Improvement of emission reduction in nano additive Simarouba glauca biodiesel blends

In this paper discussed about the emission profile from nano additive blended biodiesel. It is observed that minimum carbon dioxide was emitted in the presence of zinc oxide blends when compared to B20 and diesel. The hydrocarbon emission for the diesel and B20 was higher than that of the B20ZnO50 and B20ZnO100 blended fuels. The higher oxide of nitrogen emissions was observed with the B20ZnO50 and B20ZnO100 blended fuels at all engine loads when compared to B20 and diesel.     

Exhaust emission study on neat biodiesel and alcohol blends fueled diesel engine

In this study, neat biodiesel with octanol additive was employed in a diesel engine and its effects on engine emission were studied. The five fuels evaluated were neat palm kernal oil biodiesel, octanol blended with biodiesel by 10%, 20%, and 30% volume, and diesel. All the emissions are reduced by the addition of octanol in biodiesel in all loads owing to the higher oxygen concentration of air/fuel mixtures and improved atomization. Hence, it is concluded that the neat biodiesel and octanol blends can be employed as an alternative fuel for existing unmodified diesel engines owing to its lesser emission characteristics.     

降低酸化油生物柴油NOx和烟度排放的试验研究

本文主要针对降低柴油机燃用酸化油生物柴油及其混合燃料的NOx、烟度排放的方法进行了试验研究。采用乙醇/生物柴油混合燃料法和推迟供油提前角两种方法在R4105T型柴油机上进行了试验。结果表明,在不影响动力性前提下燃用添加5%的乙醇的混合柴油,NOx及碳烟的排放均有明显下降。推迟供油提前角能有效的降低NOx的排放,但碳烟排放量增加,功率下降,燃料经济性变差。     

Effect of nanoparticle on emission and performance characteristics of a diesel engine fueled with cashew nut shell biodiesel

High-rise in the air pollution levels due to combustion of the fossil fuel gives us the opportunity to discover environmentally friendly and clean fuels for the engines. Biodiesel originated from cashew nut shell oil through transesterification process can be blended or used as a neat fuel in unmodified engines. This work investigates the effect of alumina nanoparticles on emission and performance characteristics of cashew nut shell biodiesel. Neat cashew nut shell biodiesel prepared by conventional transesterification is termed as BD100 and biodiesel prepared by modified transesterification with the addition of alumina nanoparticles is termed as BD100A. Experimental results on unmodified diesel engine revealed that emission parameters such as CO, HC, NOx, and smoke were decreased by 5.3%, 7.4%, 10.23%, and 16.1% for BD100% and 8.8%, 10.1%, 12.4%, and 18.4% for B100A, respectively, compared to diesel fuel. At full load conditions, compared to diesel fuel, the BTE dropped by 1.1% and 2.3%, whereas the BSFC increased by 3.8% and 5.1% for B100A and B100 correspondingly.     

Synergistic effect of hydrogen induction with biofuel obtained from winery waste (grapeseed oil) for CI engine application

The purpose of this study is to experimentally investigate the use of grapeseed oil as a fuel substitute obtained from biomass waste from winery industry and the synergic effect of hydrogen addition for compression ignition engine application. The experiments were carried out in a single cylinder, four stroke diesel engine for various loads and energy share of hydrogen. Combustion, performance and emission characteristics of grapeseed biodiesel, neat grapeseed oil and diesel have been analysed and compared with the results obtained with hydrogen induction in the intake manifold in dual fuel mode. At full load, maximum brake thermal efficiency of the engine with diesel, grapeseed biodiesel and neat grapeseed oil has increased from 32.34%, 30.28% and 25.94% to 36.04%, 33.97% and 30.95% for a maximum hydrogen energy share of 14.46%, 14.1% and 12.8% respectively. Although there is an increasing trend in Nitric Oxide emission with hydrogen induction, smoke, brake specific hydrocarbon, carbon monoxide, and carbon dioxide emissions respectively, reduces. Nitric oxide emission of Grapeseed biodiesel with maximum hydrogen share at full load is higher by 43.61% and smoke emission lower by 19.73% compared to biodiesel operation without hydrogen induction.     

