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1.
Effect of Dislocations on VLWIR HgCdTe Photodiodes 总被引:5,自引:0,他引:5
T. Parodos E.A. Fitzgerald A. Caster S. Tobin J. Marciniec J. Welsch A. Hairston P. Lamarre J. Riendeau B. Woodward S. Hu M. Reine P. Lovecchio 《Journal of Electronic Materials》2007,36(8):1068-1076
The effects of dislocations on very-long-wavelength infrared (VLWIR) HgCdTe photodiodes (cutoff wavelength >14 μm at 40 K) have been determined experimentally and analyzed. The photodiodes are in the back-illuminated configuration, fabricated from HgCdTe p-on-n double-layer heterostructure (DLHJ) films grown at BAE Systems by liquid phase epitaxy (LPE) onto lattice-matched (111) CdZnTe substrates. Arrays were hybridized to silicon ROICs to form focal plane arrays (FPAs). After characterization for dark current and response, the arrays were dehybridized and stripped of their metals and passivation layers. Dislocations were revealed using a Hähnert and Schenk (H&;S) etch. Pixel traceability was maintained throughout the analysis, permitting one-to-one correlation between photodiode performance and dislocation density measured within that photodiode. We found that response and dark current were correlated to etch pit density (EPD), which we assumed to be equal to dislocation density. Our results support earlier dislocation studies on larger-bandgap HgCdTe, which showed response was only weakly impacted by EPD, while dark current was strongly affected by EPD. Measured EPD values ranged from low 105 to low 107 cm?2. Potential causes for this range in EPD are discussed. 相似文献
2.
H. Nishino S. Murakami T. Saito Y. Nishijima H. Takigawa 《Journal of Electronic Materials》1995,24(5):533-537
We studied dislocation etch pit density (EPD) profiles in HgCdTe(lOO) layers grown on GaAs(lOO) by metalorganic chemical vapor
deposition. Dislocation profiles in HgCdTe(lll)B and HgCdTe(lOO) layers differ as follows: Misfit dislocations in HgCdTe(lll)B
layers are concentrated near the HgCdTe/CdTe interfaces because of slip planes parallel to the interfaces. Away from the HgCdTe/CdTe
interface, the HgCdTe(111)B dislocation density remains almost constant. In HgCdTe(lOO) layers, however, the dislocations
propagate monotonically to the surface and the dislocation density decreases gradually as dislocations are incorporated with
increasing HgCdTe(lOO) layer thicknesses. The dislocation reduction was small in HgCdTe(lOO) layers more than 10 μm from the
HgCdTe/CdTe interface. The CdTe(lOO) buffer thickness and dislocation density were similarly related. Since dislocations glide
to accommodate the lattice distortion and this movement increases the probability of dislocation incorporation, incorporation
proceeds in limited regions from each interface where the lattice distortion and strain are sufficient. We obtained the minimum
EPD in HgCdTe(100) of 1 to 3 x 106 cm-2 by growing both the epitaxial layers more than 8 μm thick. 相似文献
3.
G. M. Williams R. E. De Wames J. Bajaj E. R. Blazejewski 《Journal of Electronic Materials》1993,22(8):931-941
We have investigated the properties of excess low frequency noise in illuminated mid wavelength infrared and long wavelength
infrared HgCdTe photodiodes at zero bias. The current power spectrum (Si) dependence is usually close to inverse frequency (f), but substantial variations have been observed. The magnitude of l/f
spectra is voltage independent for small bias voltages, but is proportional to the square of the photocurrent (I). Consequently,
the l/f knee increases, with photocurrent. Variable area device studies indicate that the noise sources are more closely associated
with the device area (Aj) than perimeter, indicating bulk limitations. The power spectrum can be represented by an empirical relationship of the form
Si=αphI
2/fAj. This defines a figure of merit, αph which takes into the account the relationship between current dependence and device geometry. αph is device dependent, suggesting that randomly distributed defects play a role in the difference. This is also supported by
noting that devices fabricated in material grown on lattice matched substrates have lower αph (10−16 cm2) than those fabricated in material grown on nonlattice matched substrates (10−14 cm2), which usually have two orders of magnitude larger dislocation density. We conclude that photo-induced l/f noise can be
reduced via defect reduction and is not fundamental. Data on our best devices indicates that αph is somewhat lower for smaller band gap material. The temperature dependence of photo-induced excess low frequency noise is
much weaker than that of bias induced excess low frequency noise, indicating unrelated generation mechanisms. In addition,
photo-induced l/f adds in quadrature with bias induced l/f noise and is not well correlated in magnitude with either bias
induced l/f noise or detector dark currents. 相似文献
4.
