Non-dimensional assessments to estimate decompression failure in polymers for hydrogen systems

Polymer materials subjected to gases at high-pressure can have issues during decompression. For instance, a sudden decompression can promote the formation of cavities inside the material. This phenomenon is known as cavitation or eXposive Decompression Failure (XDF). There is a body of scientific articles discussing different aspects of cavitation phenomenon, which indicate that the degree of damage is proportional to saturation pressure, depressurisation rate, and material thickness, among other parameters.In this article we propose a general approach by non-dimensional parameters to estimate the risk of cavitation. Numerical results were validated with bibliographic evidence of cavitation in polymers, for both thermoplastics and elastomers. Present results can be used as guidelines for design of systems involving polymers under high pressure, such as o-rings or liners in type IV hydrogen containers.     

Simulation and exploration of cavitation process during microalgae oil extracting with ultrasonic-assisted for hydrogen production

Microalgae is promising to be used as feedstock resources for hydrogen production due to its high oil and grease contents. This promotes the development of extraction technology of microalgae oil. In this study, based on the Rayleigh-Plesset equation, the effects of temperature, pressure, ultrasonic power and frequency on the bubble motion of ethanol ultrasound cavitation are investigated. Subsequently, the effects of different process parameters on the extraction rate are studied using Schizochytrium sp. as raw material by stirring or ultrasonic-assisted extraction. And the composition of algae extraction oil is analyzed. The results show that the amplitude of cavitation bubbles increases with the increase of ultrasonic power and decrease of ultrasonic frequency. The extraction rate of algae oil reaches 93.76 ± 0.48% when the ultrasonic power is 150 W, the reaction time is 30 min, the temperature is 50 °C and the liquid-solid ratio is 10:1.     

Application of intensive hydrodynamic cavitation in liquids for synthesis of hydrogen and nanoparticles

In this paper, the results of experimental studies of hydrogen and nanoparticles production using intensive hydrodynamic cavitation in liquids are presented. Physicochemical processes occurring in a cavitation bubble at the last stage of its compression are very similar to processes occurring in the explosion chamber.The values of pressure and temperature achieved in this case ensure the thermodynamic stability of the reaction products and the production of a gaseous hydrogen and nanoclusters as a result of decomposition of molecules of liquid, which is confirmed by theoretical calculations.The controlled addition of hydrogen-containing liquids and the change in the compression conditions of cavitation bubbles make it possible to control the process of hydrogen synthesis, which is an important step in the development of modern high-tech alternative energy methods.The pulsation of a spherical cavity is described by the Kirkwood – Bethe equations, which are one of the most accurate mathematical models of pulsation processes at an arbitrary velocity of the cavity boundary. The model allows to describe the process of pulsations of cavitation cavities, conduct comprehensive parametric studies and evaluate the effect of various process parameters on the collapse of cavities.This work continues with the experiments on cavitation synthesis of carbon nanostructures. With the rapid movement of chemically pure hydrocarbons along the profiled channel in the form of a Venturi nozzle, cavitation bubbles form in the liquid, which are then compressed in the working chamber, in which a sharp pressure surge is created. The pressure in the shock wave, which reaches 80–90 MPa, ensures the collapse of cavitation bubbles close to adiabatic compression. As a result of the number of rapidly occurring physicochemical processes of evaporation, heating, and thermal dissociation of hydrocarbon vapors, a solid carbon phase including graphene oxide nanoparticles and a gaseous hydrogen-containing phase are synthesized in the cavitation, which is then subjected to separation. Synthesized graphene oxide nanoparticles possess activated surface due to the cavitation action and can be subsequently used as substrates for modification with functional nanoparticles, e.g. silver nanoparticles with antibacterial properties.The article is of great help to scientists and design engineers who are engaged in the development of promising hydrogen generating facilities and hydrogen complexes.     

Salinity,temperature and pressure effect on hydrogen wettability of carbonate rocks

Hydrogen had been injected into the geologic formations, and the geologic formation wettability would influence the hydrogen storage. Hydrogen wettability of sandstone reservoirs (quartz), mica and other rocks have been explored in the previous study. However, the research on hydrogen wettability of carbonate rocks was lacked. In this study, we studied the carbonate rock wettability alteration when exposed to the hydrogen environments. Salinity, temperature and pressure effect on H₂/carbonate rock/brine wettability were explored. When the solutions ions concentration increased, the advancing/receding contact angle would increase, and divalent ions could make the contact angle higher than monovalent ion, which was because ions could compress the electric double layer. The carbonate rock powder in brine showed negative charge, and the zeta potential increased with higher ions concentration. When temperature increased and the pressure decreased, the contact angle would decrease, which was related to the H₂ gas density and molecular interactions.     