Improving the low temperature properties of biodiesel fuel

The use of biodiesel as a diesel fuel extender and lubricity improver is rapidly increasing. While most of the properties of biodiesel are comparable to petroleum based diesel fuel, improvement of its low temperature flow characteristic still remains one of the major challenges when using biodiesel as an alternative fuel for diesel engines. The biodiesel fuels derived from fats or oils with significant amounts of saturated fatty compounds will display higher cloud points and pour points. This paper is aimed to investigate the cold flow properties of 100% biodiesel fuel obtained from Madhuca indica, one of the important species in the Indian context. In this paper, the cold flow properties of biodiesel were evaluated with and without pour point depressants towards the objectives of identifying the pumping and injecting of these biodiesel in CI engines under cold climates. Effect of ethanol, kerosene and commercial additive on cold flow behavior of this biodiesel was studied. A considerable reduction in pour point has been noticed by using these cold flow improvers. The performance and emission with ethanol blended Mahua biodiesel fuel and ethanol–diesel blended Mahua biodiesel fuel have also been studied. A considerable reduction in emission was obtained. Ethanol blended biodiesel is totally a renewable, viable alternative fuel for improved cold flow behavior and better emission characteristics without affecting the engine performance.     

The effect of Sr-doped zinc oxide nanoadditives on the performance and emission parameters of a VCR engine powered by soybean biodiesel

In the present study, the effects of soybean biodiesel (SB)–diesel blends containing 1% strontium (Sr) doped zinc oxide (ZnO) nanoparticles (NPs) on the performance and emission parameters of a variable compression ratio (VCR) engine were investigated. To make the fuel blends, 25% soybean biodiesel (SB25) was added to the diesel. To improve the blend's stability, Sr/ZnO NP additions were blended with SB25 at 50 and 75 ppm utilizing an ultrasonication method and a surfactant at 2%. Various physicochemical techniques, such as X-ray diffraction, field-emission scanning electron microscopy, energy-dispersive X-ray spectroscopy, and ultraviolet spectroscopy, were used to characterize the produced NPs. These blends improved overall engine characteristics when used with a VCR. In comparison to the absence of nanoadditives, the brake thermal efficiency increased by 10.37% and the brake-specific fuel consumption decreased by 16.76% while using 50 ppm Sr/ZnO NPs additive in SB25 (SB25Sr/ZnO50). In addition, the presence of Sr/ZnO in SB25 results in lower harmful emissions such as hydrocarbon, CO, CO₂, and smoke, which are reduced by 11.20%, 13.81%, 41.43%, and 21.34%, respectively, when compared to SB25 fuel. The Sr/ZnO NPs in the blend are an excellent choice for improving engine emission and performance.     

Partial hydrogenation and hydrogen induction: A comparative study with B20 operation in a turbocharged CRDI diesel engine

Numerous studies explored the possibility and effective strategies for supplementing hydrogen along with fossil or biofuels on internal combustion engines. Hydrogen is also being employed for formulating fuels such as hydrogen compressed natural gas in the gaseous form and hydrogenated biofuels in the liquid form. The present study evaluates (i) hydrogen usage on the fuel formulation and (ii) investigates the engine operation of an automotive turbocharged diesel engine operated with karanja biodiesel blended diesel (B20) as a reference fuel. Existing literature outlines that biodiesel blends possess lower energy content and emit higher nitric oxide (NO) emission than fossil diesel. The present research paper partially hydrogenates karanja biodiesel using an autoclave reactor with a palladium catalyst to increase the saturation levels and mitigate the biodiesel-NO penalty. Besides, the drop in energy release of B20 is compensated through the provision of hydrogen induction along the intake manifold. The hydrogen flow rates to the turbocharged engine are maintained at a fixed energy share of 10%. Both biodiesel and hydrogenated biodiesel were blended on a volume basis (20%) with fossil diesel (80%) and are designated as B20 and HB20, respectively. The test results reveal that HB20 effectively mitigates the biodiesel-NO penalty with a maximum reduction of 29.8% compared to B20. Further, hydrogen induction yielded a significant improvement (23.7%) in fuel consumption with HB20 relative to B20 without hydrogen addition. The compounding effect of hydrogen usage on the engine operation and fuel formulation exhibited a better performance and emission trade-off at mid load conditions.     