1/f noise in HgCdTe photodiodes has been attributed to a variety of sources, most of which are associated with some form of
excess current. At DRS, we have measured the 1/f noise in vertically integrated (VIP) and high-density vertically integrated
photodiodes (HDVIP), over a wide range of compositions and temperature, for strictly well-behaved diffusion current limited
operation. It is found that (1) the 1/f noise current is directly dependent on dark current density; (2) material composition
and temperature are irrelevant, except in as much as they determine the magnitude of the current density; (3) in high-quality
diodes, the 1/f noise is independent of background flux; and (4) surface passivation is relevant. These observations have
been compared to the 1/f noise theory of Schiebel, which uses McWhorter’s fluctuation of the surface charge tunneling model
to modulate diode diffusion current. Agreement is obtained with Schiebel’s theory for realistic surface trap densities in
the 1012/cm2 range, which will obviously be characteristic of the passivation used. The relevance of this work relative to high operating
temperature phtodiodes is discussed. 相似文献
5.
A. I. D’Souza J. Bajaj R. E. De Wames D. D. Edwall P. S. Wijewarnasuriya N. Nayar 《Journal of Electronic Materials》1998,27(6):727-732
Mid wavelength infrared p-on-n double layer planar heterostructure (DLPH) photodiodes have been fabricated in HgCdTe double
layers grown in situ by liquid phase epitaxy (LPE), on CdZnTe and for the first time on CdTe/sapphire (PACE-1). Characterization of these devices
shed light on the nature of the material limits on device performance for devices performing near theoretical limits. LPE
double layers on CdZnTe and on PACE-1 substrates were grown in a horizontal slider furnace. All the photodiodes are p-on-n
heterostructures with indium as the n-type dopant and arsenic the p-type dopant. Incorporation of arsenic is via implantation
followed by an annealing step that was the same for all the devices fabricated. The devices are passivated with MBE CdTe.
Photodiodes have been characterized as a function of temperature. R0Aimp values obtained between 300 and 78K are comparable for the two substrates and are approximately a factor of five below theoretical
values calculated from measured material parameters. The data, for the PACE-1 substrate, indicates diffusion limited performance
down to 110K. Area dependence gives further indications as to the origin of diffusion currents. Comparable R0Aimp for various diode sizes indicates a p-side origin. R0A and optical characteristics for the photodiodes grown on lattice-matched CdZnTe substrates and lattice mismatched PACE-1
are comparable. Howover, differences were observed in the noise characteristics of the photodiodes. Noise was measured on
50 × 50 μm devices held under a 100 mV reverse bias. At 110K, noise spectrum for devices from the two substrates is in the
low 10−15 A/Hz1/2 range. This value reflects the Johnson noise of the room temperature 1010 Ω feedback resistor in the current amplifier that limits the minimum measurable noise. Noise at 1 Hz, −100 mV and 120K for
the 4.95 μm PACE-1 devices is in the 1–2 × 10−14 A/Hz1/2, a factor of 5–10 lower than previously grown typical PACE-1 n+-on-p layers. Noise at 120K for the 4.60 μm PACE-1 and LPE on CdZnTe was again below the measurement technique limit. Greatest
distinction in the noise characteristics for the different substrates was observed at 163K. No excess low frequency noise
was observed for devices fabricated on layers grown by LPE on lattice-matched CdZnTe substrates. Photodiode noise measured
at 1Hz, −100 mV and 163K in the 4.60 μm PACE-1 layer is in the 1–2×10−13 A/Hz1/2, again a factor of 5–10 lower than previously grown PACE-1 n+-on-p layers. More variation in noise (4×10−13−2×10−12 A/Hz1/2) was observed for devices in the 4.95 μm PACE-1 layer. DLPH devices fabricated in HgCdTe layers grown by LPE on lattice-matched
CdZnTe and on lattice-mismatched PACE-1 have comparable R0A and quantum efficiency values. The distinguishing feature is that the noise is greater for devices fabricated in the layer
grown on lattice mismatched substrates, suggesting dislocations inherent in lattice mismatched material affects excess low
frequency noise but not zero bias impedance. 相似文献
6.