Determination of key parameters responsible for polymeric liner collapse in hyperbaric type IV hydrogen storage vessels

Depressurization tests at a laboratory scale, coupled with numerical modelling, are used to determine the key parameters responsible for the polymeric liner collapse in hyperbaric type IV hydrogen storage vessels. X-ray tomography allows to determine the damages suffered by the sample during the depressurization step. Results show that the differential pressure induced during the depressurization step between the liner/composite interface and the free surface of the liner is the main factor responsible for the collapse of the liner. For a given temperature, this pressure gradient can be modified by changing the maximum H₂ pressure, the emptying rate or by adding a residual pressure plateau. Temperature is also of prime importance by influencing the yield point of the liner, the interface resistance and the amount of gas dissolved into the vessel. Thus, increasing temperature also increases the risk of liner collapse for the same gas exposure conditions.     

Catalyzed hydrogen spillover for hydrogen storage on microporous organic polymers

Catalyzed hydrogen spillover for hydrogen storage on microporous organic materials has been studied in this work. The method, i.e. “preparation of Pt nanoparticle first and then in situ formation of microporous materials” has been developed for the synthesis of microporous hypercrosslinked polymers with highly dispersed Pt nanoparticles. Hydrogen adsorption isotherms are measured at 77.3 K and up to 1.13 bar, and 298.15 K and up to 19 bar. By containing 2 wt % Pt nanoparticles, the hydrogen storage capacity of hypercrosslinked polymers is enhanced to 0.21 wt % at 298.15 K and 19 bar. Compared to the similar materials without Pt nanoparticles, the H₂ adsorption amount has been enhanced by a factor of 1.75.     

Metal hydride hydrogen storage and compression systems for energy storage technologies

Along with a brief overview of literature data on energy storage technologies utilising hydrogen and metal hydrides, this article presents results of the related R&D activities carried out by the authors. The focus is put on proper selection of metal hydride materials on the basis of AB₅- and AB₂-type intermetallic compounds for hydrogen storage and compression applications, based on the analysis of PCT properties of the materials in systems with H₂ gas. The article also presents features of integrated energy storage systems utilising metal hydride hydrogen storage and compression, as well as their metal hydride based components developed at IPCP and HySA Systems.     

Technical assessment of cryo-compressed hydrogen storage tank systems for automotive applications

On-board and off-board performance and cost of cryo-compressed hydrogen storage are assessed and compared to the targets for automotive applications. The on-board performance of the system and high-volume manufacturing cost were determined for liquid hydrogen refueling with a single-flow nozzle and a pump that delivers liquid H₂ to the insulated cryogenic tank capable of being pressurized to 272 atm. The off-board performance and cost of delivering liquid hydrogen were determined for two scenarios in which hydrogen is produced by central steam methane reforming (SMR) or by central electrolysis. The main conclusions are that the cryo-compressed storage system has the potential of meeting the ultimate target for system gravimetric capacity, mid-term target for system volumetric capacity, and the target for hydrogen loss during dormancy under certain conditions of minimum daily driving. However, the high-volume manufacturing cost and the fuel cost for the SMR hydrogen production scenario are, respectively, 2–4 and 1.6–2.4 times the current targets, and the well-to-tank efficiency is well short of the 60% target specified for off-board regenerable materials.     

Algorithm for optimal pairing of res and hydrogen energy storage systems

The global climate and environmental crisis dictate the need for the development and implementation of environmentally friendly and efficient technical solutions, for example, generation based on renewable energy sources. However, the annually increasing demand for electricity (according to the forecasts of the U.S. Energy Information Administration, the amount of energy consumed for the period 2006–2030 will increase by 44 %) cannot be fully provided by alternative energy. The main reason is not so much the high cost of these technologies, like unstable power generation, which determines the need for an additional reserve of regulated power.The solution to this problem can be the combined use of generation based on renewable energy sources with energy storage units of large capacity. Currently, a promising direction is the use of excess electricity for the production of hydrogen and its further accumulation in hydrogen storage. In this case an additional energy can be generated using industrial fuel cells (electrochemical generators) to compensate for the power shortage.At the same time, the distinctive advantage of hydrogen energy storage systems lies in the ability to accumulate a large amount of energy for long periods of time. This fact makes it possible to increase the reliability of the functioning of the electric power system, to provide power supply with a sufficiently long interruption (in case of faults) or allocation for isolated operation.With an increase in the unit capacity and the share of renewable generation in the total installed capacity, researches that aimed to systematic analysis of the impact of the implemented generation unit and the energy storage system on the parameters of the mode of the electric power system become more relevant. There are a number of tasks can be noted related to determining the optimal location and size of the generation unit and energy storage systems being implemented in terms of reducing power losses and maintaining an appropriate voltage level in the nodes of the electric power system. In this article, a variant of solving the optimization task for a typical 15-bus IEEE scheme is presented by means of software calculation using the bubble sorting method. To achieve this goal, the following tasks were solved: the objective function, which indicates the optimal location and size of the generation unit, and constraints, for example, the available deviation of voltage level, were formed; the software implementation of the algorithm for calculating power flows and power losses using the bubble sorting method was carried out. The results of the work of the program code for two scenarios are presented: for instance, installation of one renewable generation unit with a different range of possible capacities, and are compared with the data obtained in the MATLAB/Simulink software package.     