Comparison between blended mode and fumigation mode on combustion,performance and emissions of a diesel engine fueled with ternary fuel (diesel-biodiesel-ethanol) based on engine speed

According to the literature, there is in lack of a comprehensive study to compare the combustion, performance and emissions of a diesel engine using diesel, biodiesel and ethanol fuels (DBE) in the blended mode and fumigation mode under various engine speeds. This study was conducted to fill this knowledge gap by comparing the effect of blended, fumigation and combined fumigation + blended (F + B) modes on the combustion, performance and emissions of a diesel engine under a constant engine load (50% of full torque) with five engine speeds ranging from 1400 rpm to 2200 rpm. A constant overall fuel composition of 80% diesel, 5% biodiesel and 15% ethanol, by volume % (D80B5E15), was utilized to provide the same fuel for comparing the three fueling modes.According to the average results of five engine speeds, the blended mode has higher peak heat release rate (HRR), ignition delay (ID), brake thermal efficiency (BTE), brake specific nitrogen monoxide (BSNO) and brake specific nitrogen oxides (BSNO_X), but lower duration of combustion (DOC), brake specific fuel consumption (BSFC), brake specific carbon dioxide (BSCO₂), brake specific carbon monoxide (BSCO), brake specific hydrocarbon (BSHC), brake specific nitrogen dioxide (BSNO₂), brake specific particulate matter (BSPM), total number concentration (TNC) and geometric mean diameter (GMD), and similar peak in-cylinder pressure compared to the fumigation mode. In addition, for almost all the parameters, results obtained in the F + B mode are in between those of the blended and fumigation modes. In regard to the effect of engine speed, the results reveal that the increase in engine speed causes reduction in peak in-cylinder pressure, BTE, BSHC, BSNO_X, BSNO and BSNO₂, but increase in peak HRR, ID, DOC, BSFC, BSCO₂, BSPM and TNC, and similar BSCO and GMD for almost all the tested fueling modes. It can be inferred that the blended mode is the suitable fueling mode, compared with the fumigation mode, under the operating conditions investigated in this study.     

Unregulated emissions and health risk potential from biodiesel (KB5, KB20) and methanol blend (M5) fuelled transportation diesel engines

Diesel engine emissions consist of several harmful gaseous species, some of which are regulated by stringent emission norms, while many others are not. These unregulated emission species are responsible for adverse environmental impact and serious health hazards upon prolonged exposure. In this study, a four-cylinder, 1.4 l, compression ignition (CI) engine was used for characterization of unregulated gaseous exhaust emissions measured at 2500 rpm at varying engine loads (0, 25, 50, 75 and 100%). The test fuels investigated were Karanja biodiesel blended with diesel (KB5, KB20), methanol blended with diesel (M5) and baseline mineral diesel. Fourier transform infrared (FTIR) emission analyzer was used to measure unregulated emission species and raw exhaust gas emission analyzer was used to measure regulated emission species in exhaust. Results show an increasing trend for some of the unregulated species from blends of biodiesel such as formaldehyde, acetaldehyde, ethanol, n-butane however methane reduced upon using these oxygenated fuel blends except methanol, compared to baseline mineral diesel. Nevertheless, no significant changes were observed for sulfur dioxide, iso-butane, n-octane, n-pentane, formic acid, benzene, acetylene and ethylene upon using biodiesel and methanol blends.     

