A parametric study on thermodynamic performance of a SOFC oriented hybrid energy system

In this paper, a parametric study of the performance of a SOFC system for several types of supplied fuels is carried out. A SOFC system which is assisted by some energy resources, namely biomass, solar energy and natural gas, i.e. methane, is designed in order to realize this study.This system consists of four main components which are Solid Oxide Fuel Cell (SOFC), Proton Exchange Membrane Electrolyser (PEME), Photovoltaic system (PV), and Anaerobic Digester for biogas production (AD). The system is designed by considering three fundamental operation modes which are day-time (M1), night-time (M2), and winter-time (M3), in accordance with the duration of solar irradiation period. In order to evaluate the performance of the system, comprehensive energy and exergy analyses are performed, as major system parameters are changed for the operation modes considered. In this study, maximum total energy and exergy efficiency values of 0.60 and 0.49, respectively, are achieved when the overall energy and exergy performance of the system is evaluated, at 5500 A/m² current density for M3 operation mode among the three operation modes considered. Finally, the maximum net electrical energy and exergy efficiencies are achieved for 633 °C SOFC fuel inlet temperature and 8000 A/m² current density, in this study.     

Novel hybrid two-stage alkali metal thermoelectric converter and thermally regenerative electrochemical cycle to exploit waste heat of solid oxide fuel cell: Performance assessment and optimization

An innovative combination of a two-stage alkali metal thermoelectric converter (TAMTEC), and thermally regenerative electrical cycle (TREC) is employed to utilize the high-quality heat dissipated from solid oxide fuel cell (SOFC) for further electricity production. The superiority and effectiveness of the SOFC-TAMTEC-TREC system are verified compared to existing SOFC-based hybrid systems and sole SOFC. The performance of the system based on energy, exergy, and economic indicators is evaluated by varying the main design parameters. Parametric assessment demonstrates that the SOFC-TAMTEC-TREC system can reach the maximum power density of 12126 W m^?2 with energy and exergy efficiencies of 47.13% and 50.46% as TAMTEC proportional constant increases to 10^7.5 m² and rising SOFC pore and gain diameters to 3.77 × 10^?6 m and 2.5 × 10^?6 m, respectively reduce the cost rate density of system by 3.55 $ h^?1 m^?2. Furthermore, to achieve the maximum power density and exergy efficiency, and minimum cost rate density, NSGA-III multi-criteria optimization, and decision-making techniques are conducted. Outcomes indicate that Shannon entropy leads to the maximum power density of 8597.2 W m^?2 with a 35.94% enhancement relative to a single SOFC and 1 $ h^?1 m^?2 increment in cost rate density of the hybrid system, while LINMAP and TOPSIS ascertain the minimum increase in the cost rate density by 0.6 $ h^?1 m^?2 with 31.04% improvement in power density relative to single SOFC.     

An oil palm-based biorefinery concept for cellulosic ethanol and phytochemicals production: Sustainability evaluation using exergetic life cycle assessment

In this study, thermo-environmental sustainability of an oil palm-based biorefinery concept for the co-production of cellulosic ethanol and phytochemicals from oil palm fronds (OPFs) was evaluated based on exergetic life cycle assessment (ExLCA). For the production of 1 tonne bioethanol, the exergy content of oil palm seeds was upgraded from 236 MJ to 77,999 MJ during the farming process for OPFs production. Again, the high exergy content of the OPFs was degraded by about 62.02% and 98.36% when they were converted into cellulosic ethanol and phenolic compounds respectively. With a total exergy destruction of about 958,606 MJ (internal) and 120,491 MJ (external or exergy of wastes), the biorefinery recorded an overall exergy efficiency and thermodynamic sustainability index (TSI) of about 59.05% and 2.44 per tonne of OPFs' bioethanol respectively. Due to the use of fossil fuels, pesticides, fertilizers and other toxic chemicals during the production, the global warming potential (GWP = 2265.69 kg CO₂ eq.), acidification potential (AP = 355.34 kg SO₂ eq.) and human toxicity potential (HTP = 142.79 kg DCB eq.) were the most significant environmental impact categories for a tonne of bioethanol produced in the biorefinery. The simultaneous saccharification and fermentation (SSF) unit emerged as the most exergetically efficient (89.66%), thermodynamically sustainable (TSI = 9.67) and environmentally friendly (6.59% of total GWP) production system.     

