The potential and economic viability of hydrogen production from the use of hydroelectric and wind farms surplus energy in Brazil: A national and pioneering analysis

Energy security is an issue at stake in governments all over the world, and also in Brazil. Although the country's energetic matrix is largely based on hydropower sources, the need for diversification is increasingly needed. The possibility of hybrids between hydropower and wind power for hydrogen production emerges as a clean alternative source for energy security. In high-throughput seasons, excess energy could be used to produce hydrogen, which could supply shortages of energy. This study shows the potential for producing hydrogen in Brazil, using excess energy from hydroelectric and wind farms. Taking into account one hour per day of surplus energy production, it would be possible to generate 6.50E+09 Nm³.y⁻¹ of H₂. On the other hand, considering two and three hours, the H₂ generation would be equal to 1.30E+10 Nm³.y⁻¹ and 2.00E+10 Nm³.y⁻¹, respectively. This study calculated the economic viability for hydrogen production, at a cost of 0.303 USD.kWh⁻¹, a higher cost if compared to that of the wind and hydroelectric plants.     

Green hydrogen-based pathways and alternatives: Towards the renewable energy transition in South America's regions – Part A

In recent years, there has been an increased concern regarding the impacts of climate change caused by the increase in anthropogenic CO₂ emissions, and the search for clean energy sources has grown. Hydrogen produced from renewable sources is an alternative to the demand for clean energy. Argentina, Paraguay and Uruguay are countries located in South America with a considerable number of rivers and hydroelectric plants. This study shows the potential production of hydrogen in these countries using the excess energy from hydroelectric plants. While Argentina has a potential generation of 3.44E+10 Kg.year^?1 of H₂, Paraguay and Uruguay presented, respectively, 5.32E+10 Kg.year^?1 and 2.19E+10 Kg.year^?1. Taking into account the economic viability analysis, H production and storage had a profit of 0.2253 US$.m^?3 for Paraguay, 0.2249 US$.m^?3 for Uruguay and a cost of 0.2263 US$.m^?3 in Argentina. The results of this research contribute to the renewable, sustainable energy transition and in accordance with the precepts of the circular economy for the search for new sources of energy. This idea needs to be encouraged around the world, including developing countries.     

Green hydrogen-based pathways and alternatives: Towards the renewable energy transition in South America's regions–Part B

Hydropower compounds most of the energy matrix of the countries of the Latin America and Caribbean region (LAC). Considering the concern in reducing Green House Gases emissions (GHG) from hydropower plants and hydrogen production from fossil sources, green hydrogen (H₂) appears as an energy vector able to mitigate this impact. Improving the efficiency of the plant and producing renewable energy the element is an interesting alternative from the ecological and economic point of view. This study aims to estimate the potential of H₂ production from wasted energy, through the electrolysis of water in hydroelectric plants in Colombia and Venezuela. The construction of two scenarios allowed obtaining a difference, considering a spilled flow of 2/3 in the first scenario and 1/3 in the second. In Colombia, hydrogen production reached 3.39 E+08 Nm³ at a cost of 2.05 E+05 USD/kWh in scenario1, and 1.70 E+08 Nm³ costing 4.10 E+05 USD/kWh in scenario 2. Regarding the Venezuelan context, the country obtained lower production values of H₂, ranging between 7.76 E+07 Nm³.d^?1 and 4.31 E+07 Nm³.d^?1, and production cost between 9.45 E+09 USD/kWh and 1.89 E+10 USD/kWh. Thus, the final cost for the production and storage of H₂ was estimated at 0.2239 USD.kg^?1. Ultimately, Colombia and Venezuela have a large potential to supply the demand for nitrogen fertilizers with green ammonia production, apply green hydrogen in manufacturing and use the surplus for energy substitution of Liquefied Petroleum Gas - LPG. In Colombia, the chemical energy offered is equivalent to 6.681 E+11 MJ/year^?1 and in Venezuela, the result is equal to 1.697 E+11 MJ/year^?1 in the conservative scenario. Finally, the countries have great potential for the diversification of the energy matrix and the insertion of renewables in the system.     

