Optimisation of dry cell electrolyser and hydroxy gas production to utilise in a diesel engine operated with blends of orange peel oil in dual-fuel mode

This study aims at producing hydroxy (HHO) gas using a dry cell electrolysis setup and utilising it along with orange oil in a diesel engine. First an electrolyser was designed considering the optimised values of the material (SS316L), electrolyte (NaOH), and electrode gap (2 mm). Then the biodiesel obtained from the waste orange peels, after transesterification, were blended with diesel at 25 and 50% by vol. The HHO gas was produced by the water electrolysis method by a plate-type electrolyser having a maximum production rate of 2.5 LPM with NaOH as the electrolyte. HHO gas was inducted through the inlet manifold along with the fresh air at a constant rate of 2 LPM with both the biodiesel blends. The performance, emission, and combustion outcomes of the single cylinder diesel engine for different load conditions (0–100%) were tested for all the blends with and without HHO addition. The results showed a considerable increase in brake thermal efficiency of 1.54% at full load condition, with a noticeable decrease in fuel consumption by 11.1% compared to conventional diesel fuel, was achieved for the O25 blend with HHO induction. Moreover, emissions like hydrocarbon, carbon monoxide and smoke were reduced by 17.6, 29.5, and 12.1%, respectively. However, the improvement in combustion outcomes led to the increase in nitrogen oxides emission by 9.67%. This study helped to understand the production process of HHO gas by dry cell electrolyser and its effect on the blend of orange oil methyl ester and diesel in dual-fuel mode.     

Evaluation of vibration characteristics of a hydroxyl (HHO) gas generator installed diesel engine fuelled with different diesel–biodiesel blends

There are two main reasons of alternative fuel search of scientists: environmental problems resulted from combustion of fossil fuels and limited reserves of crude oil. Biodiesel and Hydrogen (H₂) are two of the most promising alternative fuels with their environmental friendly combustion profiles. The aim of this study was to evaluate vibration level of a hydroxyl (HHO) gas generator installed and diesel engine using different kinds of biodiesel fuels. In this study, at different flow rates, the effect of HHO gas addition on engine vibration performance was investigated with a Mitsubishi Canter 4D34-2A diesel engine. HHO gas introduced to the test engine via its intake manifold with 2, 4 and 6 L per minute (LPM) flow rates when the engine was fuelled with sunflower, canola, and corn biodiesels. The vibration data was collected between 1200 and 2400 rpm engine speeds by 300 rpm intervals. Finally, artificial neural network (ANN) approach was conducted in order to predict the effect of fuel properties and HHO amount on engine vibration level.     

Production and use of HHO gas in IC engines

HHO gas, which is obtained by the electrolysis of water, is a promising alternative fuel. This paper presents a review of important features and techniques used for producing HHO gas. Various aspects of the thermodynamics and chemical kinetics of electrolysis reactions are discussed. Design and operating parameters for improving the gas production rate are identified. Widely different hypotheses regarding the structure and composition of HHO gas are compared in depth. The state of the art on the use of HHO gas in Internal Combustion (IC) engines is presented in the latter part of the paper. It is seen that the introduction of HHO gas increases engine torque, power and thermal efficiency, while simultaneously reducing the formation of NO_x, CO, HC and CO₂. The major challenges in using HHO gas in engines are identified as system complexity, safety, cost and efficiency of electrolysis.     

Impact of HHO produced from dry and wet cell electrolyzers on diesel engine performance,emissions and combustion characteristics

Water electrolysis produces HHO gas by using sodium hydroxide catalyst. Dry and wet cells designs are applied producing the gas flow rates at 0.5 and 0.75 LPM, respectively. Tests are done in a diesel engine at engine speed variation and full load. Performance, combustion characteristics and emissions investigations of diesel engines using HHO gas from dry and wet cells are performed. HHO gas addition enhances the brake thermal efficiency by 2 and 2.5% but the exhaust gas temperature highest decreases for dry and wet cells are 8 and 10%, respectively about diesel oil. The maximum decreases are evaluated as for CO (15, 22%), HC (31, 39%), NO_x (35, 42%) and smoke emissions (25, 35%), respectively for dry and wet cells about diesel fuel. The improvements in cylinder pressures are 5 and 10%, respectively and the heat release rate enhancements are 4.5 and 6.5%, respectively about pure diesel for dry and wet configurations.     