Effect of hydrogen enrichment and TiO2 nanoparticles on waste cooking palm biodiesel run CRDI engine

In this study, we deal with the production and utilization of waste-cooking palm biodiesel (WCB) and.evaluated the influence of the addition of titanium dioxide (TiO₂) nanoparticles in hydrogen-enriched single-cylinder CRDI diesel engine. XRD, SEM, and EDX decide the structure and morphology of TiO₂ nanoparticles. The TiO₂ nanoparticles were dispersed in the tested fuels at a dosage of 50–75 ppm with the aid of ultra-sonication. Based on the oxidation stability study, the B20 + 75 ppm (TiO₂) fuel blend is the pilot fuel for the engine test. Further, the engine is enriched with a hydrogen (H₂) flow of 10 lpm. Results revealed that the performance parameters were improved with the addition of H₂ enrichment and TiO₂ nanoparticles compared to D. The brake thermal efficiency of the engine was improved by 8.21%. In comparison, brake-specific fuel consumption decreased by 42.86%. Furthermore, adding nanoparticles also reduced CO and HC emissions by 74% and 27.27%, respectively, whereas the NO_x emission was slightly increased. Thus, the findings demonstrated that hydrogen-enriched nanoparticles added to biodiesel might be considered a substitute for fossil fuels and report a positive impact on diesel engine performance without requiring significant modifications.     

Assessing the effects of partially decarbonising a diesel engine by co-fuelling with dissociated ammonia

The proven feasibility of ammonia combustion in compression-ignition engines has led to it being considered as a carbon-free replacement for diesel fuel. Due to its high auto-ignition temperature, however, a more realistic strategy would be to aim for a step-change reduction in carbon emissions by co-fuelling a diesel engine with ammonia. In assessing this strategy, ammonia gas was introduced into the air-intake manifold of a compression-ignition engine, while diesel fuel was injected directly into the cylinder to ignite the mixture. By substituting only 3% of the air intake by ammonia, the diesel consumption and the CO₂ emissions decreased by 15%. The combustion and emission characteristics were then compared when the same percentage of air intake (by mass) was substituted by either dissociated ammonia (a mixture of H₂, N₂ with small percentages of NH₃) or pure hydrogen, to mimic the other possible forms in which the co-fuel can be delivered to the engine. The addition of pure hydrogen resulted in the best engine performance, both in terms of combustion efficiency and regulated emission quality. The thermal combustion efficiency declined by only ∼0.5% when the H₂ was replaced by undissociated ammonia at low load, but N₂O now appeared in the emissions. Co-fuelling the engine with dissociated ammonia may provide the ideal compromise in terms of thermal combustion efficiency and emission quality, while also providing a waste-heat recovery mechanism.     

Analysis of blended fuel properties and engine performance with palm biodiesel–diesel blended fuel

Depleting fossil fuel sources accompanied by continuously growing energy demands lead to increased interest in alternative energy sources. Blended biodiesel–diesel fuel has been approved as a commercial fuel at a low blending ratio. However, problems related to fuel properties are persistent at high blending ratios. Hence, in this study, the feasibility of biodiesel produced from palm oil was investigated. Characterization of blended fuel properties with increasing palm biodiesel ratio is conducted to evaluate engine performance test results. The qualifying of blended fuel properties was used to indicate the maximum blending ratio suitable for use in unmodified diesel engines according to the blended fuel standard ASTM D7467. The property test results revealed that blended fuel properties meet blended fuel standard requirements at up to 30% palm oil biodiesel. Furthermore, blending is efficient for reduction of the pour point from 14 °C for unblended biodiesel to less than 0 °C at a 30% biodiesel blending ratio. However, the energy content reduces by about 1.42% for each 10% increment of biodiesel. Engine test results demonstrated that there was no statistically significant difference for engine brake thermal efficiency among tested blended fuels compared to mineral diesel, and the lowest engine cyclic variation was achieved with blended fuel B30.     

Emission analysis of diesel engine fueled with soybean biodiesel and its water blends

The present study is carried out to formulate stable water-in-soybean biodiesel emulsion fuel and investigate its emission characteristics in a single cylinder diesel engine. Four types of emulsion fuels, which consist of a different percentage of water (5%, 10%, 15%, and 20%) in soybean biodiesel, were prepared with suitable surfactant and properties were measured. The physicochemical properties are on par with EN 14214 standards. The experimental result of test fuels indicates that the soybean biodiesel promotes a lower level of hydrocarbon (HC), carbon monoxide (CO) and smoke emissions compared to base diesel except for nitrogen oxide (NOx) emission. Increase in water concentration with soybean biodiesel significantly reduces the NOx emission and smoke opacity. The HC and CO emissions are further reduced with emulsified biodiesel up to 10% water concentration and beyond that limit, marginal increases are recorded. Overall, it is observed that inclusion of water with soybean biodiesel reduces the HC, CO, NOx and smoke emissions when compared to base diesel and soybean biodiesel, and 10% water in soybean biodiesel is an appropriate solution to reduce the overall emissions in the soybean-fuelled diesel engine.     

