显微镜、扫描电镜分别观察了材料在不同状态下的显微组织及低周疲劳断口特征.结果表明：Gd的添加能细化铸态AZ91D镁合金的晶粒,加入3.0%Gd可以提高镁合金的低周疲劳性能.     

Initial corrosion behaviors of AZ91 magnesium alloy in the presence of SO2

The effects of SO2 on the initial atmospheric corrosion of AZ91D magnesium alloy were investigated in laboratory. Met-allographic observation, SEM (Scanning Electron Microscopy), XRD (X-ray Diffraction) and XPS (X-ray Proton Spectrograph) were used to analyze and discuss the initial surface morphology of corrosion layers and corrosion products. The corrosion rate of the alloy increases with increasing the content of SO2. The initial attack has the characteristics of localized corrosion and preferentially concentrates on a phase. MgO and Mg(OH)2 form at first, which provide a protective layer, then the existence of SO2 decreases the pH of the thin solution on the alloy, accelerates dissolution process, and promotes the formation of MgSO3·6H2O and MgSO4·6H2O, meanwhile cracks were found on the corrosion products with corrosion continuation. These soluble corrosion products and the cracks provide the paths for filtering oxygen and corrosion pollutants into the matrix, which results in severe localized co