Energy,exergy, and environmental (3E) assessments of an integrated molten carbonate fuel cell (MCFC), Stirling engine and organic Rankine cycle (ORC) cogeneration system fed by a biomass-fueled gasifier

In this paper, a novel syngas-fed combined cogeneration plant, integrating a biomass gasifier, a molten carbonate fuel cell (MCFC), a heat recovery steam generator (HRSG) unit, a Stirling engine, and an organic Rankine cycle (ORC), is introduced and thermodynamically analyzed to recognize its potentials compared to the previous solo/combined systems. For the proposed system, energetic, exergetic as well as environmental evaluations are performed. Based on the results, the gasifier and the fuel cell have a significant contribution to the exergy destruction of the system. Through a parametric study, the current density and the stack temperature difference are known as the main effective factors on the plant performance. Meanwhile, dividing the whole system into three sub-models, i.e., model (1): power production plant including the gasifier and MCFC without including Stirling engine, HRSG, and ORC unit, model (2): the cogeneration system without ORC unit, and model (3): the whole cogeneration system, an environmental impact assessment is carried out regarding CO₂ emission. Considering paper as biomass revealed that maximum value of exergy efficiency is 50.18% with CO₂ emissions of 28.9 × 10⁻² t.MWh⁻¹ which compared to the solo MCFC system indicates 28.40% increase and 13.3 × 10⁻² t.MWh⁻¹ decrease in exergy efficiency and CO₂ emission, respectively.     

A study on sustainability analysis of solid oxide fuel cell and proton exchange membrane electrolyzer integrated hybrid multi-generation system

The main objective of this study is to perform the sustainability analysis of a proton exchange membrane electrolyzer (PEME) and solid oxide fuel cell (SOFC) integrated hybrid multi-generation system that is designed to operate in four modes. In this regard, the effects of performance parameters of PEME and SOFC systems on the sustainability of hybrid multi-generation system are parametrically investigated. Accordingly, in terms of hydrogen production, the best value of hydrogen production is estimated to be 33.09 kg/h for both M1 and M2 operating modes. Moreover, in terms of the sustainability indicators, the maximum power generation of the system is calculated to be 13.9 MW while maximum energy and exergy efficiencies and exergetic sustainability index are respectively obtained to be 89%, 47% and 0.85 in M3 operating mode. However, minimum total product cost per unit energy generation is estimated to be 15.64 $/GJ in M1 operating mode. Furthermore, in terms of the exergetic sustainability index, the maximum effect ratios of the SOFC and PEME on the hybrid multi-generation system are respectively determined to be 5.076 and 16.124 in M1 operating mode.     

Life cycle sustainability assessment of electricity options for the UK

The UK electricity mix will change significantly in the future. This provides an opportunity to consider the full life cycle sustainability of the options currently considered as most suitable for the UK: gas, nuclear, offshore wind and photovoltaics (PV). In an attempt to identify the most sustainable options and inform policy, this paper applies a sustainability assessment framework developed previously by the authors to compare these electricity options. To put discussion in context, coal is also considered as a significant contributor to the current electricity supply. Each option is assessed and compared in terms of its economic, environmental and social implications, using a range of sustainability indicators. The results show that no one technology is superior and that certain trade‐offs must be made. For example, nuclear and offshore wind power have the lowest life cycle environmental impacts, except for freshwater ecotoxicity for which gas is the best option; coal and gas are the cheapest options (£74 and 66/MWh, respectively, at 10% discount), but both have high global warming potential (1072 and 379 g CO₂ eq./kWh); PV has relatively low global warming potential (88 g CO₂ eq./kWh) but high cost (£302/MWh), as well as high ozone layer and resource depletion. Nuclear, wind and PV increase some aspects of energy security: in the case of nuclear, this is due to inherent fuel storage capabilities (energy density 290 million times that of natural gas), whereas wind and PV decrease fossil fuel import requirements by up to 0.2 toe/MWh. However, all three options require additional installed capacity for grid management. Nuclear also poses complex risk and intergenerational questions such as the creation of 10.16 m³/TWh of nuclear waste for long‐term geological storage. Copyright © 2012 John Wiley & Sons, Ltd.     

