Transient thermo-solutal convection of water near 4 °C with opposing gradients in a square cavity

A numerical study of two-dimensional thermo-solutal convection of water in a square cavity heated from below and salted from above for various value of Lewis number is conducted. The maximum density associated with water around 4 °C occurs inside the cavity, as the top wall is maintained at 0 °C while the bottom wall temperature varies in the range 8–12 °C. The maximum density region acts as an obstacle to prohibit convectional heat, mass, and momentum transfer. These effects are investigated numerically in the domain −5 × 10² < Ra_T < 2 × 10⁴, 1 × 10⁵ < Ra_S < 8 × 10⁶ and L = 0.015 m length of square cavity where Ra is the Rayleigh number of the fluid. The effect of Lewis number on the heat, mass, and momentum transfer is also systematically studied. For certain range of parameters, it is interesting to find that the flow pattern may change inversely from rolling (fluid particles raise along both vertical side walls and fall along the vertical center line) to plume motion (fluid particles raise along the vertical center line and fall along both side walls) as the bottom wall temperature and top wall concentration increase. Further increase in the value of Rayleigh number results in oscillating two cell flow structure in the cavity. It is found that there is a temporal maximum absolute value of average Nusselt and Sherwood number followed by a temporal minimum absolute value of average Nusselt and Sherwood number in a small time interval (0 < t < 300 s) and the steady state is reached after a certain time interval at the bottom wall. These time intervals are reduced with increasing Lewis number. Also, critical Grashof number which accounts for oscillatory heat and mass transfer with Lewis number is studied and it reveals that an increase in Lewis number results in slowing down oscillation and oscillation cycle becomes shorter with increasing species Grashof number.     

Heat transfer and fluid flow in shrouded pin fin arrays with and without tip clearance

Shrouded pin fin arrays with tip clearances (Cg) up to 25% of pin height were experimentally evaluated. Pressure loss was measured (2 × 10² < Re_D < 2 × 10⁴) and liquid crystal thermography was employed to obtain temperature distributions from which the impact of Cg on the mean heat transfer rate was determined for 2 × 10² < Re_D < 1 × 10⁴. Cg was found to influence pressure drop performance to the greatest extent at low Re_D, (<5 × 10³), with the effect being significantly diminished by Re_D = 1.5 × 10⁴. On a per unit pumping power basis, higher heat transfer rates were observed for dimensionless clearances (Cg/D) less than 0.2 as compared to the non-clearance case.     

Effects of water in phthalocyanine layers

The molecular water concentration inside zinc phthalocyanine (ZnPc) thin films was measured. After exposure to air, gas effusion experiments show that the ZnPc layers contain (1.7±0.4)×10²⁰ water molecules per cm³, which corresponds to 1 H₂O per 10 ZnPc units. We can distinguish a mobile and an immobilized population of H₂O in ZnPc films. The mobile part effuses out at room temperature when exposing the films to a low pressure of 10⁻² mbar, whereas temperature activation is needed to reach a complete out-diffusion of water. The effusion process was observed to proceed with a diffusion coefficient D_H2O of (1.3±0.3)×10⁻¹⁰ cm² s⁻¹ at 296 K. The rate of water effusion directly correlates with the timescale of the decrease of surface conductivity when exposing the layers to an equally low pressure. This indicates the existence of an electrically active surface layer of water molecules, which is refilled from the bulk of water molecules during the effusion process.     

Oxygen- and hydrogen-permeation measurements on-mixed conducting SrFeCo0.5Oy ceramic membrane material

The SrFeCo_0.5O_y system combines high electronic/ionic conductivity with appreciable oxygen permeability at elevated temperatures. This system has potential use in high-temperature electrochemical applications such as solid oxide fuel cells, batteries, sensors, and oxygen separation membranes. Dense ceramic membranes of SrFeCo_0.5O_y are prepared by pressing a ceramic powder prepared by using a sol–gel combustion technique. Oxygen and hydrogen permeation at high temperature on this material are studied. Measurements are conducted using a time-dependent permeation method at the temperature in the range of 1073–1273 K with oxygen- and hydrogen-driving pressures in the range (3×10²)–(1×10⁵) Pa (300–1000 mbar). The maximum oxygen-permeated flux at 1273 K is 6.5×10⁻³ mol m⁻² s⁻¹. The activation energies for the O₂-permeation fluxes and diffusivities are 240 and 194 kJ/mol, respectively. Due to the high fragility, the high temperature for the measurements and the high oxygen permeation through such material, a special membrane holder, and compression sealing system have been designed and realized for the permeation apparatus.     