Using HHO (Hydroxy) and hydrogen enriched castor oil biodiesel in compression ignition engine

Hydrogen and HHO enriched biodiesel fuels have not been investigated extensively for compression ignition engine. This study investigated the performance and emissions characteristics of a diesel engine fueled with hydrogen or HHO enriched Castor oil methyl ester (CME)-diesel blends. The production and blending of CME was carried out with a 20% volumetric ratio (CME20) using diesel fuel. In addition, the enrichment of intake air was carried out using pure HHO or hydrogen through the intake manifold with no structural changes – with the exception of the reduction of the amount of diesel fuel – for a naturally aspirated, four cylinder diesel engine with a volume of 3.6 L. Hydrogen amount was kept constant with a ratio of 10 L/min throughout the experiments. Engine performance parameters, including Brake Power, Brake Torque, Brake Specific Fuel Consumption and exhaust emissions – including NOx and CO, – were tested at engine speeds between 1200 and 2600 rpm. It is seen that HHO enriched CME has better results compared to pure hydrogen enrichment to CME. An average improvement of 4.3% with HHO enriched CME20 was found compared to diesel fuel results while pure hydrogen enriched CME20 fuel resulted with an average increase of 2.6%. Also, it was found that the addition of pure hydrogen to CME had a positive effect on exhaust gas emissions compared to that adding HHO. The effects of both enriched fuels on the engine performance were minimal compared to that of diesel fuel. However, the improvements on exhaust gas emissions were significant.     

Effects of hydrogenation of fossil fuels with hydrogen and hydroxy gas on performance and emissions of internal combustion engines

Energy security is an important consideration for development of future transport fuels. Among the all gaseous fuels hydrogen or hydroxy (HHO) gas is considered to be one of the clean alternative fuels. Hydrogen is very flammable gas and storing and transporting of hydrogen gas safely is very difficult. Today, vehicles using pure hydrogen as fuel require stations with compressed or liquefied hydrogen stocks at high pressures from hydrogen production centres established with large investments.Different electrode design and different electrolytes have been tested to find the best electrode design and electrolyte for higher amount of HHO production using same electric energy. HHO is used as an additional fuel without storage tanks in the four strokes, 4-cylinder compression ignition engine and two-stroke, one-cylinder spark ignition engine without any structural changes. Later, previously developed commercially available dry cell HHO reactor used as a fuel additive to neat diesel fuel and biodiesel fuel mixtures. HHO gas is used to hydrogenate the compressed natural gas (CNG) and different amounts of HHO-CNG fuel mixtures are used in a pilot injection CI engine. Pure diesel fuel and diesel fuel + biodiesel mixtures with different volumetric flow rates are also used as pilot injection fuel in the test engine. The effects of HHO enrichment on engine performance and emissions in compression-ignition and spark-ignition engines have been examined in detail. It is found from the experiments that plate type reactor with NaOH produced more HHO gas with the same amount of catalyst and electric energy. All experimental results from Gasoline and Diesel Engines show that performance and exhaust emission values have improved with hydroxy gas addition to the fossil fuels except NO_x exhaust emissions. The maximum average improvements in terms of performance and emissions of the gasoline and the diesel engine are both graphically and numerically expressed in results and discussions. The maximum average improvements obtained for brake power, brake torque and BSFC values of the gasoline engine were 27%, 32.4% and 16.3%, respectively. Furthermore, maximum improvements in performance data obtained with the use of HHO enriched biodiesel fuel mixture in diesel engine were 8.31% for brake power, 7.1% for brake torque and 10% for BSFC.     