Hydrogen production from wind energy in Western Canada for upgrading bitumen from oil sands

Hydrogen is produced via steam methane reforming (SMR) for bitumen upgrading which results in significant greenhouse gas (GHG) emissions. Wind energy based hydrogen can reduce the GHG footprint of the bitumen upgrading industry. This paper is aimed at developing a detailed data-intensive techno-economic model for assessment of hydrogen production from wind energy via the electrolysis of water. The proposed wind/hydrogen plant is based on an expansion of an existing wind farm with unit wind turbine size of 1.8 MW and with a dual functionality of hydrogen production and electricity generation. An electrolyser size of 240 kW (50 Nm³ H₂/h) and 360 kW (90 Nm³ H₂/h) proved to be the optimal sizes for constant and variable flow rate electrolysers, respectively. The electrolyser sizes aforementioned yielded a minimum hydrogen production price at base case conditions of $10.15/kg H₂ and $7.55/kg H₂. The inclusion of a Feed-in-Tariff (FIT) of $0.13/kWh renders the production price of hydrogen equal to SMR i.e. $0.96/kg H_2, with an internal rate of return (IRR) of 24%. The minimum hydrogen delivery cost was $4.96/kg H₂ at base case conditions. The life cycle CO₂ emissions is 6.35 kg CO₂/kg H₂ including hydrogen delivery to the upgrader via compressed gas trucks.     

The potential of hydrogen production from high and low-temperature electrolysis methods using solar and nuclear energy sources: the transition to a hydrogen economy in Brazil

Brazil has great potential for diversification and decarbonization of its energy matrix, with the insertion of a clean and renewable energy source such as hydrogen. This paper seeks to evaluate the surplus energy potential of solar and nuclear plants installed in the country for the production of green and purple hydrogen using high and low temperature electrolysis methods. Based on official reports and databases of energy production and demand, the results indicated that the total potential of surplus solar energy is equal to 4.29E+07 (kWh.d^?1). Further, the total potential of electricity production from the hydrogen obtained through surplus solar energy was equivalent to1.87E+07 (kWh.d^?1); and the total cost of producing solar hydrogen is equal to 1.07E+03 (USD.kWh^?1). In conclusion, the study contributed to demonstrate the pathways to the establishment of strategies that assist the transition to a hydrogen economy in Brazil.     

Theoretical analysis of green hydrogen from hydropower: A case study of the Northwest Columbia River system

Within the Pacific Northwest region of the United States, there is the unique opportunity to explore alternative energy management solutions of the Columbia River's multi-use hydropower system. As with various European hydropower systems that experience large variability in water runoff, but lack adequate reservoir storage capacity, the Columbia River System is a viable source for renewable hydrogen production. This paper studies the theoretical potential of green hydrogen production from excess hydropower energy from the Columbia River System. The potential surplus hydroelectric energy and hydrogen production potential from surplus energy (during March through July months) are estimated from 11 hydroelectric projects along with the Columbia River System. Results show that the system's total monthly average hydrogen production potential ranges from 2.22 × 10⁶ to 8.96 × 10⁶ kg H₂ with the utilization of surplus energy over a historical 80 water year period (1928–2008). This study concludes that hydrogen production from spilled hydropower energy and its use in the transportation sector is a viable opportunity to lead the country towards a hydrogen economy.     