C. A. Musca J. Antoszewski J. M. Dell L. Faraone S. Terterian 《Journal of Electronic Materials》2003,32(7):622-626
Planar p-on-n HgCdTe heterojunction photodiodes have been fabricated using a plasma-induced type conversion process for device
junction isolation. The technique is presented as a fully planar alternative technology to the commonly used mesa isolation
structure. The starting material consisted of an indium-doped n-type mid-wavelength infrared (MWIR) HgCdTe absorbing layer
that was capped by a 1-μm-thick wider bandgap arsenic-doped p-type layer. Junction-isolated p-on-n diodes were formed by selectively
p-to-n type converting the p-type cap layer using a plasma process. Photodiode dark current-voltage measurements were performed
as a function of temperature, along with noise and responsivity. The devices have cut-off wavelengths between 4.8 μm and 5.0
μm, exhibit diffusion-limited dark currents down to 145 K, give R0A values greater than 1 × 107Ω·cm2 at 80 K and greater than 1 × 105Ω·cm2 at 120 K, and have negligible 1/f noise current at zero applied bias. 相似文献
7.
Heteroepitaxy of HgCdTe(112) infrared detector structures on Si(112) substrates by molecular-beam epitaxy 总被引:4,自引:0,他引:4
T. J. De Lyon R. D. Rajavel J. E. Jensen O. K. Wu S. M. Johnson C. A. Cockrum G. M. Venzor 《Journal of Electronic Materials》1996,25(8):1341-1346
High-quality, single-crystal epitaxial films of CdTe(112)B and HgCdTe(112)B have been grown directly on Si(112) substrates
without the need for GaAs interfacial layers. The CdTe and HgCdTe films have been characterized with optical microscopy, x-ray
diffraction, wet chemical defect etching, and secondary ion mass spectrometry. HgCdTe/Si infrared detectors have also been
fabricated and tested. The CdTe(112)B films are highly specular, twin-free, and have x-ray rocking curves as narrow as 72
arc-sec and near-surface etch pit density (EPD) of 2 × 106 cm−2 for 8 μm thick films. HgCdTe(112)B films deposited on Si substrates have x-ray rocking curve FWHM as low as 76 arc-sec and
EPD of 3-22 × 106 cm−2. These MBE-grown epitaxial structures have been used to fabricate the first high-performance HgCdTe IR detectors grown directly
on Si without use of an intermediate GaAs buffer layer. HgCdTe/Si infrared detectors have been fabricated with 40% quantum
efficiency and R0A = 1.64 × 104 Ωm2 (0 FOV) for devices with 7.8 μm cutoff wavelength at 78Kto demonstrate the capability of MBE for growth of large-area HgCdTe
arrays on Si. 相似文献
8.