Dual-fuel diesel engine run with injected pilot biodiesel-diesel fuel blend with inducted oxy-hydrogen (HHO) gas

Oxy-hydrogen gas (HHO) is a carbon-free fuel, which is produced by the water electrolysis process. It can be used as an alternative to hydrogen since the current global hydrogen production and storage may not meet the required demand for transportation applications. This research work investigates the engine behavior of a compression ignition (CI) engine operated in dual-fuel mode by inducting HHO as a primary fuel and injecting two different pilot fuels viz., diesel, and JME20 (a blend composed of 80% diesel with 20% Jatropha methyl ester) at optimized engine conditions. The results revealed that; heat release rate, brake thermal efficiency, exhaust gas temperature, and nitric oxide emission are found to be higher about 5.2%, 1.1%, 18.6%, and 19.6% respectively, while unburnt hydrocarbon, carbon monoxide, and smoke emissions are reduced by about 33.3%, 29.4%, and 18.7% respectively in Opt.JME20 + HHO operation compared to that of the baseline data at maximum load.     

Effects of oxyhydrogen on the CI engine fueled with the biodiesel blends: A performance,combustion and emission characteristics study

The main purpose of this study is to analyse the effects of oxy hydrogen (HHO) along with the Moringa oleifera biodiesel blend on engine performance, combustion and emission characteristics. HHO gases were generated using the typical electrolysis process using the potassium hydroxide solution. The experiments were performed under various engine loads of 25%, 50%, 75%, and 100% in a constant speed engine. Biodiesel from the M. oleifera was prepared by the transesterification process. Further, the procured biodiesel blends mixed with neat diesel at the concentration of 20% (B20) and 40% (B40). In addition to above, the HHO gas flow rate to the engine chamber maintained at the flow rate of 0.5 L^-1. The use of the 20% and 40% blends with HHO reported less BTE compared to the neat diesel. However, B20 reported marginal rise in the BTE due to the addition of the HHO gas. On the other hand, addition of HHO gas to the blends significantly dropped the brake specific fuel consumption. With regard to the emissions, addition of the biodiesel blends reduced the concentration of the CO, HC, and CO₂. Nevertheless, no reduction reported in the formation of the NO. However, adding the HHO to the biodiesel reduced the average NOx by 6%, which is a substantial effect. Overall, HHO enriching biodiesel blends are the potential replacement for the existing fossil fuels for its superior fuel properties compared to the conventional diesel.     

Effect of hydroxy (HHO) gas addition on performance and exhaust emissions in compression ignition engines

In this study, hydroxy gas (HHO) was produced by the electrolysis process of different electrolytes (KOH_(aq), NaOH_(aq), NaCl_(aq)) with various electrode designs in a leak proof plexiglass reactor (hydrogen generator). Hydroxy gas was used as a supplementary fuel in a four cylinder, four stroke, compression ignition (CI) engine without any modification and without need for storage tanks. Its effects on exhaust emissions and engine performance characteristics were investigated. Experiments showed that constant HHO flow rate at low engine speeds (under the critical speed of 1750 rpm for this experimental study), turned advantages of HHO system into disadvantages for engine torque, carbon monoxide (CO), hydrocarbon (HC) emissions and specific fuel consumption (SFC). Investigations demonstrated that HHO flow rate had to be diminished in relation to engine speed below 1750 rpm due to the long opening time of intake manifolds at low speeds. This caused excessive volume occupation of hydroxy in cylinders which prevented correct air to be taken into the combustion chambers and consequently, decreased volumetric efficiency was inevitable. Decreased volumetric efficiency influenced combustion efficiency which had negative effects on engine torque and exhaust emissions. Therefore, a hydroxy electronic control unit (HECU) was designed and manufactured to decrease HHO flow rate by decreasing voltage and current automatically by programming the data logger to compensate disadvantages of HHO gas on SFC, engine torque and exhaust emissions under engine speed of 1750 rpm. The flow rate of HHO gas was measured by using various amounts of KOH, NaOH, NaCl (catalysts). These catalysts were added into the water to diminish hydrogen and oxygen bonds and NaOH was specified as the most appropriate catalyst. It was observed that if the molality of NaOH in solution exceeded 1% by mass, electrical current supplied from the battery increased dramatically due to the too much reduction of electrical resistance. HHO system addition to the engine without any modification resulted in increasing engine torque output by an average of 19.1%, reducing CO emissions by an average of 13.5%, HC emissions by an average of 5% and SFC by an average of 14%.     