A correct perspective for hydrogen from engineered diagenesis

Wind and solar photovoltaic electricity production have already reached very low levels of levelized cost of energy (LCOE). Electrolyzers have already reached high efficiencies which are further improving, while costs are dramatically reducing. They are commercial products. Green hydrogen (H₂) is the product of excess wind and solar electricity, specifically electricity that will be otherwise wasted, without the huge energy storage needed presently almost completely missing. By growing the installed capacity of wind and solar power plants, there will be a non-dispatchable production by wind and solar more often in excess, but sometimes also in defect, of the grid demand, in presence of limited energy storage. H₂ is one of the key energy storage technologies needed to ensure grid stability. Production of H₂ above what is needed to stabilize the grid significantly helps in applications such as land, and sea but especially air transport where the storage of energy onboard in a fuel is preferable to the storage of energy as electricity into a battery. The engineered diagenesis for H₂ is unlikely better than green hH₂. Apart from being a nice idea to be proven workable, with a technology readiness level (TRL) presently of zero, and thus impossible to be objectively compared with commercial products, the engineered diagenesis for H₂, even if possible, also does not help with non-dispatchable renewable energy production. The concept may also have negative environmental aspects similar to fracking which have not been considered yet, and also bear huge economic costs in addition to environmental. Here we review the pros and cons of this novel technology, which once proven workable, which is not the case yet, should be considered as a possible way to complement rather than replace green H₂ production.     

Production of hydrogen for export from wind and solar energy,natural gas,and coal in Australia

Hydrogen production for export to Japan and Korea is increasingly popular in Australia. The theoretically possible paths include the use of the excess wind and solar energy supply to the grid to produce hydrogen from natural gas or coal. As a contribution to this debate, here I discuss the present contribution of wind and solar to the electricity grid, how this contribution might be expanded to make a grid wind and solar only, what is the energy storage needed to permit this supply, and what is the ratio of domestic total primary energy supply to electricity use. These factors are required to determine the likeliness of producing hydrogen for export. The wind and solar energy capacity, presently at 6.7 and 11.4 GW, have to increase almost 8 times up to values of 53 and 90 GW respectively to support a wind and solar energy only electricity grid for the southeast states only. Additionally, it is necessary to build-up energy storage of actual power >50 GW and stored energy >3000 GW h to stabilize the grid. If the other states and territories are considered, and also the total primary energy supply (TPES) rather than just electricity, the wind and solar capacity must be increased of a further 6–8 times. It is concluded that it is extremely unlikely that hydrogen for export could be produced from the splitting of the water molecule by using excess wind and solar energy, and it is very unlikely that wind and solar may fully cover the local TPES needs. The most likely scenario is production hydrogen via syngas from either natural gas or coal. Production from natural gas and coal needs further development of techniques, to include CO₂ capture, a way to reuse or store CO₂, and finally, the better energy efficiency of the conversion processes. There are several challenges for using natural gas or coal to produce hydrogen with near-zero greenhouse gas emissions. Carbon capture, utilization, and storage technologies that ensure no CO₂ is released in the production process, and new technologies to separate the oxygen from the air, and in case of natural gas, the water, and the CO₂ from the combustion products, are urgently needed to make sense of the fossil fuel hydrogen production. There is no benefit from producing hydrogen from fossil fuels without addressing the CO₂ issue, as well as the fuel energy penalty issue during conversion, that is simply translating in a net loss of fuel energy with the same CO₂ emission.     

Hydrogen generation from the reaction of Al pretreated in acidic or alkaline solution and water

Al and Al₂O₃ film react with strong acid or alkaline solution, bring the extensive corrosion. To decrease the corrosion, Al is first pretreated with a small amount of HCl, NaOH, NaAlO₂ and a mixture of NaAlO₂+Al(OH)₃ in this work. Al pretreatment allows for the rapid removal of oxide film, shortens the induction time and ensures the initial Al–H₂O reaction rate. Typically, immersion of the pretreated Al by a mixture of NaAlO₂+Al(OH)₃ into water, generates hydrogen rapidly without an induction time, and the average H₂ generation rate reaches 5.5 mL min⁻¹. As the Al–H₂O reaction proceeds, the potential changes, which is similar to hydrogen evolution of pretreated Al in water. Hydrogen generated rapidly with the consecutive addition of Al, and the initial hydrogen generation rate reaches ~37 mL min⁻¹. Therefore, Al pretreatment by a mixed alkaline solution is an effective method to accelerate hydrogen generation for the first cycle. Rapid and consecutive hydrogen generation by the Al–H₂O reaction could provide on-demand and high-purity hydrogen, meet some equipment requirements and promote the competition in renewable-energy sources.     