Min Yung Lee Young Ho Kim Nam Ho Lee Yong Soo Lee Hee Chul Lee 《Journal of Electronic Materials》2006,35(6):1429-1433
In this study, we investigated the effects of gamma radiation on ZnS/CdTe-passivated HgCdTe photodiodes that were fabricated
with one of two different surface treatments using bromine, Br2, or hydrazine, N2H4. Unlike the ZnS-passivated HgCdTe photodiodes, the ZnS/CdTe-passivated HgCdTe photodiodes showed no degradation in resistance-area
product at zero bias (R0A) values after gamma irradiation of up to 1 Mrad. However, there is a significant difference between the bromine- and hydrazine-treated
samples. Regardless of the dose of gamma radiation, there was little change in the forward current characteristics of the
hydrazine-treated diode in comparison with the conventional bromine-treated diode. The hydrazine-treated diode showed fairly
uniform R0A values of >107 Ω-cm2 up to 1 Mrad of gamma irradiation, whereas the bromine-treated diode showed an abrupt change in R0A values from ∼106 Ω-cm2 to ∼107 Ω-cm2 after gamma irradiation. Therefore, for use in a gamma radiation environment, the best combination for high-performance HgCdTe
photodiodes is a ZnS/CdTe passivant that has been treated with hydrazine. 相似文献
9.
Sensitivities on 0.1 eV HgCdTe photoconductors with new electrode configuration and in different sizes were measured at 77K and under 1014phcm?2s?1 photon background conditions. After data for responsivity, generation-recombination noise (g-r noise) and minority carrier lifetime were reproduced by solving a one dimensional diffusion equation on excess minority carrier, discussions on 1/f noise were made and the following characteristics were concluded: (1) 1/f noise does not originate near electrodes for bias current. (2) 1/f noise hardly depends on sensor size and temperature in the 77–95K range, while g-r noise does. (3) 1/f noise is proportional to bias electric field, i.e. current density. (4) 1/f noise does not depend on photon background. From characteristics (2) and (4), it was concluded that 1/f noise has nothing to do with g-r noise. Finally, a new empirical formula was proposed for 1/f noise. 相似文献
10.
P. Mitra F. C. Case M. B. Reine T. Parodos S. P. Tobin P. W. Norton 《Journal of Electronic Materials》1999,28(6):589-595
New results are reported on the growth of high performance medium wavelength infrared (3–5 μm) (MWIR) HgCdTe photodiodes in
the three-layer P-n-N configuration. The detector structures were grown in situ by metalorganic vapor phase epitaxy (MOVPE) on (211)B oriented CdZnTe substrates. The mobilities of the single n-type layers
with x-values of ∼0.30 are in the range of (3–4.5)×104 cm2/V-s at 80K. The lifetimes on unpassivated films range from 1–5 and 4–10 μs at 80 and 180K, respectively, which are within
a factor of two or less of the lifetimes calculated for Auger-1 and radiative recombination. The P-n-N films were processed
into variable-area backside-illuminated diagnostic arrays and tested for quantum efficiency, spectral response, RDA, I–V curves and 1/f noise in the 120–180K range. The internal one-dimensional quantum efficiencies are in the range of 85–100%.
The optical collection lengths are typically ∼25 μm. I–V curves showed that diffusion current is the dominant junction current
mechanism for temperatures ≥100K. R0A values are at the one-dimensional limit for n-side diffusion currents over the 100–180K range. 1/f noise was measured to
be very low at 120K and is the same as that measured in similarly processed arrays from recent LPE grown P-on-N heterojunctions.
The results demonstrate that MOVPE growth can be used for large area, high performance MWIR HgCdTe detector arrays operating
in the 120–180K temperature range. 相似文献
11.
G. Brill S. Farrell Y. P. Chen P. S. Wijewarnasuriya Mulpuri V. Rao J. D. Benson N. Dhar 《Journal of Electronic Materials》2010,39(7):967-973
Current growth methods of HgCdTe/Cd(Se)Te/Si by molecular-beam epitaxy (MBE) result in a dislocation density of mid 106 cm−2 to low 107 cm−2. Although the exact mechanism is unknown, it is well accepted that this high level of dislocation density leads to poorer
long-wavelength infrared (LWIR) focal-plane array (FPA) performance, especially in terms of operability. We have conducted
a detailed study of ex situ cycle annealing of HgCdTe/Cd(Se)Te/Si material in order to reduce the total number of dislocations present in as-grown material.