Life cycle environmental impact comparison of solid oxide fuel cells fueled by natural gas,hydrogen, ammonia and methanol for combined heat and power generation

This study aims to provide a comprehensive environmental life cycle assessment of heat and power production through solid oxide fuel cells (SOFCs) fueled by various chemical feeds namely; natural gas, hydrogen, ammonia and methanol. The life cycle assessment (LCA) includes the complete phases from raw material extraction or chemical fuel synthesis to consumption in the electrochemical reaction as a cradle-to-grave approach. The LCA study is performed using GaBi software, where the selected impact assessment methodology is ReCiPe 1.08. The selected environmental impact categories are climate change, fossil depletion, human toxicity, water depletion, particulate matter formation, and photochemical oxidant formation. The production pathways of the feed gases are selected based on the mature technologies as well as emerging water electrolysis via wind electricity. Natural gas is extracted from the wells and processed in the processing plant to be fed to SOFC. Hydrogen is generated by steam methane reforming method using the natural gas in the plant. Methanol is also produced by steam methane reforming and methanol synthesis reaction. Ammonia is synthesized using the hydrogen obtained from steam methane reforming and combined with nitrogen from air in a Haber-Bosch plant. Both hydrogen and ammonia are also produced via wind energy-driven decentralized electrolysis in order to emphasize the cleaner fuel production. The results of this study show that feeding SOFC systems with carbon-free fuels eliminates the greenhouse gas emissions during operation, however additional steps required for natural gas to hydrogen, ammonia and methanol conversion, make the complete process more environmentally problematic. However, if hydrogen and ammonia are produced from renewable sources such as wind-based electricity, the environmental impacts reduce significantly, yielding about 0.05 and 0.16 kg CO₂ eq., respectively, per kWh electricity generation from SOFC.     

Oxy-hydrogen gas as an alternative fuel for heat and power generation applications - A review

One of the important goals in today's world is sustainable power generation by using low or zero polluting fuels and energy conversion devices. In this context, utilization of gaseous fuels in internal combustion (IC) engines is focused more due to their better fuel mixing ability with air, higher combustion efficiency, easier transportation, and lower pollutant formation. Liquefied petroleum gas (LPG), compressed natural gas (CNG), hydrogen, and biogas are considered as commonly available alternative gaseous fuels for IC engines. Yet, a search for other possible alternative gaseous fuels is continuing in the world. In recent years, Oxy-hydrogen (HHO) also known as Brown's gas has been explored by many researchers in the world, for the possibility of using it for heat and power applications. Because of this, a comprehensive review of the production of HHO using different generators and its utilization in heat and power applications has been carried out, and the discussions are presented in this paper.     

Impact of HHO gas enrichment and high purity biodiesel on the performance of a 315 cc diesel engine

Biodiesel and oxyhydrogen (HHO) gas have shown promising results in improving engine performance and emissions. In this work, the effects of HHO gas and 5% biodiesel blends (B5) and their combined use in a 315 cc diesel engine have been analyzed. Biodiesel is produced by base catalyzed transesterification and cleaned by emulsification. Its calculated cetane index (CCI) was 61.4. HHO gas is produced from electrolysis of concentrated potassium hydroxide solution. The use of 5% biodiesel blend resulted in a significant rise of 9.4% in the brake thermal efficiency (BTE) and a maximum reduction of 8.19% in the brake specific fuel consumption (BSFC). HHO enrichment of diesel and biodiesel at 2.81 L/min through the intake manifold improved the torque and power by an average of over 3%. HHO addition also improved the BTE of diesel by a maximum of 3.67%. The combination of high CCI biodiesel fuel and HHO creates a mixture that has shortened the ignition delay (ID) to the point that adverse effects were observed due to the premature combustion as shown by the average decrease in the BTE of 2.97% compared to B5. Thus, B5, on its own, is found to be the optimum fuel under these conditions.     

