nc-Si∶H薄膜的三阶非线性光学性质

用简并四波混频技术 (DFWM)研究了nc Si∶H薄膜的三阶非线性光学性质 ,观察到了这种纳米薄膜材料的位相共轭信号 ,测得晶态比为XC1 =15 %和XC2 =30 % 的二个样品在光波波长为 5 89nm处的三阶非线性极化率分别为 χ1(3 ) =3 8× 10 - 6 esu和 χ2(3 ) =4 3× 10 - 7esu ,并对其光学非线性产生机理作了探讨     

具有ITO电极的QCM设计与性能研究

为了提高石英晶体微天平(QCM)的检测灵敏度,提出了一种具有氧化铟锡(ITO)电极结构的QCM。利用有限元分析软件在QCM芯片电极区采用密度等效法实现计算量的简化,在通过电极尺寸优化得到具有理想能陷效应的QCM的基础上,采用控制磁控溅射的气体压强、工作电压、电流等方法,得到具有导电性好,平滑度高,透光性优良的ITO电极。经振荡频率测试及质量灵敏度分析计算表明,ITO电极的QCM频率稳定性良好(频率变化仅3 Hz),质量灵敏度是金电极QCM的1.5倍。     

大肠杆菌O157:H7压电免疫传感器研究及表征

构建了一种可以快速检测大肠杆菌O157:H7的石英微天平(QCM)压电免疫传感器,并用原子力显微镜(AFM)和电化学方法分别对传感的各个步骤进行了表征,整个检测系统均由实验室自己构建。利用QCM的金电极自组装膜特性、抗原抗体的特异性结合和结合后的频差改变(Δf)来检测溶液中O157:H7含量,最后对传感器的再生性进行了初步探索。结果显示,该检测系统可以在1.5h内检测2.0×102~2.0×108CFU/mL的目标菌,并可重复再生使用。     

修饰掺硼金刚石电极循环伏安法检测尿酸

用直流等离子体喷射化学气相沉积(CVD)法制备掺 硼金刚石(BDD)薄膜电极。通过扫描电镜(SEM)观察到薄膜表面分布均匀致密;霍尔测 试仪检测薄膜的电阻率为0.023Ω·cm,载流子浓度为6.423×10¹⁹ cm－3;循环伏安法(CVa)测得其电极电势窗为 3.4V;分析了浓度为10μmol/L的 尿酸(UA)溶液在BDD电极表面的电化学响应,表明扫描速率的平方根与氧化峰电流呈线性关 系。通过对比茜素黄、牛磺酸和L-半胱氨酸3种物质对BDD电极进行修饰,表明由L-半胱氨 酸修饰BDD电极的电催化氧化能力最强;在浓度为1×10－7～1×10－4 mol/L范围内,浓度的对数与氧化峰电流呈线性关系,且检测限为 1×10－8 mol/L。实验结果表明,20倍浓度的葡萄糖和抗坏血酸对UA的 检测不构成影响。     

光学头安装误差对循迹信号的影响

光学头的安装误差导致盘片轨道与光电探测器的切向轴线存在夹角,在光盘标量衍射模型的基础上,引入光学头出瞳上的旋转角度误差参数,根据CD-ROM和DVD-ROM的盘片参数,计算并分析了旋转误差对三光束法和差动相位检测(DPD)法循迹信号的影响。计算结果表明:旋转误差使三光束法循迹信号的幅值近似呈周期性变化,它是在生产过程中需要严格控制的参数以保证循迹信号的幅值最大化;旋转误差在0~25°范围内时,对DPD信号幅值影响较小,在25°~45°时,使DPD信号的幅值降低,大于45°时,使DPD信号的极性发生变化。     

KTP光学参量振荡器输出激光的空间模式和光束质量

理论上通过二维傅里叶变换求解耦合波方程 ,分析了KTP光学参量振荡器 (OPO)信号光的空间分布 ;实验上利用Nd∶YAG倍频激光 ( 5 3 2nm)抽运非临界 (θ =90°,φ=0°) 及临界相位匹配KTP (θ =62 7°,φ=0°) OPO ,测量了参量光的空间分布、远场发散角及M2 因子等参数 ,讨论了抽运功率、谐振腔长、残余光后向二次抽运对OPO参量光的发散角和光束质量因子M2 的影响。     

Radon变换的计算机模拟

从数学上,严格论述了Radon变换的概念和数学意义。将Radon变换的数学坐标系统直接建立在物理场上,不仅将抽象的数学模型直观化,而且使Radon变换的物理意义简单明了。用三峰函数模拟了三维物体的切片,计算了该模拟平面场全方向180°范围内、角度间隔为1°的全部投影,从而给出了Ra-don变换应用于光学层析(OCT)的方法。     