The effect of biodiesel and bioethanol blended diesel fuel on nanoparticles and exhaust emissions from CRDI diesel engine

Biofuel (biodiesel, bioethanol) is considered one of the most promising alternative fuels to petrol fuels. The objective of the work is to study the characteristics of the particle size distribution, the reaction characteristics of nanoparticles on the catalyst, and the exhaust emission characteristics when a common rail direct injection (CRDI) diesel engine is run on biofuel-blended diesel fuels. In this study, the engine performance, emission characteristics, and particle size distribution of a CRDI diesel engine that was equipped with a warm-up catalytic converters (WCC) or a catalyzed particulate filter (CPF) were examined in an ECE (Economic Commission Europe) R49 test and a European stationary cycle (ESC) test. The engine performance under a biofuel-blended diesel fuel was similar to that under D100 fuel, and the high fuel consumption was due to the lowered calorific value that ensued from mixing with biofuels. The use of a biodiesel–diesel blend fuel reduced the total hydrocarbon (THC) and carbon monoxide (CO) emissions but increased nitrogen oxide (NO_x) emissions due to the increased oxygen content in the fuel. The smoke emission was reduced by 50% with the use of the bioethanol–diesel blend. Emission conversion efficiencies in the WCC and CPF under biofuel-blended diesel fuels were similar to those under D100 fuel. The use of biofuel-blended diesel fuel reduced the total number of particles emitted from the engine; however, the use of biodiesel–diesel blends resulted in more emissions of particles that were smaller than 50 nm, when compared with the use of D100. The use of a mixed fuel of biodiesel and bioethanol (BD15E5) was much more effective for the reduction of the particle number and particle mass, when compared to the use of BD20 fuel.     

Effect of diethyl ether additive in Jatropha biodiesel-diesel fuel blends on the variable compression ratio diesel engine performance and emissions characteristics at different loads and compression ratios

An investigational analysis was performed to assess the effect of diethyl ether (DEE) that acts as an oxygenated additive in Jatropha biodiesel and diesel fuel blends on the performance enhancement and emission reduction of a variable compression ratio (CR) diesel engine. The DEE (10% vol) is added to different concentration levels of Jatropha biodiesel (B5, B10, and B20). The Jatropha biodiesel (JME) is prepared by the transesterification reaction and DEE is prepared through acid distillation of ethanol. The various tests were conducted by varying the loads at 25%, 50%, 75%, and 100% (3, 6, 9, and 12 kg). The DEE was entirely miscible with diesel and Jatropha biodiesel, the addition of DEE increases the cetane and calorific value, kinematic viscosity of the fuel blends compared with neat diesel or Jatropha biodiesel. The results illustrate that at higher loads and CRs, the engine performance parameters such as brake thermal efficiency enhances and reduces the brake-specific fuel consumption for DEE-Jatropha biodiesel-diesel fuel blends. Blend A3 (10% DEE + 20% JME + 70% diesel) demonstrated an overall improvement in the engine performance parameters and emission characteristics compared with A1, A2, and diesel fuel blends. It is concluded that the DEE-JME-diesel fuel blend is a promising source of fuel for diesel engine at maximum load.     

Environmental effect of CeO2 nanoadditive on biodiesel

The role of additives for biodiesel has gained most reliable position in the current scenario as they reasonably formulate base fuel composition that contribute to efficiency reliability and long life of an engine. They also can have surprisingly large effects even when used in low (ppm) range. With the use of fuel additives for blending the biodiesel in compression ignition engine, one can expect diminished engine exhaust emission characteristics and also improved fuel properties, which could enhance the combustion characteristics. There are many reports based on the biodiesel blended with nanoparticles additive; however, there is a vacuum in the research pertaining to the use of the most common, low-cost, and eco-friendly CeO₂ nanoparticles as additive to prepare blended canola biodiesel fuel. Moreover, there are very few literatures available on the usage of CeO₂ blended biodiesel. In the present study, an attempt has been made to reduce and understand the engine emission of biodiesel blended with CeO₂ nanoparticles.     