An experimental investigation of the impact of added HHO gas on automotive emissions under idle conditions

The paper describes an experiment aimed at specifying the effects of adding Brown's gas (HHO gas) in automotive engines operating at idle speed. HHO gas was obtained from the author's parallel plate generator with a single central anode and two side cathodes separated by six neutral plates. The generator was powered by an external power source (power supply unit) and produced a constant HHO gas flow rate in the experiment. The so obtained HHO gas was added to the engine intake systems of 5 passenger cars – three SI engines, i.e. Fiat Cinquecento, Renault Twingo, and Opel Corsa and two CI engines, i.e. Skoda Octavia and Opel Combo. The engines operated in idling conditions. The MAHA MGT5 analyzer measured the concentrations of CO, HC, NOx in the exhaust gases of those cars first fueled by stock fuel (SF) only and then with added HHO gas, i.e. SF + HHO. The ambient conditions remained constant.The results show that fueling with an HHO gas additive has an impact on emissions: CO and HC concentrations in the exhaust gases were reduced in the most of the cases; NOx concentration was reduced in the SI engines but increased in the Diesel ones. Adding HHO gas to the engine intake system of the Fiat Cinquecento operating at idle slightly deteriorated the combustion process there (the impact of carburetor-based supply without feedback). Although HC concentration was lower by 24%, the amount of CO increased by 34% and nitrogen oxides hardly changed. CO concentration if any decreased in the other vehicles.The concentration of HC in the exhaust gases of each of the vehicles show that adding HHO gas to the original fuel, regardless of fueling methods and techniques, reduces the concentration of unburned hydrocarbons: by more than 20% in the Fiat and by about 40% in the others. The NOx concentration in the exhaust gases of each of the vehicles show that after adding HHO to the original fuel, the amount of NOx depends on a fueling method. In the SI engines with indirect injection, adding HHO gas to the intake system reduced the NOx concentration. In the Fiat with a carburetor without feedback, the NOx concentration remained practically unchanged but it increased in the CI engines if HHO gas was added to their intake systems.     

Potential importance of hydrogen as a future solution to environmental and transportation problems

Air pollution is a serious public health problem throughout the world, especially in industrialized and developing countries. In industrialized and developing countries, motor vehicle emissions are major contributors to urban air quality. Hydrogen is one of the clean fuel options for reducing motor vehicle emissions. Hydrogen is not an energy source. It is not a primary energy existing freely in nature. Hydrogen is a secondary form of energy that has to be manufactured like electricity. It is an energy carrier. Hydrogen has a strategic importance in the pursuit of a low-emission, environment-benign, cleaner and more sustainable energy system. Combustion product of hydrogen is clean, which consists of water and a little amount of nitrogen oxides. Hydrogen has very special properties as a transportation fuel, including a rapid burning speed, a high effective octane number, and no toxicity or ozone-forming potential. It has much wider limits of flammability in air than methane and gasoline. Hydrogen has become the dominant transport fuel, and is produced centrally from a mixture of clean coal and fossil fuels (with C-sequestration), nuclear power, and large-scale renewables. Large-scale hydrogen production is probable on the longer time scale. In the current and medium term the production options for hydrogen are first based on distributed hydrogen production from electrolysis of water and reforming of natural gas and coal. Each of centralized hydrogen production methods scenarios could produce 40 million tons per year of hydrogen. Hydrogen production using steam reforming of methane is the most economical method among the current commercial processes. In this method, natural gas feedstock costs generally contribute approximately 52–68% to the final hydrogen price for larger plants, and 40% for smaller plants, with remaining expenses composed of capital charges. The hydrogen production cost from natural gas via steam reforming of methane varies from about 1.25 US$/kg for large systems to about 3.50 US$/kg for small systems with a natural gas price of 6 US$/GJ. Hydrogen is cheap by using solar energy or by water electrolysis where electricity is cheap, etc.     