Exergetic analysis of transcritical CO2 residential air-conditioning system based on experimental data

The experimental system for the transcritical CO₂ residential air-conditioning with an internal heat exchanger was built. The effects of working conditions on system performance were experimentally studied. Based on the experimental dada, the second law analysis on the transcritical CO₂ system was performed. The effects of working conditions on the total exergetic efficiency of the system were investigated. The results show that in the studied parameter ranges, the exergetic efficiency of the system increases with the increases of gas cooler side air inlet temperature, gas cooler side air inlet velocity and evaporating temperature. And it will decrease with the increases of evaporator side air inlet temperature and velocity. Then, a complete exergetic analysis was performed for the entire CO₂ transcritical cycle including compressor, gas cooler, expansion valve, evaporator and internal heat exchanger under different working conditions. The average exergy loss in gas cooler is the highest one under all working conditions which is about 30.7% of the total exergy loss in the system. The second is the average exergy loss in expansion valve which is about 24.9% of the total exergy loss, followed by the exergy losses in evaporator and compressor, which account for 21.9% and 19.5%, respectively. The exergy loss in internal heat exchanger is the lowest one which is only about 3.0%. So in the optimization design of the transcritical CO₂ residential air-conditioning system more attentions should be paid to the gas cooler and expansion valve.     

Energy and exergy analyses of OMW solar drying process

The energy and exergy analyses of the drying process of olive mill wastewater (OMW) using an indirect type natural convection solar dryer are presented. Olive mill wastewater gets sufficiently dried at temperatures between 34 °C and 52 °C. During the experimental process, air relative humidity did not exceed 58%, and solar radiation ranged from 227 W/m² to 825 W/m². Drying air mass flow was maintained within the interval 0.036–0.042 kg/s. Under these experimental conditions, 2 days were needed to reduce the moisture content to approximately one-third of the original value, in particular from 3.153 g_water/g_{dry matter} down to 1.000 g_water/g_{dry matter}.Using the first law of thermodynamics, energy analysis was carried out to estimate the amounts of energy gained from solar air heater and the ratio of energy utilization of the drying chamber. Also, applying the second law, exergy analysis was developed to determine the type and magnitude of exergy losses during the solar drying process. It was found that exergy losses took place mainly during the second day, when the available energy was less used. The exergy losses varied from 0 kJ/kg to 0.125 kJ/kg for the first day, and between 0 kJ/kg and 0.168 kJ/kg for the second. The exergetic efficiencies of the drying chamber decreased as inlet temperature was increased, provided that exergy losses became more significant. In particular, they ranged from 53.24% to 100% during the first day, and from 34.40% to 100% during the second.     

Exergy, exergoeconomic and environmental analyses and evolutionary algorithm based multi-objective optimization of combined cycle power plants

A comprehensive exergy, exergoeconomic and environmental impact analysis and optimization is reported of several combined cycle power plants (CCPPs). In the first part, thermodynamic analyses based on energy and exergy of the CCPPs are performed, and the effect of supplementary firing on the natural gas-fired CCPP is investigated. The latter step includes the effect of supplementary firing on the performance of bottoming cycle and CO₂ emissions, and utilizes the first and second laws of thermodynamics. In the second part, a multi-objective optimization is performed to determine the “best” design parameters, accounting for exergetic, economic and environmental factors. The optimization considers three objective functions: CCPP exergy efficiency, total cost rate of the system products and CO₂ emissions of the overall plant. The environmental impact in terms of CO₂ emissions is integrated with the exergoeconomic objective function as a new objective function. The results of both exergy and exergoeconomic analyses show that the largest exergy destructions occur in the CCPP combustion chamber, and that increasing the gas turbine inlet temperature decreases the CCPP cost of exergy destruction. The optimization results demonstrates that CO₂ emissions are reduced by selecting the best components and using a low fuel injection rate into the combustion chamber.     

Exergetic analysis of solid oxide fuel cell and biomass gasification integration with heat pipes

This paper presents an exergetic analysis of a combined heat and power (CHP) system, integrating a near-atmospheric solid oxide fuel cell (SOFC) with an allothermal biomass fluidised bed steam gasification process. The gasification heat requirement is supplied to the fluidised bed from the SOFC stack through high-temperature sodium heat pipes. The CHP system was modelled in AspenPlus™ software including sub-models for the gasification, SOFC, gas cleaning and heat pipes. For an average current density of 3000 A m⁻² the proposed system would consume 90 kg h⁻¹ biomass producing 170 kW_e net power with a system exergetic efficiency of 36%, out of which 34% are electrical.     