Freezing-induced splashing during impact of molten metal droplets with high Weber numbers

The impact of molten tin droplets (0.6 mm diameter) on solid surfaces was observed for a range of impact velocities (10–30 m/s), substrate temperatures (25–200 °C) and substrate materials (stainless steel, aluminum and glass). The substrate was mounted on the rim of a rotating flywheel and the collision of single droplets with the moving substrate was photographed. Droplet impact Reynolds number ranged from 2.2 × 10⁴ to 6.5 × 10⁴ and Weber number from 8.0 × 10² to 7.2 × 10³. On a hot surface there was no splashing and droplets spread to form disk-like splats with smooth edges. Solidification around the edges of droplets spreading on cold surfaces created a solid rim that obstructed flow and triggered splashing. An analytical model was developed to predict the transition temperature at which splashing disappeared by assuming that the thickness of the solid layer had to equal that of the splat in the time the droplet spread to its maximum extent in order to obstruct liquid flow. The model predicted the transition temperature for aluminum and stainless steel surfaces, assuming that thermal contact resistance between the droplet and substrate varied between 10⁻⁶ and 10⁻⁷ m² K/W. The model also predicted that tin droplets would not splash on glass surfaces maintained at or above room temperature, and this was confirmed by experiments.     

Computation of high Prandtl number turbulent thermal fields by the analytical wall-function

The extended version of the analytical wall-function (AWF) for rough wall turbulence by Suga et al. [K. Suga, T.J. Craft, H. Iacovides, An analytical wall-function for turbulent flows and heat transfer over rough walls. Int. J. Heat Fluid Flow 27 (2006) 852–866] is improved for high Prandtl number flows. The original AWF assumes a linear profile of turbulent viscosity near a wall though it is widely recognised that a theoretically correct cubic profile of the turbulent viscosity is essential for heat transfer of high Prandtl number flows. In order to predict thermal boundary layer of high Prandtl number fluid flows, the present approach thus employs a correct limiting profile of the turbulent viscosity in the analytical integration process. The presently proposed version of the AWF proves its good performance for predicting turbulent high Prandtl number thermal flows at Pr  4 × 10⁴ for smooth wall cases, and at least at Pr  10 for rough wall cases.     

Experimental investigation of performance of a multi-purpose PV-slat window

This paper reports on experimental investigation of performance of a new type of PV-slat window (PV-SW). The main functions of this PV-SW are as follows: to admit sufficient daylight, to act as a shading device for decreasing direct heat gain through window glazing and to ensure indoor air movement, which improves resident's thermal comfort. To assess the performance of this PV-SW, two test rooms of 1×1×1.5 m³ (H:W:L) volume were built using plywood and gypsum boards. At the first, the PV-SW of 0.5×0.6 m² surface area was located at the south-facing wall whereas the other room was equipped with a commercial transparent slat window of the same size.The PV-SW consists of six PV slats. The photovoltaic cells were connected in series giving a maximum electrical power output of 36 W (12 V×3 A). The circuit was connected to a direct current axial fan, located inside the room, that requires a maximum power of 43 W. The analysis of performance of this PV-SW was investigated based on power output, daylight factor and temperature difference between indoor and ambient.The experimental results showed that this multi-purpose PV-SW is extremely interesting as it can produce power up to 15 W, decrease indoor temperature and provide sufficient light for housing. The maximum indoor illumination was about 750 lx with slats angle of 68°. The room temperature was about 2–3^oC lower than that of room equipped with transparent slats.     

Study of the heat transfer characteristics in turbulent combined wall and offset jet flows

The heat transfer study of a combined wall jet and offset jet flow with different wall jet and offset jet flow velocities are considered. The flow is considered two-dimensional, steady, incompressible, turbulent at high Reynolds number with negligible body forces. The streamline curvature modification of the standard k–ε model is used to carry out the turbulence modeling. The Reynolds number is varied from 10⁴ to 4 × 10⁴ and Pr = 0.71 is taken for all computations. Constant wall temperature and constant wall heat flux boundary conditions are considered. The results are presented in the form of local Nusselt number, local heat flux, surface temperature in case of constant heat flux condition, average Nusselt number and total heat transfer.     