Hydrogen from solar energy,a clean energy carrier from a sustainable source of energy

Solar energy is going to play a crucial role in the future energy scenario of the world that conducts interests to solar-to-hydrogen as a means of achieving a clean energy carrier. Hydrogen is a sustainable energy carrier, capable of substituting fossil fuels and decreasing carbon dioxide (CO₂) emission to save the world from global warming. Hydrogen production from ubiquitous sustainable solar energy and an abundantly available water is an environmentally friendly solution for globally increasing energy demands and ensures long-term energy security. Among various solar hydrogen production routes, this study concentrates on solar thermolysis, solar thermal hydrogen via electrolysis, thermochemical water splitting, fossil fuels decarbonization, and photovoltaic-based hydrogen production with special focus on the concentrated photovoltaic (CPV) system. Energy management and thermodynamic analysis of CPV-based hydrogen production as the near-term sustainable option are developed. The capability of three electrolysis systems including alkaline water electrolysis (AWE), polymer electrolyte membrane electrolysis, and solid oxide electrolysis for coupling to solar systems for H₂ production is discussed. Since the cost of solar hydrogen has a very large range because of the various employed technologies, the challenges, pros and cons of the different methods, and the commercialization processes are also noticed. Among three electrolysis technologies considered for postulated solar hydrogen economy, AWE is found the most mature to integrate with the CPV system. Although substantial progresses have been made in solar hydrogen production technologies, the review indicates that these systems require further maturation to emulate the produced grid-based hydrogen.     

HHO enrichment of bio-diesohol fuel blends in a single cylinder diesel engine

One of the primary aims of this experimental investigation is to examine hydroxy-gas enrichment effects on environmentally friendly but performance-reducing alternative fuels such as ethanol and biodiesel. Hydroxy gas is a product of the pure water electrolysis method. Entire HHO system has integrated into engine test rig for this purpose. Two different biodiesohol fuel blend prepared and named by their volumetric compositions. Biodiesohol used to describe biodiesel, ethanol and standard diesel blends. Specific fuel properties are measured and ensured to be in EN590 and EN14214 standards. Experiments were conducted on a single cylinder diesel engine which was fuelled with diesel-biodiesel-ethanol fuel blends those enriched by 1 L per minute HHO gas during the entire tests. All of the experiments performed under full load condition within the range of 1200–3200 rpm engine speed. From the view of performance; brake power, brake specific fuel consumption and thermal efficiency results discussed. Besides, carbon monoxide and nitrogen oxides results measured and presented as exhaust emission. Standard diesel fuel outputs determined as a reference line to analyze the changes. A number of studies have been conducted with fuels used in this experimental study and their mixture in different ratios as well, but an examination of the HHO addition to biodiesel is performed for the first time in this research area of the literature.     

Optimized photovoltiac system for hydrogen production

Hydrogen, which can be produced by water electrolysis, can play an important role as an alternative to conventional fuels. It is regarded as a potential future energy carrier. Photovoltaic arrays can be used in supplying the water electrolysis systems by their energy requirements. The use of photovoltaic energy in such systems is very suitable where the solar hydrogen energy systems are considered one of the cleanest hydrogen production technologies, where the hydrogen is obtained from sunlight by directly connecting the photovoltaic arrays and the hydrogen generator. This paper presents a small PV power system for hydrogen production using the photovoltaic module connected to the hydrogen electrolyzer with and without maximum power point tracker. The experimental results developed good results for hydrogen production flow rates, in the case of using maximum power point tracker with respect to the directly connected electrolyzer to the photovoltaic modules.     