Potential analysis of hydrogen storage systems in aircraft design

The substitution of fossil fuels with renewable energy sources such as hydrogen is a decisive factor in making aviation environmentally compatible. A key parameter for the use of hydrogen is the storage system. In the design of a flight-capable storage system, not only the mass but especially the volume of the hydrogen has to be considered. Therefore, in this paper different techniques are compared and evaluated from the point of view of their application in aircraft design. The analyses are performed on two reference aircraft, the Airbus A320 and the Embraer E 190, in the short- and medium-haul range. Simplified, it is assumed that the respective max. Take-off mass (MTOM) remains constant. The change of the necessary periphery has no influence on the MTOM. A tank concept could be designed, which can find applications in today's conventional aircraft design.     

Replication of liner collapse phenomenon observed in hyperbaric type IV hydrogen storage vessel by explosive decompression experiments

An experimental design based on representative sample is described in order to reproduce the detachment and deformation of the inner polymer layer (called liner) of hyperbaric hydrogen storage vessels during the emptying step. It is the first step of a better understanding of the mechanisms involved in the creation of a liner collapse. Results showed that a hydraulic testing machine fitted with a pressure hydrogen chamber enables to create a liner collapse on small samples by explosive decompression experiments. Tomographic observations have revealed that the collapse appears at the polymer liner/composite interface in areas that are not sufficiently bonded, nor consistently. Determination of liner collapse amplitudes, assessed by tomography, has underlined that, under some specific conditions, the deformation of the liner is permanent even when hydrogen has completely desorbed from the sample. In addition to liner collapses, composite cracks were also highlighted.     

Hierarchical methodology for modeling hydrogen storage systems. Part I: Scoping models

Detailed models for hydrogen storage systems provide essential design information about flow and temperature distributions, as well as, the utilization of a hydrogen storage media. However, before constructing a detailed model it is necessary to know the geometry and length scales of the system, along with its heat transfer requirements, which depend on the limiting reaction kinetics. More fundamentally, before committing significant time and resources to the development of a detailed model, it is necessary to know whether a conceptual storage system design is viable. For this reason, a hierarchical system of models progressing from scoping models to detailed analyses was developed. This paper, which discusses the scoping models, is the first in a two part series that presents a collection of hierarchical models for the design and evaluation of hydrogen storage systems.     

Hierarchical methodology for modeling hydrogen storage systems. Part II: Detailed models

There is significant interest in hydrogen storage systems that employ a media which either adsorbs, absorbs or reacts with hydrogen in a nearly reversible manner. In any media based storage system the rate of hydrogen uptake and the system capacity is governed by a number of complex, coupled physical processes. To design and evaluate such storage systems, a comprehensive methodology was developed, consisting of a hierarchical sequence of models that range from scoping calculations to numerical models that couple reaction kinetics with heat and mass transfer for both the hydrogen charging and discharging phases. The scoping models were presented in Part I [Hardy BJ, Anton DL. Hierarchical methodology for modeling hydrogen storage systems, Part I: scoping models. Int J Hydrogen Energy 2009;34(5):2269–77.] of this two part series of papers. This paper describes a detailed numerical model that integrates the phenomena occurring when hydrogen is charged and discharged. A specific application of the methodology is made to a system using NaAlH₄ as the storage media.     