Development and assessment of concentrated solar energy driven ammonia synthesis from liquefied natural gas

The proposed system targets the production of carbon dioxide-free hydrogen from liquefied natural gas through a solar-driven catalytic thermal cracking process integrated into the ammonia synthesis unit. The catalytic material is being regenerated in an adjacent vessel by burning the deposited coke. As a result, pure carbon dioxide stream is obtained and can be used directly in urea synthesis, sequestration or other related applications. It is expected that the system will reduce the amount of fossil fuel consumption in the ammonia synthesis and mitigate the associated environmental impacts. The energetic and exergetic analyses are carried out to assess the performance of the developed system and to identify the optimum operating conditions. At an operating temperature of 900 °C of thermocatalytic cracking, the optimum pressure for optimal production of hydrogen is determined to be 23.8 bar. The corresponding overall energy and exergy efficiencies are calculated as 35.8% and 37.4%, respectively. At the same conditions, the energy and exergy efficiencies of the thermal cracking unit reach 61.8% and 59.3%, respectively. Several parametric studies are conducted to evaluate the effects of operating conditions at the cracker, irradiance day-night ratio, and consideration of CO₂ for transport and sequestration activities on the overall performance and production of the system. Ammonia production can reach 974 Metric Tons per Day (MTPD) and 893 MTPD considering operating conditions of 900 °C and 800 °C, and inlet LNG flow rate of 688 MTPD and 630 MTPD, respectively.     

Thermo-environmental analysis of a new molten carbonate fuel cell-based tri-generation plant using stirling engine,generator absorber exchanger and vapour absorption refrigeration: A comparative study

This study aims to present a novel tri-generation plant consisting of a molten carbonate fuel cell (MCFC) unit coupled with a Stirling engine (SE), a heat recovery steam generator (HRSG), and two types of absorption refrigeration cycles (ARCs), i.e., Generator Absorber eXchanger (GAX) and Vapour Absorption Refrigeration (VAR). The proposed system is evaluated from energy, exergy, as well as environmental impact (3E) points of view. To carry out the parametric study, three sub-models are also introduced for the whole system. The sub-model (1) investigates the solo MCFC with the new configuration. In the sub-model (2), the SE and HRSG are added to boost the power generation and overall system efficiency through employing the heat wasted in the sub-model (1). In the last sub-model, for cooling purposes, the surplus heat of MCFC is reutilized using an absorption refrigeration cycle. Besides, to make a comparative study between GAX and VAR systems, the sub-model (3) is classified into two different schemes: (a) with a VAR cycle, and (b) with a GAX cycle. The results reveal that the exergy efficiency and CO₂ emissions of the sub-models (1), (2), and (3) are 48.04%, 51.24%, 52.35% (VAR cycle), 52.12% (GAX cycle), 0.388 t/MWh, 0.364 t/MWh, 0.357 t/MWh (VAR cycle), and 0.358 t/MWh (GAX cycle), respectively. Either with GAX or VAR cycle, the proposed system indicates an acceptable standard of functionality in thermodynamic and environmental perspectives.     

Energy and exergy analyses of a combined ammonia-fed solid oxide fuel cell system for vehicular applications

In this study, both energetic and exergetic performances of a combined heat and power (CHP) system for vehicular applications are evaluated. This system proposes ammonia-fed solid oxide fuel cells based on proton conducting electrolyte (SOFC-H⁺) with a heat recovery option. Fuel consumption of combined fuel cell and energy storage system is investigated for several cases. The performance of the portable SOFC system is studied in a wide range of the cell’s average current densities and fuel utilization ratios. Considering a heat recovery option, the system exergy efficiency is calculated to be 60-90% as a function of current density, whereas energy efficiency varies between 60 and 40%, respectively. The largest exergy destructions take place in the SOFC stack, micro-turbine, and first heat exchanger. The entropy generation rate in the CHP system shows a 25% decrease for every 100 °C increase in average operating temperature.     

Thermodynamic modeling and exergy investigation of a hydrogen-based integrated system consisting of SOFC and CO2 capture option

The current study deals with the thermodynamic modeling of an innovative integrated plant based on solid oxide fuel cell (SOFC) with liquefied natural gas (LNG) cold energy supply. For the suggested innovative plant the energy, and exergy simulations are fully extended and the plant comprehensively analyzed. According to mathematical simulations of the proposed plant, a MATLAB code has been extended. The results indicate that under considered initial conditions, the efficiencies of SOFC and net power generation calculated 58% and 78%, respectively and the CO₂-capture rate is obtained 79 kg/h. This study clearly shows that the integrated system reached high efficiency while having zero emissions. In addition, the efficiencies and net amount of power generation, cooling or heating output and SOFC power generation are discussed in detail as a function of different variables such utilization factor, air/fuel ratio, or SOFC inlet temperature. For enhancing the power production efficiency of SOFC, the net electricity, and CCHP exergy efficiency the plant should run in higher utilization factor and lower air/fuel ration also it's important to approximately set SOFC temperature to its ideal temperature.     