Cost evaluation of two potential nuclear power plants for hydrogen production

Hydrogen is recognized as one of the most promising alternative fuels to meet the energy demand for the future by providing a carbon-free solution. In regards to hydrogen production, there has been increasing interest to develop, innovate and commercialize more efficient, effective and economic methods, systems and applications. Nuclear based hydrogen production options through electrolysis and thermochemical cycles appear to be potentially attractive and sustainable for the expanding hydrogen sector. In the current study, two potential nuclear power plants, which are planned to be built in Akkuyu and Sinop in Turkey, are evaluated for hydrogen production scenarios and cost aspects. These two plants will employ the pressurized water reactors with the electricity production capacities of 4800 MW (consisting of 4 units of 1200 MW) for Akkuyu nuclear power plant and 4480 MW (consisting of 4 units of 1120 MW) for Sinop nuclear power plant. Each of these plants are expected to cost about 20 billion US dollars. In the present study, these two plants are considered for hydrogen production and their cost evaluations by employing the special software entitled “Hydrogen Economic Evaluation Program (HEEP)” developed by International Atomic Energy Agency (IAEA) which includes numerous options for hydrogen generation, storage and transportation. The costs of capital, fuel, electricity, decommissioning and consumables are calculated and evaluated in detail for hydrogen generation, storage and transportation in Turkey. The results show that the amount of hydrogen cost varies from 3.18 $/kg H₂ to 6.17 $/kg H₂.     

Life cycle cost analysis: A case study of hydrogen energy application on the Orkney Islands

Hydrogen can compensate for the intermittent nature of some renewable energy sources and encompass the options of supplying renewables to offset the use of fossil fuels. The integrating of hydrogen application into the energy system will change the current energy market. Therefore, this paper deploys the life cycle cost analysis of hydrogen production by polymer electrolyte membrane (PEM) electrolysis and applications for electricity and mobility purposes. The hydrogen production process includes electricity generated from wind turbines, PEM electrolyser, hydrogen compression, storage, and distribution by H₂ truck and tube trailer. The hydrogen application process includes PEM fuel cell stacks generating electricity, a H₂ refuelling station supplying hydrogen, and range extender fuel cell electric vehicles (RE-FCEVs). The cost analysis is conducted from a demonstration project of green hydrogen on a remote archipelago. The methodology of life cycle cost is employed to conduct the cost of hydrogen production and application. Five scenarios are developed to compare the cost of hydrogen applications with the conventional energy sources considering CO₂ emission cost. The comparisons show the cost of using hydrogen for energy purposes is still higher than the cost of using fossil fuels. The largest contributor of the cost is the electricity consumption. In the sensitivity analysis, policy supports such as feed-in tariff (FITs) could bring completive of hydrogen with fossil fuels in current energy market.     

Critical assessment of the production scale required for fossil parity of green electrolytic hydrogen

Hydrogen produced from renewable electricity through Power-to-Hydrogen can facilitate the integration of high levels of variable renewable electricity into the energy system. An electrolyser is a device that splits water into hydrogen and oxygen using electricity. When electricity is produced from renewable energy sources, electrolytic hydrogen can be considered to be green. At the same time, electrolysers can help integrate renewable electricity into power systems, as their electricity consumption can be adjusted to follow wind and solar power generation. Green hydrogen then also becomes a carrier for renewable electricity. Key green hydrogen production technologies, mostly PEM and alkaline electrolysers, are still further maturing, both in technical (efficiency), economical (CAPEX) and durability (lifetime) performance. Nonetheless, we will show in this contribution how fossil parity for green hydrogen, i.e. a Total Cost of Ownership (TCO) similar to grey H₂ coming from todays CO₂ intensive SMR processes, can already be achieved today. Moreover, this can be realised at a scale which corresponds to the basic units of renewable electricity generation, i.e. a few MW.     