Carbon black and hydrogen production process analysis

The adoption of new environmentally responsible technologies, as well as, energy efficiency improvements in equipment and processes help to reduce CO2 rate emission into the atmosphere, contributing in delaying the consequences of intensive use of fossil fuels. For more effective actions, it is necessary to make the transition from the fossil-based to the renewable source economy. In this context, hydrogen fuel has a special role as clean vector of energy. Hydrogen has the potential to be decisive in mitigating greenhouse gas emissions, but fossil fuels high profitability due to global energy dependency actually drives the global economy.While renewable energy sources are not worldwide fully established, new technologies should be developed and used for the recovery of energetic streams nowadays wasted, to decarbonize hydrocarbons and to improve systems efficiency creating a path that can help nations and industries in the needed energy economy transition. Hydrogen gas can be generated by various methods from different sources such as coal and water. Currently, almost all of the hydrogen production is for industrial purpose and comes from the Steam Reforming, while the use of hydrogen in fuel cells is only incipient.The article analysis the plasma pyrolysis of hydrocarbons as a decarbonization option to contribute as a step towards hydrogen economy. It presents the Carbon Black and Hydrogen Process (CB&H Process) as an alternative option for hydrogen generation at large scale facility, suitable for supplying large amounts of high-purity carbon in elemental form. CB&H Process refers to a plant with hydrogen thermal plasma reactor able to decompose Hydrocarbons (HC's) into Hydrogen (H2) and Carbon Black (CB), a cleaner technology than its competing processes, capable of generating two products with high added value. Considering the Brazilian context in which more than 80% of the generated electricity comes from renewable sources, the use of electricity as one of the inputs in the process does not compromise the objective of reducing greenhouse gas emissions. It is important to consider that the use of renewable energy to produce two products derived from fossil fuels in a clean way represents integration of technologies into a more efficient system and an arrangement that contributes to the transition from fossil fuels to renewables.The economic viability of the CB&H process as a hydrogen generation unit (centralized) for refining applications also depends on the cost of hydrogen production by competing processes. Steam Methane Reforming (SMR) is a widespread method that produces twice the amount of hydrogen generated by natural gas plasma pyrolysis, but it emits CO2 gas and consumes water, while CB&H process produces solid carbon. For this reason, the paper seeks the carbon production cost by plasma pyrolysis as a breakeven point for large-scale hydrogen generation without water consumption and carbon dioxide emissions.     

Analytical modelling and experimental validation of proton exchange membrane electrolyser for hydrogen production

Proton Exchange Membrane (PEM) Electrolysers (ELSs) are considered as pollution-free with enhanced efficiency technology. Hydrogen can be easily produced from different resources like biomass, water electrolysis, natural gas, propane, and methanol. Hydrogen generation from water electrolysis, which is the splitting of water molecules into hydrogen and oxygen using electricity, can be beneficial when used in combination with variable Renewable Energy (RE) technologies such as solar and wind. When the electricity used for water electrolysis is produced by a variable RE source, the hydrogen stores the unused energy for a later use and can be considered as a renewable fuel and energy resource for the transport and energy sectors.This paper aims to propose a novel graphical model design for the PEM-ELS for hydrogen production based on the electrochemical, thermodynamical and thermal equations. The model under study is experimentally validated using a small-scale laboratory electrolyser. Simulation results, using Matlab-Simulink?, show an adequate parameter agreement with those found experimentally. Therefore, the impact of the different parameters on the electrolyser dynamic performance is introduced and the relevant analytical-experimental comparison is shown. The temperature effect on the PEM-ELS dynamic behaviour is also discussed.     

Comparing prospective hydrogen pathways with conventional fuels and grid electricity in India through well-to-tank assessment

The present study uses Greenhouse Gases, Regulated Emissions, and Energy Use in Technologies Model (GREET), to compare hydrogen generated via multiple pathways (Natural gas, methanol reforming; coal, petcoke, biomass gasification etc) with the conventional fuels like diesel and compressed natural gas and grid electricity under Indian context through a comprehensive well to tank assessment based on net CO₂ equivalent emission and energy consumption. Limited availability of customized studies comparing hydrogen production and supply with other energy options in India distinguishes the present work as it provides a fresh insight into potential pathways for hydrogen production while assessing feedstock availability and raw water consumption. The study reveals that biomass gasification and solar electrolysis are among the least GHG emitting pathways to fill one unit of energy equivalent in the tank. Hydrogen produced through natural gas reforming is 70% less emission intensive and 38% more energy efficient than Indian grid electricity.