Exergetic sustainability indicators for a high pressure hydrogen production and storage system

This study examines the exergetic sustainability effect of PEM electrolyzer (PEME) integrated high pressure hydrogen gas storage system whose capacity is 3 kg/h. For this purpose, the indicators, previously used in the literature, are taken into account and their variations are parametrically studied as a function of the PEME operating pressure and storage pressure by considering i) PEME operating temperature at 70 °C, ii) PEME operating pressures at 10, 30, 50 and 100 bar, iii) hydrogen gas flow rate at 3 kg/h and iv) storage pressure between 200 and 900 bar. Consequently, the results from the parametric investigation indicate that, with the ascent of storage pressure from 200 to 900 bar at a constant PEME operating pressure (=50 bar), exergetic efficiency changes decreasingly between 0.612 and 0.607 while exergetic sustainability between 1.575 and 1.545. However, it is estimated that waste exergy ratio changes increasingly between 0.388 and 0.393 while environmental effect factor between 0.635 and 0.647. Additionally, it is said that the higher PEME outlet pressure causes the higher exergetic sustainability index, the lower environmental effect factor, the lower waste exergy output, the higher exergetic efficiency. However, the higher storage pressure causes the lower exergetic efficiency, the higher waste exergy output, the higher environmental effect factor and the lower exergetic sustainability index. Thus, it is recommended that this type of the system should be operated at higher PEME outlet pressure, and at an optimum hydrogen storage pressure.     

Exergoeconomic analysis of a hybrid system based on steam biomass gasification products for hydrogen production

In this paper, a conceptual hybrid biomass gasification system is developed to produce hydrogen and is exergoeconomically analyzed. The system is based on steam biomass gasification with the lumped solid oxide fuel cell (SOFC) and solid oxide electrolyser cell (SOEC) subsystem as the core components. The gasifier gasifies sawdust in a steam medium and operates at a temperature range of 1023-1423 K and near atmospheric pressure. The analysis is conducted for a specific steam biomass ratio of 0.8 kmol-steam/kmol-biomass. The gasification process is assumed to be self-thermally standing. The pressurized SOFC and SOEC are of planar types and operate at 1000 K and 1.2 bar. The system can produce multi-outputs, such as hydrogen (with a production capacity range of 21.8-25.2 kgh⁻¹), power and heat. The internal hydrogen consumption in the lumped SOFC-SOEC subsystem increases from 8.1 to 8.6 kg/h. The SOFC performs an efficiency of 50.3% and utilizes the hydrogen produced from the steam that decomposes in the SOEC. The exergoeconomic analysis is performed to investigate and describe the exergetic and economic interactions between the system components through calculations of the unit exergy cost of the process streams. It obtains a set of cost balance equations belonging to an exergy flow with material streams to and from the components which constitute the system. Solving the developed cost balance equations provides the cost values of the exergy streams. For the gasification temperature range and the electricity cost of 0.1046 $/kWh considered, the unit exergy cost of hydrogen ranges from 0.258 to 0.211 $/kWh.     

Exergetic analysis and optimization of a solar-powered reformed methanol fuel cell micro-powerplant

The present study proposes a combination of solar-powered components (two heaters, an evaporator, and a steam reformer) with a proton exchange membrane fuel cell to form a powerplant that converts methanol to electricity. The solar radiation heats up the mass flows of methanol-water mixture and air and sustains the endothermic methanol steam reformer at a sufficient reaction temperature (typically between 220 and 300 °C). In order to compare the different types of energy (thermal, chemical, and electrical), an exergetic analysis is applied to the entire system, considering only the useful part of energy that can be converted to work. The effect of the solar radiation intensity and of different operational and geometrical parameters like the total inlet flow rate of methanol-water mixture, the size of the fuel cell, and the cell voltage on the performance of the entire system is investigated. The total exergetic efficiency comparing the electrical power output with the exergy input in form of chemical and solar exergy reaches values of up to 35%, while the exergetic efficiency only accounting for the conversion of chemical fuel to electricity (and neglecting the ‘cost-free’ solar input) is increased up to 59%. At the same time, an electrical power density per irradiated area of more than 920 W m⁻² is obtained for a solar heat flux of 1000 W m⁻².     