Bioenergy industries development in China: Dilemma and solution

Having 2.8 × 10⁸–3.0 × 10⁸ t/a of wood energy, 4.0 × 10⁶ t/a of oil seeds, 7.7 × 10⁸ t/a of crops straw, 3.97 × 10⁹ t/a of poultry and livestock manure, 1.48 × 10⁸ t/a of municipal waste, and 4.37 × 10¹⁰ t/a of organic wastewater, China is in possession of good resource condition for the development of bioenergy industries. Until the end of 2007, China has popularized 2.65 × 10⁷ rural household biogas, established 8318 large and middle-scale biogas projects, and produced 1.08 × 10¹⁰ m³/a of biogas; the production of bioethanol, biodiesel, biomass briquettes fuel and biomass power generation reached to 1.5 × 10⁶ t/a, 3.0 × 10⁵ t/a, 6.0 × 10⁴ t/a and 6.42 × 10⁹ kWh, respectively. In recent years, bioenergy industries developed increasingly fast in China. However, the industrial base was weak with some dilemma existing in raw material supply, technological capability, industry standards, policy and regulation, and follow-up services, etc. From the viewpoint of long-term effective development system for bioenergy industries in China, a series of policy suggestions have been offered, such as strengthening strategy research, improving bioenergy industries development policies and plan, enhancing scientific research input, persisting in technology innovation, establishing product quality standard, improving industrial standard system, opening market and accelerating commercialization, etc. It is expected that the advices mentioned above could be helpful for the improvement of bioenergy industries development.     

Preparation of dense and uniform La0.6Sr0.4Co0.2Fe0.8O3−δ (LSCF) films for fundamental studies of SOFC cathodes

Thin films of La_0.6Sr_0.4Co_0.2Fe_0.8O_3−δ (LSCF) were deposited on (1 0 0) silicon and on GDC electrolyte substrates by rf-magnetron sputtering using a single-phase oxide target of LSCF. The conditions for sputtering were systematically studied to get dense and uniform films, including substrate temperature (23–600 °C) background pressure (1.2 × 10⁻² to 3.0 × 10⁻² mbar), power, and deposition time. Results indicate that to produce a dense, uniform, and crack-free LSCF film, the best substrate temperature is 23 °C and the argon pressure is 2.5 × 10⁻² mbar. Further, the electrochemical properties of a dense LSCF film were also determined in a cell consisting of a dense LSCF film (as working electrode), a GDC electrolyte membrane, and a porous LSCF counter electrode. Successful fabrication of high quality (dense and uniform) LSCF films with control of thickness, morphology, and crystallinity is vital to fundamental studies of cathode materials for solid oxide fuel cells.     

Effect of proton irradiation on electrical properties of CuInSe2 thin films

High-energy proton irradiation (380 keV and 1 MeV) on the electrical properties of CuInSe₂ (CIS) thin films has been investigated. The samples were epitaxially grown on GaAs (0 0 1) substrates by Radio Frequency sputtering. As the proton fluence exceeded 1×10¹³ cm⁻², the carrier concentration and mobility of the CIS thin films were decreased. The carrier removal rate with proton fluence was estimated to be about 1000 cm⁻¹. The electrical properties of CIS thin films before and after irradiation were studied between 80 and 300 K. From the temperature dependence of the carrier concentration in CIS thin films, we found N_D=9.5×10¹⁶ cm⁻³, N_A=3.7×10¹⁶ cm⁻³ and E_D=21 meV from the fitting to the experimental data on the basis of the charge balance equation. After irradiation, a defect level was created, and N_T=1×10¹⁷ cm⁻³ for a fluence of 3×10¹³ cm⁻², N_T=5.7×10¹⁷ cm⁻³ for a fluence of 1×10¹⁴ cm⁻² and E_T=95 meV were also obtained from the same fitting. The new defect, which acted as an electron trap, was due to proton irradiation, and the defect density was increased with proton fluence.     

Interfacial thermal resistance measurement between metallic wire and polymer in polymer matrix composites

The addition of thermally conductive particles is an effective way to increase thermal conductivity of polymers. For highly filled composites and therefore for a high effective thermal conductivity, the heat transfer at the matrix/particle interface becomes a key point to obtain further improvement. However the interfacial thermal resistance R_i between particles and matrix is difficult to measure because of the low sensitivity of temperature to R_i and because of the small size of the particles. A setup has been developed to measure R_i between nickel wires (fiber-like particles) of a few tens micrometer diameter and a polymer matrix. The temperature measurement of the heating wire associated with a thermal model allowed to estimate values of R_i between 0.3 × 10⁻⁵ and 1.6 × 10⁻⁵ m² K W⁻¹ and for various wire diameters and sample temperatures. Some R_i measurements have been validated using a thermo-elastic model.     