基于激光回馈效应的液晶双折射特性测量

准确的双折射特性测量对于液晶的实际应用具有重要意义。研究了液晶材料的工作原理,以激光回馈效应为基础,搭建了各向异性外腔回馈双折射测量系统,对不同驱动电压下液晶的双折射特性进行测量。测量结果表明,各向异性外腔回馈双折射测量系统测量精度在0.3°之内;通过施加0~24V交流电压,液晶材料双折射率在2.74×10-1~2.39×10-3范围内变化,对应各向异性呈现出460°~5°的大范围位相延迟值。电压范围在0.7~2V时,电压-双折射率关系表现出较好的线性度,通过线性拟合对该范围内电压-双折射率关系进行计算,其线性度优于95.5%。液晶材料可以提供稳定的位相延迟,同一电压值下的位相延迟短期重复性优于0.52°,长期重复性优于4.5°。     

分子印迹膜SPR传感器检测氯磺隆的方法

研究使用了中国科学院电子学研究所自行研制的高灵敏度单通道SPR分析仪和进样装置,仪器为棱镜耦合型SPR传感器结构,其检测角度范围是40°～70°,折射率检测范围为1.04～1.47,谐振角的精度在0.001°。适用于SPR分析仪的分子印迹芯片采用PVC-MIP共聚膜法制备,SPR角度扫描结果表明,200nm以下厚度芯片具有较好的SPR吸收特性。以氯磺隆为模板的分子印迹膜与不加氯磺隆的分子印迹膜对比实验发现前者具有特异性结合的能力。实验对浓度0.1,0.2,0.5和1μg/mL的氯磺隆进行了SPR定点检测,这四种浓度氯磺隆的折射率响应信号满足线性关系,相关系数R=0.996 4。实验中对低浓度的氯磺隆进行反复检测,检测到50ng/mL的氯磺隆,满足农残检测的要求。     

大功率半导体激光器光束整形

提出一种新型堆积式半导体激光器(LD)光束整形方案,材料为K9玻璃,其入射面为一长方形,出射面为一正方形,一个侧面为平面,另一个为斜面,斜面倾角为3°。利用此棱镜对LD输出光束进行变换,可得到7mm×7mm的正方形光斑,光强起伏小于5%,在此范围内的光能量占总辐射能量77%。     

基于V型腔增强吸收光谱技术的一氧化碳检测研究

论文基于光反馈原理及V型增强腔技术,结合量子串级激光器,搭建了CO吸收光谱检测系统.研究并实现了光反馈效应(反馈相位自动可调)、偶数和奇数腔模式效应、激光器阈值电流降低效应.系统有效反射率达到99.979%,在物理长度为47 cm的光腔内实现了4.48 km有效吸收路径.通过自动调节V型腔长,使光谱分辨率从0.005 3 cm~(-1)提高到0.001 1 cm~(-1).通过阿伦方差分析,确定了最高信噪比的积分时间为53 s.气体压强40 torr,温度20°C时,系统对CO(R(6)吸收线)检测准确度及检测极限分别达到(97.79±0.07)%和(0.49±0.04)ppb.也分析和证明了气体压强对CO的峰值吸收强度、检测准确度及检测极限的影响.     

Multifunctional π-conjugated poly (3-methylthiophene) nanotubes for optoelectronic and field emissive devices

Multifunctional properties of nanomaterials becomes a hot topic in nano research for the development of multifunctional devices, because modern devices need multifunctional platform for the high efficient plural performance on a single device. Here, we introduce a multifunctional π-conjugated poly (3-methylthiophene) (P3MT) nanotube (NT), showing controllable optical and electrical properties through the control of doping level. P3MT NTs were electrochemically synthesized in the low temperature (−40 °C) on the nanoporous template. The change of doping level by post cyclic voltammetry (CV) treatment on the P3MT lead the variance of polaron/bipolaron band, resulting into the drastic change of ultraviolet-visible absorption and photoluminescence properties. While P3MT NTs before CV treatment show an ohmic behavior in the current-voltage characteristics, those after CV treatment show high photocurrent. From the field emission experiment, the P3MT NTs before CV treatment have a relatively low turn-on electric field and stable electron emission property compared to the P3MT NTs after CV treatment. This shows that the π-conjugated polymers should be shed new light on their multifunctionality for the potential application to the multifunctional platform of opto-electronic nanodevices.     

Influence of laser wavelength instability, polarization fading and phase fluctuation on local heterodyne detection wavelength scanning BOTDR

In this paper, the influence of laser wavelength instability, polarization fading and phase fluctuation on local heterodyne detection wavelength scanning Brillouin optical time domain reflectometer (WS-BOTDR) is theoretically analyzed, and a local heterodyne detection WS-BOTDR system is built for experimental verification. The experimental results show that with the increase of sensing distance, the adverse effect of laser wavelength instability, polarization fading and phase fluctuation on local heterodyne detection WS-BOTDR is gradually aggravated, which will lead to the broadening and distortion of the wavelength power spectrum (WPS), resulting in large errors in demodulated Brillouin central wavelength (BCW) and temperature. The average temperature measurement errors at the positions of 1 km, 5 km, 9 km non-heating section and 9.45 km heating section are 1.76 °C, 3.42 °C, 3.89° C and 4.3 °C, respectively.     