We have successfully and consistently shown a reduction of one half to one full order of magnitude in the number of dislocations
as counted by etch pit density (EPD) methods. Additionally, we have observed a corresponding decrease in x-ray full-width
at half-maximum (FWHM) of ex situ annealed HgCdTe/Si layers. Among all parameters studied, the total number of annealing cycles seems to have the greatest
impact on dislocation reduction. Currently, we have obtained numerous HgCdTe/Si layers which have EPD values measuring ~1 × 106 cm−2 after completion of thermal cycle annealing. Preliminary Hall measurements indicate that electrical characteristics of the
material can be maintained. 相似文献
12.
13.
Yu-Zung Chiou Yan-Kuin Su Shoou-Jinn Chang Jeng Gong Yi-Chao Lin Sen-Hai Liu Chia-Sheng Chang 《Quantum Electronics, IEEE Journal of》2003,39(5):681-685
InGaN-GaN multiquantum well (MQW) p-n junction photodiodes with semi-transparent Ni-Au electrodes were fabricated and characterized. It was found that the fabricated InGaN-GaN p-n junction photodiodes exhibit a 20-V breakdown voltage and a photocurrent to dark current contrast ratio of /spl sim/10/sup 5/ when a 0.4-V reverse bias was applied. The peak responsivity at 380 nm was 1.28 and 1.76 A/W with a 0.1- and 3-V applied reverse bias, respectively. Furthermore, an internal gain was found from our InGaN-GaN MQW p-n junction photodiodes possibly due to the long-lifetime of GaN based materials. Also, it was found that the low frequency noise of our photodiodes was dominated by the 1/f type noise. For a given bandwidth of 500 Hz, the corresponding noise equivalent power and normalized detectivity D/sup */ were found to be 6.34/spl times/10/sup -13/ W and 4.45/spl times/10/sup 11/ cm/spl middot/Hz/sup 0.5/ W/sup -1/, respectively. 相似文献
14.
C. T. Elliott N. T. Gordon R. S. Hall T. J. Phillips C. L. Jones A. Best 《Journal of Electronic Materials》1997,26(6):643-648
We have studied the 1/f noise current in narrow gap semiconductor heterostructure diodes fabricated in mercury cadmium telluride
(HgCdTe) and designed to operate in a non-equilibrium mode at room temperature. HgCdTe heterostructure diodes exhibit Auger
suppression giving current-voltage characteristics with high peak-to-valley ratios (up to 35), and low extracted saturation
current densities (e.g., 20 Acnr−2 at 10 pm at 295K) but high 1/f knee frequencies (e.g., 100 MHz at 10 μm at 295K). A comparison is made with the noise levels
found in room temperature non-equilibrium mode heterostructure InAlSb/InSb diodes. The devices are being used at high frequencies
for CO2 laser heterodyne detector demonstrators. For the devices to be useful in low frame-rate imaging arrays, the 1/f noise level
must be sufficiently low that the signal is not swamped. Ideally, the knee frequency should be below the frame rate. The relationship
between the noise current and reverse bias voltage, current density, and temperature will be examined in order to attempt
to identify the principal 1/f generation mechanisms. 相似文献
15.
Analysis of 1/f noise in LWIR HgCdTe photodiodes 总被引:2,自引:0,他引:2
Soo Ho Bae Sang Jun Lee Young Ho Kim Hee Chul Lee Choong Ki Kim 《Journal of Electronic Materials》2000,29(6):877-882
We study the 1/f noise currents and dark currents in LWIR HgCdTe photodiodes. The measured dark currents of the diodes processed
by post implantation annealing with different annealing times are analyzed using current model fitting methods. The different
dark current components, such as diffusion current, generation-recombination current, band-to-band tunneling current, and
trap assisted tunneling current, at various bias voltages can be separated from the measured dark currents. By the fitting
analysis, some physical parameters are extracted and different annealing effects can be explained by the parameters. The improvements
in diode characteristics by post implantation annealing can be explained by the changes of trap density, donor concentration,
minority carrier lifetime, and generation lifetime. The 1/f noise currents are measured over a wide range of reverse bias
voltages, and correlated with the extracted dark currents by superposition of the noise generated by the different dark current
mechanisms. It turns out that the band-to-band tunneling has a smaller correlation with the 1/f noise than other current components,
and the trap center seems to be responsible for the 1/f noise characteristics of the LWIR HgCdTe photodiodes. 相似文献
16.