Semi-pilot scale production of hydrogen from Organic Fraction of Solid Municipal Waste and electricity generation from process effluents

The production of hydrogen from Organic Fraction of Solid Municipal Waste (OFSMW) was studied on a semi-pilot scale. The potential of generating electricity using the process effluents was further assessed using a two-chambered Microbial Fuel Cell. A maximum hydrogen fraction of 46.7% and hydrogen yield of 246.93 ml H₂ g⁻¹ Total Volatile Solids was obtained at optimum operational setpoints of 7.9, 30.29 °C and 60 h for pH, temperature and hydraulic retention time (HRT) respectively. A maximum electrical power density of 0.21 W m^-2 (0.74 A m⁻²) was recorded at 500 Ω and the chemical oxygen demand (COD) removal efficiency of 50.1% was achieved from the process. The process economics of energy generation from organic wastes could be significantly improved by integrating a two-stage process of fermentative hydrogen production and electricity generation.     

Hydrogen-based PEM auxiliary power unit

Hydrogen is an energy carrier which can be used for the storage of intermittent and renewable energy sources. In this paper, the general characteristics of an integrated and automated hydrogen-based auxiliary power unit (APU) are presented. A PEM water electrolyzer (production capacity ranging from zero up to 1 Nm³ H₂/h), which can be powered by a panel of photovoltaic cells, is used to produce hydrogen at day hours. Hydrogen is dried and stored in hydride reservoir tanks (the storage capacity of individual reservoirs is 1 Nm³ H₂). Then hydrogen is used for the co-generation of heat and electricity at night hours using a PEM fuel cell (1 kW maximum output power). The main electrochemical and technological features of the overall system are presented. This kind of APU can potentially be used as an electric power source for domestic applications, for the production of electricity on remote sites or as a mobile hydrogen refuelling station for transport applications in urban areas.     

The role of hydrogen in high wind energy penetration electricity systems: The Irish case

The deployment of wind energy is constrained by wind uncontrollability, which poses operational problems on the electricity supply system at high penetration levels, lessening the value of wind-generated electricity to a significant extent. This paper studies the viability of hydrogen production via electrolysis using wind power that cannot be easily accommodated on the system. The potential benefits of hydrogen and its role in enabling a large penetration of wind energy are assessed, within the context of the enormous wind energy resource in Ireland. The exploitation of this wind resource may in the future give rise to significant amounts of surplus wind electricity, which could be used to produce hydrogen, the zero-emissions fuel that many experts believe will eventually replace fossil fuels in the transport sector. In this paper the operation of a wind powered hydrogen production system is simulated and optimised. The results reveal that, even allowing for significant cost-reductions in electrolyser and associated balance-of-plant equipment, low average surplus wind electricity cost and a high hydrogen market price are also necessary to achieve the economic viability of the technology. These conditions would facilitate the installation of electrolysis units of sufficient capacity to allow an appreciable increase in installed wind power in Ireland. The simulation model was also used to determine the CO₂ abatement potential associated with the wind energy/hydrogen production.     

Estimating global hydrogen production from wind

It is likely that intermittent renewable sources such as wind and solar will provide the greatest opportunity for future large-scale hydrogen production. Here, on-shore wind is examined. Global wind energy is estimated by placing one 2 MW turbine/km² over the surface of the earth. Wind energy production is based on monthly mean wind speed data. Wind turbines are grouped to form arrays that are linked to local hydrogen generation and transmission networks. Hydrogen generation is done via low-pressure electrolysis and transmission via high-pressure gas pipelines. The wind/hydrogen system is considered within a global energy system that must not only provide hydrogen, but also energy for electricity consumption at the local generation site. The technical potential of the hydrogen produced is estimated to be 116 EJ. Uneven distribution of the hydrogen-rich sites results in the need to export much of the hydrogen produced to energy-poor regions. To overcome system losses, a combined wind/HVDC/hydrogen system is considered.     