Syngas production via partial oxidation of dimethyl ether over Rh/Ce0.75Zr0.25O2 catalyst and its application for SOFC feeding

Dimethyl ether (DME) partial oxidation (PO) was studied over 1 wt% Rh/Ce_0.75Zr_0.25O₂ catalyst at temperatures 300–700 °C, O₂:C molar ratio of 0.25 and GHSV 10000 h⁻¹. The catalyst was active and stable under reaction conditions. Complete conversion of DME was reached at 500 °C, but equilibrium product distribution was observed only at T ≥ 650 °C. High concentration of CH₄ and low contents of CO and H₂ were observed at 500–625 °C 75 cm³ of composite catalyst 0.24 wt% Rh/Ce_0.75Zr_0.25O₂/Al₂O₃/FeCrAl showed excellent catalytic performance in DME PO at O₂:C molar ratio of 0.29 and inlet temperature 840 °C which corresponded to carbon-free region. 100% DME conversion was reached at GHSV of 45,000 h⁻¹. The produced syngas contained (vol. %): 33.4 H₂, 34.8 N₂, 22.7 CO, 3.6 CO₂ and 1.6 CH₄. Composite catalyst demonstrated the specific syngas productivity (based on CO and H₂) in DME PO of 42.8 m³·L_cat⁻¹·h⁻¹ (STP) and the syngas productivity of more than 3 m³·h⁻¹ (STP) that was sufficient for 3 kW_e SOFC feeding. PO of natural gas and liquified petroleum gas can be carried out over the same catalyst with similar productivity, realizing the concept of multifuel hydrogen generation. The syngas composition obtained via DME PO was shown to be sufficient for YSZ-based SOFC feeding.     

Measures of the environmental footprint of the front end of the nuclear fuel cycle

Previous estimates of environmental impacts associated with the front end of the nuclear fuel cycle (FEFC) have focused primarily on energy consumption and CO₂ emissions. Results have varied widely. This work builds upon reports from operating facilities and other primary data sources to build a database of front end environmental impacts. This work also addresses land transformation and water withdrawals associated with the processes of the FEFC. These processes include uranium extraction, conversion, enrichment, fuel fabrication, depleted uranium disposition, and transportation.To allow summing the impacts across processes, all impacts were normalized per tonne of natural uranium mined as well as per MWh(e) of electricity produced, a more conventional unit for measuring environmental impacts that facilitates comparison with other studies. This conversion was based on mass balances and process efficiencies associated with the current once-through LWR fuel cycle.Total energy input is calculated at 8.7 × 10^− 3 GJ(e)/MWh(e) of electricity and 5.9 × 10^− 3 GJ(t)/MWh(e) of thermal energy. It is dominated by the energy required for uranium extraction, conversion to fluoride compound for subsequent enrichment, and enrichment. An estimate of the carbon footprint is made from the direct energy consumption at 1.7 kg CO₂/MWh(e). Water use is likewise dominated by requirements of uranium extraction, totaling 154 L/MWh(e). Land use is calculated at 8 × 10^− 3 m²/MWh(e), over 90% of which is due to uranium extraction. Quantified impacts are limited to those resulting from activities performed within the FEFC process facilities (i.e. within the plant gates). Energy embodied in material inputs such as process chemicals and fuel cladding is identified but not explicitly quantified in this study. Inclusion of indirect energy associated with embodied energy as well as construction and decommissioning of facilities could increase the FEFC energy intensity estimate by a factor of up to 2.     

Exergetic life cycle assessment of a hydrogen production process

Exergetic life cycle assessment (ExLCA) is applied with life cycle assessment (LCA) to a hydrogen production process. This comparative environmental study examines a nuclear-based hydrogen production via thermochemical water splitting using a copper–chlorine cycle. LCA, which is an analytical tool to identify, quantify and decrease the overall environmental impact of a system or a product, is extended to ExLCA. Exergy efficiencies and air pollution emissions are evaluated for all process steps, including the uranium processing, nuclear and hydrogen production plants. LCA results are presented in four categories: acidification potential, eutrophication potential, global warming potential and ozone depletion potential. A parametric study is performed for various plant lifetimes. The ExLCA results indicate that the greatest irreversibility is caused by uranium processing. The primary contributor of the life cycle irreversibility of the nuclear-based hydrogen production process is fuel (uranium) processing, for which the exergy efficiency is 26.7% and the exergy destruction is 2916.3 MJ. The lowest global warming potential per megajoule exergy of hydrogen is 5.65 g CO₂-eq achieved a plant capacity of 125,000 kg H₂/day. The corresponding value for a plant capacity of 62,500 kg H₂/day is 5.75 g CO₂-eq.