生物柴油对直喷式柴油机燃烧和排放的影响

列举了生物柴油的基本物化特性。介绍了生物柴油对直喷式柴油机燃烧和排放的影响。相比普通柴油,燃用生物柴油可以减少CO、CO_2、SO_2、HC、微粒以及碳烟的排放且不会影响柴油机工作性能。采用EGR、乳化油、多次喷射及微粒捕捉器等措施可以进一步降低使用生物柴油的微粒和NOx排放。生物柴油作为一种可再生的替代能源,以其良好的环境效应受到越来越多的关注。     

Effect of metal based additive on performance emission and combustion characteristics of diesel engine fuelled with biodiesel

This study investigates the use of ferric chloride (FeCl₃) as a fuel borne catalyst (FBC) for waste cooking palm oil based biodiesel. The metal based additive was added to biodiesel at a dosage of 20 μmol/L. Experiments were conducted to study the effect of ferric chloride added to biodiesel on performance, emission and combustion characteristics of a direct injection diesel engine operated at a constant speed of 1500 rpm at different operating conditions. The results revealed that the FBC added biodiesel resulted in a decreased brake specific fuel consumption (BSFC) of 8.6% while the brake thermal efficiency increased by 6.3%. FBC added biodiesel showed lower nitric oxide (NO) emission and slightly higher carbon dioxide (CO₂) emission as compared to diesel. Carbon monoxide (CO), total hydrocarbon (THC) and smoke emission of FBC added biodiesel decreased by 52.6%, 26.6% and 6.9% respectively compared to biodiesel without FBC at an optimum operating condition of 280 bar injection pressure and 25.5^o bTDC injection timing. Higher cylinder gas pressure, heat release rate and shorter ignition delay period were observed with FBC added biodiesel at these conditions.     

Effects of hydrogenation of fossil fuels with hydrogen and hydroxy gas on performance and emissions of internal combustion engines

Energy security is an important consideration for development of future transport fuels. Among the all gaseous fuels hydrogen or hydroxy (HHO) gas is considered to be one of the clean alternative fuels. Hydrogen is very flammable gas and storing and transporting of hydrogen gas safely is very difficult. Today, vehicles using pure hydrogen as fuel require stations with compressed or liquefied hydrogen stocks at high pressures from hydrogen production centres established with large investments.Different electrode design and different electrolytes have been tested to find the best electrode design and electrolyte for higher amount of HHO production using same electric energy. HHO is used as an additional fuel without storage tanks in the four strokes, 4-cylinder compression ignition engine and two-stroke, one-cylinder spark ignition engine without any structural changes. Later, previously developed commercially available dry cell HHO reactor used as a fuel additive to neat diesel fuel and biodiesel fuel mixtures. HHO gas is used to hydrogenate the compressed natural gas (CNG) and different amounts of HHO-CNG fuel mixtures are used in a pilot injection CI engine. Pure diesel fuel and diesel fuel + biodiesel mixtures with different volumetric flow rates are also used as pilot injection fuel in the test engine. The effects of HHO enrichment on engine performance and emissions in compression-ignition and spark-ignition engines have been examined in detail. It is found from the experiments that plate type reactor with NaOH produced more HHO gas with the same amount of catalyst and electric energy. All experimental results from Gasoline and Diesel Engines show that performance and exhaust emission values have improved with hydroxy gas addition to the fossil fuels except NO_x exhaust emissions. The maximum average improvements in terms of performance and emissions of the gasoline and the diesel engine are both graphically and numerically expressed in results and discussions. The maximum average improvements obtained for brake power, brake torque and BSFC values of the gasoline engine were 27%, 32.4% and 16.3%, respectively. Furthermore, maximum improvements in performance data obtained with the use of HHO enriched biodiesel fuel mixture in diesel engine were 8.31% for brake power, 7.1% for brake torque and 10% for BSFC.