Effect of dislocations on performance of LWIR HgCdTe photodiodes 总被引:2,自引:0,他引:2
The epitaxial growth of HgCdTe on alternative substrates has emerged as an enabling technology for the fabrication of large-area
infrared (IR) focal plane arrays (FPAs). One key technical issue is high dislocation densities in HgCdTe epilayers grown on
alternative substrates. This is particularly important with regards to the growth of HgCdTe on heteroepitaxial Si-based substrates,
which have a higher dislocation density than the bulk CdZnTe substrates typically used for epitaxial HgCdTe material growth.
In the paper a simple model of dislocations as cylindrical regions confined by surfaces with definite surface recombination
is proposed. Both radius of dislocations and its surface recombination velocity are determined by comparison of theoretical
predictions with carrier lifetime experimental data described by other authors. It is observed that the carrier lifetime depends
strongly on recombination velocity; whereas the dependence of the carrier lifetime on dislocation core radius is weaker. The
minority carrier lifetime is approximately inversely proportional to the dislocation density for densities higher than 105 cm−2. Below this value, the minority carrier lifetime does not change with dislocation density. The influence of dislocation density
on the R0A product of long wavelength infrared (LWIR) HgCdTe photodiodes is also discussed. It is also shown that parameters of dislocations
have a strong effect on the R0A product at temperature around 77 K in the range of dislocation density above 106 cm−2. The quantum efficiency is not a strong function of dislocation density. 相似文献
17.
R.J. Westerhout C.A. Musca J. Antoszewski J.M. Dell L. Faraone 《Journal of Electronic Materials》2007,36(8):884-889
In this work, gated midwave infrared (MWIR) Hg1–x
Cd
x
Te photodiodes are used to investigate the physical origin of 1/f noise generation. Gated photodiodes were fabricated on liquid-phase epitaxy p-type HgCdTe MWIR material with a vacancy-doped concentration of 1.6 × 1016 cm−3 and x = 0.31. CdTe was thermally deposited and used as both a passivant and a mask for the plasma-based type conversion, and ZnS
was used as an insulator. Fabricated devices show a R
0
A of 1–5 × 104 Ωcm2 with zero gate bias. Application of 2 V to the gate improves the R
0
A by more than two orders of magnitude to 6.0 × 106 Ωcm2, which corresponds to the p-type surface being at transition between depletion and weak inversion. Trap-assisted tunneling (TAT) current was observed
at negative gate biases and reverse junction biases. For gate biases greater than 3 V, a field-induced junction breakdown
was observed. An I
n
= α
I
β
f
−0.5 trend was observed above 200 pA reverse bias dark current, with α = 3.5 × 10−5 and β = 0.82, which corresponds to the TAT dominated region. Below 200 pA, junction generation-recombination (GR) current starts
to dominate and this previously mentioned trend is no longer observed. Junction GR current was not seen to be correlated with
1/f noise in these photodiodes. 相似文献
18.
Heinrich Figgemeier Martin Bruder Karl-Martin Mahlein Richard Wollrab Johann Ziegler 《Journal of Electronic Materials》2003,32(7):588-591
HgCdTe detector performance and yield are strongly dependant on CdZnTe substrate and HgCdTe epilayer properties, and on key
device processes, especially for 8–12 μm application. Due to the correlation and optimization between these figures and diode
performance, AIM has developed a mature HgCdTe technology for superior detector performance and high production rate. To meet
high yield and performance for long wavelength (LW) HgCdTe diodes, dislocation densities of < 1 × 10t cm−2 both in substrate and epilayer have to be ensured. By a unique AIM substrate growth process, dislocation densities of 2 ×
104-9 × 104 cm−2 are achieved for all substrates and epilayers (100% yield). The etch pit density (EPD) on 〈111〉 epilayers is revealed by
an AIM proprietary etching procedure. One critical effect is the dislocations in the diode area, which can originate from
the substrate and epilayer growth and the subsequent device processes, respectively. Our studies have shown that device processes
can cause additional dislocations in the diode area.