Preparation of sulfonated poly(ether ether ketone)s containing amino groups/epoxy resin composite membranes and their in situ crosslinking for application in fuel cells

A series of amino-containing sulfonated poly(aryl ether ketone)/4,4′-diglycidyl(biphenyl) epoxy resin (DGBP) composite membranes for proton exchange membranes fuel cells (PEMFCs) are prepared by solution blending and casting. The reaction kinetics and the effects of introduction of DGBP content on the properties of the composite membranes are thoroughly investigated. The crosslinked composite membranes after treatment at either 120 °C or 200 °C have improved oxidative and dimensional stability than those without crosslinking. Despite the fact that crosslinked membranes generally have lower proton conductivity in comparison with the original ones, the proton conductivities of the membranes treated at 120 °C are above 2.22 × 10⁻² S cm⁻¹ at room temperature and 9.42 × 10⁻² S cm⁻¹ at 100 °C. Even for the samples treated at 200 °C, their proton conductivities are still higher than 1.26 × 10⁻² S cm⁻¹ at room temperature and higher than 8.67 × 10⁻² S cm⁻¹ at 100 °C, which are well satisfied with elementary requirement of fuel cells. In addition, all the evaluated membranes have low methanol permeability. For example, the methanol permeability of AP6FSPEEK/DGBP1 cured at 200 °C is 0.33 × 10⁻⁶ cm² s⁻¹, which is an order magnitude lower than Nafion 117. Therefore, these novel crosslinked composite membranes could be potential usage in fuel cells.     

The electro-optical properties of amorphous indium tin oxide films prepared at room temperature by pulsed laser deposition

The electrical and optical properties of pulsed laser deposited amorphous indium tin oxide films at room temperature are discussed. The films were grown from indium oxide (In₂O₃) targets of different tin (Sn) doping content (0, 5 and 10 wt%) at different oxygen pressures (P_O2) ranging from 1×10⁻³ to 5×10⁻² Torr. The electrical and optical properties of the films were examined by Hall measurements and optical spectrophotometry. It was found that high conductivity amorphous films could be prepared at room temperature irrespective of the Sn doping content. The properties of these films deposited from 0, 5, 10 wt% Sn-doped In₂O₃ targets show a similar response to changes in P_O2. The maximal conductivity of (4.0, 2.1 and 1.8)×10³ S/cm and optical transmittance (visible) higher than 90% were obtained at P_O2 region of (1–1.5)×10⁻² Torr. An undoped In₂O₃ film produced the highest conductivity of 4×10³ S/cm in these studies.     

Research and development of geothermal energy production in Hungary

The basement of the Pannonian (Carpathian) basin is represented by Paleozoic metamorphic and Mesozoic dolomite and limestone formations. The Tertiary basin gradually subsided during the Alpine orogeny down to 6000 m and was filled by elastic sediments with several water horizons.A heat flow of 2.0 to 3.4 μcal/cm²s gives temperature gradients between 45 and 70 °C/km in the basin. At 2000 m depth the virgin rock temperature is between 110 and 150°C. 80 geothermal wells about 2000 m deep have shown the great geothermal potential of the basin.The main hot water reservoir is the Upper Pliocene (Pannonian) sandstone formation. Hot water is produced by wells from the blanket or sheet sand and sandstone, intercalated frequently by siltstone. Between a 100–300 m interval, 3 to 8 permeable layers are exploited resulting in 1–3 m³/min hot water at 80–99°C temperature.Wells at present are overflowing with shut-in pressures of 3–5 atm.The Pannonian basin is a conduction-dominated reservoir. Convection systems are negligible, hot igneous systems do not exist. The assessment of geothermal resources revealed that the content of the water-bearing rocks down to 3000 m amounts to 12,600 × 10¹⁸cal. In the Tertiary sediments 10,560 × 10¹⁸cal and in the Upper Pannonian, 1938 × 10¹⁸cal are stored. In the Upper Pannonian geothermal reservoir, below 1000 m, where the virgin rock temperature is between 70 and 140°C, the stored heat is 768 × 10⁸cal. A 10¹⁸ cal is equivalent to the combustion heat of 100 million tons of oil. The amount of recoverable geothermal energy from 768 × 10⁸cal is 7.42 × 10¹⁸cal, i.e. about 10,000 MW century, not considering reinjection.At present the Pannonian geothermal reservoir stores the greatest amount of identified heat which can be mobilized and used. Hungary has 496 geothermal wells with a nominal capacity of 428 m³/min, producing 1342 MW heat. 147 wells have an outflow temperature of more than 60°C producing 190 m³/min, that is, 845 MW. In 1974 290 MWyear of geothermal energy was utilized in agriculture, district heating and industry.     