A high-precision system of fiber Bragg grating temperature sensing demodulation based on light power detection

A system of fiber Bragg grating (FBG) temperature sensing demodulation based on light power detection is proposed in this paper. Compared with the traditional demodulation method based on wavelength scanning, light power detection is more direct and avoids the use of spectrometer. Moreover, the light power in the system is converted into the electrical signal by the receiver optical subassembly (ROSA) and converted to the digital signal. The micro controller unit (MCU) processes the digital signal to realize the real-time temperature monitoring, which avoids the use of optical power meter (OPM). With the advantages of simple structure and low cost, the system is portable and practical. The experimental results show that the linearity coefficients R-square between light power and the sampling voltage are 0.999 08 and 0.998 93 in the temperature range from 10 °C to 85 °C, respectively. According to the results, the proved sensor has a repeatability error of 1%, a linearity error of 1.35%, and a hysteresis error of 0.7%, which indicates that the system is of high stability and high precision. The experimental results are consistent with the theory, which verifies the system''s feasibility.     

High-power laser diodes based on asymmetric separate-confinement heterostructures

Asymmetric separate-confinement laser heterostructures with ultrawide waveguides based on AlGaAs/GaAs/InGaAs solid solutions, with an emission wavelength of ～1080 nm, are grown by MOCVD. The optical and electrical properties of mesa-stripe lasers with a stripe width of ～100 μm are studied. Lasers based on asymmetric heterostructures with ultrawide (>1 μm) waveguides demonstrate lasing in the fundamental transverse mode with an internal optical loss of as low as 0.34 cm^?1. In laser diodes with a cavity length of more than 3 mm, the thermal resistance is reduced to 2°C/W, and the characteristic temperature T ₀= 10°C is obtained in the range 0–100°C. A record-breaking wallplug efficiency of 74% and an output optical power of 16 W are reached in CW mode. Mean-time-between-failures testing for 1000 h at 65°C with an operation power of 3–4 W results in the power decreasing by 3–7%.     

Synthesis and electrocatalytic properties of manganese dioxide for non-enzymatic hydrogen peroxide sensing

Manganese dioxide nanoparticles were synthesized by chemical reduction route at different growth temperatures of 40 °C, 80 °C, 100 °C and were characterized using X-ray Diffraction (XRD), Field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), Cyclic Voltammetry (CV) and chronoamperometry (CA) analysis. FESEM results show that on increasing growth temperature the morphology changes from clusters into mixture of rods and flakes. XPS analysis reveals the formation of MnO₂. Then these particles were immobilized on Pt electrode. A platinum (Pt) electrode modified with low dimensional MnO₂ was investigated as a chronoamperometric (CA) sensor for hydrogen peroxide sensing (H₂O₂). The sample prepared at 100 °C shows good electrocatalytic ability for H₂O₂ sensing when compared with the samples prepared at 40 °C and 80 °C. At an operating potential of 0.3 V vs. Ag/AgCl catalytic oxidation of the analyte is measured for chronoamperometric (CA) monitoring. The CA signals are linearly proportional to the concentration of H₂O₂. It is also found that the morphology of the nanostructure plays a vital role in the detection of H₂O₂.     

大面阵高分辨率三变倍双远心光学设计

针对芯片在塑封工艺中的表面缺陷检测,设计一款大面阵高分辨率三变倍双远心光学系统。通过远心理想模型分析和像差优化,得到一款大视场、高精度、可变倍、低畸变的双远心光学系统。该系统采用6500W像素的大面阵工业相机,由13片球形透镜组成,工作波长在可见光范围内,F数为7,放大倍率为-0305x、-0427x和-0500x,系统总长小于362mm。设计结果表明,不同倍率下的全视场调制传递函数在奈奎斯特频率156 lp/mm处都大于01,最大畸变不超过02,物方远心度小于02°,该光学系统成像质量良好,在工业表面缺陷检测光学设计领域有着一定的参考价值。     

Real-time optical techniques and QMS to characterize growth in a modified commercial OMVPE reactor

We describe a modified commercial OMVPE reactor that incorporates quadrupole mass spectrometry (QMS) with a broadband parallel-processing optical spectrometer that simultaneously performs spectroscopic ellipsometry (SE) and reflectance-difference spectroscopy (RDS) measurements. We demonstrate its use by determining the surface temperature of Si to a precision of ±1°C and investigating the initial stages of GaP heteroepitaxy on Si(100). Analysis of the real-time SE data indicates that under our conditions GaP and Si interpenetrate as optically identifiable materials on a thickness scale of 100Å.