Diode yield was clearly improved by a combination of wet and dry etching for diode contact etching. 相似文献
19.
P. Mitra F. C. Case H. L. Glass V. M. Speziale J. P. Flint S. P. Tobin P. W. Norton 《Journal of Electronic Materials》2001,30(6):779-784
We report the growth of HgCdTe on (552)B CdZnTe by metalorganic vapor phase epitaxy (MOVPE). The (552) plane is obtained by
180 rotation of the (211) plane about the [111] twist axis. Both are 19.47 degrees from (111), but in opposite directions.
HgCdTe grown on the (552)B-oriented CdZnTe has a growth rate similar to the (211)B, but the surface morphology is very different.
The (552)B films exhibit no void defects, but do exhibit ∼40 μm size hillocks at densities of 10–50 cm−2. The hillocks, however, are significantly flatter and shorter than those observed on (100) metalorganic vapor phase epitaxy
(MOVPE) HgCdTe films. For a 12–14 μm thick film the height of the highest point on the hillock is less than 0.75 μm. No twinning
was observed by back-reflection Laue x-ray diffraction for (552)B HgCdTe films and the x-ray double crystal rocking curve
widths are comparable to those obtained on (211)B films grown side-by-side and with similar alloy composition. Etch pit density
(EPD) measurements show EPD values in the range of (0.6–5)×105 cm−2, again very similar to those currently observed in (211)B MOVPE HgCdTe. The transport properties and ease of dopant incorporation
and activation are all comparable to those obtained in (211)B HgCdTe. Mid-wave infrared (MWIR) photodiode detector arrays
were fabricated on (552)B HgCdTe films grown in the P-n-N device configuration (upper case denotes layers with wider bandgaps).
Radiometric characterization at T=120–160 K show that the detectors have classical spectral response with a cutoff wavelength
of 5.22 μm at 120 K, quantum efficiency ∼78%, and diffusion current is the dominant dark current mechanism near zero bias
voltage. Overall, the results suggest that (552)B may be the preferred orientation for MOVPE growth of HgCdTe on CdZnTe to
achieve improved operability in focal plane arrays. 相似文献
20.
M. Martinka L. A. Almeida J. D. Benson J. H. Dinan 《Journal of Electronic Materials》2002,31(7):732-737
Because the performance of HgCdTe-based photodiodes can be significantly degraded by the presence of dislocations, we have
systematically investigated and suppressed lattice-mismatch-induced cross-hatch formation and the associated generation of
dislocations in (211)B HgCdTe/CdZnTe. A series of HgCdTe epilayers were deposited simultaneously on pairs of substrates with
differing ZnTe mole fractions. Epilayers’ CdTe mole fraction and substrates’ ZnTe mole fractions were measured using optical-transmission
spectra. Lattice mismatch and residual strain were estimated from room-temperature, x-ray diffraction, and double-crystal
rocking-curve measurements (DCRC). It was found that cross-hatch patterns were suppressed in epilayers deposited on nearly
lattice-matched substrates (|Δa/asub|<0.02%). Such epilayers exhibited excellent crystalline quality as revealed by defect-decoration etching (etch-pit density
(EPD)<105 cm−2) and x-ray diffraction (full-width at half-maximum (FWHM) ∼10 arcsec). In addition to determining the upper limits of lattice
mismatch needed to eliminate cross-hatch, we investigated the use of reticulated substrates as a means to suppress cross-hatch.
We found that growth on reticulated mesa structures (<100 μm) with edges parallel to [01-1] resulted in epilayers with substantially
reduced cross-hatch-line densities despite large lattice mismatch (Δa/asub <0.04%). The use of reticulated substrates could suppress cross-hatch because of lateral-alloy variation in large substrates
and complex multistack epilayers (e.g., multicolor detectors). 相似文献