Design and validation of Clathrate-CNT systems for solid state hydrogen storage

Solid state hydrogen storage addresses the problems of high pressurization in compressed gaseous state and energy intensive liquefaction in liquid state. Clathrate structures have shown promising results as host material for storing hydrogen as hydrate. The effect of different promoters on improving storage capabilities of clathrates have been studied at 263 K and 10 MPa hydrogen pressure. Hydrogen adsorption kinetics of four different clathrates using promoters Tetrahydrofuran, Tetrahydropyran, 1,3 Dioxolane and 2,3 Dihydrofuran with Multiwall Carbon nanotube as substrate was carried out. The results showed ～1.5 wt% hydrogen adsorption within 90 min using CNT substrate. This is one of the first reports on usage of CNT as a substrate material for hydrogen storage in clathrate systems. It was observed that CNT shows synergitic effect in the hydrogen adsorption with fast kinetics (less than 90 min). The weight of substrate material (CNT) was also taken into consideration while calculating the weight % of hydrogen adsorption. The present study also involves design and simulation of a hydrogen storage canister (using CNT based clathrate) with embedded helical coolant coils on COMSOL Multiphysics software to analyse the effects of temperature management on improving hydrogen storage capability of the clathrate reactor bed. Results of simulation includes variation of hydrate concentration and temperature in clathrate reactor bed with the passage of time. The theoretical studies pave way for validating the scalability of clatharates as a viable hydrogen energy system.     

Development of a hydrogen catalytic heater for heating metal hydride hydrogen storage systems

This paper describes the design, fabrication and performance evaluation of a high efficiency, compact heater that uses the catalytic oxidation of hydrogen to provide heat to a hydrogen storage system. The heater was designed to transfer up to 30 kW of heat from the catalytic reaction to the hydrogen storage system via a recirculating heat transfer fluid.     

System simulation models for on-board hydrogen storage systems

System simulation models for automotive on-board hydrogen storage systems provide a measure of the ability of an engineered system and storage media to meet system performance targets. Thoughtful engineering design for a particular storage media can help the system achieve desired performance goals. This paper presents system simulation models for two different advanced hydrogen storage technologies – a cryo-adsorption system and a metal hydride system. AX-21 superactivated carbon and sodium alanate are employed as representative storage media for the cryo-adsorbent system and the metal hydride system respectively. Lumped parameter models incorporating guidance from detailed transport models are employed in building the system simulation models.     

Large-scale compressed hydrogen storage as part of renewable electricity storage systems

Storing energy in the form of hydrogen is a promising green alternative. Thus, there is a high interest to analyze the status quo of the different storage options. This paper focuses on the large-scale compressed hydrogen storage options with respect to three categories: storage vessels, geological storage, and other underground storage alternatives. In this study, we investigated a wide variety of compressed hydrogen storage technologies, discussing in fair detail their theory of operation, potential, and challenges. The analysis confirms that a techno-economic chain analysis is required to evaluate the viability of one storage option over another for a case by case. Some of the discussed technologies are immature; however, this does not rule out these technologies; rather, it portrays the research opportunities in the field and the foreseen potential of these technologies. Furthermore, we see that hydrogen would have a significant role in balancing intermittent renewable electricity production.     

A new model for the prediction of oxygen interference in hydrogen storage systems

A new model is developed to analyze oxygen interference in hydrogen storage materials. It is based on the competitive adsorption isotherm between the two gases, with the parameters fitted from molecular dynamic simulations. The model is applied to a system consisting of graphene sheets separated by different distances. For a gas-phase mixture of hydrogen (99.9%) and oxygen (0.1%) in interaction with porous graphite of 6.5 Å (optimum size) it can be observed that after 50 cycles of charging/discharging the blocking of active sites of the material by oxygen is ∼10%, due to progressive pollution of the system by oxygen. The model presented here may easily be extended to other systems of interest, involving other blocking species or adsorbent materials.     

Preparation,scale-up and testing of nanoscale,doped amide systems for hydrogen storage

A comparative study of the LiNH₂–MgH₂ hydrogen storage system has been made, and several additives (LiBH₄, KH and ZrCoH₃) have been tested as single catalysts and in various combinations in order to study potential synergistic effects.     

Excellent catalytic effect of LaNi5 on hydrogen storage properties for aluminium hydride at mild temperature

The catalytic effect of rare-earth hydrogen storage alloy is investigated for dehydrogenation of alane, which shows a significantly reduced onset dehydrogenation temperature (86 °C) with a high-purity hydrogen storage capacity of 8.6 wt% and an improved dehydrogenation kinetics property (6.3 wt% of dehydrogenation at 100 °C within 60 min). The related mechanism is that the catalytic sites on the surface of the hydrogen storage alloy and the hydrogen storage sites of the entire bulk phase of the hydrogen storage reduce the dehydrogenation temperature of AlH₃ and improve the dehydrogenation kinetic performance of AlH₃. This facile and effective method significantly improves the dehydrogenation of AlH₃ and provides a promising strategy for metal hydride modification.