Towards The Hydrogen Economy: Estimation of green hydrogen production potential and the impact of its uses in Ecuador as a case study

The estimation of the green hydrogen (H₂) production potential represents the initial stage on the road to integrating the Hydrogen Economy into the energy systems of a country or region. This article has two purposes; the first focuses on identifying and analyzing studies on the amount of green H₂ obtainable in countries and regions across the globe. In total, 64 studies in 29 countries are reported, of which the geographical distribution of the estimates of green H₂ potential is obtained. Additionally, the most widely used renewable energy sources and the conversion technologies favored for their production were identified. The Americas and Argentina were the continents and the country, respectively, with the largest number of studies. At the same time, solar photovoltaic (PV) and electrolysis are the most studied production methods. The second purpose is to quantify the total potential of green H₂ in the Republic of Ecuador and explore its uses as an energy vector and chemical input in niches of opportunity detected from the analysis of its energy balance. In this regard, the total potential of green H₂ in Ecuador of 4.38 × 10⁸ tons/year is obtained, being the production of electrolytic H₂ with PV electricity the one with the highest contribution. The amount of H₂ available satisfies, in excess, the demand for the proposed uses: as fuel and chemical input. These results contribute to the knowledge of the object of study by making visible the interest of the countries in having such estimates and identifying the most attractive production route in the first place, and secondly, providing essential elements for the development of more detailed research and energy planning on the gradual incorporation of the Hydrogen Economy in Ecuador.     

Hydrogen generation by alcohol reforming in a tandem cell consisting of a coupled fuel cell and electrolyser

The performance of a novel electro-reformer for the production of hydrogen by electro-reforming alcohols (methanol, ethanol and glycerol) without an external electrical energy input is described. This tandem cell consists of an alcohol fuel cell coupled directly to an alcohol reformer, negating the requirement for external electricity supply and thus reducing the cost of operation and installation. The tandem cell uses a polymer electrolyte membrane (PEM) based fuel cell and electrolyser. At 80 °C, hydrogen was generated from methanol, by the tandem PEM cell, at current densities above 200 mA cm⁻², without using an external electricity supply. At this condition the electro-reformer voltage was 0.32 V at an energy input (supplied by the fuel cell component) of 0.91 kWh/Nm³; i.e. less than 20% of the theoretical value for hydrogen generation by water electrolysis (4.7 kWh/Nm³) with zero electrical energy input from any external power source. The hydrogen generation rate was 6.2 × 10⁻⁴ mol (H₂) h⁻¹. The hydrogen production rate of the tandem cell with ethanol and glycerol was approximately an order of magnitude lower, than that with methanol.     

Robust hydrogen generation over layered crystalline silicon materials via integrated H2 evolution routes

Hydrogen generation is the initial challenge in utilization of hydrogen energy. In this work, robust hydrogen generation with a high yield of 53,930 μmol g⁻¹ is demonstrated over layered crystalline silicon material derived from topochemical reaction from CaSi₂. The physicochemical properties of the resultant layered crystalline Si material before and after H₂ generation are investigated in detail to illustrate the H₂ generation mechanism. Integrated H₂ evolution routes, including destruction of Si–H bonds, oxidation of Si–Si bonds (hydrolysis of Si) and photocatalytic splitting water, are revealed to be responsible for the robust H₂ generation. This work delivers a facile route to synthesize layered crystalline Si material with promising H₂ generation performance and gives a deeply insight into the H₂ evolution mechanisms of Si-based materials.     

An analysis of hydrogen production from renewable electricity sources

Three aspects of producing hydrogen via renewable electricity sources are analyzed to determine the potential for solar and wind hydrogen production pathways: a renewable hydrogen resource assessment, a cost analysis of hydrogen production via electrolysis, and the annual energy requirements of producing hydrogen for refueling. The results indicate that ample resources exist to produce transportation fuel from wind and solar power. However, hydrogen prices are highly dependent on electricity prices. For renewables to produce hydrogen at $2 kg⁻¹, using electrolyzers available in 2004, electricity prices would have to be less than $0.01 kWh⁻¹. Additionally, energy requirements for hydrogen refueling stations are in excess of 20 GWh/year. It may be challenging for dedicated renewable systems at the filling station to meet such requirements. Therefore, while plentiful resources exist to provide clean electricity for the production of hydrogen for transportation fuel, challenges remain to identify optimum economic and technical configurations to provide renewable energy to distributed hydrogen refueling stations.