Optical and electrochromic properties of oxygen sputtered tungsten oxide (WO3) thin films

Thin films of tungsten oxide (WO₃) were deposited onto glass, ITO coated glass and silicon substrates by pulsed DC magnetron sputtering (in active arc suppression mode) of tungsten metal with pure oxygen as sputter gas. The films were deposited at various oxygen pressures in the range 1.5×10⁻²−5.2×10⁻² mbar. The influence of oxygen sputters gas pressure on the structural, optical and electrochromic properties of the WO₃ thin films has been investigated. All the films grown at various oxygen pressures were found to be amorphous and near stoichiometric. A high refractive index of 2.1 (at λ=550 nm) was obtained for the film deposited at a sputtering pressure of 5.2×10⁻² mbar and it decreases at lower oxygen sputter pressure. The maximum optical band gap of 3.14 eV was obtained for the film deposited at 3.1×10⁻² mbar, and it decreases with increasing sputter pressure. The decrease in band gap and increase in refractive index for the films deposited at 5.2×10⁻² mbar is attributed to the densification of films due to ‘negative ion effects’ in sputter deposition of highly oxygenated targets. The electrochromic studies were performed by protonic intercalation/de-intercalation in the films using 0.5 M HCl dissolved in distilled water as electrolyte. The films deposited at high oxygen pressure are found to exhibit better electrochromic properties with high optical modulation (75%), high coloration efficiency (CE) (141.0 cm²/C) and less switching time at λ=550 nm; the enhanced electrochromism in these films is attributed to their low film density, smaller particle size and larger thickness. However, the faster color/bleach dynamics is these films is ascribed to the large insertion/removal of protons, as evident from the contact potential measurements (CPD) using Kelvin probe. The work function of the films deposited at 1.5 and 5.2×10⁻² mbar are 4.41 and 4.30 eV, respectively.     

Electronic and photovoltaic properties of Al/p-Si/copper phthalocyanine photodiode junction barrier

Al/p-Si/copper phthalocyanine photovoltaic device has been fabricated and characterised by current–voltage and capacitance–voltage measurements. Electrical properties of the device were determined by current–voltage characterizations under dark and illumination conditions. The density distribution of the interface states of the photodiode was found to vary from 8.88×10¹² eV⁻¹ cm⁻² in E_ss-0.54 eV to 4.51×10¹² eV⁻¹ cm⁻² in E_ss-0.61 eV. The device shows a photovoltaic behaviour with a maximum open circuit voltage Voc of 0.16 V and short-circuits current I_sc of 0.45 μA under 3500 lux light intensity.     

5–20 MeV proton irradiation effects on GaAs/Ge solar cells for space use

This paper reports the high-energy proton irradiation effects on GaAs/Ge space solar cells. The solar cells were irradiated by protons with energy of 5–20 MeV at a fluence ranging from 1×10⁹ to 7×10¹³ cm⁻², and then their electric parameters were measured at AM0. It was shown that the I_sc, V_oc and P_max degrade as the fluence increases, respectively, but the degradation rates of I_sc, V_oc and P_max decrease as the proton energy increases, and the degradation is relative to proton irradiation-induced defect Ec−0.41 eV in irradiated GaAs/Ge cells.     

Porous alumina templates and nanostructured CdS for thin film solar cell applications

Nanostructured CdS was grown by electrodeposition of cadmium sulfide inside a porous alumina template. Uniform pore size and spacing in the template was achieved when the starting material for the template was aluminum foil. Typical pore size was 45 nm. Nanostructured CdS was also deposited by electrodeposition on indium tin oxide (ITO)-coated glass and by solution growth on ITO-coated glass. Schottky diodes were formed on nanocrystalline CdS and the analysis of their current–voltage characteristics yielded a diode ideality factor (n) of 2.6 and a reverse saturation current density (J_S) of 1.00×10⁻⁵ A/cm². Corresponding values for the Schottky diode on polycrystalline CdS were 3.4 and 1.93×10⁻⁶ A/cm².